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ISSN: 2414-3146

February 2024 issue

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metal-organic compounds

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In the cation of the title complex, the central palladium(II) atom is surrounded by two bidentate ligands, 2,2′-bi­pyridine and 4,4′-dimeth­oxy-2,2′-bi­pyridine, in a distorted square-planar environment.

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In the crystal structure of the title compound, the ruthenium(II) metal center is surrounded by two bidentate 2,2′-bi­pyridine, an isonicotinamide ligand, and a water in a distorted octa­hedral geometry. Hydrogen bonding is present between counter-ion and ligand.

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The structure of the title compound is triclinic containing half of the mol­ecule in the asymmetric unit. Each zinc atom is coordinated to a pyridyl and oxime nitro­gen from one ligand and a third nitro­gen from the other dpko pyridyl ring and two acetato anions.

organic compounds

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Both mol­ecules in the asymmetric unit of the title compound are twisted. In the crystal, weak C—H⋯π inter­actions link the mol­ecules into a three-dimensional network.
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