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inorganic compounds\(\def\hfill{\hskip 5em}\def\hfil{\hskip 3em}\def\eqno#1{\hfil {#1}}\)

Journal logoIUCrDATA
ISSN: 2414-3146
Volume 3| Part 3| March 2018| x180363
https://doi.org/10.1107/S2414314618003632

Crystal structure of the λ-Al13Fe4-type inter­metallic (Al,Cu)13(Fe,Cu)4

CROSSMARK_Color_square_no_text.svg
Cong Liua and Changzeng Fana*

aState Key Laboratory of Metastable Materials Science and Technology, Yanshan University, Qinhuangdao 066004, People's Republic of China
*Correspondence e-mail: chzfan@ysu.edu.cn

Edited by T. J. Prior, University of Hull, England (Received 28 February 2018; accepted 1 March 2018; online 6 March 2018)

An (Al,Cu)13(Fe,Cu)4 phase of [trideca(aluminium/copper) tetra(iron/copper)] was obtained by the high-pressure sinter­ing (HPS) process of a mixture with composition Al78Cu15Fe7. Structure analysis suggests that Cu atoms can replace both Al and Fe atoms. Such findings support previous anomalous X-ray scattering (AXS) results although deviate from other reports. The new phase adopts the λ-Al13Fe4 structure type where Cu atoms partially occupy the 2c and 4i sites for Al and Fe atoms, respectively, with occupancies of 0.233 (5) and 0.173 (16).

CCDC reference: 1826904

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[Scheme 3D1]

Structure description

An unnamed Al78Cu15Fe7 phase was identified in association with icosa­hedrite (Ma et al., 2016[Ma, C., Lin, C., Bindi, L. & Steinhardt, P. J. (2016). LPI Contributions, 1921.]), the first naturally occurring quasicrystal (Bindi et al., 2009[Bindi, L., Steinhardt, P. J., Yao, N. & Lu, P. J. (2009). Science, 324, 1306-1309.]). In simulating its growth mechanism by high pressure sinter­ing (HPS), a λ-Al13Fe4-type phase with composition Al4.85Cu0.07Fe1.46 [trideca(aluminium/copper) tetra(iron/copper)] was found. The complex inter­metallic compound λ-phase possesses more than 100 atoms in the unit cell along with Fe atoms arranged in Fe–Al–Fe groups, which are encapsulated by aluminium atoms (Armbrüster et al., 2012[Armbrüster, M., Kovnir, K., Friedrich, M., Teschner, D., Wowsnick, G., Hahne, M., Gille, P., Szentmiklósi, L., Feuerbacher, M., Heggen, M., Girgsdies, F., Rosenthal, D., Schlögl, R. & Grin, Y. (2012). Nat. Mater. 11, 690-693.]). The synthesized Al4.85Cu0.07Fe1.46 phase can also be viewed as a stacking of flat (F) and puckered (P) layers in a F1P1F2P2 sequence in the [010] direction (Matilainen et al., 2015[Matilainen, A., Pussi, K., Diehl, R. D., Hahne, M., Gille, P., Gaudry, É., Serkovic Loli, L. N., McGuirk, G. M., de Weerd, M.-C., Fournée, V. & Ledieu, J. (2015). Phys. Rev. B, 92, 014109.]). The puckered layers are mirrored against the F2 layer. In total, the unit cell contains 102 atoms, where the flat layer is composed of 16 Al atoms and one commonly occupied Al/Cu atom, 7 Fe atoms and one commonly occupied Fe/Cu atom. The puckered layer has 22 Al and 4 Fe atoms.

