inorganic compounds
λ-Al13Fe4-type intermetallic (Al,Cu)13(Fe,Cu)4
of theaState Key Laboratory of Metastable Materials Science and Technology, Yanshan University, Qinhuangdao 066004, People's Republic of China
*Correspondence e-mail: chzfan@ysu.edu.cn
An (Al,Cu)13(Fe,Cu)4 phase of [trideca(aluminium/copper) tetra(iron/copper)] was obtained by the high-pressure sintering (HPS) process of a mixture with composition Al78Cu15Fe7. Structure analysis suggests that Cu atoms can replace both Al and Fe atoms. Such findings support previous anomalous X-ray scattering (AXS) results although deviate from other reports. The new phase adopts the λ-Al13Fe4 structure type where Cu atoms partially occupy the 2c and 4i sites for Al and Fe atoms, respectively, with occupancies of 0.233 (5) and 0.173 (16).
CCDC reference: 1826904
Structure description
An unnamed Al78Cu15Fe7 phase was identified in association with icosahedrite (Ma et al., 2016), the first naturally occurring (Bindi et al., 2009). In simulating its growth mechanism by high pressure sintering (HPS), a λ-Al13Fe4-type phase with composition Al4.85Cu0.07Fe1.46 [trideca(aluminium/copper) tetra(iron/copper)] was found. The complex intermetallic compound λ-phase possesses more than 100 atoms in the along with Fe atoms arranged in Fe–Al–Fe groups, which are encapsulated by aluminium atoms (Armbrüster et al., 2012). The synthesized Al4.85Cu0.07Fe1.46 phase can also be viewed as a stacking of flat (F) and puckered (P) layers in a F1P1F2P2 sequence in the [010] direction (Matilainen et al., 2015). The puckered layers are mirrored against the F2 layer. In total, the contains 102 atoms, where the flat layer is composed of 16 Al atoms and one commonly occupied Al/Cu atom, 7 Fe atoms and one commonly occupied Fe/Cu atom. The puckered layer has 22 Al and 4 Fe atoms.
Fig. 1 shows the [010] projection of the of the new ternary Al–Cu–Fe phase. The environment of the Al/Cu atoms and Fe/Cu atoms are shown in Fig. 2. The Al/Cu atoms share the 2c site and are connected by 8 Al atoms and 2 Fe atoms. The Fe/Cu atoms share the 4i site and are connected by 11 Al atoms. Therefore, the new phase can be described as (Al,Cu)13(Fe,Cu)4 where Cu atoms replace both Al and Fe atoms, in accordance with the AXS results (Genba et al., 2002) but different from conventional viewpoints (Freiburg & Grushko, 1994).
Synthesis and crystallization
The pure elements Al (indicated purity 99.8%), Cu (indicated purity 99.95%) and Fe (indicated purity 99.8%) were mixed in the stoichiometric ratio 78:15:7 and initially ground in an agate mortar. Blended powders were then placed in a grinding tool of diameter 5 mm and pressed into a tablet at about 4 MPa slowly and continuously for about five minutes. A cylindrical block 5 mm in diameter and 8 mm in height was obtained without cracks or deformations. The cylindrical block was then inserted in a six-anvil high-pressure apparatus for HPS experiments. Inside the anvil, the block was encapsulated into an h-BN crucible covered by an h-BN gasket and wrapped in a graphite stove. Both ends of the graphite stove were filled with pyrophyllite and dolomite composite medium and sealed by conductive steel. Finally, all of these components were put into pyrophyllite rock that served as pressure transition medium (see Supporting information). The sample was pressurized up to 5 GPa and heated to 1473 K for 30 minutes (similiar conditions as employed by Hollister et al., 2014), cooled to 1073 K and held at this temperature for one hour, and then cooled down rapidly to room temperature. A fragment of dimension 0.08 × 0.05 × 0.03 mm3 was selected and mounted on a glass fiber for single-crystal X-ray diffraction measurements.
Refinement
Crystal data, data collection and structure . After considering all atoms in the Al13Fe4 structure, the original Al1 atom (Wyckoff position 2c) was modelled as occupied with both Al and Cu atoms with occupancies of 0.767 (5) and 0.233 (5), respectively. In addition, the Fe2 position was modelled by partially occupied Fe atoms [occupancy 0.827 (16)] and Cu atoms [occupancy 0.173 (16)]. Although the refined formula Al4.85Cu0.07Fe1.46 shows significant deficiency in Cu compared to that of initial stoichiometry, it is in good agreement with the EDS measurements.
details are summarized in Table 1Structural data
CCDC reference: 1826904
https://doi.org/10.1107/S2414314618003632/pj4005sup1.cif
contains datablock I. DOI:Structure factors: contains datablock I. DOI: https://doi.org/10.1107/S2414314618003632/pj4005Isup2.hkl
Fig. 1S: Sketch of assembled crucible for HPS. DOI: https://doi.org/10.1107/S2414314618003632/pj4005sup3.pdf
Data collection: APEX3 (Bruker, 2015); cell
SAINT (Bruker, 2015); data reduction: SAINT (Bruker, 2015); program(s) used to solve structure: SHELXT (Sheldrick, 2015a); program(s) used to refine structure: SHELXL2014 (Sheldrick, 2015b); molecular graphics: DIAMOND (Brandenburg & Putz, 2017); software used to prepare material for publication: publCIF (Westrip, 2010).Al4.85Cu0.07Fe1.46 | F(000) = 1648 |
Mr = 216.70 | Dx = 3.866 Mg m−3 |
Monoclinic, C2/m | Mo Kα radiation, λ = 0.71073 Å |
a = 15.4749 (10) Å | Cell parameters from 1749 reflections |
b = 8.0913 (5) Å | θ = 2.8–30.5° |
c = 12.4882 (9) Å | µ = 7.06 mm−1 |
β = 107.768 (2)° | T = 293 K |
V = 1489.09 (17) Å3 | Grain, silver |
Z = 16 | 0.08 × 0.05 × 0.03 mm |
Bruker D8 Venture Photon 100 CMOS diffractometer | 1749 reflections with I > 2σ(I) |
phi and ω scans | Rint = 0.044 |
Absorption correction: multi-scan (SADABS; Krause et al., 2015) | θmax = 30.5°, θmin = 2.8° |
Tmin = 0.576, Tmax = 0.746 | h = −21→22 |
12161 measured reflections | k = −11→10 |
2319 independent reflections | l = −14→17 |
Refinement on F2 | 138 parameters |
Least-squares matrix: full | 0 restraints |
R[F2 > 2σ(F2)] = 0.038 | w = 1/[σ2(Fo2) + (0.030P)2 + 1.0855P] where P = (Fo2 + 2Fc2)/3 |
wR(F2) = 0.070 | (Δ/σ)max = 0.001 |
S = 1.07 | Δρmax = 1.12 e Å−3 |
2319 reflections | Δρmin = −0.99 e Å−3 |
Geometry. All esds (except the esd in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell esds are taken into account individually in the estimation of esds in distances, angles and torsion angles; correlations between esds in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell esds is used for estimating esds involving l.s. planes. |
