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Journal logoIUCrDATA
ISSN: 2414-3146

December 2019 issue

Highlighted illustration

Cover illustration: In (2,2'-bi­pyridine-[kappa]2N,N')(pyridine-2,6-di­carboxyl­ato-[kappa]2N,O)palladium(II) monohydrate, [Pd(C7H3NO4)(C10H8N2)]·H2O, the PdII cation is four-coordinated in a distorted square-planar coordination geometry defined by the two N atoms of the 2,2'-bi­pyridine ligand, one O atom and one N atom from the pyridine-2,6-di­carboxyl­ate anion. The complex and solvent water mol­ecule are linked by inter­molecular hydrogen bonds. In the crystal, the complex mol­ecules are stacked in columns along the a axis. See: Kwang Ha [IUCrData (2019). 4, x191625].

metal-organic compounds


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The central PdII ion has an N3O square-planar coordination sphere defined by two bidentate ligands: 2,2′-bi­pyridine and the pyridine-2,6-di­carboxyl­ate anion.

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The title compound, [Os(C6HF4S)4(PPh3)], crystallized from an ethanol solution as a monoclinic polymorph of the previously reported triclinic form.

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The Cd2+ cations and Cl ions form M4Cl8 clusters with six of the Cl ions bridging and two pendant and the ligand is bidentate.

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The structure of the salt consisting of two-dimensional strands of anionic [Mn(NCS)3] units and 1-ethy-3-methyl­imidazolim cations was refined by single-crystal X-ray diffraction analysis in the P21/c space group.

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The octa­hedral coordination sphere of NiII in the cationic complex of the title salt is considerably distorted.

organic compounds


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The dihedral angle between the benzene and thio­phene rings in the title compound is 54.62 (3)°.

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The crystal structure of the benzene monosolvate of the well known organic diphosphite ligand C46H44O8P2 (BIPHEPHOS) is reported for the first time. Single crystals were obtained from a benzene solution after layering with n-heptane at room temperature.

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The di­hydro­pyridine ring adopts a shallow boat conformation. The mean plane of the di­hydro­pyridine ring (all atoms) subtends dihedral angles of 66.54 (1), 73.71 (1) and 79.47 (1)° with with the two phenyl rings and the chloro­phenyl ring, respectively. In the crystal, N—H⋯O hydrogen bonds link the mol­ecules into [001] chains.

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The dihedral angle between the pyrrole rings in the title compound is 79.47 (9)°. In the crystal, N—H⋯O hydrogen bonds link the mol­ecules into [11\overline{1}] chains.

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The crystal structure of the title compound has been solved by single-crystal X-ray diffraction at 173 K. The crystals of the substance have been grown from the substances liquid phase at 277 K.

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In the title compound, intra­molecular O—H⋯N and C—H⋯π inter­actions help to establish the relative orientations of the pendant rings.
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