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June 2026 issue
Early view articles
organic compounds
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accessThe title imidazolium picrate salt crystallizes in the triclinic space group P1. The asymmetric unit consists of one imidazolium cation and one picrate anion. There is an intramolecular N—H⋯O hydrogen bond within the imidazolium cation and an intermolecular N—H⋯O hydrogen bond between the imidazolium cation and the picrate anion. In the crystal, the ions are further associated through π–π stacking interactions,
CCDC reference: 2555221
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accessIn the title compound, the dihedral angle between the aromatic rings is 13.06 (6)° and an intramolecular O—H⋯S hydrogen bond supports the molecular conformation. In the extended structure, weak C—H⋯O hydrogen bonds connect the molecules into [010] chains.
CCDC reference: 2500235
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accessThe title compound crystallizes in the triclinic space group P1. The ethene derivative is substituted by two phenyl groups in 2-position and two 3,5-dimethylpyrazolinium units in 1-position, which makes this alkene into a dication. Two chloride ions act as counter-ions in the crystal structure and are linked via N—H⋯Cl and C—H⋯Cl interactions with the alkene. The crystal structure features a three-dimensional network stabilized by N—H⋯Cl, C—H⋯Cl and C—H⋯π interactions.
CCDC reference: 2557894
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accessSingle crystals of 2-[(3-chloro-2-methylphenyl)amino]quinoline-3-carboxylic acid were obtained from slow evaporation of an ethyl acetate solution. In the crystal, the molecules pair up to form acid–acid homodimers.
CCDC reference: 2558014

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