x | y | z | Uiso*/Ueq | Occ. (<1) | |
Al1 | 0.500000 | 0.500000 | 0.500000 | 0.0098 (5) | 0.767 (5) |
Cu1 | 0.500000 | 0.500000 | 0.500000 | 0.0098 (5) | 0.233 (5) |
Al2 | 0.67744 (10) | 0.500000 | 0.71929 (12) | 0.0130 (3) | |
Al3 | 0.63633 (7) | 0.71530 (13) | 0.52217 (8) | 0.0092 (2) | |
Al4 | 0.80481 (10) | 1.000000 | 0.77266 (12) | 0.0077 (3) | |
Al5 | 0.76330 (10) | 0.500000 | 0.46467 (13) | 0.0126 (3) | |
Al6 | 0.49067 (7) | 0.27023 (14) | 0.33038 (8) | 0.0094 (2) | |
Al7 | 0.52074 (9) | 0.500000 | 0.17059 (11) | 0.0078 (3) | |
Al8 | 0.500000 | 0.74935 (18) | 0.000000 | 0.0081 (3) | |
Al9 | 0.36802 (7) | 0.71228 (13) | 0.11008 (8) | 0.0077 (2) | |
Al10 | 0.24072 (10) | 0.500000 | −0.03857 (13) | 0.0118 (3) | |
Al11 | 0.08628 (9) | 0.500000 | −0.21245 (11) | 0.0041 (3) | |
Al12 | 0.06612 (10) | 0.500000 | 0.17389 (11) | 0.0079 (3) | |
Al13 | 0.18526 (7) | 0.71741 (13) | 0.11114 (8) | 0.0067 (2) | |
Al14 | 0.17782 (7) | 0.72118 (13) | 0.33455 (8) | 0.0081 (2) | |
Al15 | 0.07414 (9) | 0.500000 | 0.58060 (11) | 0.0068 (3) | |
Fe1 | 0.40231 (4) | 0.500000 | −0.01441 (5) | 0.00449 (16) | |
Fe2 | 0.08507 (4) | 0.500000 | 0.38222 (5) | 0.0057 (2) | 0.827 (16) |
Cu2 | 0.08507 (4) | 0.500000 | 0.38222 (5) | 0.0057 (2) | 0.173 (16) |
Fe3 | 0.09041 (4) | 0.500000 | −0.01203 (5) | 0.00434 (16) | |
Fe4 | 0.68011 (3) | 0.79257 (6) | 0.72198 (4) | 0.00551 (13) | |
Fe5 | 0.59919 (4) | 0.500000 | 0.37535 (5) | 0.00489 (15) |
U11 | U22 | U33 | U12 | U13 | U23 | |
Al1 | 0.0104 (9) | 0.0077 (9) | 0.0144 (9) | 0.000 | 0.0082 (7) | 0.000 |
Cu1 | 0.0104 (9) | 0.0077 (9) | 0.0144 (9) | 0.000 | 0.0082 (7) | 0.000 |
Al2 | 0.0183 (9) | 0.0072 (8) | 0.0132 (8) | 0.000 | 0.0040 (7) | 0.000 |
Al3 | 0.0100 (5) | 0.0113 (6) | 0.0066 (5) | −0.0016 (5) | 0.0031 (4) | −0.0020 (4) |
Al4 | 0.0066 (7) | 0.0062 (8) | 0.0090 (7) | 0.000 | 0.0006 (6) | 0.000 |
Al5 | 0.0066 (7) | 0.0088 (8) | 0.0189 (8) | 0.000 | −0.0011 (6) | 0.000 |
Al6 | 0.0068 (5) | 0.0108 (6) | 0.0090 (5) | −0.0036 (4) | 0.0001 (4) | 0.0009 (4) |
Al7 | 0.0062 (7) | 0.0101 (8) | 0.0059 (7) | 0.000 | 0.0000 (6) | 0.000 |
Al8 | 0.0070 (7) | 0.0064 (8) | 0.0113 (7) | 0.000 | 0.0031 (6) | 0.000 |
Al9 | 0.0076 (5) | 0.0093 (6) | 0.0060 (5) | 0.0016 (4) | 0.0016 (4) | −0.0008 (4) |
Al10 | 0.0048 (7) | 0.0097 (8) | 0.0221 (8) | 0.000 | 0.0061 (6) | 0.000 |
Al11 | 0.0069 (7) | 0.0008 (7) | 0.0050 (6) | 0.000 | 0.0025 (5) | 0.000 |
Al12 | 0.0080 (7) | 0.0084 (8) | 0.0074 (7) | 0.000 | 0.0023 (6) | 0.000 |
Al13 | 0.0059 (5) | 0.0089 (6) | 0.0050 (5) | −0.0015 (4) | 0.0011 (4) | −0.0013 (4) |
Al14 | 0.0097 (5) | 0.0086 (6) | 0.0072 (5) | −0.0023 (4) | 0.0044 (4) | −0.0010 (4) |
Al15 | 0.0078 (7) | 0.0055 (8) | 0.0068 (7) | 0.000 | 0.0018 (6) | 0.000 |
Fe1 | 0.0036 (3) | 0.0049 (4) | 0.0050 (3) | 0.000 | 0.0015 (3) | 0.000 |
Fe2 | 0.0058 (4) | 0.0055 (4) | 0.0062 (3) | 0.000 | 0.0024 (3) | 0.000 |
Cu2 | 0.0058 (4) | 0.0055 (4) | 0.0062 (3) | 0.000 | 0.0024 (3) | 0.000 |
Fe3 | 0.0037 (3) | 0.0049 (4) | 0.0044 (3) | 0.000 | 0.0013 (3) | 0.000 |
Fe4 | 0.0045 (2) | 0.0067 (3) | 0.0053 (2) | 0.0003 (2) | 0.00140 (18) | −0.00024 (18) |
Fe5 | 0.0047 (3) | 0.0043 (4) | 0.0047 (3) | 0.000 | 0.0000 (2) | 0.000 |
Al1—Fe5 | 2.4975 (7) | Al7—Al6 | 2.8672 (15) |
Al1—Fe5i | 2.4976 (7) | Al7—Al6iii | 2.8672 (15) |
Al1—Al6 | 2.7889 (11) | Al7—Al8xiii | 2.8801 (14) |
Al1—Al6i | 2.7889 (11) | Al7—Al8 | 2.8801 (14) |
Al1—Al6ii | 2.7889 (11) | Al8—Fe3v | 2.4942 (13) |
Al1—Al6iii | 2.7889 (11) | Al8—Fe3xiv | 2.4942 (13) |
Cu1—Fe5 | 2.4975 (7) | Al8—Fe1xiii | 2.4944 (13) |
Cu1—Fe5i | 2.4976 (7) | Al8—Fe1 | 2.4945 (13) |
Cu1—Al6 | 2.7889 (11) | Al8—Al13iv | 2.7909 (10) |
Cu1—Al6i | 2.7889 (11) | Al8—Al13xiv | 2.7909 (10) |
Cu1—Al6ii | 2.7889 (11) | Al8—Al9 | 2.8044 (10) |
Cu1—Al6iii | 2.7889 (11) | Al8—Al9xv | 2.8044 (10) |
Al2—Fe4 | 2.3677 (5) | Al8—Al12v | 2.9188 (14) |
Al2—Fe4iii | 2.3677 (5) | Al8—Al12xiv | 2.9188 (14) |
Al2—Al3 | 2.9229 (16) | Al9—Fe1 | 2.4804 (11) |
Al2—Al3iii | 2.9229 (16) | Al9—Fe4ii | 2.5157 (11) |
Al2—Al9ii | 2.9834 (16) | Al9—Al11xiv | 2.6462 (12) |
Al2—Al9i | 2.9834 (16) | Al9—Al13xiv | 2.6918 (14) |
Al3—Fe4 | 2.4585 (11) | Al9—Fe3xiv | 2.7952 (11) |
Al3—Fe5 | 2.4665 (11) | Al9—Al13 | 2.8327 (14) |
Al3—Al14iv | 2.6616 (13) | Al9—Al10 | 2.8364 (16) |
Al3—Al15v | 2.6821 (12) | Al9—Al10xiv | 2.8516 (13) |
Al3—Cu1 | 2.6843 (10) | Al10—Fe1 | 2.4257 (15) |
Al3—Al1 | 2.6843 (10) | Al10—Fe3 | 2.4475 (15) |
Al3—Al6iii | 2.7452 (14) | Al10—Al11 | 2.694 (2) |
Al3—Al5vi | 2.7550 (13) | Al10—Al13xiv | 2.8277 (13) |
Al3—Fe2v | 2.8538 (11) | Al10—Al13xvi | 2.8277 (13) |
Al3—Al5 | 2.8762 (16) | Al10—Al13iii | 2.8820 (15) |
Al3—Al14ii | 2.8870 (15) | Al10—Al13 | 2.8820 (15) |
Al4—Fe4vii | 2.4891 (11) | Al11—Fe3 | 2.4842 (14) |
Al4—Fe4 | 2.4891 (11) | Al11—Fe4xvii | 2.5142 (11) |
Al4—Al7vi | 2.574 (2) | Al11—Fe4xviii | 2.5142 (11) |
Al4—Fe1viii | 2.6265 (15) | Al11—Al15xix | 2.5333 (19) |
Al4—Al14ii | 2.6785 (13) | Al11—Al12xx | 2.547 (2) |
Al4—Al14ix | 2.6785 (13) | Al11—Fe2xx | 2.8452 (15) |
Al4—Al13ix | 2.6872 (12) | Al12—Fe3 | 2.4627 (15) |
Al4—Al13ii | 2.6872 (12) | Al12—Cu2 | 2.5276 (15) |
Al4—Fe5vi | 2.7018 (16) | Al12—Fe2 | 2.5276 (15) |
Al4—Al10viii | 2.823 (2) | Al12—Fe3xx | 2.6391 (16) |
Al4—Al5vi | 2.827 (2) | Al12—Al13 | 2.8265 (15) |
Al5—Fe5 | 2.4423 (16) | Al12—Al13iii | 2.8265 (15) |
Al5—Fe2i | 2.5344 (16) | Al12—Al14 | 2.8460 (15) |
Al5—Al15i | 2.741 (2) | Al12—Al14iii | 2.8460 (15) |
Al5—Al14x | 2.8580 (14) | Al13—Fe3 | 2.4974 (11) |
Al5—Al14iv | 2.8580 (14) | Al13—Fe4ii | 2.5305 (11) |
Al5—Al14ii | 2.9875 (16) | Al13—Fe1xiv | 2.7431 (11) |
Al5—Al14i | 2.9875 (16) | Al13—Al14 | 2.8274 (14) |
Al6—Fe5 | 2.4528 (11) | Al14—Cu2 | 2.4776 (11) |
Al6—Fe4i | 2.5722 (11) | Al14—Fe2 | 2.4776 (11) |
Al6—Fe2x | 2.5994 (11) | Al14—Fe4ii | 2.5715 (11) |
Al6—Al11xi | 2.7013 (13) | Al14—Fe5xxi | 2.6847 (11) |
Al6—Al15xii | 2.7755 (13) | Al15—Fe2 | 2.5342 (15) |
Al6—Al9iii | 2.8292 (14) | Al15—Cu2 | 2.5342 (15) |
Al6—Al14x | 2.9077 (15) | Al15—Al15xxii | 2.549 (3) |
