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April 2025 issue

Cover illustration: The significant structural feature in the AgI complex (nitrito-κ2O:O′)bis[tris(4-fluorophenyl)phosphine-κP]silver(I), [Ag(NO2)(C18H12F3P)2], is the small bite angle of the nitrito ligand [49.80 (5)°], which influences the overall geometry. See: Malan, Potgieter & Meijboom [IUCrData (2025). 8, x250296].
inorganic compounds
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The title single-crystal (icosamagnesium dodecaaluminium icosazinc), was obtained during the synthesis of an Mg–Al–Zn alloy at high pressure and temperature. There are significant difference between the current model and that of previous studies.
CCDC reference: 2440948
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A monoclinic ordered Mg9Ru2 phase with C2/c space-group symmetry rather than previously reported cubic Mg44Ru7 or Mg3Ru2 was obtained via high-pressure sintering during the effort of synthesizing a target Mg—Ru—B compound.
CCDC reference: 2440944
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A CaCu1.424Fe0.576Si2 phase was obtained during high-pressure sintering of an Si-rich quasicrystal composition prealloy with the nominal chemical composition Si61Cu30Ca7Fe2. The obtained phase crystallizes in the space group I4/mmm (No. 139), with a = b = 4.041 Å and c = 10.010 Å.
CCDC reference: 2442775
metal-organic compounds
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The significant structural feature in the title AgI complex is the small bite angle of the nitrito ligand [49.80 (5)°], which influences the overall geometry.
CCDC reference: 2440532
organic compounds
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The crystal structure of a protonated Schiff base, isolated as its nitrate salt, exhibits a supramolecular chain-like architecture that propagates along the crystallographic b-axis direction and features intermolecular O—H⋯O and C—H⋯O hydrogen-bonding.
CCDC reference: 2412828
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A two-dimensional supramolecular architecture mediated by N—H⋯N and N—H⋯O hydrogen bonds is formed in the crystal of the title compound.
CCDC reference: 2443758
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In the title compound, the pendant phenyl ring is twisted by 43.85 (1)° with respect to the acridine moiety. The extended structure features aromatic π–π stacking with a centroid-to-centroid distance of 3.489 (2) Å and weak C—H⋯O hydrogen bonds.
CCDC reference: 2442640
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In the title hydrate, the dihedral angle between the aromatic rings is 9.6 (3)°. In the crystal, N—H⋯O and O—H⋯N hydrogen bonds link the components into (101) sheets.
CCDC reference: 2445786
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The title compound, 3-chloropropiophenone C9H9ClO, consists of an almost planar molecule that is charaterized by very small torsion angles within the alkyl side chain (torsion angles < 6.3°).
CCDC reference: 1501322