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ISSN: 2414-3146

October 2026 issue

Early view articles

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metal-organic compounds


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The crystal structure of the title salt comprises [PyH]+ and [SnIIBr3]− ions. The structural parameters of the two cations and two anions in the asymmetric unit are presented and discussed in relation to the values in other compounds. Inter­molecular inter­actions such as tetrel bonds, π–π inter­actions and N—H⋯Br hydrogen bonds are analysed.

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A dinuclear silver(I) com­plex of 6-phenyl-2,2′:6′,2′′-terpyridine features bridging terpyridine ligands and a short intra­molecular Ag⋯Ag contact indicative of an argentophilic inter­action.

organic compounds


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In the title compound, the dihedral angles between the central iso­thia­zole ring and pendant phenyl and p-meth­oxy­phenyl rings are 41.57 (15) and 4.63 (13)°, respectively. In the extended structure, weak C—H⋯π inter­actions may help to consolidate the packing.

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The title com­pound was synthesized using the acid catalyst NH4HF2 in a water/methanol solution.