issue contents
October 2024 issue
organic compounds
Download citation
Download citation
Open access
In the title compound, C6H10N2O2, the piperazine-2,3-dione ring adopts a half-chair conformation. In the crystal, the molecules are linked by weak C—H⋯O hydrogen bonds, forming (010) sheets.
CCDC reference: 2386002
Download citation
Download citation
Open access
Bright-yellow single crystals of the title compound were synthesized as part of a project that explores the formation of earth-abundant transition-metal complexes of amidine oxides (AMOXs), to study their photophysical and redox properties. The HNCNO moiety of the compound shows double-bond delocalization over the N—C—N part, evident from the similar C—N bond distances.
CCDC reference: 2388273
Download citation
Download citation
Open access
The crystal structure of a new S-methyl substituted dithiocarbazate imine containing the 5-methylisatin moiety is described.
CCDC reference: 2388258
Download citation
Download citation
Open access
The crystal structure of a zwitterionic unsymmetrical hydroxyformamidine methanol monosolvate is reported.
CCDC reference: 2389686
Download citation
Download citation
Open access
The crystal structure of a zwitterionic, non-symmetric hydroxyformamidine derivative is described.
CCDC reference: 2389590
Download citation
Download citation
Open access
The title compound is significantly distorted from planarity, with a twist angle between the planes through the hydroxybenzene and acetamide groups being 23.5 (2)°. This conformation is supported by intramolecular C—H⋯O and N—H⋯Cl contacts. In the crystal, N—H⋯O hydrogen-bonding contacts between acetamide groups and O—H⋯O contacts between hydroxyl groups form tapes propagating parallel to [103].
CCDC reference: 2392239
Download citation
Download citation
Open access
The crystal structure, non-bonding interactions and packing features of a novel galactose conjugated porphyrin are presented and discussed.
CCDC reference: 2388518
Download citation
Download citation
Open access
In the crystal of the title compound, the molecules are linked by N—H⋯N hydrogen bonds, generating a C(4) chain extending along the c-axis direction.
CCDC reference: 2376300
Download citation
Download citation
Open access
The title compound was prepared as a racemate of R,R- and S,S-enantiomers by reduction of the corresponding hydroxyiminoketone. In the crystal, layers are formed via hydrogen bridges of four ammonium groups to chloride ions; these lamellae are connected via interdigitated benzoic ester groups.
CCDC reference: 2393082
Download citation
Download citation
Open access
The asymmetric unit contains two complete molecules. Classical hydrogen bonds, as well as C—H⋯O contacts, connect the molecules to infinite chains along the c-axis direction.
CCDC reference: 2393641