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ISSN: 2414-3146

January 2025 issue

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Cover illustration: The compound di-tert-butyl­diiso­thio­cyanato­tin(IV), [Sn(C4H9)2(NCS)2], which crystallizes with one and a half mol­ecules in the asymmetric unit, represents a new structure type for inter­molecular sulfur⋯tin inter­actions, which is characterized by an anti­parallel arrangement of the dipole moments of the individual mol­ecules. In the resulting zigzag chains, the mol­ecules are related to each other by mirror planes and twofold rotation axes, both perpendicular to the propagation plane, while translation is realized via a glide plane in the crystallographic c-axis direction, a combination of symmetry elements unique in the structural chemistry of diorganotin(IV) dihalides and pseudohalides, R2SnX2 with X = Hal or NCS. See: Kamrowski & Reuter [IUCrData (2025). 8, x241244].

metal-organic compounds


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Di-tert-butyl­diiso­thio­cyanato­tin(IV), tBu2Sn(NCS)2, exhibits a new kind of inter­molecular association via Sn⋯S inter­actions resulting in an anti­parallel, zigzag arrangement of the mol­ecular dipole moments. The chain-like structure motif is classified as Am2c according to its structure determining symmetry elements.

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The coordination environment around RuII is best described as pseudo-octa­hedral, resembling the familiar half-sandwich ‘three-legged piano-stool’ structure.

organic compounds


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Intra- and inter-mol­ecular O—H⋯O hydrogen bonds are observed in the structure of the title compound.

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A salt co-crystal comprising pyridin-1-ium carb­oxy­formate and 2-chloro­acetic acid is stabilized by conventional and charge-assisted hydrogen bonds within a one-dimensional chain.

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The title compound is the symmetric glycolide derived from benzilic acid featuring a disordered tetra­hydro­furan solvent mol­ecule in the crystal structure.

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The crystal structure of a hydrate of the title benzo[d]thia­zole derivate is reported, which features a complex hydrogen-bonded network.

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In the title compound, which is of inter­est with respect to stereochemistry and the anomeric effect, two acetyl substituents adopt equatorial orientations and two are axial. The extended structure displays C—H⋯O hydrogen bonding.
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