Fig. 1[link] shows the [010] projection of the crystal structure of the new ternary Al–Cu–Fe phase. The environment of the Al/Cu atoms and Fe/Cu atoms are shown in Fig. 2[link]. The Al/Cu atoms share the 2c site and are connected by 8 Al atoms and 2 Fe atoms. The Fe/Cu atoms share the 4i site and are connected by 11 Al atoms. Therefore, the new phase can be described as (Al,Cu)13(Fe,Cu)4 where Cu atoms replace both Al and Fe atoms, in accordance with the AXS results (Genba et al., 2002[Genba, M., Sugiyama, K., Hiraga, K. & Yokoyama, Y. (2002). J. Alloys Compd. 342, 143-147.]) but different from conventional viewpoints (Freiburg & Grushko, 1994[Freiburg, C. & Grushko, B. (1994). J. Alloys Compd. 210, 149-152.]).

[Figure 1]
Figure 1
The [010] projection of the crystal structure of the new ternary Al–Cu–Fe phase. The monoclinic unit cell is outlined by a red parallelogram. The tiling formed by (a) connecting transition metal atoms for the flat layer with penta­gons, rhombi, and (b) in the case of the puckered layer with elongated hexa­gons (edge length around 6.5 Å). The circled Al atoms refer to the glue atoms and the assigned minus Fe atoms mean that they are located below the middle plane position.
[Figure 2]
Figure 2
The environment of Al/Cu (left) atoms and Fe/Cu (right) atoms in detail. Displacement ellipsoids are given at the 99.8% probability level. [Symmetry codes: (i) 1 − x, 1 − y, 1 − z; (ii) 1 − x, y, 1 − z; (iii) x, 1 − y, z; (iv) [{1\over 2}] + x, [{3\over 2}] − y, z; (xxi) −[{1\over 2}] + x, [{1\over 2}] + y, z; (xxii) −x, 1 − y, 1 − z; (xxiii) −[{1\over 2}] + x, [{3\over 2}] − y, z; (xxiv) −[{1\over 2}] + x, −[{1\over 2}] + y, z.]

Synthesis and crystallization

The pure elements Al (indicated purity 99.8%), Cu (indicated purity 99.95%) and Fe (indicated purity 99.8%) were mixed in the stoichiometric ratio 78:15:7 and initially ground in an agate mortar. Blended powders were then placed in a grinding tool of diameter 5 mm and pressed into a tablet at about 4 MPa slowly and continuously for about five minutes. A cylindrical block 5 mm in diameter and 8 mm in height was obtained without cracks or deformations. The cylindrical block was then inserted in a six-anvil high-pressure apparatus for HPS experiments. Inside the anvil, the block was encapsulated into an h-BN crucible covered by an h-BN gasket and wrapped in a graphite stove. Both ends of the graphite stove were filled with pyrophyllite and dolomite composite medium and sealed by conductive steel. Finally, all of these components were put into pyrophyllite rock that served as pressure transition medium (see Supporting information). The sample was pressurized up to 5 GPa and heated to 1473 K for 30 minutes (similiar conditions as employed by Hollister et al., 2014[Hollister, L. S., Bindi, L., Yao, N., Poirier, G. R., Andronicos, C. L., MacPherson, G. J., Lin, C., Distler, V. V., Eddy, M. P., Kostin, A., Kryachko, V., Steinhardt, W. M., Yudovskaya, M., Eiler, J. M., Guan, Y., Clarke, J. J. & Steinhardt, P. J. (2014). Nat. Commun. 5, 4040-1.]), cooled to 1073 K and held at this temperature for one hour, and then cooled down rapidly to room temperature. A fragment of dimension 0.08 × 0.05 × 0.03 mm3 was selected and mounted on a glass fiber for single-crystal X-ray diffraction measurements.

Refinement

Crystal data, data collection and structure refinement details are summarized in Table 1[link]. After considering all atoms in the Al13Fe4 structure, the original Al1 atom (Wyckoff position 2c) was modelled as occupied with both Al and Cu atoms with occupancies of 0.767 (5) and 0.233 (5), respectively. In addition, the Fe2 position was modelled by partially occupied Fe atoms [occupancy 0.827 (16)] and Cu atoms [occupancy 0.173 (16)]. Although the refined formula Al4.85Cu0.07Fe1.46 shows significant deficiency in Cu compared to that of initial stoichiometry, it is in good agreement with the EDS measurements.

