catena-Poly[[(benzyl­diphenyl­phosphine-κP)silver(I)]-μ-nitrato-κ²O:O′-[(benzyl­diphenyl­phosphine-κP)silver(I)]-μ-nitrato-κ⁴O,O′:O′,O′′]

The title silver(I) benzyl­diphenyl­phosphine complex crystallizes as a one-dimensional chain propagating through nitrato anions bound to each adjacent silver cation via both bis-monodentate and bis-bidentate coordination.

Bis[(4-methyl­phen­yl)di­phenyl­phosphine-κP](nitrito-κ²O,O′)silver(I)

The title silver(I) diphenyl-p-tolyl­phosphine complex crystallizes with one complete mol­ecule in the asymmetric unit that features a bidentate nitrito, as well as two diphenyl-p-tolyl­phosphine ligands coordinated to a Ag^I center.

Poly[bis­(μ₂-N,N-di­methyl­formamide-κ²O:O)bis­(μ₄-thio­phene-2,5-di­carboxyl­ato-κ⁴O:O′:O′′:O′′′)dicobalt(II)]

The asymmetric unit of the title three-dimensional metal–organic hybrid compound comprises two cobalt(II) cations, one residing on a twofold axis and the other on a centre of inversion, one thio­phene-2,5-di­carboxyl­ate (tdc²⁻) ligand and one coordinated di­methyl­formamide (DMF) solvent mol­ecule. A pair of carboxyl and one DMF connect the adjacent cobalt(II) cations into an infinite chain, leading to a rod-spacer framework with rhombus-window channels, yet no residual solvent-accessible voids are present because the coordinated DMF are oriented into the potential channels.

Bis[3,5-di­fluoro-2-(pyridin-2-yl)phen­yl](4,4′-di­meth­oxy-2,2′-bi­pyridine)­iridium(III) hexa­fluorido­phosphate

The title compound, bis­[3,5-di­fluoro-2-(pyridin-2-yl)phen­yl](4,4′-dimeth­oxy-2,2′-bi­pyridine)­iridium(III) hexa­fluorido­phosphate, is a distorted octa­hedral cyclo­metalated complex that exhibits a trans effect.

Tetra­carbonyldi-μ-chlorido-di­chlorido­bis­(η⁵-cyclo­penta­dien­yl)diirondigallium(2 Fe—Ga)

The title compound has an iron–gallium bond distance of 2.3028 (3) Å. The gallium atoms are connected by two bridging chlorine atoms, each gallium also has one terminal chlorine. The mol­ecule has an inversion center located between the gallium atoms. The cyclo­penta­dienyl ligand was modeled for disorder.

Bis(nitrato-κO)(1,4,8,11-tetra­aza­cyclo­tetra­decane-κ⁴N)zinc(II) methanol monosolvate

The coordination of the central Zn^II atoms in the two different Zn-cyclam units is distorted octa­hedral.

N-(2,3,5,6-Tetra­fluoropyridin-4-yl)formamide

In the title compound, the C_p—N—C—O (p = pyridine) grouping has an anti conformation.

1-(Hex-5-en-1-yl)-4-{[3-methyl-2,3-di­hydro-1,3-benzo­thia­zol-2-yl­idene]meth­yl}quinolin-1-ium iodide monohydrate

The structure of 4-hexenyl thia­zole orange is presented.

4,4′-Methyl­enebis[N-(2-hy­droxy-3-meth­oxy­benzyl­idene)-2,6-diiso­propyl­aniline]

In the V-shaped bis-bidentate bulky Schiff base title mol­ecule, the phenolic –OH group forms intra­molecular hydrogen bonds. In the crystal, weak inter­molecular C—H⋯O inter­actions connect the mol­ecules.