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ISSN: 2414-3146

July 2024 issue

Early view articles

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metal-organic compounds

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The reaction of 2-(benzotriazol-1-yl) acetic acid with CoCl2 at room temperature in ethanol generates the title three-dimensional cobalt-based coordination polymer.

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The title compound is a ruthenium–gallium metal cluster. The ruthenium and gallium have a direct metal–metal bond with a length of 2.4575 (2) Å.

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The title compound is a binuclear complex of molybdenum with a ethyl­enedi­amine­tretra­acetate ligand bridging two MoO3 units.

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The ZnII atom in the complex cation of the title salt has a square-pyramidal coordination environment defined by four nitro­gen atoms from cyclen (1,4,7,10-tetra­aza­cyclo­dodeca­ne) in the basal plane and one chlorido ligand in the apical position.

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The Pd atom is coordinated by two nitro­gen atoms from two trans-aligned imine ligands and two chlorine atoms in an essentially square-planar environment.

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A new neutral triazole-based N-heterocyclic carbene rhodium(I) complex [RhCl(C8H12)(C8H15N3)], has been synthesized and structurally characterized. The complex crystallizes with two mol­ecules in the asymmetric unit. The rhodium center has a distorted square-planar conformation, formed by a cyclo­octa-1,5-diene (COD) ligand, an N-heterocyclic carbene (NHC) ligand, and a chloride ligand.
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