Figure 3
Overlay of complex A of the salt, shown in red, with previously characterized (Lerch et al., 2024c) neutral complex (1), showing that the Rh—CNHC bond has rotated 180° in the synthesis of the cationic complex from the neutral precursor. The overlay is constructed with CNHC, Rh, and Cl/P atoms matched between the neutral complex (1) and complex A of the title salt (2) with an r.m.s. deviation of 0.029 Å between the matched atoms. |