Poly[[μ-1,3-bis­(pyridin-3-yl)urea]bis­(μ₄-succinato)dicopper(II)], a ribbon-like coordination polymer

A divalent copper one-dimensional ribbon copper(II) coordination polymer, with 1,3-bis­(pyridin-3-yl)urea and succinate ligands, was structurally characterized by single-crystal X-ray diffraction.

Poly[[(μ₃-adamantane-1,3-di­carboxyl­ato)aqua­[μ-N-(pyridin-3-yl)isonicotinamide]­nickel(II)] monohydrate], a layered coordination polymer with (4,4) topology

The title com­pound contains octa­hedrally coordinated Ni^II ions ligated by adamantane-1,3-di­carboxyl­ate and N-(pyridin-3-yl)isonicotinamide ligands forming coordination polymer layers with a (4,4) grid topology.

catena-Poly[[di­aqua­bis­(1,3-di­hydro-3-oxo­isobenzo­furan-1-acetato)­copper(II)]-μ-N,N′-(ethane-1,2-di­yl)dinicotinamide]

In situ lactonization of 2-carb­oxy­cinnamic acid to form bis­(1,3-di­hydro-3-oxo-1-isobenzo­furan­acetate (dibf) resulted in the the crystallization of [Cu(dibf)(edn)(H₂O)₂]_n coordination polymer chains [edn = N,N′-(ethane-1,2-di­yl)dinicotinamide].

Bis­(di­meth­oxy­ethane-1κ²O,O′)penta­kis­(1,1,1,3,3,3-hexa­fluoro­propan-2-olato)-2κ³O,3κ²O-μ-hy­droxido-1:3κ²O-μ₃-oxido-1:2:3κ³O-magnesiumdialuminium

The title complex was formed as a partial hydrolysis product of [Mg(dme)₃][Al(hfip)₄]₂ (dme = di­meth­oxy­ethane and hfipH = hexa­fluoro­iso­propanol), a promising electrolyte salt for magnesium batteries.

Poly[[[μ-1,4-bis­(pyridin-4-ylcarbon­yl)piperazine-κ²N:N′][μ-2-(2-carboxyl­atoeth-1-en-1-yl)benzoato-κ²O:O²]zinc(II)] 2.5 hydrate]: a tri-periodic coordination polymer with a dimer-based six-connected pcu topology

The title compound contains five-coordinate Zn^II ions inter­mediate between square-pyramidal and trigonal–bipyramidal coordination geometries. The Zn^II ions are connected by 2-carb­oxy­cinnamate (cca) ligands and N,N′-bis-(pyridine-4-carboxamido)­piperazine (4-pcap) ligands to construct a non-inter­penetrated, tri-periodic coordination polymer with embedded [Zn₂(OCO)₂] dimeric units. Treating these as six-connected nodes reveals an overall (4¹²6³) pcu topology.

Poly[di­aqua­[μ-1,4-bis­(pyridin-4-ylmeth­yl)pip­era­zine][μ-4-(carboxyl­atoeth­yl)benzoato]nickel(II)]

The divalent nickel compound {[Ni(ceb)(bpmp)(H₂O)₂]_n, (ceb is (4-(carb­oxy­eth­yl)benzoate; bpmp is 1,4-bis­(pyridin-4-ylmeth­yl)piperazine) crystallizes as a fivefold inter­penetrated tri-periodic coordination polymer without co-crystallized species.

Tetra­kis(μ-acetato-κ²O:O′)bis­[(tetra­hydro­furan-κO)chromium(II)]

Centrosymmetric [Cr₂(OAc)₄(THF)₂] consists of two Cr^II atoms that are bridged by four acetate ions to yield a typical paddle-wheel structure. Furthermore, each chromium atom bears an axially bound THF ligand to give a square-pyramidal coordination.

Poly[[μ-1,3-bis­(pyridin-3-yl)urea]bis­(μ₄-glutarato)dicopper(II)]

A divalent copper tri-periodic coordination polymer with no co-crystallized species and underlying pcu topology, {[Cu₂(glu)₂(3-dpu)]_n, was prepared and structurally characterized by single-crystal X-ray diffraction.

(3¹E,3²Z,7¹E,7²Z)-4,8-Bis(3,5-di­chloro­phen­yl)-1⁴,3³,5³,7³-tetra­propyl-1¹H,3²H,5¹H,7²H-1,5(2,5),3,7(5,2)-tetra­pyrrola-2,6(2,5)-di­thiophena­cyclo­octa­phane

In the title compound, [24]di­thia­amethyrin(1.0.0.1.0.0); C₅₀H₄₄Cl₄N₄S₂, the macrocycle can be described as a highly planar structure with a mean-plane deviation (MPD) value of 0.0416 Å. The mol­ecular conformation is stabilized by two intra­molecular N—H⋯N inter­actions. In the crystal, mol­ecules are also linked via C—H⋯π inter­actions forming a three-dimensional network.

N,N′-[1,4-Phenyl­enebis(imino­carbon­yl)]bis­(L-phenyl­alanine) tetra­hydro­furan disolvate

In the crystal structure of the title bis-urea derivative, the host mol­ecules are linked by N—H⋯O=C hydrogen bonds and C—H⋯O contacts with (6) and (7) ring motifs.

Bis(4-acet­oxy-N-ethyl-N-n-propyl­tryptammonium) fumarate–fumaric acid (1/1)

The structure of the synthetic psychedelic prodrug 4-hy­droxy-N-ethyl-N-n-propyl­tryptamine is reported as its salt with a fumarate dianion and a fumaric acid adduct.

(2,4-Di­chloro­benzyl­idene)[2-(1H-indol-3-yl)eth­yl]amine

The mol­ecules of the title compound are linked by N—H⋯N hydrogen bonds, generating a C(7) chain extending along the a-axis direction.

1-(Pyrrolidin-1-yl)ethan-1-iminium chloride

The title salt was serendipitously obtained while using a mixed solvent system during an S_N2 reaction between an alkyl halide and pyrrolidine.

(Z)-Benzyl 2-(5-methyl-2-oxoindolin-3-yl­idene)hydrazinecarbodi­thio­ate

The crystal structure of a new di­thio­carbazate imine, obtained from the condensation reaction of S-benzyl­dithio­carbazate and 5-methyl­isatin, is described.

1-Ethyl-4-iso­propyl-1,2,4-triazolium bromide

The title compound crystallizes with Z = 6 in space group P2₁/m.

4-Amino-3,5-di­chloro­pyridinium 3-hy­droxy­pico­linate monohydrate

The title hydrated salt features a dense array of hydrogen bonds, forming a three-dimensional network.

3-Nitro­benzo­nitrile

3-Nitro­benzo­nitrile crystallizes in the Sohncke space group P2₁.