Al7—Fe1 | 2.4723 (15) | Al15—Fe4xxiii | 2.6185 (12) |
Al7—Fe5 | 2.4734 (15) | Al15—Fe4xxiv | 2.6185 (12) |
Al7—Fe1xiii | 2.5768 (15) | Al15—Fe2xxii | 2.6428 (15) |
Al7—Al9 | 2.8313 (15) | Fe1—Fe1xiii | 2.9337 (13) |
Al7—Al9iii | 2.8313 (15) | Fe3—Fe3xx | 2.9040 (13) |
Fe4vii—Al4—Fe4 | 84.80 (5) | Al13iii—Al10—Al13 | 75.23 (5) |
Fe4vii—Al4—Al7vi | 137.45 (3) | Fe3—Al11—Fe4xvii | 119.23 (4) |
Fe4—Al4—Al7vi | 137.45 (3) | Fe3—Al11—Fe4xviii | 119.23 (4) |
Fe4vii—Al4—Fe1viii | 114.75 (4) | Fe4xvii—Al11—Fe4xviii | 83.76 (5) |
Fe4—Al4—Fe1viii | 114.75 (4) | Fe3—Al11—Al15xix | 177.35 (7) |
Al7vi—Al4—Fe1viii | 59.40 (5) | Fe4xvii—Al11—Al15xix | 62.50 (4) |
Fe4vii—Al4—Al14ii | 128.98 (6) | Fe4xviii—Al11—Al15xix | 62.50 (4) |
Fe4—Al4—Al14ii | 59.55 (3) | Fe3—Al11—Al12xx | 63.26 (5) |
Al7vi—Al4—Al14ii | 83.15 (4) | Fe4xvii—Al11—Al12xx | 136.19 (3) |
Fe1viii—Al4—Al14ii | 113.07 (4) | Fe4xviii—Al11—Al12xx | 136.19 (3) |
Fe4vii—Al4—Al14ix | 59.55 (3) | Al15xix—Al11—Al12xx | 114.09 (7) |
Fe4—Al4—Al14ix | 128.98 (6) | Fe3—Al11—Al9xiv | 65.94 (3) |
Al7vi—Al4—Al14ix | 83.15 (4) | Fe4xvii—Al11—Al9xiv | 58.29 (3) |
Fe1viii—Al4—Al14ix | 113.07 (4) | Fe4xviii—Al11—Al9xiv | 130.46 (6) |
Al14ii—Al4—Al14ix | 114.76 (7) | Al15xix—Al11—Al9xiv | 114.74 (4) |
Fe4vii—Al4—Al13ix | 58.38 (3) | Al12xx—Al11—Al9xiv | 92.01 (4) |
Fe4—Al4—Al13ix | 128.55 (6) | Fe3—Al11—Al9xvi | 65.94 (3) |
Al7vi—Al4—Al13ix | 88.22 (4) | Fe4xvii—Al11—Al9xvi | 130.46 (6) |
Fe1viii—Al4—Al13ix | 62.15 (3) | Fe4xviii—Al11—Al9xvi | 58.29 (3) |
Al14ii—Al4—Al13ix | 171.37 (7) | Al15xix—Al11—Al9xvi | 114.74 (4) |
Al14ix—Al4—Al13ix | 63.60 (3) | Al12xx—Al11—Al9xvi | 92.01 (4) |
Fe4vii—Al4—Al13ii | 128.55 (6) | Al9xiv—Al11—Al9xvi | 123.22 (7) |
Fe4—Al4—Al13ii | 58.38 (3) | Fe3—Al11—Al10 | 56.23 (4) |
Al7vi—Al4—Al13ii | 88.22 (4) | Fe4xvii—Al11—Al10 | 78.70 (4) |
Fe1viii—Al4—Al13ii | 62.15 (3) | Fe4xviii—Al11—Al10 | 78.70 (4) |
Al14ii—Al4—Al13ii | 63.60 (3) | Al15xix—Al11—Al10 | 126.41 (7) |
Al14ix—Al4—Al13ii | 171.37 (7) | Al12xx—Al11—Al10 | 119.50 (7) |
Al13ix—Al4—Al13ii | 116.62 (7) | Al9xiv—Al11—Al10 | 64.54 (3) |
Fe4vii—Al4—Fe5vi | 111.81 (4) | Al9xvi—Al11—Al10 | 64.54 (3) |
Fe4—Al4—Fe5vi | 111.81 (4) | Fe3—Al11—Al6xi | 114.88 (4) |
Al7vi—Al4—Fe5vi | 55.86 (4) | Fe4xvii—Al11—Al6xi | 124.41 (6) |
Fe1viii—Al4—Fe5vi | 115.26 (6) | Fe4xviii—Al11—Al6xi | 58.97 (3) |
Al14ii—Al4—Fe5vi | 59.86 (3) | Al15xix—Al11—Al6xi | 63.94 (4) |
Al14ix—Al4—Fe5vi | 59.86 (3) | Al12xx—Al11—Al6xi | 79.83 (4) |
Al13ix—Al4—Fe5vi | 114.62 (4) | Al9xiv—Al11—Al6xi | 169.68 (6) |
Al13ii—Al4—Fe5vi | 114.62 (4) | Al9xvi—Al11—Al6xi | 63.87 (3) |
Fe4vii—Al4—Al10viii | 76.68 (4) | Al10—Al11—Al6xi | 125.06 (3) |
Fe4—Al4—Al10viii | 76.68 (4) | Fe3—Al11—Al6xxvi | 114.88 (4) |
Al7vi—Al4—Al10viii | 112.11 (6) | Fe4xvii—Al11—Al6xxvi | 58.97 (3) |
Fe1viii—Al4—Al10viii | 52.72 (4) | Fe4xviii—Al11—Al6xxvi | 124.41 (6) |
Al14ii—Al4—Al10viii | 122.14 (3) | Al15xix—Al11—Al6xxvi | 63.95 (4) |
Al14ix—Al4—Al10viii | 122.14 (3) | Al12xx—Al11—Al6xxvi | 79.83 (4) |
Al13ix—Al4—Al10viii | 61.70 (3) | Al9xiv—Al11—Al6xxvi | 63.87 (3) |
Al13ii—Al4—Al10viii | 61.70 (3) | Al9xvi—Al11—Al6xxvi | 169.68 (6) |
Fe5vi—Al4—Al10viii | 167.97 (7) | Al10—Al11—Al6xxvi | 125.06 (3) |
Fe4vii—Al4—Al5vi | 73.82 (4) | Al6xi—Al11—Al6xxvi | 108.08 (6) |
Fe4—Al4—Al5vi | 73.82 (4) | Fe3—Al11—Fe2xx | 118.84 (5) |
Al7vi—Al4—Al5vi | 108.23 (6) | Fe4xvii—Al11—Fe2xx | 104.89 (4) |
Fe1viii—Al4—Al5vi | 167.63 (7) | Fe4xviii—Al11—Fe2xx | 104.89 (4) |
Al14ii—Al4—Al5vi | 62.48 (4) | Al15xix—Al11—Fe2xx | 58.52 (4) |
Al14ix—Al4—Al5vi | 62.48 (4) | Al12xx—Al11—Fe2xx | 55.57 (4) |
Al13ix—Al4—Al5vi | 120.52 (3) | Al9xiv—Al11—Fe2xx | 114.26 (4) |
Al13ii—Al4—Al5vi | 120.52 (3) | Al9xvi—Al11—Fe2xx | 114.26 (4) |
Fe5vi—Al4—Al5vi | 52.38 (4) | Al10—Al11—Fe2xx | 175.07 (6) |
Al10viii—Al4—Al5vi | 139.65 (7) | Al6xi—Al11—Fe2xx | 55.82 (3) |
Fe4—Al2—Fe4iii | 177.84 (8) | Al6xxvi—Al11—Fe2xx | 55.82 (3) |
Fe4—Al2—Al3 | 54.16 (3) | Fe3—Al12—Cu2 | 165.30 (7) |
Fe4iii—Al2—Al3 | 127.32 (6) | Fe3—Al12—Fe2 | 165.30 (7) |
Fe4—Al2—Al3iii | 127.32 (6) | Fe3—Al12—Al11xx | 126.50 (7) |
Fe4iii—Al2—Al3iii | 54.16 (3) | Fe2—Al12—Al11xx | 68.20 (5) |
Al3—Al2—Al3iii | 73.17 (5) | Fe3—Al12—Fe3xx | 69.29 (4) |
Fe4—Al2—Al9ii | 54.63 (3) | Fe2—Al12—Fe3xx | 125.41 (6) |
Fe4iii—Al2—Al9ii | 124.91 (6) | Al11xx—Al12—Fe3xx | 57.21 (5) |
Al3—Al2—Al9ii | 102.72 (3) | Fe3—Al12—Al13 | 55.84 (3) |
Al3iii—Al2—Al9ii | 155.03 (7) | Cu2—Al12—Al13 | 113.87 (5) |
Fe4—Al2—Al9i | 124.91 (6) | Fe2—Al12—Al13 | 113.87 (5) |
Fe4iii—Al2—Al9i | 54.63 (3) | Al11xx—Al12—Al13 | 140.57 (3) |
Al3—Al2—Al9i | 155.02 (7) | Fe3xx—Al12—Al13 | 108.15 (5) |
Al3iii—Al2—Al9i | 102.72 (3) | Fe3—Al12—Al13iii | 55.84 (3) |
Al9ii—Al2—Al9i | 70.30 (5) | Fe2—Al12—Al13iii | 113.87 (5) |
Fe4—Al3—Fe5 | 149.72 (5) | Al11xx—Al12—Al13iii | 140.57 (3) |
Fe4—Al3—Al14iv | 141.13 (5) | Fe3xx—Al12—Al13iii | 108.15 (5) |
Fe5—Al3—Al14iv | 63.00 (3) | Al13—Al12—Al13iii | 76.98 (5) |
Fe4—Al3—Al15v | 61.06 (4) | Fe3—Al12—Al14 | 115.47 (5) |
Fe5—Al3—Al15v | 141.94 (5) | Cu2—Al12—Al14 | 54.52 (3) |
Al14iv—Al3—Al15v | 106.06 (5) | Fe2—Al12—Al14 | 54.52 (3) |
Fe4—Al3—Cu1 | 103.55 (4) | Al11xx—Al12—Al14 | 105.36 (5) |
Fe5—Al3—Cu1 | 57.82 (3) | Fe3xx—Al12—Al14 | 139.29 (3) |
Al14iv—Al3—Cu1 | 115.32 (4) | Al13—Al12—Al14 | 59.79 (4) |
Al15v—Al3—Cu1 | 104.45 (4) | Al13iii—Al12—Al14 | 106.24 (6) |
Fe4—Al3—Al1 | 103.55 (4) | Fe3—Al12—Al14iii | 115.47 (5) |
Fe5—Al3—Al1 | 57.82 (3) | Fe2—Al12—Al14iii | 54.52 (3) |
Al14iv—Al3—Al1 | 115.32 (4) | Al11xx—Al12—Al14iii | 105.36 (5) |
Al15v—Al3—Al1 | 104.45 (4) | Fe3xx—Al12—Al14iii | 139.29 (3) |
Fe4—Al3—Al6iii | 140.65 (5) | Al13—Al12—Al14iii | 106.24 (6) |
Fe5—Al3—Al6iii | 55.84 (3) | Al13iii—Al12—Al14iii | 59.79 (3) |
Al14iv—Al3—Al6iii | 65.04 (4) | Al14—Al12—Al14iii | 77.93 (6) |
Al15v—Al3—Al6iii | 86.19 (5) | Fe3—Al12—Al8xxiv | 54.43 (3) |
Al1—Al3—Al6iii | 61.80 (3) | Fe2—Al12—Al8xxiv | 132.07 (3) |
Fe4—Al3—Al5vi | 75.59 (4) | Al11xx—Al12—Al8xxiv | 90.35 (4) |
Fe5—Al3—Al5vi | 129.35 (5) | Fe3xx—Al12—Al8xxiv | 53.04 (3) |
Al14iv—Al3—Al5vi | 66.92 (5) | Al13—Al12—Al8xxiv | 109.66 (5) |
Al15v—Al3—Al5vi | 60.54 (4) | Al13iii—Al12—Al8xxiv | 58.10 (3) |
Al1—Al3—Al5vi | 163.70 (5) | Al14—Al12—Al8xxiv | 163.95 (6) |
