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Figure 1
The discrete cluster unit of [Nb6Cl12I2(H2O)4]·8THF with surrounding THF solvent mol­ecules. Atoms are drawn as displacement ellipsoids at the 50% probability level. The {Nb6} metal atom octa­hedron is shown in a polyhedral representation, O—H⋯O hydrogen bonds are shown as red dashed lines. Of the disordered THF mol­ecule, only the major component (A) is shown for better visibility.

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