Table 1
Experimental details

Crystal data
Chemical formula Al4.85Cu0.07Fe1.46
Mr 216.70
Crystal system, space group Monoclinic, C2/m
Temperature (K) 293
a, b, c (Å) 15.4749 (10), 8.0913 (5), 12.4882 (9)
β (°) 107.768 (2)
V (Å3) 1489.09 (17)
Z 16
Radiation type Mo Kα
μ (mm−1) 7.06
Crystal size (mm) 0.08 × 0.05 × 0.03
 
Data collection
Diffractometer Bruker D8 Venture Photon 100 CMOS
Absorption correction Multi-scan (SADABS; Krause et al., 2015[Krause, L., Herbst-Irmer, R., Sheldrick, G. M. & Stalke, D. (2015). J. Appl. Cryst. 48, 3-10.])
Tmin, Tmax 0.576, 0.746
No. of measured, independent and observed [I > 2σ(I)] reflections 12161, 2319, 1749
Rint 0.044
(sin θ/λ)max (Å−1) 0.715
 
Refinement
R[F2 > 2σ(F2)], wR(F2), S 0.038, 0.070, 1.07
No. of reflections 2319
No. of parameters 138
Δρmax, Δρmin (e Å−3) 1.12, −0.99
Computer programs: APEX3 and SAINT (Bruker, 2015[Bruker (2015). APEX3 and SAINT Bruker AXS Inc. Madison, Wisconsin, USA.]), SHELXT (Sheldrick, 2015a[Sheldrick, G. M. (2015a). Acta Cryst. A71, 3-8.]), SHELXL2014 (Sheldrick, 2015b[Sheldrick, G. M. (2015b). Acta Cryst. C71, 3-8.]), DIAMOND (Brandenburg & Putz, 2017[Brandenburg, K. & Putz, H. (2017). DIAMOND. Crystal Impact GbR, Bonn, Germany.]) and publCIF (Westrip, 2010[Westrip, S. P. (2010). J. Appl. Cryst. 43, 920-925.]).

Structural data

CCDC reference: 1826904

Crystal structure: contains datablock I. DOI: https://doi.org/10.1107/S2414314618003632/pj4005sup1.cif

Structure factors: contains datablock I. DOI: https://doi.org/10.1107/S2414314618003632/pj4005Isup2.hkl

Fig. 1S: Sketch of assembled crucible for HPS. DOI: https://doi.org/10.1107/S2414314618003632/pj4005sup3.pdf

checkCIF report


Computing details top

Data collection: APEX3 (Bruker, 2015); cell refinement: SAINT (Bruker, 2015); data reduction: SAINT (Bruker, 2015); program(s) used to solve structure: SHELXT (Sheldrick, 2015a); program(s) used to refine structure: SHELXL2014 (Sheldrick, 2015b); molecular graphics: DIAMOND (Brandenburg & Putz, 2017); software used to prepare material for publication: publCIF (Westrip, 2010).

trideca(aluminium/copper) tetra(iron/copper) top
Crystal data top
Al4.85Cu0.07Fe1.46F(000) = 1648
Mr = 216.70Dx = 3.866 Mg m−3
Monoclinic, C2/mMo Kα radiation, λ = 0.71073 Å
a = 15.4749 (10) ÅCell parameters from 1749 reflections
b = 8.0913 (5) Åθ = 2.8–30.5°
c = 12.4882 (9) ŵ = 7.06 mm−1
β = 107.768 (2)°T = 293 K
V = 1489.09 (17) Å3Grain, silver
Z = 160.08 × 0.05 × 0.03 mm
Data collection top
Bruker D8 Venture Photon 100 CMOS
diffractometer		1749 reflections with I > 2σ(I)
phi and ω scansRint = 0.044
Absorption correction: multi-scan
(SADABS; Krause et al., 2015)		θmax = 30.5°, θmin = 2.8°
Tmin = 0.576, Tmax = 0.746h = −21→22
12161 measured reflectionsk = −11→10
2319 independent reflectionsl = −14→17
Refinement top
Refinement on F2138 parameters
Least-squares matrix: full0 restraints
R[F2 > 2σ(F2)] = 0.038 w = 1/[σ2(Fo2) + (0.030P)2 + 1.0855P]
where P = (Fo2 + 2Fc2)/3
wR(F2) = 0.070(Δ/σ)max = 0.001
S = 1.07Δρmax = 1.12 e Å−3
2319 reflectionsΔρmin = −0.99 e Å−3
Special details top

