issue contents
November 2021 issue
inorganic compounds
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NOBF4 crystallizes in the baryte structure type with orthorhombic Pnma symmetry and exhibits cationic disorder.
CCDC reference: 2122392
metal-organic compounds
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In the title compound, the iridium(I) atom has a distorted square-planar coordination environment.
CCDC reference: 2118414
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The crystal structure of the title complex, [PdCl(dppe)(INAM)]NO3.CH3CN consists of a PdII metal center in a distorted square-planar environment with hydrogen-bond interactions contributing to the crystal packing. An acetonitrile molecule completes the asymmetric unit.
CCDC reference: 2120285
organic compounds
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In the crystal of the title organic salt, the cation and the anion are connected via bifurcated N—H⋯(O,O) hydrogen bonds, forming a centrosymmetric 2:1 unit of the cation and anion. The units are further linked by O—H⋯O and N—H⋯Cl hydrogen bonds.
CCDC reference: 2119367
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The structure of the tetramethylammonium salt of cyanourea is reported.
CCDC reference: 2116890
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The title 1,2-diazole derivative is highly twisted with the dihedral angle between the pendant rings being 74.5 (1)°. In the crystal, weak C—H⋯O interactions feature predominantly within the three-dimensional architecture.
CCDC reference: 2121290