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ISSN: 2414-3146

March 2025 issue

Early view articles

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metal-organic compounds


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The crystal structure of an arene ruthenium(II) complex bearing a bidentate Schiff base ligand is reported.

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In the title compound, [Fe(N3)2(C9H8N2)2]·H2O or [Fe(N3)2(AQ)2]·H2O, the FeII ion is distorted octa­hedrally coordinated by two azide ions in a cis position with a syn orientation, while the two amino groups of the AQ ligands are in a cis and the two pyridiyl N atoms are in a trans position.

organic compounds


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In the title compound, the dihedral angle between the 2H-chromen-2-one ring system and the tert-butyl­acetate moiety is 72.72 (9)°. In the crystal, the mol­ecules are connected through C—H⋯O hydrogen bonds, generating C(6) chains and R22(20) loops that are reinforced by weak aromatic π–π stacking inter­actions.

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The title compound contains two almost coplanar phenyl rings and an intra­molecular O—H⋯O hydrogen bond.

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The title compound is a rhodanided derivative of ortho-toluidine. The mol­ecules are connected into a three-dimensional network in the crystal structure by means of classical hydrogen bonds and C–H⋯N contacts.

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The chair-shaped mol­ecules in the crystal consist in two pairs of enanti­omers with two conformations (ratio 1:3), differing only in the position of two ring carbon atoms.
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