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ISSN: 2414-3146

April 2026 issue

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Cover illustration: The reaction of copper(II) perchlorate hexa­hydrate with 4-pyridone and pyrazine in 1-propanol serendipitously yielded crystals of the solvated double salt bis(μ-1,4-di­hydro­pyridin-4-one-κ2O:O)di-μ-perchlorato-κ4O:O′-bis­[aqua­(1,4-di­hydro­pyridin-4-one-κO)copper(II)] tetra­aqua­bis­(1,4-di­hydropyridin-4-one-κO)copper(II) tetra­kis­(perchlorate) 1,4-di­hydro­pyridin-4-one disolvate, [Cu(C5H5NO)2(H2O)4][Cu2(ClO4)2(C5H5NO)4(H2O)2](ClO4)4·2C5H5NO, as a byproduct. Both the monometallic Cu complex and the dimeric species exhibit classic Jahn-Teller-like elongations. Both complexes and the 4-pyridone mol­ecules are bound together by a network of classical hydrogen bonds. See: Turnbull, Landee & Wikaira [IUCrData (2026). 8, x260349].

metal-organic compounds


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The reaction of copper(II) perchlorate hexa­hydrate with 4-pyridone and pyrazine in 1-propanol serendipitously yielded crystals of the solvated title double salt as a byproduct. Both the monometallic Cu complex and the dimeric species exhibit classic Jahn-Teller-like elongations. Both complexes and the 4-pyridone mol­ecules are bound together by a network of classical hydrogen bonds.

organic compounds


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The extended structure of the title hydrated salt is consolidated by numerous N—H⋯O and O—H⋯O hydrogen bonds.

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Two mol­ecules of 7-tert-butyl-1,3-bis­(eth­oxy­meth­yl)pyrene form a dimer unit through π–π inter­actions in the crystal.

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The crystal structure of 5-amino­levulinic acid hydro­chloride has been solved and refined using synchrotron X-ray powder diffraction data, and optimized using density functional theory techniques.

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The crystal structure of bepotastine besylate was refined using synchrotron X-ray powder diffraction data and optimized using density functional theory techniques.
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