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July 2025 issue

Cover illustration: The RhIII complex (nitrito-κO)(nitro-κN)(nitrosyl-κN)bis(triphenylphosphane-κP)rhodium(III), [Rh(NO)(NO2)2(C18H15P)2], is a rare example of a mononuclear compound with nitrito, nitro and nitrosyl ligands. The complex is polymorphic with two distinct crystals recovered, one of which is reported here. The crystal structure of the other crystal did not refine in a satisfactory manner so its structural set-up remains an open question. See: Albert, Gau & Rajaseelan [IUCrData (2025). 8, x250598].
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