Geometry. All esds (except the esd in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell esds are taken into account individually in the estimation of esds in distances, angles and torsion angles; correlations between esds in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell esds is used for estimating esds involving l.s. planes.

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å2) top
xyzUiso*/UeqOcc. (<1)
Al10.5000000.5000000.5000000.0098 (5)0.767 (5)
Cu10.5000000.5000000.5000000.0098 (5)0.233 (5)
Al20.67744 (10)0.5000000.71929 (12)0.0130 (3)
Al30.63633 (7)0.71530 (13)0.52217 (8)0.0092 (2)
Al40.80481 (10)1.0000000.77266 (12)0.0077 (3)
Al50.76330 (10)0.5000000.46467 (13)0.0126 (3)
Al60.49067 (7)0.27023 (14)0.33038 (8)0.0094 (2)
Al70.52074 (9)0.5000000.17059 (11)0.0078 (3)
Al80.5000000.74935 (18)0.0000000.0081 (3)
Al90.36802 (7)0.71228 (13)0.11008 (8)0.0077 (2)
Al100.24072 (10)0.500000−0.03857 (13)0.0118 (3)
Al110.08628 (9)0.500000−0.21245 (11)0.0041 (3)
Al120.06612 (10)0.5000000.17389 (11)0.0079 (3)
Al130.18526 (7)0.71741 (13)0.11114 (8)0.0067 (2)
Al140.17782 (7)0.72118 (13)0.33455 (8)0.0081 (2)
Al150.07414 (9)0.5000000.58060 (11)0.0068 (3)
Fe10.40231 (4)0.500000−0.01441 (5)0.00449 (16)
Fe20.08507 (4)0.5000000.38222 (5)0.0057 (2)0.827 (16)
Cu20.08507 (4)0.5000000.38222 (5)0.0057 (2)0.173 (16)
Fe30.09041 (4)0.500000−0.01203 (5)0.00434 (16)
Fe40.68011 (3)0.79257 (6)0.72198 (4)0.00551 (13)
Fe50.59919 (4)0.5000000.37535 (5)0.00489 (15)
Atomic displacement parameters (Å2) top
U11U22U33U12U13U23
Al10.0104 (9)0.0077 (9)0.0144 (9)0.0000.0082 (7)0.000
Cu10.0104 (9)0.0077 (9)0.0144 (9)0.0000.0082 (7)0.000
Al20.0183 (9)0.0072 (8)0.0132 (8)0.0000.0040 (7)0.000
Al30.0100 (5)0.0113 (6)0.0066 (5)−0.0016 (5)0.0031 (4)−0.0020 (4)
Al40.0066 (7)0.0062 (8)0.0090 (7)0.0000.0006 (6)0.000
Al50.0066 (7)0.0088 (8)0.0189 (8)0.000−0.0011 (6)0.000
