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January 2022 issue
inorganic compounds
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The Al61.49Mn11.35Ni4 phase was synthesized by high-temperature sintering and its crystal structure has been re-determined.
CCDC reference: 2141311
metal-organic compounds
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A three-dimensional supermolecule based on 4-(1,2,4-triazol-1-yl)benzoic acid was prepared under solvothermal conditions. In the crystal, intermolecular N—H⋯N hydrogen bonds between the amine function and the central N atom of the triazole ring lead to the formation of ribbons parallel to [11].
CCDC reference: 2141669
organic compounds
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The title compound crystallizes as the mesomeric isomer, which helped establish that the 1,3 elimination of bromine by triphenylphosphine occurs with inversion of configuration at each chiral carbon atom.
CCDC reference: 2130377
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The aminodisaccharide adopts a conformation close to that of the parent α-lactose and is immersed in an extensive hydrogen-bonding network.
CCDC reference: 2119923
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The title compound features a polarized π-system due to resonance between the N—C(H)=C(H)—B and ionic N+=C(H)—C(H)=B− canonical forms.
CCDC reference: 2129837