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ISSN: 2414-3146

December 2021 issue

Highlighted illustration

Cover illustration: Di­chlorido­(η6-p-cymene)[tris­(4-meth­oxy­phen­yl)phosphane]ruthenium(II), [RuCl2(C10H14)(C21H21O3P)] crystallizes with two independent complex mol­ecules in the asymmetric unit. Despite having similar effective cone angle values, the phosphane ligands of the two independent mol­ecules show a marked variation in the orientations of their substituents. In the crystal, weak C—H⋯Cl/O/π inter­actions are observed. See: Davis & Muller [IUCrData (2021). 6, x211259].

metal-organic compounds


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The title compound, [RuCl2(C10H14)(C21H21O3P)] crystallizes with two independent complex mol­ecules in the asymmetric unit. In the crystal, weak C—H⋯Cl/O/π inter­actions are observed.

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In the binuclear nickel(II) title compound, the ligand 2,2′,2′′,2′′′-{[pyrazine-2,3,5,6-tetra­yltetra­kis­(methyl­ene)]tetra­kis­(sulfanedi­yl)}tetra­acetic acid coordinates two NiII cations in a bis-penta­dentate manner and the sixfold coordination sphere of each nickel(II) atom is completed by a water mol­ecule.

organic compounds


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The title di­chloro-substituted hemiketal derivative of a cis–syn–cis triquinane is described.

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The title compound, C4H2N2S, is a 1,3-thia­zole substituted in the 4-position by a nitrile group.

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Singl crystals of the title compound were synthesized by the dehydrative condensation of α-L-sorbose and methanol.
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