Al6iii—Al3—Al5vi | 108.31 (5) | Al14iii—Al12—Al8xxiv | 95.00 (3) |
Fe4—Al3—Fe2v | 110.81 (4) | Fe3—Al12—Al8xiv | 54.43 (3) |
Fe5—Al3—Fe2v | 99.01 (4) | Fe2—Al12—Al8xiv | 132.07 (3) |
Al14iv—Al3—Fe2v | 53.25 (3) | Al11xx—Al12—Al8xiv | 90.35 (4) |
Al15v—Al3—Fe2v | 54.38 (4) | Fe3xx—Al12—Al8xiv | 53.04 (3) |
Al1—Al3—Fe2v | 113.45 (4) | Al13—Al12—Al8xiv | 58.10 (3) |
Al6iii—Al3—Fe2v | 55.28 (3) | Al13iii—Al12—Al8xiv | 109.66 (5) |
Al5vi—Al3—Fe2v | 53.69 (4) | Al14—Al12—Al8xiv | 95.00 (3) |
Fe4—Al3—Al5 | 114.19 (5) | Al14iii—Al12—Al8xiv | 163.95 (6) |
Fe5—Al3—Al5 | 53.74 (4) | Al8xxiv—Al12—Al8xiv | 88.03 (6) |
Al14iv—Al3—Al5 | 62.00 (4) | Fe3—Al13—Fe4ii | 149.09 (5) |
Al15v—Al3—Al5 | 156.54 (5) | Fe3—Al13—Al4ix | 149.09 (5) |
Cu1—Al3—Al5 | 99.00 (4) | Fe4ii—Al13—Al4ix | 56.89 (4) |
Al1—Al3—Al5 | 99.00 (4) | Fe3—Al13—Al9xiv | 65.06 (3) |
Al6iii—Al3—Al5 | 104.45 (5) | Fe4ii—Al13—Al9xiv | 135.38 (5) |
Al5vi—Al3—Al5 | 96.06 (3) | Al4ix—Al13—Al9xiv | 108.87 (5) |
Fe2v—Al3—Al5 | 114.79 (4) | Fe3—Al13—Fe1xiv | 101.39 (4) |
Fe4—Al3—Al14ii | 56.83 (3) | Fe4ii—Al13—Fe1xiv | 109.53 (4) |
Fe5—Al3—Al14ii | 115.75 (5) | Al4ix—Al13—Fe1xiv | 57.84 (4) |
Al14iv—Al3—Al14ii | 94.59 (4) | Al9xiv—Al13—Fe1xiv | 54.30 (3) |
Al15v—Al3—Al14ii | 100.92 (5) | Fe3—Al13—Al8xiv | 55.95 (4) |
Al1—Al3—Al14ii | 132.65 (4) | Fe4ii—Al13—Al8xiv | 148.11 (5) |
Al6iii—Al3—Al14ii | 159.63 (5) | Al4ix—Al13—Al8xiv | 93.86 (5) |
Al5vi—Al3—Al14ii | 60.82 (4) | Al9xiv—Al13—Al8xiv | 61.50 (3) |
Fe2v—Al3—Al14ii | 113.85 (4) | Fe1xiv—Al13—Al8xiv | 53.57 (4) |
Al5—Al3—Al14ii | 62.45 (4) | Fe3—Al13—Al12 | 54.68 (3) |
Fe4—Al3—Al2 | 51.32 (3) | Fe4ii—Al13—Al12 | 111.35 (5) |
Fe5—Al3—Al2 | 98.43 (4) | Al4ix—Al13—Al12 | 108.33 (5) |
Al14iv—Al3—Al2 | 143.85 (5) | Al9xiv—Al13—Al12 | 113.25 (5) |
Al15v—Al3—Al2 | 106.66 (5) | Fe1xiv—Al13—Al12 | 111.38 (4) |
Cu1—Al3—Al2 | 70.26 (4) | Al8xiv—Al13—Al12 | 62.61 (4) |
Al1—Al3—Al2 | 70.26 (4) | Fe3—Al13—Al14 | 114.97 (4) |
Al6iii—Al3—Al2 | 132.07 (5) | Fe4ii—Al13—Al14 | 57.04 (3) |
Al5vi—Al3—Al2 | 118.31 (5) | Al4ix—Al13—Al14 | 58.05 (4) |
Fe2v—Al3—Al2 | 160.96 (5) | Al9xiv—Al13—Al14 | 156.71 (5) |
Al5—Al3—Al2 | 81.93 (5) | Fe1xiv—Al13—Al14 | 105.20 (4) |
Al14ii—Al3—Al2 | 64.42 (4) | Al8xiv—Al13—Al14 | 98.32 (4) |
Fe5—Al5—Fe2i | 159.85 (7) | Al12—Al13—Al14 | 60.45 (4) |
Fe5—Al5—Al15i | 142.89 (7) | Fe3—Al13—Al10xiv | 126.27 (5) |
Fe2i—Al5—Al15i | 57.25 (4) | Fe4ii—Al13—Al10xiv | 75.96 (4) |
Fe5—Al5—Al3vi | 121.06 (4) | Al4ix—Al13—Al10xiv | 61.51 (4) |
Fe2i—Al5—Al3vi | 65.15 (4) | Al9xiv—Al13—Al10xiv | 61.79 (4) |
Al15i—Al5—Al3vi | 58.41 (3) | Fe1xiv—Al13—Al10xiv | 51.60 (3) |
Fe5—Al5—Al3xxv | 121.06 (4) | Al8xiv—Al13—Al10xiv | 102.58 (5) |
Fe2i—Al5—Al3xxv | 65.15 (4) | Al12—Al13—Al10xiv | 162.64 (5) |
Al15i—Al5—Al3xxv | 58.41 (3) | Al14—Al13—Al10xiv | 116.75 (5) |
Al3vi—Al5—Al3xxv | 113.47 (7) | Fe3—Al13—Al9 | 112.75 (4) |
Fe5—Al5—Al4vi | 61.19 (5) | Fe4ii—Al13—Al9 | 55.60 (3) |
Fe2i—Al5—Al4vi | 138.96 (7) | Al4ix—Al13—Al9 | 97.03 (5) |
Al15i—Al5—Al4vi | 81.70 (6) | Al9xiv—Al13—Al9 | 89.53 (4) |
Al3vi—Al5—Al4vi | 94.91 (5) | Fe1xiv—Al13—Al9 | 111.71 (4) |
Al3xxv—Al5—Al4vi | 94.91 (5) | Al8xiv—Al13—Al9 | 151.00 (4) |
Fe5—Al5—Al14x | 60.26 (3) | Al12—Al13—Al9 | 136.79 (5) |
Fe2i—Al5—Al14x | 126.18 (3) | Al14—Al13—Al9 | 110.25 (4) |
Al15i—Al5—Al14x | 100.22 (5) | Al10xiv—Al13—Al9 | 60.50 (4) |
Al3vi—Al5—Al14x | 148.06 (7) | Fe3—Al13—Al10 | 53.55 (3) |
Al3xxv—Al5—Al14x | 61.87 (3) | Fe4ii—Al13—Al10 | 110.34 (5) |
Al4vi—Al5—Al14x | 56.22 (3) | Al4ix—Al13—Al10 | 152.92 (5) |
Fe5—Al5—Al14iv | 60.26 (3) | Al9xiv—Al13—Al10 | 61.43 (4) |
Fe2i—Al5—Al14iv | 126.18 (3) | Fe1xiv—Al13—Al10 | 115.34 (4) |
Al15i—Al5—Al14iv | 100.22 (5) | Al8xiv—Al13—Al10 | 101.55 (5) |
Al3vi—Al5—Al14iv | 61.87 (3) | Al12—Al13—Al10 | 98.54 (4) |
Al3xxv—Al5—Al14iv | 148.06 (7) | Al14—Al13—Al10 | 139.16 (5) |
Al4vi—Al5—Al14iv | 56.22 (3) | Al10xiv—Al13—Al10 | 93.19 (3) |
Al14x—Al5—Al14iv | 104.25 (6) | Al9—Al13—Al10 | 59.51 (4) |
Fe5—Al5—Al3iii | 54.52 (4) | Fe2—Al14—Fe4ii | 146.58 (5) |
Fe2i—Al5—Al3iii | 110.94 (5) | Fe2—Al14—Al3xxiii | 67.35 (4) |
Al15i—Al5—Al3iii | 142.30 (3) | Fe4ii—Al14—Al3xxiii | 130.88 (5) |
Al3vi—Al5—Al3iii | 155.12 (6) | Fe2—Al14—Al4ix | 151.93 (6) |
Al3xxv—Al5—Al3iii | 83.93 (3) | Fe4ii—Al14—Al4ix | 56.56 (4) |
Al4vi—Al5—Al3iii | 101.38 (5) | Al3xxiii—Al14—Al4ix | 111.43 (5) |
Al14x—Al5—Al3iii | 55.31 (3) | Fe2—Al14—Fe5xxi | 103.42 (4) |
Al14iv—Al5—Al3iii | 112.77 (6) | Fe4ii—Al14—Fe5xxi | 109.77 (4) |
Fe5—Al5—Al3 | 54.52 (4) | Al3xxiii—Al14—Fe5xxi | 54.95 (3) |
Fe2i—Al5—Al3 | 110.94 (5) | Al4ix—Al14—Fe5xxi | 60.50 (4) |
Al15i—Al5—Al3 | 142.30 (3) | Cu2—Al14—Al13 | 115.49 (4) |
Al3vi—Al5—Al3 | 83.93 (3) | Fe2—Al14—Al13 | 115.49 (4) |
Al3xxv—Al5—Al3 | 155.12 (6) | Fe4ii—Al14—Al13 | 55.66 (3) |
Al4vi—Al5—Al3 | 101.38 (5) | Al3xxiii—Al14—Al13 | 164.61 (5) |
Al14x—Al5—Al3 | 112.77 (6) | Al4ix—Al14—Al13 | 58.35 (4) |
Al14iv—Al5—Al3 | 55.31 (3) | Fe5xxi—Al14—Al13 | 110.71 (4) |
Al3iii—Al5—Al3 | 74.56 (6) | Cu2—Al14—Al12 | 56.18 (4) |
Fe5—Al5—Al14ii | 113.06 (5) | Fe2—Al14—Al12 | 56.18 (4) |
Fe2i—Al5—Al14ii | 52.54 (3) | Fe4ii—Al14—Al12 | 109.50 (5) |
Al15i—Al5—Al14ii | 96.26 (5) | Al3xxiii—Al14—Al12 | 118.96 (5) |
Al3vi—Al5—Al14ii | 55.04 (3) | Al4ix—Al14—Al12 | 108.01 (5) |
Al3xxv—Al5—Al14ii | 115.39 (6) | Fe5xxi—Al14—Al12 | 116.70 (5) |
Al4vi—Al5—Al14ii | 143.20 (3) | Al13—Al14—Al12 | 59.76 (4) |
Al14x—Al5—Al14ii | 156.89 (6) | Fe2—Al14—Al5xxi | 129.43 (5) |
Al14iv—Al5—Al14ii | 88.51 (3) | Fe4ii—Al14—Al5xxi | 72.10 (4) |
Al3iii—Al5—Al14ii | 102.12 (5) | Al3xxiii—Al14—Al5xxi | 62.69 (5) |
Al3—Al5—Al14ii | 58.95 (4) | Al4ix—Al14—Al5xxi | 61.30 (4) |
Fe5—Al5—Al14i | 113.06 (5) | Fe5xxi—Al14—Al5xxi | 52.17 (3) |
Fe2i—Al5—Al14i | 52.54 (3) | Al13—Al14—Al5xxi | 114.73 (5) |
Al15i—Al5—Al14i | 96.26 (5) | Al12—Al14—Al5xxi | 166.75 (5) |
Al3vi—Al5—Al14i | 115.39 (6) | Fe2—Al14—Al3ii | 112.32 (4) |
Al3xxv—Al5—Al14i | 55.04 (3) | Fe4ii—Al14—Al3ii | 53.16 (3) |
Al4vi—Al5—Al14i | 143.20 (3) | Al3xxiii—Al14—Al3ii | 85.41 (4) |
Al14x—Al5—Al14i | 88.51 (3) | Al4ix—Al14—Al3ii | 95.21 (5) |
Al14iv—Al5—Al14i | 156.89 (6) | Fe5xxi—Al14—Al3ii | 108.64 (4) |
Al3iii—Al5—Al14i | 58.95 (4) | Al13—Al14—Al3ii | 106.17 (4) |
