(Benzyl­thiol­ato-κS)phenyl­mercury(II)

The X-ray structure of an organomerury(II)thio derivative, prepared from a substituted di­thio­carbamate, is reported.

Bis{3,5-di-tert-butyl-N-[(4-di­methylamino)phenyl]salicylaldiminato}cobalt(II)

In the mol­ecule of the title compound, the cobalt(II) atom shows a distorted tetra­hedal geometry. In the crystal, inversion-related pairs of mol­ecules are weakly connected by C—H⋯π inter­actions into dimeric units.

(4Z)-4-(2-Oxo­propyl­idene)-1,3-bis­(prop-2-en-1-yl)-2,3,4,5-tetra­hydro-1H-1,5-benzodiazepin-2-one

The mol­ecular and crystal structure of the title benzodiazepinone derivative is reported. The conformation of the acetyl group is partially determined by an intra­molecular N—H⋯O hydrogen bond. In the crystal, pairwise C—H⋯O hydrogen bonds form inversion dimers.

N′-[Bis(methyl­sulfan­yl)methyl­idene]-2-meth­oxy­benzohydrazide

The title compound was synthesized from potassium (2-meth­oxy­benzo­yl)hydrazinecarbodi­thio­ate by the reaction of methyl iodide and characterized by single-crystal X-ray diffraction data along with elemental analysis, IR and NMR spectroscopy.

(3β,5α,25R)-12-(Hy­droxy­imino)­spiro­stan-3-yl acetate

The title steroidal compound, derived from hecogenin, forms supra­molecular chains C(8) in the crystal, oriented parallel to the short axis a.

Methyl 3-(2,5-dimeth­oxy-3,4,6-tri­methyl­phen­yl)propano­ate

The mol­ecular and crystal structure of the title compound is reported. The crystal structure is stabilized by C—H⋯O hydrogen bonds and a weak C—H⋯π(ring) contact.

5-Hy­droxy-2-phenyl-7-(prop-2-yn-1-yl­oxy)-4H-chromen-4-one

In the title compound, the planar chromenone ring system is nearly co-planar with the phenyl ring, the dihedral angle being 3.85 (8)°.

4-{[5-Methyl-2-(propan-2-yl)phen­oxy]meth­yl}-1-(4-nitro­benz­yl)-1H-1,2,3-triazole

The mol­ecular and crystal structure of the title triazole derivative is reported. The crystal structure features C—H⋯N and C—H⋯O hydrogen bonds and N=O⋯π(ring) contacts.

4-[(1H-Imidazol-1-yl)meth­yl]-1-(4-nitro­benz­yl)-1H-1,2,3-triazole

The mol­ecular and crystal structure of the title triazole derivative is reported. The crystal structure is stabilized by C—H⋯N and C—H⋯O hydrogen bonds and N=O⋯π inter­actions, stacking the mol­ecules along the c-axis direction.

(2E)-N-Methyl-2-[1-(4-methyl­cyclo­hex-3-en-1-yl)ethyl­idene]hydrazinecarbo­thio­amide

The mol­ecular and crystal structure of the title hydrazinecarbothi­amide derivative is reported. The crystal structure features N—H⋯S hydrogen bonds.

1,4-Di-n-octyl-1,2,3,4-tetra­hydro­quinoxaline-2,3-dione

In the title compound, the n-octyl chains are largely in `extended' conformations so that the mol­ecules pack to generally form polar and non-polar regions. The major inter­molecular inter­action appears to be complementary π-stacking between oppositely oriented tetra­hydro­quinoxaline units.

N²,N²,N⁶,N⁶-Tetra­phenyl­pyridine-2,6-di­amine

The title compound has an unsymmetrical structure. In the crystal, C—H⋯N inter­actions between the phenyl and pyridyl rings lead to a mol­ecular array along the b axis.

N-[(1aR,5aR,8R,9aR)-1,1-Di­chloro-1a,5,5,7-tetra­methyl-1a,2,3,4,5,5a,8,9-octa­hydro-1H-benzo[a]cyclo­propa[b][7]annulen-8-yl]acetamide

The title modified β-himachalene compound is built up from fused six- and seven-membered rings and an additional three-membered ring.

2-(3-Methyl­phen­yl)-1,2-benzoselenazol-3(2H)-one

In the title ebselen derivative, the mean plane of the benzisoselenazolyl ring system is inclined to the 3-methyl­phenyl ring by 5.37 (11)°. In the crystal, mol­ecules are linked by C—H⋯O hydrogen bonds and short inter­molecular Se⋯O contacts of 2.6917 (19) Å, forming chains along the c-axis direction.

2-Oxo-2H-chromen-3-yl 4-fluoro­benzoate

In the title compound, the dihedral angle between the coumarin ring system and the benzene ring is 70.18 (6)°. In the crystal, π–π inter­actions link the mol­ecules into a three-dimensional framework.

