issue contents
July 2018 issue
metal-organic compounds
Download citation
Download citation
Open access
The title compound, a two-dimensional layered coordination polymer, was prepared during synthetic attempts to prepare a cadmium coordination polymer containing both cis-cyclohex-4-ene-1,2-dicarboxylate (chedc) and propane-1,3-diylbis(piperidine-4,1-diyl)bis(pyridin-4-ylmethanone) (4-ppbp) ligands.
CCDC reference: 1851771
Download citation
Download citation
Open access
The title compound is an cobalt(III) dibromide complex having a cis arrangement of the bromido, bis(ethylene-1,2-diamine) and n-butyl substituents.
CCDC reference: 894716
Download citation
Download citation
Open access
In the complex cation of the title compound, the CoIII ion has a distorted octahedral N5Cl coordination set.
CCDC reference: 794322
organic compounds
Download citation
Download citation
Open access
The molecular and crystal structures of the title dihydroimidazolone derivative are reported. The crystal packing consists of chains along the c-axis direction, formed by a combination of C—H⋯O hydrogen bonds and C—H⋯π(ring) interactions.
CCDC reference: 1852189
Download citation
Download citation
Open access
The structure of this coumarin ester derivative features C=O⋯π and π–π stacking interactions, which were investigated using Hirshfeld surface analysis.
CCDC reference: 1839611
Download citation
Download citation
Open access
The seven-membered ring adopts a boat conformation. In the crystal, inversion-related C—H⋯N hydrogen bonds form dimers, which pack in an alternating fashion.
CCDC reference: 1853275
Download citation
Download citation
Open access
The title molecule crystallizes with two molecules with similar conformations in the asymmetric unit. In the crystal, molecules are linked by C—H⋯O and C—H⋯N hydrogen bonds and C—H⋯π interaction, forming a three-dimensional network.
CCDC reference: 1853501
Download citation
Download citation
Open access
The asymmetric unit comprises four independent molecules (A–D) of C17H13N5O. In the crystal, molecules form two separate stacks parallel to the b-axis direction: one consists of A and D molecules, and the other of B and C molecules.
CCDC reference: 1854087
Download citation
Download citation
Open access
In the title solvate, N—H⋯O, C—H⋯O and C—H⋯S hydrogen bonds, together with C—H⋯π interactions, stack chains of molecules along the a-axis direction.
CCDC reference: 1855614
Download citation
Download citation
Open access
In 4-phenyl-2,5,5a,6,7,8,9,9a-octahydro-1H-1,5-benzodiazepin-2-one, the cyclohexyl portion is disordered over two alternate chair conformations in a 91:9 ratio.
CCDC reference: 1855622
Download citation
Download citation
Open access
The crystal structure of C3-symmetric tris(4-methoxyphenyl)stibine is reported.
CCDC reference: 1854911
Download citation
Download citation
Open access
The molecular and crystal structure of 3′,4′-diphenyl-3H,4′H-spiro[benzo[b]thiophene-2,5′-isoxazol]-3-one is reported as spiro-isoxazolines are important organic precursors to a number of molecules with biological activities.
CCDC reference: 1855760
Download citation
Download citation
Open access
The chromene portion of the title flavanoid derivative is planar, with the various substituents lying close to the same plane. This is due, in part, to the presence of a strong intramolecular C—H⋯O hydrogen bond and two weak C—H⋯O contacts.
CCDC reference: 1855031
Download citation
Download citation
Open access
The phenoxy group is nearly perpendicular to the dihydropyrimidinium ring. In the crystal, O—H⋯O, N—H⋯O and C—H⋯O hydrogen bonds form corrugated layers parallel to the ac plane.
CCDC reference: 1857057