C-type Yb₂Te₃O₉

Yb₂Te₃O₉ is isotypic with Tm₂Te₃O₉ and Lu₂Te₃O₉ and crystallizes in the C-type modification of Ln₂Te₃O₉ compounds.

Ti₄Fe₂C_0.82O_0.18

Ti₄Fe₂C_0.82O_0.18 is the first example where C and O atoms co-occupy the same site in filled Ti₂Fe structures.

Bis[2-(isoquinolin-1-yl)phenyl-κ²N,C¹](2-phenyl-1H-imidazo[4,5-f][1,10]phenanthroline-κ²N,N′)iridium(III) hexa­fluorido­phosphate methanol monosolvate

The title iridium complex is the first X-ray characterized compound including both 1-phenyl­iso­quinoline and 2-phenyl-1H-imidazo[4,5-f][1,10]phenanthroline ligands.

catena-Poly[[(8-amino­quinoline)­cobalt(II)]-di-μ-azido]

[Co(C₉H₈N₂)(N₃)₂]_n exhibits a distorted octa­hedral coordination geometry. Bridging azide ligands result in chains along [100].

μ-Chlorido-bis­{[1-benzyl-3-(2,4,6-tri­methyl­phen­yl)imidazol-2-yl­idene-κC]silver(I)} chloride 1,2-di­chloro­ethane hemisolvate

The solid-state structural analysis of the title compound reveals that the two mol­ecules of bis­(1-benzyl-3-mesitylimidazol-2-yl­idene)silver are connected via a bridging chloride atom. The structure also reveals non-classical inter­molecular hydrogen-bonding inter­actions involving the chloride counter-anion.

Δ-Bis[(S)-2-(4-iso­propyl-4,5-di­hydro­oxazol-2-yl)phenolato-κ²N,O¹](1,10-phenanthroline-κ²N,N′)ruthenium(III) hexa­fluorido­phosphate

The title compound is an example for a chiral-at-metal complex, with the Ru^III atom having an octa­hedral coordination environment by three bidentate ligands.

Di-μ-adipato-κ⁴O¹,O^1′:O⁶,O^6′-bis­[(2,2′-di­pyridyl­amine-κ²N,N′)zinc(II)] trihydrate

The title dinuclear and centrosymmetric complex mol­ecule exhibits a highly distorted octa­hedral O₄N₂ coordination set about the central zinc(II) atom.

[(1,2,5,6-η)-Cyclo­octa-1,5-diene](1-ethyl-4-iso­butyl-1,2,4-triazol-5-yl­idene)(tri­phenyl­phosphane)iridium(I) tetra­fluorido­borate di­chloro­methane hemisolvate

A new triazole-based N-heterocyclic carbene cationic iridium(I) complex with a tetra­fluorido­borate counter-anion and hemi-solvating di­chloro­methane, [Ir(C₈H₁₂)(C₁₈H₁₅P)(C₈H₁₅N₃)][BF₄]·0.5CH₂Cl₂, has been structurally characterized.

(E)-1-(3,4-Di­meth­oxy­phen­yl)-3-(1,3-di­phenyl-1H-pyrazol-4-yl)prop-2-en-1-one

The crystal structure of a pyrazole chalcone is reported.

(1R,2S,4aR,6S,8R,8aS)-1-(3-Hy­droxy­propano­yl)-1,3,6,8-tetra­methyl-1,2,4a,5,6,7,8,8a-octa­hydronaphthalene-2-carb­oxy­lic acid

The single-crystal structure elucidation of diplodiatoxin, a toxic metabolite of Diplodia maydis, is described.

Redetermined structure of methyl 3-{4,4-di­fluoro-2-[2-(meth­oxy­car­bon­yl)­ethyl]-1,3,5,7-tetra­methyl-4-bora-3a,4a-di­aza-s-in­dacen-6-yl}pro­pion­ate

In the title compound, a highly fluorescent boron–dipyrromethene dye, the methyl­propionate moieties have different conformations. In the crystal, weak C—H⋯F and C—H⋯O inter­actions link the mol­ecules.

2-Bromo­acetamide

The title compound, C₂H₄BrNO, crystallizes in the monoclinic space group P2₁/c with one mol­ecule in the asymmetric unit.