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ISSN: 2414-3146

October 2024 issue

Highlighted illustration

Cover illustration: Bright-yellow single crystals of 4-bromo-N,N′-di­phenyl­benzimidamide N′-oxide, C19H15BrN2O, were synthesized as part of a project that explores the formation of earth-abundant transition-metal complexes of amidine oxides (AMOXs), to study their photophysical and redox properties. The HNCNO moiety of the compound shows double-bond delocalization over the N—C—N part, evident from the similar C—N bond distances. The extended structure features cyclic dimers linked by pairs of N—H⋯O and C—H⋯O hydrogen bonds. See: Saha, Chartrand, Cibian, Maris & Hanan [IUCrData (2024). 8, x240968].

organic compounds


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In the title compound, C6H10N2O2, the piperazine-2,3-dione ring adopts a half-chair conformation. In the crystal, the mol­ecules are linked by weak C—H⋯O hydrogen bonds, forming (010) sheets.

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Bright-yellow single crystals of the title compound were synthesized as part of a project that explores the formation of earth-abundant transition-metal complexes of amidine oxides (AMOXs), to study their photophysical and redox properties. The HNCNO moiety of the compound shows double-bond delocalization over the N—C—N part, evident from the similar C—N bond distances.

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The crystal structure of a new S-methyl substituted di­thio­carbazate imine containing the 5-methyl­isatin moiety is described.

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The crystal structure of a zwitterionic unsymmetrical hy­droxy­formamidine methanol monosolvate is reported.

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The crystal structure of a zwitterionic, non-symmetric hy­droxy­formamidine derivative is described.

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The title compound is significantly distorted from planarity, with a twist angle between the planes through the hy­droxy­benzene and acetamide groups being 23.5 (2)°. This conformation is supported by intra­molecular C—H⋯O and N—H⋯Cl contacts. In the crystal, N—H⋯O hydrogen-bonding contacts between acetamide groups and O—H⋯O contacts between hydroxyl groups form tapes propagating parallel to [103].

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The crystal structure, non-bonding inter­actions and packing features of a novel galactose conjugated porphyrin are presented and discussed.

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In the crystal of the title compound, the mol­ecules are linked by N—H⋯N hydrogen bonds, generating a C(4) chain extending along the c-axis direction.

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The title compound was prepared as a racemate of R,R- and S,S-enanti­omers by reduction of the corresponding hy­droxy­imino­ketone. In the crystal, layers are formed via hydrogen bridges of four ammonium groups to chloride ions; these lamellae are connected via inter­digitated benzoic ester groups.

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The asymmetric unit contains two complete mol­ecules. Classical hydrogen bonds, as well as C—H⋯O contacts, connect the mol­ecules to infinite chains along the c-axis direction.
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