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June 2020 issue
metal-organic compounds
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The title compound consists of a centrosymmetric bimetallic complex charge-balanced by free 4-nitrobenzoate anions. Each CoII ion exhibits a distorted cis-CoN2O4 octahedral coordination environment. In the crystal, the dications and anions are linked by O—H⋯O and C—H⋯O hydrogen bonds.
CCDC reference: 2009578
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Pairs of bis-monodentate 5-nitro-2-phenylsulfanyl-benzoate ligands bridge two CuII atoms related by inversion symmetry. The square-pyramidal coordination geometry of each copper(II) atom is completed by an acetronitile ligand at the apex. The intramolecular Cu⋯Cu distance in the dimer is 2.6478 (3) Å.
CCDC reference: 2009944
organic compounds
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The molecular structure of the title compound, (BenzMIm)Br (BenzMIm=1-benzyl-3-methylimidazolium), consists of separated bromide anions and 1-benzyl-3-methylimidazolium cations connected via short C—H⋯Br contacts.
CCDC reference: 2009703
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The title compound was prepared via a Claisen-Schmidt condensation through a solventless, green synthesis technique. The resulting crystals formed in the monoclinic space group P21/c, and adopting the common E configuration.
CCDC reference: 1894469
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The crystal structure of a pharmacophore hybrid of chalcone and resveratrol is reported.
CCDC reference: 2009305
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The Flack and Watkin 2AD plot based on 1941 acentric Friedel pairs for the title chloroform solvate shows that the observed intensity differences for Friedel opposites are dominated by random and systematic errors, erasing information about resonant scattering.
CCDC reference: 2009153
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In the title molecule, the phenyl rings areinclined to one another by 48.04 (9)°. In the crystal, weak C—H⋯π(ring) interactions form a layered structure.
CCDC reference: 2009913
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In the title hemisolvate, the dihedral angles between the central heterocyclic ring and pendant benzene rings are 82.9 (8) and 88.7 (9)° and the complete benzene solvent molecule of crystallization is generated by a crystallographic centre of inversion. In the crystal, one very weak C—H⋯I interaction links the molecules into [001] chains.
CCDC reference: 2012458