Al60.0068 (5)0.0108 (6)0.0090 (5)−0.0036 (4)0.0001 (4)0.0009 (4)
Al70.0062 (7)0.0101 (8)0.0059 (7)0.0000.0000 (6)0.000
Al80.0070 (7)0.0064 (8)0.0113 (7)0.0000.0031 (6)0.000
Al90.0076 (5)0.0093 (6)0.0060 (5)0.0016 (4)0.0016 (4)−0.0008 (4)
Al100.0048 (7)0.0097 (8)0.0221 (8)0.0000.0061 (6)0.000
Al110.0069 (7)0.0008 (7)0.0050 (6)0.0000.0025 (5)0.000
Al120.0080 (7)0.0084 (8)0.0074 (7)0.0000.0023 (6)0.000
Al130.0059 (5)0.0089 (6)0.0050 (5)−0.0015 (4)0.0011 (4)−0.0013 (4)
Al140.0097 (5)0.0086 (6)0.0072 (5)−0.0023 (4)0.0044 (4)−0.0010 (4)
Al150.0078 (7)0.0055 (8)0.0068 (7)0.0000.0018 (6)0.000
Fe10.0036 (3)0.0049 (4)0.0050 (3)0.0000.0015 (3)0.000
Fe20.0058 (4)0.0055 (4)0.0062 (3)0.0000.0024 (3)0.000
Cu20.0058 (4)0.0055 (4)0.0062 (3)0.0000.0024 (3)0.000
Fe30.0037 (3)0.0049 (4)0.0044 (3)0.0000.0013 (3)0.000
Fe40.0045 (2)0.0067 (3)0.0053 (2)0.0003 (2)0.00140 (18)−0.00024 (18)
Fe50.0047 (3)0.0043 (4)0.0047 (3)0.0000.0000 (2)0.000
Geometric parameters (Å, º) top
Al1—Fe52.4975 (7)Al7—Al62.8672 (15)
Al1—Fe5i2.4976 (7)Al7—Al6iii2.8672 (15)
Al1—Al62.7889 (11)Al7—Al8xiii2.8801 (14)
Al1—Al6i2.7889 (11)Al7—Al82.8801 (14)
Al1—Al6ii2.7889 (11)Al8—Fe3v2.4942 (13)
Al1—Al6iii2.7889 (11)Al8—Fe3xiv2.4942 (13)
Cu1—Fe52.4975 (7)Al8—Fe1xiii2.4944 (13)
Cu1—Fe5i2.4976 (7)Al8—Fe12.4945 (13)
Cu1—Al62.7889 (11)Al8—Al13iv2.7909 (10)
Cu1—Al6i2.7889 (11)Al8—Al13xiv2.7909 (10)
Cu1—Al6ii2.7889 (11)Al8—Al92.8044 (10)
Cu1—Al6iii2.7889 (11)Al8—Al9xv2.8044 (10)
Al2—Fe42.3677 (5)Al8—Al12v2.9188 (14)
Al2—Fe4iii2.3677 (5)Al8—Al12xiv2.9188 (14)
Al2—Al32.9229 (16)Al9—Fe12.4804 (11)
Al2—Al3iii2.9229 (16)Al9—Fe4ii2.5157 (11)
Al2—Al9ii2.9834 (16)Al9—Al11xiv2.6462 (12)
Al2—Al9i2.9834 (16)Al9—Al13xiv2.6918 (14)
Al3—Fe42.4585 (11)Al9—Fe3xiv2.7952 (11)
Al3—Fe52.4665 (11)Al9—Al132.8327 (14)
Al3—Al14iv2.6616 (13)Al9—Al102.8364 (16)
Al3—Al15v2.6821 (12)Al9—Al10xiv2.8516 (13)
Al3—Cu12.6843 (10)Al10—Fe12.4257 (15)
Al3—Al12.6843 (10)Al10—Fe32.4475 (15)