Al3—Al5—Al14i | 102.12 (5) | Al12—Al14—Al3ii | 134.62 (5) |
Al14ii—Al5—Al14i | 73.60 (5) | Al5xxi—Al14—Al3ii | 57.31 (4) |
Fe5—Al1—Fe5i | 180.0 | Fe2—Al14—Al6xxi | 57.05 (3) |
Fe5—Al1—Al3 | 56.71 (2) | Fe4ii—Al14—Al6xxi | 153.47 (5) |
Fe5i—Al1—Al3 | 123.29 (2) | Al3xxiii—Al14—Al6xxi | 58.87 (4) |
Fe5—Al1—Al3i | 123.29 (2) | Al4ix—Al14—Al6xxi | 97.32 (5) |
Fe5i—Al1—Al3i | 56.71 (2) | Fe5xxi—Al14—Al6xxi | 51.84 (3) |
Al3—Al1—Al3i | 180.0 | Al13—Al14—Al6xxi | 108.91 (4) |
Fe5—Al1—Al3iii | 56.71 (2) | Al12—Al14—Al6xxi | 71.69 (4) |
Fe5i—Al1—Al3iii | 123.29 (2) | Al5xxi—Al14—Al6xxi | 100.84 (5) |
Al3—Al1—Al3iii | 80.93 (5) | Al3ii—Al14—Al6xxi | 144.27 (5) |
Al3i—Al1—Al3iii | 99.07 (5) | Fe2—Al14—Al5i | 54.29 (3) |
Fe5—Al1—Al3ii | 123.29 (2) | Fe4ii—Al14—Al5i | 107.32 (5) |
Fe5i—Al1—Al3ii | 56.71 (2) | Al3xxiii—Al14—Al5i | 58.03 (4) |
Al3—Al1—Al3ii | 99.07 (5) | Al4ix—Al14—Al5i | 150.77 (5) |
Al3i—Al1—Al3ii | 80.93 (5) | Fe5xxi—Al14—Al5i | 112.58 (4) |
Al3iii—Al1—Al3ii | 180.00 (4) | Al13—Al14—Al5i | 136.71 (5) |
Fe5—Al1—Al6 | 54.96 (2) | Al12—Al14—Al5i | 100.31 (4) |
Fe5i—Al1—Al6 | 125.04 (2) | Al5xxi—Al14—Al5i | 91.49 (3) |
Al3—Al1—Al6 | 111.58 (3) | Al3ii—Al14—Al5i | 58.60 (4) |
Al3i—Al1—Al6 | 68.42 (3) | Al6xxi—Al14—Al5i | 98.27 (4) |
Al3iii—Al1—Al6 | 60.17 (3) | Al11xxvii—Al15—Fe2 | 172.31 (7) |
Al3ii—Al1—Al6 | 119.83 (3) | Al11xxvii—Al15—Cu2 | 172.31 (7) |
Fe5—Al1—Al6i | 125.04 (2) | Al11xxvii—Al15—Al15xxii | 125.05 (9) |
Fe5i—Al1—Al6i | 54.96 (2) | Fe2—Al15—Al15xxii | 62.65 (6) |
Al3—Al1—Al6i | 68.42 (3) | Al11xxvii—Al15—Fe4xxiii | 58.39 (4) |
Al3i—Al1—Al6i | 111.58 (3) | Fe2—Al15—Fe4xxiii | 116.38 (4) |
Al3iii—Al1—Al6i | 119.83 (3) | Al15xxii—Al15—Fe4xxiii | 139.47 (3) |
Al3ii—Al1—Al6i | 60.17 (3) | Al11xxvii—Al15—Fe4xxiv | 58.39 (4) |
Al6—Al1—Al6i | 180.0 | Fe2—Al15—Fe4xxiv | 116.38 (4) |
Fe5—Al1—Al6ii | 125.04 (2) | Al15xxii—Al15—Fe4xxiv | 139.47 (3) |
Fe5i—Al1—Al6ii | 54.96 (2) | Fe4xxiii—Al15—Fe4xxiv | 79.73 (4) |
Al3—Al1—Al6ii | 119.83 (3) | Al11xxvii—Al15—Fe2xxii | 66.65 (5) |
Al3i—Al1—Al6ii | 60.17 (3) | Fe2—Al15—Fe2xxii | 121.04 (5) |
Al3iii—Al1—Al6ii | 68.42 (3) | Al15xxii—Al15—Fe2xxii | 58.40 (5) |
Al3ii—Al1—Al6ii | 111.58 (3) | Fe4xxiii—Al15—Fe2xxii | 107.89 (4) |
Al6—Al1—Al6ii | 96.39 (4) | Fe4xxiv—Al15—Fe2xxii | 107.89 (4) |
Al6i—Al1—Al6ii | 83.62 (4) | Al11xxvii—Al15—Al3xxiii | 110.88 (4) |
Fe5—Al1—Al6iii | 54.96 (2) | Fe2—Al15—Al3xxiii | 66.27 (3) |
Fe5i—Al1—Al6iii | 125.04 (2) | Al15xxii—Al15—Al3xxiii | 95.53 (5) |
Al3—Al1—Al6iii | 60.17 (3) | Fe4xxiii—Al15—Al3xxiii | 55.25 (3) |
Al3i—Al1—Al6iii | 119.83 (3) | Fe4xxiv—Al15—Al3xxiii | 122.08 (6) |
Al3iii—Al1—Al6iii | 111.58 (3) | Fe2xxii—Al15—Al3xxiii | 118.62 (3) |
Al3ii—Al1—Al6iii | 68.42 (3) | Al11xxvii—Al15—Al3xxiv | 110.88 (4) |
Al6—Al1—Al6iii | 83.61 (4) | Fe2—Al15—Al3xxiv | 66.26 (3) |
Al6i—Al1—Al6iii | 96.38 (4) | Al15xxii—Al15—Al3xxiv | 95.53 (5) |
Al6ii—Al1—Al6iii | 180.0 | Fe4xxiii—Al15—Al3xxiv | 122.08 (6) |
Fe5—Cu1—Fe5i | 180.0 | Fe4xxiv—Al15—Al3xxiv | 55.25 (3) |
Fe5—Cu1—Al3 | 56.71 (2) | Fe2xxii—Al15—Al3xxiv | 118.62 (3) |
Fe5i—Cu1—Al3 | 123.29 (2) | Al3xxiii—Al15—Al3xxiv | 118.38 (7) |
Fe5—Cu1—Al3i | 123.29 (2) | Al11xxvii—Al15—Al5i | 115.05 (7) |
Fe5i—Cu1—Al3i | 56.71 (2) | Fe2—Al15—Al5i | 57.26 (4) |
Al3—Cu1—Al3i | 180.0 | Al15xxii—Al15—Al5i | 119.91 (8) |
Fe5—Cu1—Al3iii | 56.71 (2) | Fe4xxiii—Al15—Al5i | 73.37 (4) |
Fe5i—Cu1—Al3iii | 123.29 (2) | Fe4xxiv—Al15—Al5i | 73.37 (4) |
Al3—Cu1—Al3iii | 80.93 (5) | Fe2xxii—Al15—Al5i | 178.30 (7) |
Al3i—Cu1—Al3iii | 99.07 (5) | Al3xxiii—Al15—Al5i | 61.05 (3) |
Fe5—Cu1—Al3ii | 123.29 (2) | Al3xxiv—Al15—Al5i | 61.05 (3) |
Fe5i—Cu1—Al3ii | 56.71 (2) | Al11xxvii—Al15—Al6xxviii | 60.97 (4) |
Al3—Cu1—Al3ii | 99.07 (5) | Fe2—Al15—Al6xxviii | 122.12 (4) |
Al3i—Cu1—Al3ii | 80.93 (5) | Al15xxii—Al15—Al6xxviii | 88.17 (5) |
Al3iii—Cu1—Al3ii | 180.00 (4) | Fe4xxiii—Al15—Al6xxviii | 56.87 (3) |
Fe5—Cu1—Al6 | 54.96 (2) | Fe4xxiv—Al15—Al6xxviii | 117.61 (5) |
Fe5i—Cu1—Al6 | 125.04 (2) | Fe2xxii—Al15—Al6xxviii | 57.27 (3) |
Al3—Cu1—Al6 | 111.58 (3) | Al3xxiii—Al15—Al6xxviii | 68.65 (3) |
Al3i—Cu1—Al6 | 68.42 (3) | Al3xxiv—Al15—Al6xxviii | 171.54 (6) |
Al3iii—Cu1—Al6 | 60.17 (3) | Al5i—Al15—Al6xxviii | 123.31 (4) |
Al3ii—Cu1—Al6 | 119.83 (3) | Al11xxvii—Al15—Al6xii | 60.97 (4) |
Fe5—Cu1—Al6i | 125.04 (2) | Fe2—Al15—Al6xii | 122.12 (4) |
Fe5i—Cu1—Al6i | 54.96 (2) | Al15xxii—Al15—Al6xii | 88.17 (5) |
Al3—Cu1—Al6i | 68.42 (3) | Fe4xxiii—Al15—Al6xii | 117.61 (5) |
Al3i—Cu1—Al6i | 111.58 (3) | Fe4xxiv—Al15—Al6xii | 56.87 (3) |
Al3iii—Cu1—Al6i | 119.83 (3) | Fe2xxii—Al15—Al6xii | 57.27 (3) |
Al3ii—Cu1—Al6i | 60.17 (3) | Al3xxiii—Al15—Al6xii | 171.54 (6) |
Al6—Cu1—Al6i | 180.0 | Al3xxiv—Al15—Al6xii | 68.65 (3) |
Fe5—Cu1—Al6ii | 125.04 (2) | Al5i—Al15—Al6xii | 123.31 (4) |
Fe5i—Cu1—Al6ii | 54.96 (2) | Al6xxviii—Al15—Al6xii | 103.96 (6) |
Al3—Cu1—Al6ii | 119.83 (3) | Al2—Fe4—Al3 | 74.52 (5) |
Al3i—Cu1—Al6ii | 60.17 (3) | Al2—Fe4—Al4 | 133.36 (5) |
Al3iii—Cu1—Al6ii | 68.42 (3) | Al3—Fe4—Al4 | 112.44 (4) |
Al3ii—Cu1—Al6ii | 111.58 (3) | Al2—Fe4—Al11viii | 131.51 (5) |
Al6—Cu1—Al6ii | 96.39 (4) | Al3—Fe4—Al11viii | 119.51 (4) |
Al6i—Cu1—Al6ii | 83.62 (4) | Al4—Fe4—Al11viii | 86.96 (4) |
Fe5—Cu1—Al6iii | 54.96 (2) | Al2—Fe4—Al9ii | 75.25 (5) |
Fe5i—Cu1—Al6iii | 125.04 (2) | Al3—Fe4—Al9ii | 136.09 (4) |
Al3—Cu1—Al6iii | 60.17 (3) | Al4—Fe4—Al9ii | 111.46 (4) |
Al3i—Cu1—Al6iii | 119.83 (3) | Al11viii—Fe4—Al9ii | 63.48 (4) |
Al3iii—Cu1—Al6iii | 111.58 (3) | Al2—Fe4—Al13ii | 77.16 (5) |
Al3ii—Cu1—Al6iii | 68.42 (3) | Al3—Fe4—Al13ii | 132.64 (4) |
Al6—Cu1—Al6iii | 83.61 (4) | Al4—Fe4—Al13ii | 64.73 (4) |
Al6i—Cu1—Al6iii | 96.38 (4) | Al11viii—Fe4—Al13ii | 107.72 (4) |
Al6ii—Cu1—Al6iii | 180.0 | Al9ii—Fe4—Al13ii | 68.30 (3) |
Fe1—Al7—Fe5 | 162.97 (7) | Al2—Fe4—Al14ii | 77.54 (5) |
Fe1—Al7—Al4vi | 132.34 (7) | Al3—Fe4—Al14ii | 70.01 (4) |
Fe5—Al7—Al4vi | 64.70 (5) | Al4—Fe4—Al14ii | 63.89 (4) |
Fe1—Al7—Fe1xiii | 71.01 (4) | Al11viii—Fe4—Al14ii | 150.05 (4) |
Fe5—Al7—Fe1xiii | 126.02 (6) | Al9ii—Fe4—Al14ii | 131.78 (4) |
Al4vi—Al7—Fe1xiii | 61.32 (5) | Al13ii—Fe4—Al14ii | 67.30 (3) |
Fe1—Al7—Al9 | 55.27 (3) | Al2—Fe4—Al6i | 77.69 (5) |
Fe5—Al7—Al9 | 112.48 (5) | Al3—Fe4—Al6i | 75.42 (4) |
