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August 2024 issue
metal-organic compounds
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There are two independent ion pairs in the asymmetric unit with each complex cation exhibiting a distorted square-planar conformation around the rhodium(I) atom.
CCDC reference: 2374311
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The title salt features a distorted cis-trigonal-bipyramid coordination geometry around the tin atom.
CCDC reference: 299548
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The complex sits in a general position. Each NiII ion has an N4Cl2 coordination sphere. Weak hydrogen bonding exists between three of the amino groups and the chloride ions of an adjacent molecule. Chains of molecules, linked by the hydrogen bonding and short Cl⋯Cl contacts, are well separated by the 3-methoxyaniline ligands.
CCDC reference: 2376104
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In the title compound, the 2-carboxyquinolinium cation, the [SnCl6]2– anion (site symmetry ) and the water molecule of crystallization are held together by hydrogen bonds, π–π stacking and C—Cl⋯π interactions.
CCDC reference: 2378953
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The title structure is made up of diperiodic anionic CuICN networks and two independent CuII complexes that are not covalently bonded to the networks.
CCDC reference: 2379862
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The title compound is a dimeric nickel(II) coordination compound containing two different substituted pyrazoles ligands, namely 3,5-dimethylpyrazole and 3-(pyridin-2-yl) pyrazole along with acetate.
CCDC reference: 2346359
organic compounds
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The molecules of the title compound form acid–acid homodimers in the crystal structure.
CCDC reference: 2374704
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The title compound crystallizes with two molecules in the asymmetric unit. In the crystal, the two molecules associate to form an acid–acid dimer by pairwise O—H⋯O hydrogen bonds.
CCDC reference: 2374703
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The title compound is a morpholinium derivative with the positive charge located on the N atom.
CCDC reference: 2367491
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The crystal structure of a new S-methyl-substituted dithiocarbazate imine containing the 5-bromoisatin moiety is described.
CCDC reference: 2376721
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In the crystal, classical N—H⋯O hydrogen bonds as well as C—H⋯O contacts connect the cationic and anionic entities into sheets lying parallel to the ab plane.
CCDC reference: 2379208
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The components of the title molecular salt are linked by N—H⋯O hydrogen bonds and aromatic π–π stacking interactions.
CCDC reference: 2378009