Al3—Al6iii2.7452 (14)Al10—Al112.694 (2)
Al3—Al5vi2.7550 (13)Al10—Al13xiv2.8277 (13)
Al3—Fe2v2.8538 (11)Al10—Al13xvi2.8277 (13)
Al3—Al52.8762 (16)Al10—Al13iii2.8820 (15)
Al3—Al14ii2.8870 (15)Al10—Al132.8820 (15)
Al4—Fe4vii2.4891 (11)Al11—Fe32.4842 (14)
Al4—Fe42.4891 (11)Al11—Fe4xvii2.5142 (11)
Al4—Al7vi2.574 (2)Al11—Fe4xviii2.5142 (11)
Al4—Fe1viii2.6265 (15)Al11—Al15xix2.5333 (19)
Al4—Al14ii2.6785 (13)Al11—Al12xx2.547 (2)
Al4—Al14ix2.6785 (13)Al11—Fe2xx2.8452 (15)
Al4—Al13ix2.6872 (12)Al12—Fe32.4627 (15)
Al4—Al13ii2.6872 (12)Al12—Cu22.5276 (15)
Al4—Fe5vi2.7018 (16)Al12—Fe22.5276 (15)
Al4—Al10viii2.823 (2)Al12—Fe3xx2.6391 (16)
Al4—Al5vi2.827 (2)Al12—Al132.8265 (15)
Al5—Fe52.4423 (16)Al12—Al13iii2.8265 (15)
Al5—Fe2i2.5344 (16)Al12—Al142.8460 (15)
Al5—Al15i2.741 (2)Al12—Al14iii2.8460 (15)
Al5—Al14x2.8580 (14)Al13—Fe32.4974 (11)
Al5—Al14iv2.8580 (14)Al13—Fe4ii2.5305 (11)
Al5—Al14ii2.9875 (16)Al13—Fe1xiv2.7431 (11)
Al5—Al14i2.9875 (16)Al13—Al142.8274 (14)
Al6—Fe52.4528 (11)Al14—Cu22.4776 (11)
Al6—Fe4i2.5722 (11)Al14—Fe22.4776 (11)
Al6—Fe2x2.5994 (11)Al14—Fe4ii2.5715 (11)
Al6—Al11xi2.7013 (13)Al14—Fe5xxi2.6847 (11)
Al6—Al15xii2.7755 (13)Al15—Fe22.5342 (15)
Al6—Al9iii2.8292 (14)Al15—Cu22.5342 (15)
Al6—Al14x2.9077 (15)Al15—Al15xxii2.549 (3)
Al7—Fe12.4723 (15)Al15—Fe4xxiii2.6185 (12)
Al7—Fe52.4734 (15)Al15—Fe4xxiv2.6185 (12)
Al7—Fe1xiii2.5768 (15)Al15—Fe2xxii2.6428 (15)
Al7—Al92.8313 (15)Fe1—Fe1xiii2.9337 (13)
Al7—Al9iii2.8313 (15)Fe3—Fe3xx2.9040 (13)
Fe4vii—Al4—Fe484.80 (5)Al13iii—Al10—Al1375.23 (5)
Fe4vii—Al4—Al7vi137.45 (3)Fe3—Al11—Fe4xvii119.23 (4)
Fe4—Al4—Al7vi137.45 (3)Fe3—Al11—Fe4xviii119.23 (4)
Fe4vii—Al4—Fe1viii114.75 (4)Fe4xvii—Al11—Fe4xviii83.76 (5)
Fe4—Al4—Fe1viii114.75 (4)Fe3—Al11—Al15xix177.35 (7)
Al7vi—Al4—Fe1viii59.40 (5)Fe4xvii—Al11—Al15xix62.50 (4)
Fe4vii—Al4—Al14ii128.98 (6)Fe4xviii—Al11—Al15xix62.50 (4)
Fe4—Al4—Al14ii59.55 (3)Fe3—Al11—Al12xx63.26 (5)