Al4vi—Al7—Al9 | 142.52 (3) | Al4—Fe4—Al6i | 148.71 (4) |
Fe1xiii—Al7—Al9 | 109.81 (5) | Al11viii—Fe4—Al6i | 64.15 (4) |
Fe1—Al7—Al9iii | 55.27 (3) | Al9ii—Fe4—Al6i | 67.56 (3) |
Fe5—Al7—Al9iii | 112.48 (5) | Al13ii—Fe4—Al6i | 133.29 (4) |
Al4vi—Al7—Al9iii | 142.52 (3) | Al14ii—Fe4—Al6i | 141.63 (4) |
Fe1xiii—Al7—Al9iii | 109.81 (5) | Al2—Fe4—Al15v | 128.80 (5) |
Al9—Al7—Al9iii | 74.70 (5) | Al3—Fe4—Al15v | 63.69 (4) |
Fe1—Al7—Al6 | 114.77 (5) | Al4—Fe4—Al15v | 90.95 (4) |
Fe5—Al7—Al6 | 54.07 (3) | Al11viii—Fe4—Al15v | 59.11 (4) |
Al4vi—Al7—Al6 | 100.82 (5) | Al9ii—Fe4—Al15v | 116.35 (4) |
Fe1xiii—Al7—Al6 | 137.51 (3) | Al13ii—Fe4—Al15v | 153.92 (4) |
Al9—Al7—Al6 | 106.24 (5) | Al14ii—Fe4—Al15v | 111.77 (4) |
Al9iii—Al7—Al6 | 59.53 (3) | Al6i—Fe4—Al15v | 64.64 (4) |
Fe1—Al7—Al6iii | 114.77 (5) | Al5—Fe5—Al6iii | 130.42 (3) |
Fe5—Al7—Al6iii | 54.07 (3) | Al5—Fe5—Al6 | 130.42 (3) |
Al4vi—Al7—Al6iii | 100.82 (5) | Al6iii—Fe5—Al6 | 98.57 (5) |
Fe1xiii—Al7—Al6iii | 137.51 (3) | Al5—Fe5—Al3iii | 71.73 (4) |
Al9—Al7—Al6iii | 59.53 (3) | Al6iii—Fe5—Al3iii | 133.91 (4) |
Al9iii—Al7—Al6iii | 106.24 (5) | Al6—Fe5—Al3iii | 67.84 (4) |
Al6—Al7—Al6iii | 80.85 (6) | Al5—Fe5—Al3 | 71.73 (4) |
Fe1—Al7—Al8xiii | 54.92 (3) | Al6iii—Fe5—Al3 | 67.84 (4) |
Fe5—Al7—Al8xiii | 132.33 (3) | Al6—Fe5—Al3 | 133.91 (4) |
Al4vi—Al7—Al8xiii | 94.27 (4) | Al3iii—Fe5—Al3 | 89.87 (5) |
Fe1xiii—Al7—Al8xiii | 54.06 (3) | Al5—Fe5—Al7 | 125.88 (6) |
Al9—Al7—Al8xiii | 109.39 (5) | Al6iii—Fe5—Al7 | 71.19 (3) |
Al9iii—Al7—Al8xiii | 58.81 (3) | Al6—Fe5—Al7 | 71.18 (3) |
Al6—Al7—Al8xiii | 93.18 (3) | Al3iii—Fe5—Al7 | 134.27 (3) |
Al6iii—Al7—Al8xiii | 164.56 (6) | Al3—Fe5—Al7 | 134.27 (3) |
Fe1—Al7—Al8 | 54.92 (3) | Al5—Fe5—Al1 | 117.81 (4) |
Fe5—Al7—Al8 | 132.33 (3) | Al6iii—Fe5—Al1 | 68.57 (3) |
Al4vi—Al7—Al8 | 94.27 (4) | Al6—Fe5—Al1 | 68.57 (3) |
Fe1xiii—Al7—Al8 | 54.06 (3) | Al3iii—Fe5—Al1 | 65.47 (3) |
Al9—Al7—Al8 | 58.81 (3) | Al3—Fe5—Al1 | 65.47 (3) |
Al9iii—Al7—Al8 | 109.39 (5) | Al7—Fe5—Al1 | 116.31 (4) |
Al6—Al7—Al8 | 164.56 (6) | Al5—Fe5—Cu1 | 117.81 (4) |
Al6iii—Al7—Al8 | 93.18 (3) | Al6iii—Fe5—Cu1 | 68.57 (3) |
Al8xiii—Al7—Al8 | 88.94 (6) | Al6—Fe5—Cu1 | 68.57 (3) |
Fe5—Al6—Fe4i | 141.86 (5) | Al3iii—Fe5—Cu1 | 65.47 (3) |
Fe5—Al6—Fe2x | 106.68 (4) | Al3—Fe5—Cu1 | 65.47 (3) |
Fe4i—Al6—Fe2x | 110.67 (4) | Al7—Fe5—Cu1 | 116.31 (4) |
Fe5—Al6—Al11xi | 153.57 (6) | Al5—Fe5—Al14iv | 67.57 (3) |
Fe4i—Al6—Al11xi | 56.88 (4) | Al6iii—Fe5—Al14iv | 68.77 (3) |
Fe2x—Al6—Al11xi | 64.89 (4) | Al6—Fe5—Al14iv | 155.74 (4) |
Fe5—Al6—Al3iii | 56.32 (3) | Al3iii—Fe5—Al14iv | 135.91 (4) |
Fe4i—Al6—Al3iii | 137.44 (5) | Al3—Fe5—Al14iv | 62.05 (3) |
Fe2x—Al6—Al3iii | 64.48 (3) | Al7—Fe5—Al14iv | 84.94 (3) |
Al11xi—Al6—Al3iii | 128.18 (5) | Al1—Fe5—Al14iv | 121.24 (2) |
Fe5—Al6—Al15xii | 144.22 (5) | Al5—Fe5—Al14x | 67.57 (3) |
Fe4i—Al6—Al15xii | 58.49 (4) | Al6iii—Fe5—Al14x | 155.74 (4) |
Fe2x—Al6—Al15xii | 58.80 (4) | Al6—Fe5—Al14x | 68.77 (3) |
Al11xi—Al6—Al15xii | 55.08 (4) | Al3iii—Fe5—Al14x | 62.05 (3) |
Al3iii—Al6—Al15xii | 89.14 (5) | Al3—Fe5—Al14x | 135.91 (4) |
Fe5—Al6—Cu1 | 56.47 (3) | Al7—Fe5—Al14x | 84.94 (3) |
Fe4i—Al6—Cu1 | 97.80 (4) | Al1—Fe5—Al14x | 121.24 (2) |
Al11xi—Al6—Cu1 | 149.96 (5) | Al14iv—Fe5—Al14x | 114.34 (5) |
Al3iii—Al6—Cu1 | 58.03 (3) | Al5—Fe5—Al4vi | 66.44 (5) |
Al15xii—Al6—Cu1 | 99.33 (4) | Al6iii—Fe5—Al4vi | 108.92 (4) |
Fe5—Al6—Al1 | 56.47 (3) | Al6—Fe5—Al4vi | 108.92 (4) |
Fe4i—Al6—Al1 | 97.80 (4) | Al3iii—Fe5—Al4vi | 117.16 (4) |
Fe2x—Al6—Al1 | 118.47 (4) | Al3—Fe5—Al4vi | 117.17 (4) |
Al11xi—Al6—Al1 | 149.96 (5) | Al7—Fe5—Al4vi | 59.44 (5) |
Al3iii—Al6—Al1 | 58.03 (3) | Al1—Fe5—Al4vi | 175.75 (4) |
Al15xii—Al6—Al1 | 99.33 (4) | Al14iv—Fe5—Al4vi | 59.64 (3) |
Fe5—Al6—Al9iii | 113.21 (5) | Al14x—Fe5—Al4vi | 59.64 (3) |
Fe4i—Al6—Al9iii | 55.27 (3) | Al10—Fe1—Al7 | 123.94 (6) |
Fe2x—Al6—Al9iii | 116.33 (5) | Al10—Fe1—Al9iii | 70.63 (4) |
Al11xi—Al6—Al9iii | 57.12 (4) | Al7—Fe1—Al9iii | 69.73 (4) |
Al3iii—Al6—Al9iii | 167.13 (5) | Al10—Fe1—Al9 | 70.63 (4) |
Al15xii—Al6—Al9iii | 102.22 (5) | Al7—Fe1—Al9 | 69.73 (4) |
Al1—Al6—Al9iii | 124.69 (4) | Al9iii—Fe1—Al9 | 87.66 (5) |
Fe5—Al6—Al7 | 54.74 (4) | Al10—Fe1—Al8xiii | 126.02 (2) |
Fe4i—Al6—Al7 | 108.88 (4) | Al7—Fe1—Al8xiii | 70.88 (2) |
Fe2x—Al6—Al7 | 121.37 (5) | Al9iii—Fe1—Al8xiii | 68.63 (3) |
Al11xi—Al6—Al7 | 106.48 (5) | Al9—Fe1—Al8xiii | 139.09 (4) |
Al3iii—Al6—Al7 | 108.37 (5) | Al10—Fe1—Al8 | 126.02 (2) |
Al15xii—Al6—Al7 | 160.87 (5) | Al7—Fe1—Al8 | 70.88 (2) |
Cu1—Al6—Al7 | 96.58 (4) | Al9iii—Fe1—Al8 | 139.09 (4) |
Al1—Al6—Al7 | 96.58 (4) | Al9—Fe1—Al8 | 68.62 (3) |
Al9iii—Al6—Al7 | 59.60 (4) | Al8xiii—Fe1—Al8 | 107.96 (5) |
Fe5—Al6—Al14x | 59.39 (3) | Al10—Fe1—Al7xiii | 127.08 (5) |
Fe4i—Al6—Al14x | 156.65 (5) | Al7—Fe1—Al7xiii | 108.99 (4) |
Fe2x—Al6—Al14x | 53.11 (3) | Al9iii—Fe1—Al7xiii | 135.32 (3) |
Al11xi—Al6—Al14x | 99.81 (5) | Al9—Fe1—Al7xiii | 135.32 (3) |
Al3iii—Al6—Al14x | 56.09 (3) | Al8xiii—Fe1—Al7xiii | 69.19 (2) |
Al15xii—Al6—Al14x | 111.41 (5) | Al8—Fe1—Al7xiii | 69.19 (2) |
Al1—Al6—Al14x | 104.89 (4) | Al10—Fe1—Al4xviii | 67.80 (5) |
Al9iii—Al6—Al14x | 113.16 (5) | Al7—Fe1—Al4xviii | 168.26 (5) |
Al7—Al6—Al14x | 74.26 (4) | Al9iii—Fe1—Al4xviii | 117.90 (4) |
Fe3v—Al8—Fe3xiv | 71.20 (5) | Al9—Fe1—Al4xviii | 117.90 (4) |
Fe3v—Al8—Fe1xiii | 108.862 (18) | Al8xiii—Fe1—Al4xviii | 102.79 (3) |
Fe3xiv—Al8—Fe1xiii | 172.76 (2) | Al8—Fe1—Al4xviii | 102.79 (3) |
Fe3v—Al8—Fe1 | 172.76 (2) | Al7xiii—Fe1—Al4xviii | 59.28 (5) |
Fe3xiv—Al8—Fe1 | 108.861 (18) | Al10—Fe1—Al13xvi | 66.00 (3) |
Fe1xiii—Al8—Fe1 | 72.04 (5) | Al7—Fe1—Al13xvi | 122.50 (2) |
Fe3v—Al8—Al13iv | 56.06 (3) | Al9iii—Fe1—Al13xvi | 61.80 (3) |
Fe3xiv—Al8—Al13iv | 113.68 (5) | Al9—Fe1—Al13xvi | 132.99 (4) |
Fe1xiii—Al8—Al13iv | 62.23 (3) | Al8xiii—Fe1—Al13xvi | 64.19 (3) |
Fe1—Al8—Al13iv | 128.44 (5) | Al8—Fe1—Al13xvi | 155.93 (4) |
Fe3v—Al8—Al13xiv | 113.68 (5) | Al7xiii—Fe1—Al13xvi | 86.96 (3) |
Fe3xiv—Al8—Al13xiv | 56.06 (3) | Al4xviii—Fe1—Al13xvi | 60.01 (3) |
Fe1xiii—Al8—Al13xiv | 128.44 (5) | Al10—Fe1—Al13xiv | 66.00 (3) |
Fe1—Al8—Al13xiv | 62.23 (3) | Al7—Fe1—Al13xiv | 122.50 (2) |
Al13iv—Al8—Al13xiv | 168.94 (7) | Al9iii—Fe1—Al13xiv | 132.99 (4) |
