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ISSN: 2414-3146

May 2024 issue

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Cover illustration: In the structure of the complex (5-fluoro-2,6-dioxo-1,2,3,6-tetra­hydro­pyrimidin-1-ido-κN1)(1,4,8,11-tetra­aza­cyclo­tetra­decane-κ4N)zinc(II) perchlorate, the zinc(II) ion forms coordination bonds with the four nitro­gen atoms of cyclam (1,4,8,11-tetra­aza­cyclo­tetra­decane or [14]aneN4) as well as with the nitro­gen atom of a deprotonated 5-fluoro­uracil ion (FU). Cyclam adopts a trans-I type conformation within this structure. The coordination structure of the zinc(II) ion is a square pyramid with a distorted base plane formed by the four nitro­gen atoms of the cyclam. FU engages in inter­molecular hydrogen bonding with neighboring FU mol­ecules and with the cyclam mol­ecule. See: Ichimaru, Kato, Jin, Kurihara & Kurosaki [IUCrData (2024). 8, x240431]

inorganic compounds


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Na2(Fe2/3Te4/3)O6 was obtained under hydro­thermal conditions and adopts the ilmenite (FeTiO3) structure type.

metal-organic compounds


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The crystal structure of the title complex is stabilized by inter­molecular O—H⋯Cl hydrogen bonds, forming [R_{2}^{2}](18) ring motifs.

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In the structure of the title complex, the zinc(II) ion forms coordination bonds with the four nitro­gen atoms of cyclam as well as with the nitro­gen atom of a deprotonated 5-fluoro­uracil ion. Cyclam adopts a trans-I type conformation within this structure. The coordination structure of the zinc(II) ion is a square pyramid with a distorted base plane formed by the four nitro­gen atoms of the cyclam.

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The crystal structure of the title complex features O—H⋯O hydrogen bonds, which form [R_{2}^{2}](8), [R_{4}^{4}](16), [R_{4}^{4}](20) and [R_{4}^{4}](22) ring motifs.

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The mol­ecular structure of Sn(NHMes)4 is defined by a central tin(IV) atom that is coordinated by four NHMes groups in a distorted tetra­hedral arrangement.

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(C8H20N)8[Mo10O34] comprises a centrosymmetric deca­molybdate polyanion linked through N—H⋯O hydrogen bonds to di­butyl­ammonium counter-cations.

organic compounds


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The title compound forms a sheet structure of dimers exhibiting intra- and inter­molecular hydrogen bonds.

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The mol­ecule is a zwitterion, with a protonated α-amino group and a deprotonated α-carboxyl group. Within the crystal, the mol­ecules are linked by a system of hydrogen bonds formed by both the protonated and deprotonated carb­oxy­lic groups, and the protonated ammonium group.

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The N—H group of the title compound does not form a hydrogen bond due to steric hindrance.

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In the crystal of the title compound, the mol­ecules are connected through C—H⋯O hydrogen bonds, generating [100] chains, which are crosslinked by weak π–π stacking inter­actions.
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