Al7vi—Al4—Al14ii83.15 (4)Fe4xvii—Al11—Al12xx136.19 (3)
Fe1viii—Al4—Al14ii113.07 (4)Fe4xviii—Al11—Al12xx136.19 (3)
Fe4vii—Al4—Al14ix59.55 (3)Al15xix—Al11—Al12xx114.09 (7)
Fe4—Al4—Al14ix128.98 (6)Fe3—Al11—Al9xiv65.94 (3)
Al7vi—Al4—Al14ix83.15 (4)Fe4xvii—Al11—Al9xiv58.29 (3)
Fe1viii—Al4—Al14ix113.07 (4)Fe4xviii—Al11—Al9xiv130.46 (6)
Al14ii—Al4—Al14ix114.76 (7)Al15xix—Al11—Al9xiv114.74 (4)
Fe4vii—Al4—Al13ix58.38 (3)Al12xx—Al11—Al9xiv92.01 (4)
Fe4—Al4—Al13ix128.55 (6)Fe3—Al11—Al9xvi65.94 (3)
Al7vi—Al4—Al13ix88.22 (4)Fe4xvii—Al11—Al9xvi130.46 (6)
Fe1viii—Al4—Al13ix62.15 (3)Fe4xviii—Al11—Al9xvi58.29 (3)
Al14ii—Al4—Al13ix171.37 (7)Al15xix—Al11—Al9xvi114.74 (4)
Al14ix—Al4—Al13ix63.60 (3)Al12xx—Al11—Al9xvi92.01 (4)
Fe4vii—Al4—Al13ii128.55 (6)Al9xiv—Al11—Al9xvi123.22 (7)
Fe4—Al4—Al13ii58.38 (3)Fe3—Al11—Al1056.23 (4)
Al7vi—Al4—Al13ii88.22 (4)Fe4xvii—Al11—Al1078.70 (4)
Fe1viii—Al4—Al13ii62.15 (3)Fe4xviii—Al11—Al1078.70 (4)
Al14ii—Al4—Al13ii63.60 (3)Al15xix—Al11—Al10126.41 (7)
Al14ix—Al4—Al13ii171.37 (7)Al12xx—Al11—Al10119.50 (7)
Al13ix—Al4—Al13ii116.62 (7)Al9xiv—Al11—Al1064.54 (3)
Fe4vii—Al4—Fe5vi111.81 (4)Al9xvi—Al11—Al1064.54 (3)
Fe4—Al4—Fe5vi111.81 (4)Fe3—Al11—Al6xi114.88 (4)
Al7vi—Al4—Fe5vi55.86 (4)Fe4xvii—Al11—Al6xi124.41 (6)
Fe1viii—Al4—Fe5vi115.26 (6)Fe4xviii—Al11—Al6xi58.97 (3)
Al14ii—Al4—Fe5vi59.86 (3)Al15xix—Al11—Al6xi63.94 (4)
Al14ix—Al4—Fe5vi59.86 (3)Al12xx—Al11—Al6xi79.83 (4)
Al13ix—Al4—Fe5vi114.62 (4)Al9xiv—Al11—Al6xi169.68 (6)
Al13ii—Al4—Fe5vi114.62 (4)Al9xvi—Al11—Al6xi63.87 (3)
Fe4vii—Al4—Al10viii76.68 (4)Al10—Al11—Al6xi125.06 (3)
Fe4—Al4—Al10viii76.68 (4)Fe3—Al11—Al6xxvi114.88 (4)
Al7vi—Al4—Al10viii112.11 (6)Fe4xvii—Al11—Al6xxvi58.97 (3)
Fe1viii—Al4—Al10viii52.72 (4)Fe4xviii—Al11—Al6xxvi124.41 (6)
Al14ii—Al4—Al10viii122.14 (3)Al15xix—Al11—Al6xxvi63.95 (4)
Al14ix—Al4—Al10viii122.14 (3)Al12xx—Al11—Al6xxvi79.83 (4)
Al13ix—Al4—Al10viii61.70 (3)Al9xiv—Al11—Al6xxvi63.87 (3)