2-(3-Bromo-5-nitro-1H-indazol-1-yl)-1-phenyl­ethanone

The title compound is an important pharmacophore mol­ecule exhibiting a number of biological activities. The fused three-ring system is planar and almost perpendicular to the 1-phenyl­ethanone group.

4,6-Di-tert-butyl-2-({[4-(di­ethyl­amino)­phen­yl]imino}­meth­yl)phenol

The mol­ecular structure features a weak O—H⋯N hydrogen bond and C—H⋯O contacts. Weak C—H⋯π inter­actions are observed in the crystal packing.

3-Benzyl­idene-1′-methyl-4′-phenyl­dispiro­[cyclo­pentane-1,3′-pyrrolidine-2′,1′′-acenaphthene]-2,2′′-dione

In the title compound, the pyrrolidine ring adopts an envelope conformation, with the N atom as the flap, and the cyclo­penta­none ring adopts a twisted conformation. The dihedral angle between these rings is 82.02 (15)°. The packing features weak C—H⋯O inter­actions.

3-Methyl-5,6-di­phenyl-1H-pyrazolo­[1,2-a]cinnolin-1-one

The title pyrazolo­[1,2-a]cinnolin-1-one derivative, crystallizes with two independent mol­ecules (A and B), with slightly different conformations, in the asymmetric unit. In the crystal, the A and B mol­ecules are linked by a pair of C—H⋯O hydrogen bonds, forming an A–B dimer with an (14) ring motif.

8-Hy­droxy-3,4-bis­(4-meth­oxy­phen­yl)-1H-isochromen-1-one

The title compound consists of a chromene moiety substituted by two meth­oxy­phenyl groups and a hy­droxy group. The two benzene rings are inclined to one another by 67.0 (2)° and to the mean plane of the 1H-isochromene ring system by 67.21 (16) and 27.61 (17)°.

(E)-N-(1H-Pyrrol-2-yl­methyl­idene)-2-{[(E)-(1H-pyrrol-2-yl­methyl­idene)amino]­meth­yl}aniline

The title salophene-type compound crystallizes with two independent mol­ecules (A and B) in the asymmetric unit. The pyrrole rings are inclined to the central benzene ring by 43.7 (3) and 78.9 (2)° in mol­ecule A, and by 46.8 (3) and 79.3 (3)° in mol­ecule B. In the crystal, mol­ecules are linked by N—H⋯N hydrogen bonds, forming chains propagating along the a-axis direction.

2-{(E)-[(4-Anilinophen­yl)imino]­meth­yl}-4-[(E)-(4-meth­oxy­phen­yl)diazen­yl]phenol

In the title Schiff base compound, the 4-meth­oxy­benzene ring and the p-phenyl­enedi­amine ring are inclined to the phenol ring by 11.60 (2) and 46.04 (2)°, respectively, and the conformation about the C=N and N=N bonds is E.

4-Chloro-2-nitro-1-(2-phenyl­eth­yl)benzene

In the title compound, the dihedral angle between the aromatic ring planes is 6.09 (17)°. In the crystal, C—H⋯O hydrogen bonds link the mol­ecules into C(6) [001] chains.

(2E)-3-Phenyl­prop-2-en-1-yl thio­cyanate

The C—S—C bond angle in the title compound is 99.41 (9)°. In the crystal, inversion dimers linked by pairs of extremely weak C—H⋯N inter­actions occur, as does a short S⋯N contact.

Ethyl 2-[9-(5-bromo-2-hy­droxy­phen­yl)-3,3,6,6-tetra­methyl-1,8-dioxo-1,2,3,4,5,6,7,8,9,10-deca­hydro­acridin-10-yl]acetate

The central 1,4-di­hydro­pyridine ring of the title compound adopts a shallow sofa conformation (with the C atom bearing the bromo-phenol ring as the flap),

2-Iso­propyl-4,7-di­methyl-1-nitro­naphthalene

All the non-H atoms of the title compound, except the CH₃ groups of the isopropyl unit and the O atoms of the nitro group, lie on a crystallographic mirror plane.

1-Allyl-2-methyl­pyridinium chloride

The chloride anions of the title compound are sixfold coordinated by C—H⋯Cl hydrogen bonds from the pyridinium cations.

3,3′-(Hexane-1,6-di­yl)bis­(1-vinyl-4-imidazoline-2-thione)

The title compound was obtained by the reaction of sulfur with the corresponding quaternary salt in the presence of K₂CO₃. It crystallizes with two half-mol­ecules in the asymmetric unit, the complete mol­ecules being generated by inversion symmetry.

3-(2-Chloro­pyridin-3-yl)quinazoline-2,4(1H,3H)-dione chloro­form monosolvate

The solvated title compound is a product of a condensation reaction between 2-amino-N-(2-chloro­pyridin-3-yl)benzamide and phosgene. The presence of the chlorine substituent on the pyridine ring forces the latter to adopt a nearly perpendicular orientation relative to the planar quinazoline ring (r.m.s. deviation = 0.04 Å), the two ring systems being inclined to one another by 84.28 (9)°.