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Figure 3
Different representation of the tetrel bonds linking the [SnCl3] ions. (above, left) ball-and-stick model of the tin environment with geometric parameters (Å, °) and asymmetry parameters Q (values in square brackets) characterizing the tetrel bonds, (above, right) space-filling model visualizing the inter-penetration of the van der Waals radii of tin and chlorine as result of the tetrel bond formation and inter­penetration indices p (green values), (below) side-view on the twofold screw axis causing the tetrel-bond formation with the distance (Å) between two neighbouring tin atoms. Symmetry codes used to generate equivalent atoms: (1) Mathematical equation − x, Mathematical equation + y, Mathematical equation − z; (2) Mathematical equation − x, −Mathematical equation + y, Mathematical equation − z.

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