Poly[[μ₃-2-(benzotriazol-1-yl)acetato-κ³O:O′:N³]chlorido­(ethanol-κO)cobalt(II)]

The reaction of 2-(benzotriazol-1-yl) acetic acid with CoCl₂ at room temperature in ethanol generates the title three-dimensional cobalt-based coordination polymer.

Di­carbonyl-1κ²C-μ-chlorido-2:3κ²Cl:Cl-penta­chlorido-2κ²Cl,3κ³Cl-[1(η⁶)-toluene]digallium(III)ruthenium(I)(Ru—Ga)

The title compound is a ruthenium–gallium metal cluster. The ruthenium and gallium have a direct metal–metal bond with a length of 2.4575 (2) Å.

Bis(ethyl­enedi­ammonium) μ-ethyl­enedi­aminetetra­acetato-1κ³O,N,O′:2κ³O′′,N′,O′′′-bis­[tri­oxidomolybdate(VI)] tetra­hydrate

The title compound is a binuclear complex of molybdenum with a ethyl­enedi­amine­tretra­acetate ligand bridging two MoO₃ units.

[1-(Anthracen-9-ylmeth­yl)-1,4,7,10-tetra­aza­cyclododeca­ne]chlorido­zinc(II) nitrate

The Zn^II atom in the complex cation of the title salt has a square-pyramidal coordination environment defined by four nitro­gen atoms from cyclen (1,4,7,10-tetra­aza­cyclo­dodeca­ne) in the basal plane and one chlorido ligand in the apical position.

Bis{(S)-(−)-N-[(2-biphen­yl)methyl­idene]-1-(4-meth­oxy­phen­yl)ethyl­amine-κN}di­chlorido­palladium(II)

The Pd atom is coordinated by two nitro­gen atoms from two trans-aligned imine ligands and two chlorine atoms in an essentially square-planar environment.

Chlorido­[(1,2,5,6-η)-cyclo­octa-1,5-diene](1-ethyl-4-iso­butyl-1,2,4-triazol-5-yl­idene)rhodium(I)

A new neutral triazole-based N-heterocyclic carbene rhodium(I) complex [RhCl(C₈H₁₂)(C₈H₁₅N₃)], has been synthesized and structurally characterized. The complex crystallizes with two mol­ecules in the asymmetric unit. The rhodium center has a distorted square-planar conformation, formed by a cyclo­octa-1,5-diene (COD) ligand, an N-heterocyclic carbene (NHC) ligand, and a chloride ligand.

(η⁶-Benzene)­chlorido­[(S)-2-(4-iso­propyl-4,5-di­hydro­oxazol-2-yl)phenolato]ruthenium(II)

The title compound, [Ru(C₁₂H₁₄NO₂)Cl(η⁶-C₆H₆)], exhibits a half-sandwich tripod stand structure and crystallizes in the ortho­rhom­bic space group P2₁2₁2₁. The arene group is η⁶ π-coordinated to the Ru atom with a centroid-to-metal distance of 1.6590 (5) Å, with the (S)-2-(4-isopropyl-4,5-di­hydro­oxazol-2-yl)phenolate chelate ligand forming a bite angle of 86.88 (19)° through its N and phenolate O atoms.