Hexa­aquadodeca-μ₂-chlorido-octa­hedro-hexa­niobium diiodide

The crystal structure of the cluster complex [Nb₆Cl₁₂(H₂O)₆]I₂ is described. The octa­hedral Nb₆ cluster core is coordinated by twelve chlorido and six water ligands. The two iodide ions are not bonded to the cluster unit but are present in the crystal structure as the counter-anion to the cluster cation.

Barium bis­[tetra­fluorido­bromate(III)]

The crystal structure of Ba[BrF₄]₂ was refined against single-crystal X-ray diffraction data collected at 100 K, confirming the previous model from powder data.

Bis(pyridine-2-carboxyl­ato-κ²N,O)copper(II)]–benzene-1,3,5-tri­carb­oxy­lic acid–water (1/2/2)

The structure of a copper(II) complex is described.

Ethanol(nitrato)[tris­(4-cyano-3-phenyl-1H-pyrazol-1-yl)hydroborato]nickel(II)

The synthesis and structure are reported of Tp^Ph,4CNNi(NO₃)(EtOH), an octa­hedral complex containing a tridentate cyano­scorpionate ligand, a bidentate nitrate ligand and a neutral ethanol ligand.

Bis­(ethanol-κO)bis­(1-ferrocenyl-4,4,4-tri­fluoro­butane-1,3-dionato-κ²O,O′)nickel(II)

In this novel trimetallic complex, the central Ni^II ion is six-coordinate, forming an octa­hedral [NiO₆] core.

tert-Butyl 3-amino-5-bromo-1H-indazole-1-carboxyl­ate

In the packing of the title compound, π–π, C—H⋯O, C—H⋯Br, and N—H⋯N inter­actions are present.

N,N′-Di­cyclo­hexyl-N-(phthaloylglyc­yl)urea

The title urea derivative forms a one-dimensional supra­molecular structure in the solid state, via inter­molecular N—H⋯O hydrogen bonds.