forthcoming articles

The following articles are a selection of those recently accepted for publication in IUCrData.

See also Forthcoming articles in all IUCr journals.

Accepted 26 May 2025

(3Z)-4-Methyl-9-(4-methyl­benzene­sulfon­yl)-N-phenyl-3H,9H-thio­pyrano[3,4-b]indol-3-imine

The crystal structure of an unprecedented indolo­thio­pyrane imine is presented. The mol­ecule, C25H20N2O2S2, consists of three planar ring systems and adopts the shape of a staircase with two steps.

Accepted 26 May 2025

2-Amino-6-nitro-1,3-benzo­thia­zol-3-ium 3-carb­oxy-4-hy­droxy­benzene-1-sulfonate

In the title salt, the cation is protonated at the thia­zole N atom and in the anion, the sulfonate group is deprotonated and an intra­molecular O—H⋯O hydrogen bond occurs. In the crystal, cation-to-anion N—H⋯O and anion-to-anion O—H⋯O hydrogen bonds link the component ions into (101) sheets.

Accepted 24 May 2025

N-(4-Meth­oxy-2-methyl-5-nitro­phen­yl)acetamide

In the title compound, C10H12N2O4, the four substituents lie out of the phenyl plane by varying degrees. In the extended structure, the acetamide NH group donates a hydrogen bond to an acetamide carbonyl O atom, thereby forming chains propagating in the [010] direction.

Accepted 24 May 2025

2-Amino-4-ferrocenyl-5-oxo-5,6,7,8-tetra­hydro-4H-chromene-3-carbo­nitrile monohydrate

The crystal packing is consolidated by O—H⋯N, O—H⋯O, N—H⋯O, and N—H⋯π hydrogen bonds, with the solvent water mol­ecule acting as both donor and acceptor. This results in a two-dimensional hydrogen-bonded network extending parallel to the bc plane.

Accepted 23 May 2025

1-[(2-Bromo­phen­yl)di­phenyl­meth­yl]-3-(tri­fluorometh­yl)-1H-pyrazole–1-(tri­phenyl­meth­yl)-3-(tri­fluoro­meth­yl)-1H-pyrazole (0.64:0.36)

In the title disordered co-crystal, C—H⋯Br hydrogen bonds link the mol­ecules into centrosymmetric dimers, enclosing R22(16) ring motifs.

Accepted 23 May 2025

Di­chlorido­{(E)-N,N-di­methyl-2-[phen­yl(pyridin-2-yl)methyl­idene]hydrazine-1-carbo­thio­amide}cadmium(II)

The structure of the cadmium-bound model ligand, 3,3-dimethyl-1-[(E)-[phen­yl(pyridine-2-yl)methyl­idene]amino]­thio­urea (Bp44mT), which is used across medicinal chemistry and in metal-based nanoparticles research has been determined and analyzed·This complex is used to gain insight to the specificity and selectivity of the ligand and to model how 3,3-dimethyl-1-[(E)-[phen­yl(pyridine-2-yl)methyl­idene]amino]­thio­urea might be used in chelation to counter metal poisoning and for environmental remediation.

Accepted 22 May 2025

Poly[[tetra­aqua­(μ3-4-hy­droxy­pyridine-2,6-di­carboxyl­ato)di-μ2-oxalato-dipraseodymium(III)] 4.29-hydrate]

The title compound [PrIII2(HCAM)(ox)2(H2O)4]·4.29H2O features a two-dimensional coordination polymeric framework of PrIII with partially deprotonated chelidamic acid (HCAM2−) and oxalate (ox2−) linkers. The two-dimensional sheets further assemble through hydrogen bonding and π–π inter­actions into three-dimensional supra­molecular architecture.

Accepted 22 May 2025

2-Methyl-4-[(4-methyl­phen­yl)amino]­benzoic acid

The mol­ecules of the title compound form acid–acid homodimers in the crystal structure.

Accepted 12 May 2025

(S,S)-Di­iodido­{3,3′-methyl­enebis[1-(1-hy­droxy-4-methyl­pentan-2-yl)imidazol-2-ylene]}palladium(II) ethanol monosolvate

The title methyl­ene-bridged bis-N-heterocyclic carbene (NHC) palladium complex exhibits a distorted square-planar geometry around the palladium center, with the six-membered chelate ring adopting a boat conformation.


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