Fe3v—Al8—Al9 | 128.48 (5) | Al9—Fe1—Al13xiv | 61.80 (3) |
Fe3xiv—Al8—Al9 | 63.36 (3) | Al8xiii—Fe1—Al13xiv | 155.93 (3) |
Fe1xiii—Al8—Al9 | 113.21 (5) | Al8—Fe1—Al13xiv | 64.19 (3) |
Fe1—Al8—Al9 | 55.45 (3) | Al7xiii—Fe1—Al13xiv | 86.96 (3) |
Al13iv—Al8—Al9 | 123.90 (3) | Al4xviii—Fe1—Al13xiv | 60.01 (2) |
Al13xiv—Al8—Al9 | 57.51 (3) | Al13xvi—Fe1—Al13xiv | 112.93 (5) |
Fe3v—Al8—Al9xv | 63.36 (3) | Al10—Fe1—Fe1xiii | 179.91 (5) |
Fe3xiv—Al8—Al9xv | 128.48 (5) | Al7—Fe1—Fe1xiii | 56.16 (4) |
Fe1xiii—Al8—Al9xv | 55.45 (3) | Al9iii—Fe1—Fe1xiii | 109.43 (3) |
Fe1—Al8—Al9xv | 113.21 (5) | Al9—Fe1—Fe1xiii | 109.43 (3) |
Al13iv—Al8—Al9xv | 57.51 (3) | Al8xiii—Fe1—Fe1xiii | 53.98 (2) |
Al13xiv—Al8—Al9xv | 123.90 (3) | Al8—Fe1—Fe1xiii | 53.98 (2) |
Al9—Al8—Al9xv | 167.72 (7) | Al7xiii—Fe1—Fe1xiii | 52.83 (4) |
Fe3v—Al8—Al7xiii | 117.58 (3) | Al4xviii—Fe1—Fe1xiii | 112.11 (4) |
Fe3xiv—Al8—Al7xiii | 132.55 (3) | Al13xvi—Fe1—Fe1xiii | 113.96 (3) |
Fe1xiii—Al8—Al7xiii | 54.20 (4) | Al13xiv—Fe1—Fe1xiii | 113.96 (3) |
Fe1—Al8—Al7xiii | 56.75 (4) | Al10—Fe3—Al12 | 123.53 (6) |
Al13iv—Al8—Al7xiii | 107.52 (4) | Al10—Fe3—Al11 | 66.23 (5) |
Al13xiv—Al8—Al7xiii | 80.44 (4) | Al12—Fe3—Al11 | 170.24 (6) |
Al9—Al8—Al7xiii | 110.75 (5) | Al10—Fe3—Al8xxiv | 125.58 (2) |
Al9xv—Al8—Al7xiii | 59.73 (4) | Al12—Fe3—Al8xxiv | 72.15 (2) |
Fe3v—Al8—Al7 | 132.55 (3) | Al11—Fe3—Al8xxiv | 102.61 (3) |
Fe3xiv—Al8—Al7 | 117.58 (3) | Al10—Fe3—Al8xiv | 125.58 (2) |
Fe1xiii—Al8—Al7 | 56.75 (4) | Al12—Fe3—Al8xiv | 72.15 (2) |
Fe1—Al8—Al7 | 54.20 (4) | Al11—Fe3—Al8xiv | 102.61 (3) |
Al13iv—Al8—Al7 | 80.44 (4) | Al8xxiv—Fe3—Al8xiv | 108.80 (5) |
Al13xiv—Al8—Al7 | 107.52 (4) | Al10—Fe3—Al13iii | 71.29 (4) |
Al9—Al8—Al7 | 59.73 (4) | Al12—Fe3—Al13iii | 69.48 (4) |
Al9xv—Al8—Al7 | 110.75 (5) | Al11—Fe3—Al13iii | 116.75 (4) |
Al7xiii—Al8—Al7 | 91.06 (6) | Al8xxiv—Fe3—Al13iii | 67.99 (3) |
Fe3v—Al8—Al12v | 53.42 (4) | Al8xiv—Fe3—Al13iii | 140.41 (4) |
Fe3xiv—Al8—Al12v | 57.72 (4) | Al10—Fe3—Al13 | 71.29 (4) |
Fe1xiii—Al8—Al12v | 116.18 (3) | Al12—Fe3—Al13 | 69.48 (4) |
Fe1—Al8—Al12v | 133.06 (3) | Al11—Fe3—Al13 | 116.75 (4) |
Al13iv—Al8—Al12v | 59.29 (4) | Al8xxiv—Fe3—Al13 | 140.41 (4) |
Al13xiv—Al8—Al12v | 112.13 (5) | Al8xiv—Fe3—Al13 | 67.99 (3) |
Al9—Al8—Al12v | 81.49 (4) | Al13iii—Fe3—Al13 | 89.56 (5) |
Al9xv—Al8—Al12v | 107.25 (4) | Al10—Fe3—Al12xx | 125.76 (5) |
Al7xiii—Al8—Al12v | 166.33 (4) | Al12—Fe3—Al12xx | 110.71 (4) |
Al7—Al8—Al12v | 90.10 (3) | Al11—Fe3—Al12xx | 59.53 (5) |
Fe3v—Al8—Al12xiv | 57.72 (4) | Al8xxiv—Fe3—Al12xx | 69.24 (2) |
Fe3xiv—Al8—Al12xiv | 53.42 (4) | Al8xiv—Fe3—Al12xx | 69.24 (2) |
Fe1xiii—Al8—Al12xiv | 133.06 (3) | Al13iii—Fe3—Al12xx | 134.53 (3) |
Fe1—Al8—Al12xiv | 116.18 (3) | Al13—Fe3—Al12xx | 134.53 (3) |
Al13iv—Al8—Al12xiv | 112.13 (5) | Al10—Fe3—Al9xvi | 65.51 (3) |
Al13xiv—Al8—Al12xiv | 59.29 (4) | Al12—Fe3—Al9xvi | 122.33 (2) |
Al9—Al8—Al12xiv | 107.25 (4) | Al11—Fe3—Al9xvi | 59.82 (2) |
Al9xv—Al8—Al12xiv | 81.49 (4) | Al8xxiv—Fe3—Al9xvi | 63.74 (3) |
Al7xiii—Al8—Al12xiv | 90.10 (3) | Al8xiv—Fe3—Al9xvi | 155.76 (4) |
Al7—Al8—Al12xiv | 166.33 (4) | Al13iii—Fe3—Al9xvi | 60.83 (3) |
Al12v—Al8—Al12xiv | 91.97 (6) | Al13—Fe3—Al9xvi | 133.31 (4) |
Fe1—Al9—Fe4ii | 151.13 (5) | Al12xx—Fe3—Al9xvi | 86.83 (3) |
Fe1—Al9—Al11xiv | 146.65 (5) | Al10—Fe3—Al9xiv | 65.51 (3) |
Fe4ii—Al9—Al11xiv | 58.23 (4) | Al12—Fe3—Al9xiv | 122.33 (2) |
Fe1—Al9—Al13xiv | 63.91 (3) | Al11—Fe3—Al9xiv | 59.82 (2) |
Fe4ii—Al9—Al13xiv | 136.48 (5) | Al8xxiv—Fe3—Al9xiv | 155.76 (4) |
Al11xiv—Al9—Al13xiv | 105.24 (5) | Al8xiv—Fe3—Al9xiv | 63.74 (3) |
Fe1—Al9—Fe3xiv | 100.39 (4) | Al13iii—Fe3—Al9xiv | 133.31 (4) |
Fe4ii—Al9—Fe3xiv | 108.44 (4) | Al13—Fe3—Al9xiv | 60.83 (3) |
Al11xiv—Al9—Fe3xiv | 54.24 (4) | Al12xx—Fe3—Al9xiv | 86.83 (3) |
Al13xiv—Al9—Fe3xiv | 54.11 (3) | Al9xvi—Fe3—Al9xiv | 112.78 (5) |
Fe1—Al9—Al8 | 55.93 (4) | Al10—Fe3—Fe3xx | 178.25 (5) |
Fe4ii—Al9—Al8 | 145.71 (5) | Al12—Fe3—Fe3xx | 58.22 (4) |
Al11xiv—Al9—Al8 | 90.89 (5) | Al11—Fe3—Fe3xx | 112.02 (5) |
Al13xiv—Al9—Al8 | 60.99 (3) | Al8xxiv—Fe3—Fe3xx | 54.40 (2) |
Fe3xiv—Al9—Al8 | 52.90 (4) | Al8xiv—Fe3—Fe3xx | 54.40 (2) |
Fe1—Al9—Al6iii | 115.83 (5) | Al13iii—Fe3—Fe3xx | 109.88 (3) |
Fe4ii—Al9—Al6iii | 57.17 (3) | Al13—Fe3—Fe3xx | 109.88 (3) |
Al11xiv—Al9—Al6iii | 59.01 (4) | Al12xx—Fe3—Fe3xx | 52.49 (4) |
Al13xiv—Al9—Al6iii | 153.12 (5) | Al9xvi—Fe3—Fe3xx | 113.77 (3) |
Fe3xiv—Al9—Al6iii | 102.03 (4) | Al9xiv—Fe3—Fe3xx | 113.77 (3) |
Al8—Al9—Al6iii | 95.65 (4) | Al14iii—Fe2—Al14 | 92.50 (5) |
Fe1—Al9—Al7 | 55.00 (4) | Al14iii—Fe2—Al12 | 69.30 (3) |
Fe4ii—Al9—Al7 | 111.69 (5) | Al14—Fe2—Al12 | 69.30 (3) |
Al11xiv—Al9—Al7 | 109.06 (5) | Al14iii—Fe2—Al15 | 116.82 (3) |
Al13xiv—Al9—Al7 | 111.81 (5) | Al14—Fe2—Al15 | 116.82 (3) |
Fe3xiv—Al9—Al7 | 109.71 (4) | Al12—Fe2—Al15 | 170.01 (5) |
Al8—Al9—Al7 | 61.47 (4) | Al14iii—Fe2—Al5i | 73.17 (4) |
Al6iii—Al9—Al7 | 60.87 (4) | Al14—Fe2—Al5i | 73.17 (4) |
Fe1—Al9—Al13 | 114.71 (4) | Al12—Fe2—Al5i | 124.50 (5) |
Fe4ii—Al9—Al13 | 56.10 (3) | Al15—Fe2—Al5i | 65.49 (5) |
Al11xiv—Al9—Al13 | 96.02 (5) | Al14iii—Fe2—Al6xxix | 69.83 (3) |
Al13xiv—Al9—Al13 | 90.47 (4) | Al14—Fe2—Al6xxix | 150.51 (4) |
Fe3xiv—Al9—Al13 | 110.70 (4) | Al12—Fe2—Al6xxix | 82.17 (3) |
Al8—Al9—Al13 | 151.44 (4) | Al15—Fe2—Al6xxix | 92.49 (3) |
Al6iii—Al9—Al13 | 111.67 (4) | Al5i—Fe2—Al6xxix | 120.56 (3) |
Al7—Al9—Al13 | 139.54 (5) | Al14iii—Fe2—Al6xxi | 150.52 (4) |
Fe1—Al9—Al10 | 53.78 (4) | Al14—Fe2—Al6xxi | 69.83 (3) |
Fe4ii—Al9—Al10 | 112.26 (5) | Al12—Fe2—Al6xxi | 82.17 (3) |
Al11xiv—Al9—Al10 | 151.50 (5) | Al15—Fe2—Al6xxi | 92.49 (3) |
Al13xiv—Al9—Al10 | 61.46 (4) | Al5i—Fe2—Al6xxi | 120.56 (3) |
Fe3xiv—Al9—Al10 | 115.11 (4) | Al6xxix—Fe2—Al6xxi | 114.53 (5) |
Al8—Al9—Al10 | 102.02 (5) | Al14iii—Fe2—Al15xxii | 132.97 (3) |
Al6iii—Al9—Al10 | 142.43 (5) | Al14—Fe2—Al15xxii | 132.97 (3) |
Al7—Al9—Al10 | 99.43 (4) | Al12—Fe2—Al15xxii | 111.05 (5) |
Al13—Al9—Al10 | 61.11 (4) | Al15—Fe2—Al15xxii | 58.96 (5) |
Fe1—Al9—Al10xiv | 126.00 (5) | Al5i—Fe2—Al15xxii | 124.44 (5) |
Fe4ii—Al9—Al10xiv | 75.74 (4) | Al6xxix—Fe2—Al15xxii | 63.93 (3) |
Al11xiv—Al9—Al10xiv | 58.55 (4) | Al6xxi—Fe2—Al15xxii | 63.93 (3) |
