issue contents
May 2024 issue
inorganic compounds
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Na2(Fe2/3Te4/3)O6 was obtained under hydrothermal conditions and adopts the ilmenite (FeTiO3) structure type.
CCDC reference: 2357540
metal-organic compounds
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The crystal structure of the title complex is stabilized by intermolecular O—H⋯Cl hydrogen bonds, forming (18) ring motifs.
CCDC reference: 2350906
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In the structure of the title complex, the zinc(II) ion forms coordination bonds with the four nitrogen atoms of cyclam as well as with the nitrogen atom of a deprotonated 5-fluorouracil ion. Cyclam adopts a trans-I type conformation within this structure. The coordination structure of the zinc(II) ion is a square pyramid with a distorted base plane formed by the four nitrogen atoms of the cyclam.
CCDC reference: 2354211
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The crystal structure of the title complex features O—H⋯O hydrogen bonds, which form (8), (16), (20) and (22) ring motifs.
CCDC reference: 2355145
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The molecular structure of Sn(NHMes)4 is defined by a central tin(IV) atom that is coordinated by four NHMes groups in a distorted tetrahedral arrangement.
CCDC reference: 2357316
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(C8H20N)8[Mo10O34] comprises a centrosymmetric decamolybdate polyanion linked through N—H⋯O hydrogen bonds to dibutylammonium counter-cations.
CCDC reference: 2332866
organic compounds
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The title compound forms a sheet structure of dimers exhibiting intra- and intermolecular hydrogen bonds.
CCDC reference: 2352344
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The molecule is a zwitterion, with a protonated α-amino group and a deprotonated α-carboxyl group. Within the crystal, the molecules are linked by a system of hydrogen bonds formed by both the protonated and deprotonated carboxylic groups, and the protonated ammonium group.
CCDC reference: 1936514
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The N—H group of the title compound does not form a hydrogen bond due to steric hindrance.
CCDC reference: 2356945
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In the crystal of the title compound, the molecules are connected through C—H⋯O hydrogen bonds, generating [100] chains, which are crosslinked by weak π–π stacking interactions.
CCDC reference: 2336029