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January 2025 issue
Early view articles
metal-organic compounds
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Di-tert-butyldiisothiocyanatotin(IV), tBu2Sn(NCS)2, exhibits a new kind of intermolecular association via Sn⋯S interactions resulting in an antiparallel, zigzag arrangement of the molecular dipole moments. The chain-like structure motif is classified as Am2c according to its structure determining symmetry elements.
CCDC reference: 2412795
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The coordination environment around RuII is best described as pseudo-octahedral, resembling the familiar half-sandwich ‘three-legged piano-stool’ structure.
CCDC reference: 2407332
organic compounds
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Intra- and inter-molecular O—H⋯O hydrogen bonds are observed in the structure of the title compound.
CCDC reference: 2258982
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A salt co-crystal comprising pyridin-1-ium carboxyformate and 2-chloroacetic acid is stabilized by conventional and charge-assisted hydrogen bonds within a one-dimensional chain.
CCDC reference: 2412697
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The title compound is the symmetric glycolide derived from benzilic acid featuring a disordered tetrahydrofuran solvent molecule in the crystal structure.
CCDC reference: 2412616
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The crystal structure of a hydrate of the title benzo[d]thiazole derivate is reported, which features a complex hydrogen-bonded network.
CCDC reference: 2413286
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In the title compound, which is of interest with respect to stereochemistry and the anomeric effect, two acetyl substituents adopt equatorial orientations and two are axial. The extended structure displays C—H⋯O hydrogen bonding.
CCDC reference: 2415464