Al13xiv—Al9—Al10xiv | 62.57 (4) | Al14iii—Fe2—Al11xx | 107.31 (3) |
Fe3xiv—Al9—Al10xiv | 51.36 (3) | Al14—Fe2—Al11xx | 107.31 (3) |
Al8—Al9—Al10xiv | 101.98 (5) | Al12—Fe2—Al11xx | 56.22 (4) |
Al6iii—Al9—Al10xiv | 114.86 (5) | Al15—Fe2—Al11xx | 113.79 (5) |
Al7—Al9—Al10xiv | 160.66 (5) | Al5i—Fe2—Al11xx | 179.28 (5) |
Al13—Al9—Al10xiv | 59.66 (4) | Al6xxix—Fe2—Al11xx | 59.29 (3) |
Al10—Al9—Al10xiv | 93.66 (3) | Al6xxi—Fe2—Al11xx | 59.29 (3) |
Fe1—Al9—Al2i | 101.02 (4) | Al15xxii—Fe2—Al11xx | 54.83 (4) |
Fe4ii—Al9—Al2i | 50.12 (3) | Al14iii—Fe2—Al3xxiii | 131.08 (4) |
Al11xiv—Al9—Al2i | 104.35 (4) | Al14—Fe2—Al3xxiii | 59.40 (3) |
Al13xiv—Al9—Al2i | 142.15 (5) | Al12—Fe2—Al3xxiii | 123.62 (3) |
Fe3xiv—Al9—Al2i | 158.17 (4) | Al15—Fe2—Al3xxiii | 59.35 (3) |
Al8—Al9—Al2i | 141.03 (5) | Al5i—Fe2—Al3xxiii | 61.16 (3) |
Al6iii—Al9—Al2i | 64.45 (4) | Al6xxix—Fe2—Al3xxiii | 149.49 (4) |
Al7—Al9—Al2i | 79.61 (4) | Al6xxi—Fe2—Al3xxiii | 60.24 (3) |
Al13—Al9—Al2i | 63.36 (4) | Al15xxii—Fe2—Al3xxiii | 89.55 (3) |
Al10—Al9—Al2i | 81.42 (5) | Al11xx—Fe2—Al3xxiii | 118.56 (3) |
Al10xiv—Al9—Al2i | 116.65 (5) | Al14iii—Fe2—Al3xxiv | 59.40 (3) |
Fe1—Al10—Fe3 | 165.79 (8) | Al14—Fe2—Al3xxiv | 131.08 (4) |
Fe1—Al10—Al11 | 136.67 (7) | Al12—Fe2—Al3xxiv | 123.62 (3) |
Fe3—Al10—Al11 | 57.54 (4) | Al15—Fe2—Al3xxiv | 59.35 (3) |
Fe1—Al10—Al4xviii | 59.48 (5) | Al5i—Fe2—Al3xxiv | 61.16 (3) |
Fe3—Al10—Al4xviii | 134.73 (7) | Al6xxix—Fe2—Al3xxiv | 60.24 (3) |
Al11—Al10—Al4xviii | 77.19 (6) | Al6xxi—Fe2—Al3xxiv | 149.49 (4) |
Fe1—Al10—Al13xiv | 62.40 (3) | Al15xxii—Fe2—Al3xxiv | 89.55 (3) |
Fe3—Al10—Al13xiv | 122.55 (4) | Al11xx—Fe2—Al3xxiv | 118.56 (3) |
Al11—Al10—Al13xiv | 95.06 (5) | Al3xxiii—Fe2—Al3xxiv | 107.65 (5) |
Al4xviii—Al10—Al13xiv | 56.79 (3) | Al14iii—Cu2—Al14 | 92.50 (5) |
Fe1—Al10—Al13xvi | 62.40 (3) | Al14iii—Cu2—Al12 | 69.30 (3) |
Fe3—Al10—Al13xvi | 122.55 (4) | Al14—Cu2—Al12 | 69.30 (3) |
Al11—Al10—Al13xvi | 95.06 (5) | Al14iii—Cu2—Al15 | 116.82 (3) |
Al4xviii—Al10—Al13xvi | 56.79 (3) | Al14—Cu2—Al15 | 116.82 (3) |
Al13xiv—Al10—Al13xvi | 107.92 (6) | Al12—Cu2—Al15 | 170.01 (5) |
Fe1—Al10—Al9iii | 55.59 (4) | Al14iii—Cu2—Al5i | 73.17 (4) |
Fe3—Al10—Al9iii | 114.23 (5) | Al14—Cu2—Al5i | 73.17 (4) |
Al11—Al10—Al9iii | 142.71 (3) | Al12—Cu2—Al5i | 124.50 (5) |
Al4xviii—Al10—Al9iii | 101.28 (5) | Al15—Cu2—Al5i | 65.49 (5) |
Al13xiv—Al10—Al9iii | 115.53 (6) | Al14iii—Cu2—Al6xxix | 69.83 (3) |
Al13xvi—Al10—Al9iii | 56.75 (3) | Al14—Cu2—Al6xxix | 150.51 (4) |
Fe1—Al10—Al9 | 55.59 (4) | Al12—Cu2—Al6xxix | 82.17 (3) |
Fe3—Al10—Al9 | 114.23 (5) | Al15—Cu2—Al6xxix | 92.49 (3) |
Al11—Al10—Al9 | 142.71 (3) | Al5i—Cu2—Al6xxix | 120.56 (3) |
Al4xviii—Al10—Al9 | 101.28 (5) | Al14iii—Cu2—Al6xxi | 150.52 (4) |
Al13xiv—Al10—Al9 | 56.75 (3) | Al14—Cu2—Al6xxi | 69.83 (3) |
Al13xvi—Al10—Al9 | 115.53 (6) | Al12—Cu2—Al6xxi | 82.17 (3) |
Al9iii—Al10—Al9 | 74.54 (6) | Al15—Cu2—Al6xxi | 92.49 (3) |
Fe1—Al10—Al9xvi | 121.76 (4) | Al5i—Cu2—Al6xxi | 120.56 (3) |
Fe3—Al10—Al9xvi | 63.13 (3) | Al6xxix—Cu2—Al6xxi | 114.53 (5) |
Al11—Al10—Al9xvi | 56.91 (3) | Al14iii—Cu2—Al15xxii | 132.97 (3) |
Al4xviii—Al10—Al9xvi | 93.59 (4) | Al14—Cu2—Al15xxii | 132.97 (3) |
Al13xiv—Al10—Al9xvi | 144.87 (7) | Al12—Cu2—Al15xxii | 111.05 (5) |
Al13xvi—Al10—Al9xvi | 59.84 (3) | Al15—Cu2—Al15xxii | 58.96 (5) |
Al9iii—Al10—Al9xvi | 86.34 (3) | Al5i—Cu2—Al15xxii | 124.44 (5) |
Al9—Al10—Al9xvi | 157.66 (6) | Al6xxix—Cu2—Al15xxii | 63.93 (3) |
Fe1—Al10—Al9xiv | 121.76 (4) | Al6xxi—Cu2—Al15xxii | 63.93 (3) |
Fe3—Al10—Al9xiv | 63.13 (3) | Al14iii—Cu2—Al11xx | 107.31 (3) |
Al11—Al10—Al9xiv | 56.91 (3) | Al14—Cu2—Al11xx | 107.31 (3) |
Al4xviii—Al10—Al9xiv | 93.59 (4) | Al12—Cu2—Al11xx | 56.22 (4) |
Al13xiv—Al10—Al9xiv | 59.84 (3) | Al15—Cu2—Al11xx | 113.79 (5) |
Al13xvi—Al10—Al9xiv | 144.87 (7) | Al5i—Cu2—Al11xx | 179.28 (5) |
Al9iii—Al10—Al9xiv | 157.66 (6) | Al6xxix—Cu2—Al11xx | 59.29 (3) |
Al9—Al10—Al9xiv | 86.34 (3) | Al6xxi—Cu2—Al11xx | 59.29 (3) |
Al9xvi—Al10—Al9xiv | 109.45 (6) | Al15xxii—Cu2—Al11xx | 54.83 (4) |
Fe1—Al10—Al13iii | 114.78 (5) | Al14iii—Cu2—Al3xxiii | 131.08 (4) |
Fe3—Al10—Al13iii | 55.16 (3) | Al14—Cu2—Al3xxiii | 59.40 (3) |
Al11—Al10—Al13iii | 99.00 (5) | Al12—Cu2—Al3xxiii | 123.62 (3) |
Al4xviii—Al10—Al13iii | 142.36 (3) | Al15—Cu2—Al3xxiii | 59.35 (3) |
Al13xiv—Al10—Al13iii | 158.67 (6) | Al5i—Cu2—Al3xxiii | 61.16 (3) |
Al13xvi—Al10—Al13iii | 86.81 (3) | Al6xxix—Cu2—Al3xxiii | 149.49 (4) |
Al9iii—Al10—Al13iii | 59.38 (4) | Al6xxi—Cu2—Al3xxiii | 60.24 (3) |
Al9—Al10—Al13iii | 103.29 (6) | Al15xxii—Cu2—Al3xxiii | 89.55 (3) |
Al9xvi—Al10—Al13iii | 56.00 (3) | Al11xx—Cu2—Al3xxiii | 118.56 (3) |
Al9xiv—Al10—Al13iii | 115.94 (6) | Al14iii—Cu2—Al3xxiv | 59.40 (3) |
Fe1—Al10—Al13 | 114.78 (5) | Al14—Cu2—Al3xxiv | 131.08 (4) |
Fe3—Al10—Al13 | 55.16 (3) | Al12—Cu2—Al3xxiv | 123.62 (3) |
Al11—Al10—Al13 | 99.00 (5) | Al15—Cu2—Al3xxiv | 59.35 (3) |
Al4xviii—Al10—Al13 | 142.36 (3) | Al5i—Cu2—Al3xxiv | 61.16 (3) |
Al13xiv—Al10—Al13 | 86.81 (3) | Al6xxix—Cu2—Al3xxiv | 60.24 (3) |
Al13xvi—Al10—Al13 | 158.67 (6) | Al6xxi—Cu2—Al3xxiv | 149.49 (4) |
Al9iii—Al10—Al13 | 103.29 (6) | Al15xxii—Cu2—Al3xxiv | 89.55 (3) |
Al9—Al10—Al13 | 59.38 (4) | Al11xx—Cu2—Al3xxiv | 118.56 (3) |
Al9xvi—Al10—Al13 | 115.94 (6) | Al3xxiii—Cu2—Al3xxiv | 107.65 (5) |
Al9xiv—Al10—Al13 | 56.00 (3) |
Symmetry codes: (i) −x+1, −y+1, −z+1; (ii) −x+1, y, −z+1; (iii) x, −y+1, z; (iv) x+1/2, −y+3/2, z; (v) x+1/2, y+1/2, z; (vi) −x+3/2, −y+3/2, −z+1; (vii) x, −y+2, z; (viii) x+1/2, y+1/2, z+1; (ix) −x+1, −y+2, −z+1; (x) x+1/2, y−1/2, z; (xi) −x+1/2, −y+1/2, −z; (xii) −x+1/2, −y+1/2, −z+1; (xiii) −x+1, −y+1, −z; (xiv) −x+1/2, −y+3/2, −z; (xv) −x+1, y, −z; (xvi) −x+1/2, y−1/2, −z; (xvii) x−1/2, −y+3/2, z−1; (xviii) x−1/2, y−1/2, z−1; (xix) x, y, z−1; (xx) −x, −y+1, −z; (xxi) x−1/2, y+1/2, z; (xxii) −x, −y+1, −z+1; (xxiii) x−1/2, −y+3/2, z; (xxiv) x−1/2, y−1/2, z; (xxv) −x+3/2, y−1/2, −z+1; (xxvi) −x+1/2, y+1/2, −z; (xxvii) x, y, z+1; (xxviii) −x+1/2, y+1/2, −z+1; (xxix) x−1/2, −y+1/2, z. |
Acknowledgements
We greatly acknowledge the financial support from the Hebei Province Youth Top-notch Talent Program (2013–2018).
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