(η⁵-Carb­oxy­cyclo­penta­dien­yl)(η⁷-cyclo­hepta­trien­yl)manganese(I) hexa­fluorido­phosphate

The `tromancenium-8-carb­oxy­lic acid' entity with a hexa­fluorido­phosphate counter-ion represents a rare case of a cationic carb­oxy­lic acid.

Carbonyl­bis­{6,6′-[(3,3′-di-tert-butyl-5,5′-dimeth­oxy-1,1′-bi­phenyl-2,2′-di­yl)bis­(­oxy)]bis­(dibenzo[d,f][1,3,2]-dioxaphosphepine)}hydridorhodium(I) toluene-d₈ 2.25-solvate

In the title hydrido rhodium(I) monocarbonyl complex, one bis­phosphite ligand coordinates in the expected bidentate mode, whereas the other coordinates to the metal in a monodentate mode.

trans-Di­chlorido­tetra­kis­(4-meth­oxy­pyridine-κN)ruthenium(II)

The structure of the title compound exhibits disorder around a axis. The 4-meth­oxy­pyridine ligands have a propeller-like arrangement around the ruthenium at 52.01° from the RuN₄ plane.

Benzyl­hexa­decyl­dimethyl­ammonium chloride dihydrate

The structure of a C₁₆ benzalkonium chloride (C₁₆BAC) is reported.

rac-Ethyl rel-(2R,3R,4S)-4-hy­droxy-1,2-di­methyl-5-oxopyrrolidine-3-carboxyl­ate

The crystal structure of the title compound exhibits an envelope conformation for the pyrrolidine ring, which includes three chiral centres.

Diiso­propyl 2-[(4-nitro­benzo­yl)amino]­propane­dioate

The title compound crystallizes in the space group C2 with two mol­ecules in the asymmetric unit.

(E)-N-Phenyl-N-(phenyl­carbamo­yl)-3-[prop­yl(tri­methyl­sil­yl)amino]­acryl­amide chloro­form hemisolvate

The title compound, C₂₂H₂₉N₃O₂Si·0.5CHCl₃, crystallizes in the the triclinic space group P with two host mol­ecules and one chloro­form mol­ecule in the asymmetric unit. The core of the mol­ecule consists of a urea unit bound to a 3-amino-acryloyl group. An intra­molecular N—H⋯O hydrogen bond is present in both crystallographically independent mol­ecules.

15,15-Di­phenyl-2,3,4,5,6,8,9,11,12-octa­hydro­imidazo[2,1-h][1,4,12]trioxa[7]thia­[9]aza­cyclo­tetra­decin-14(15H)-one

The title mol­ecule adopts a cup-shaped conformation. In the crystal, layers lying parallel to the ab plane are formed by C—H⋯O hydrogen bonds and C—H⋯π(ring) inter­actions.

1,4-Phenyl­ene di­allyl bis­(carbonate)

The title compound represents the first instance of a 1,4-phenyl­ene bis­(carbonate) derivative characterized by X-ray diffraction.

2-Bromo-6-hydrazinyl­pyridine

The title mol­ecule is essentially flat. In the crystal the mol­ecules are linked by a system of N—H⋯N hydrogen bonds formed by the hydrazinyl group, a Br⋯Br halogen bond, and π-stacking between the pyridine rings.