Diaceto­nitrile­(2,2′-bi­pyridine-κ²N,N′)palladium(II) bis­(tri­fluoro­methane­sulfonate)

In the crystal structure of the title compound, the palladium(II) metal center is surrounded by a bidentate 2,2′-bi­pyridine ligand and two aceto­nitrile mol­ecules in a distorted square-planar geometry.

Di­chlorido­(4,4′-di­methyl-2,2′-bi­pyridine-κ²N,N′)zinc(II) aceto­nitrile monosolvate

In the crystal structure of the title compound, the central zinc(II) atom is surrounded by a bidentate 4,4′-dimethyl-2,2′-bi­pyridine ligand and two coordinating chlorides in a distorted tetra­hedral shape with π–π stacking inter­actions contributing to the crystal packing.

Tris(benzyl­diphenyl­phosphane-κP)(nitrato-κO)silver(I)

The central Ag^I atom exhibits a distorted tetra­hedral coordination environment, defined by three P atoms of three benzyl-di­phenyl­phosphane ligands and one O atom of a nitrato ligand.

(Nitrito-κ²O,O′)bis­[tris­(4-methyl­phen­yl)phosphane-κP]silver(I)

The synthesis and single-crystal structure are described of a μ-NO₂ silver(I) tris-p-tolyl­phosphine complex to be applied as an potential anti­cancer agent.

(Carbazol-9-ido-κN)di­chlorido­(η⁵:η¹-2,3,4,5-tetra­methyl­penta­fulvene)tantalum(V)

In the title compound, the exocyclic penta­fulvene carbon atom coordinates in a staggered conformation relative to the η¹-ligands.

trans-Bis(2,2′-di­pyridyl­amine-κ²N,N′)­bis­(1,1,3,3-tetra­cyano-2-eth­oxy­propenido-κN)copper(II)

The title complex exhibits a distorted octa­hedral coordination geometry. The CuN₆ coordination sphere is composed of bidentate 2,2′-dipyrid­yl)amine in the equatorial sites while the axial sites are occupied by 1,1,3,3-tetra­cyano-2-eth­oxy­propenide ligands. In the crystal, N—H⋯N hydrogen bonding results in chains parallel to [010].

2-Ethyl-4-methyl-1H-imidazol-3-ium bromide

In the title salt, the bromide ions accept N—H⋯Br hydrogen bonds from the cations, generating C(8) chains propagating in the b-axis direction.