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August 2026 issue
Early view articles
inorganic compounds
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accessSr[SnF6]·2H2O is isostructural with the analogous hexafluoridoiridate(IV) and consists of almost undistorted [SnF6]2– octahedra and of distorted [SrF5(H2O)3] square antiprisms linked via common water molecules into centrosymmetric dimers.
CCDC reference: 2577756
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accessThe crystal structure of Pb2O(OH)Br has tetragonal symmetry and differs from those of the Cl (orthorhombic) and I (monoclinic) analogues.
CCDC reference: 2578647
metal-organic compounds
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accessIn the title salt, the silver(I) ion is coordinated by both neutral 1,3,5-triaza-7-phosphaadamantane (PTA) and protonated PTAH+ ligands.
CCDC reference: 2578472
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accessThe complex cation in the title compound has a distorted square-planar conformation around the IrI atom, formed by a bidentate cycloocta-1,5-diene (COD) ligand, a phosphane ligand, and an N-heterocyclic carbene (NHC) ligand.
CCDC reference: 2581838
organic compounds
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accessThe title compound, C27H27NP2, consists of a diphenylphosphino and a tert-butyl(2-pyridyl)phosphino group bridged by a 1,2-phenylene backbone.
CCDC reference: 2578570
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accessThe title compound, 2-deoxy-D-galactitol, was prepared by sodium borohydride reduction of 2-deoxy-D-galactose and crystallized from water. Its crystal structure contains two crystallographically independent molecules in the asymmetric unit, which are linked by O—H⋯O hydrogen bonds into a three-dimensional network.
CCDC reference: 2574888
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accessThe title compound, L-iditol, was crystallized from aqueous solution. It crystallizes in the monoclinic space group P21 with one molecule in the asymmetric unit. The molecules are linked by O—H⋯O hydrogen bonds into a three-dimensional network.
CCDC reference: 2577698
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accessThe title compound, ethyl α-D-sorboside monohydrate, was prepared by Fischer glycosylation of D-sorbose with ethanol. The crystal structure contains one water molecule per sorboside molecule, and the components are linked by O—H⋯O hydrogen bonds.
CCDC reference: 2577733
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accessThe title compound is a symmetrical diarylformamidine derivative bearing diisopropyl substituents. The compound contains two independent molecules in the asymmetric unit, one being the zwitterionic and the other the neutral forms of the diarylformamidine derivative. The two molecules are connected by O—H⋯O and N—H⋯N hydrogen-bonding interactions within a cyclic assembly.
CCDC reference: 2578952
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accessThe crystal structure of the dibromide salt of metforminium(2+) in space group P21/c is compared to that of the dichloride analogue, previously reported in space group P21.
CCDC reference: 2578518
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accessThe two crystallographic independent molecules in the title compound display short intramolecular C—H⋯F hydrogen bonds.
CCDC reference: 2579961
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accessThe structure of the title compound completes structural characterization for the family of methyl-2-nitroaniline isomers. Bond lengths and angles conform to reported values in other methyl-2-nitroaniline structures, except for the large angle [36.82 (4)°] formed between the phenyl ring and nitro group mean planes, which is due to steric crowding by the neighboring methyl group
CCDC reference: 2580961
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accessThe title compound, C20H19F3O4, crystallizes with two independent molecules with similar geometry. In both molecules the tetrahydropyran, cyclohexene and cyclohexane rings of the xanthene moiety adopt half-chair, half-boat and chair conformations, respectively.
CCDC reference: 2580767
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accessThe asymmetric unit of the title 3-(4-methylphenyl)-5-phenyl-1,2-thiazole compound comprises two independent molecules with nearly planar geometries. No classical hydrogen bonds are found in the crystal structure.
CCDC reference: 2580089
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accessThe title compound, methyl α-D,L-sorboside, was prepared from an equimolar mixture of D- and L-sorbose (D:L = 1:1) by Fischer glycosidation in methanol. The asymmetric unit contains one molecule each of methyl α-D-sorboside and methyl α-L-sorboside, which are linked by O—H⋯O hydrogen bonds into a two-dimensional network parallel to (001).
CCDC reference: 2582017
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accessThe crystal structure of L-talitol, the sugar alcohol corresponding to L-talose, is presented. The molecules are linked by O—H⋯O hydrogen bonds into a three-dimensional network.
CCDC reference: 2577672

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