Al13ii—Al4—Al10viii61.70 (3)Al9xvi—Al11—Al6xxvi169.68 (6)
Fe5vi—Al4—Al10viii167.97 (7)Al10—Al11—Al6xxvi125.06 (3)
Fe4vii—Al4—Al5vi73.82 (4)Al6xi—Al11—Al6xxvi108.08 (6)
Fe4—Al4—Al5vi73.82 (4)Fe3—Al11—Fe2xx118.84 (5)
Al7vi—Al4—Al5vi108.23 (6)Fe4xvii—Al11—Fe2xx104.89 (4)
Fe1viii—Al4—Al5vi167.63 (7)Fe4xviii—Al11—Fe2xx104.89 (4)
Al14ii—Al4—Al5vi62.48 (4)Al15xix—Al11—Fe2xx58.52 (4)
Al14ix—Al4—Al5vi62.48 (4)Al12xx—Al11—Fe2xx55.57 (4)
Al13ix—Al4—Al5vi120.52 (3)Al9xiv—Al11—Fe2xx114.26 (4)
Al13ii—Al4—Al5vi120.52 (3)Al9xvi—Al11—Fe2xx114.26 (4)
Fe5vi—Al4—Al5vi52.38 (4)Al10—Al11—Fe2xx175.07 (6)
Al10viii—Al4—Al5vi139.65 (7)Al6xi—Al11—Fe2xx55.82 (3)
Fe4—Al2—Fe4iii177.84 (8)Al6xxvi—Al11—Fe2xx55.82 (3)
Fe4—Al2—Al354.16 (3)Fe3—Al12—Cu2165.30 (7)
Fe4iii—Al2—Al3127.32 (6)Fe3—Al12—Fe2165.30 (7)
Fe4—Al2—Al3iii127.32 (6)Fe3—Al12—Al11xx126.50 (7)
Fe4iii—Al2—Al3iii54.16 (3)Fe2—Al12—Al11xx68.20 (5)
Al3—Al2—Al3iii73.17 (5)Fe3—Al12—Fe3xx69.29 (4)
Fe4—Al2—Al9ii54.63 (3)Fe2—Al12—Fe3xx125.41 (6)
Fe4iii—Al2—Al9ii124.91 (6)Al11xx—Al12—Fe3xx57.21 (5)
Al3—Al2—Al9ii102.72 (3)Fe3—Al12—Al1355.84 (3)
Al3iii—Al2—Al9ii155.03 (7)Cu2—Al12—Al13113.87 (5)
Fe4—Al2—Al9i124.91 (6)Fe2—Al12—Al13113.87 (5)
Fe4iii—Al2—Al9i54.63 (3)Al11xx—Al12—Al13140.57 (3)
Al3—Al2—Al9i155.02 (7)Fe3xx—Al12—Al13108.15 (5)
Al3iii—Al2—Al9i102.72 (3)Fe3—Al12—Al13iii55.84 (3)
Al9ii—Al2—Al9i70.30 (5)Fe2—Al12—Al13iii113.87 (5)
Fe4—Al3—Fe5149.72 (5)Al11xx—Al12—Al13iii140.57 (3)
Fe4—Al3—Al14iv141.13 (5)Fe3xx—Al12—Al13iii108.15 (5)
Fe5—Al3—Al14iv63.00 (3)Al13—Al12—Al13iii76.98 (5)
Fe4—Al3—Al15v61.06 (4)Fe3—Al12—Al14115.47 (5)
Fe5—Al3—Al15v141.94 (5)Cu2—Al12—Al1454.52 (3)
Al14iv—Al3—Al15v106.06 (5)Fe2—Al12—Al1454.52 (3)
Fe4—Al3—Cu1103.55 (4)Al11xx—Al12—Al14105.36 (5)
Fe5—Al3—Cu157.82 (3)Fe3xx—Al12—Al14139.29 (3)
Al14iv—Al3—Cu1115.32 (4)Al13—Al12—Al1459.79 (4)
Al15v—Al3—Cu1104.45 (4)Al13iii—Al12—Al14106.24 (6)
Fe4—Al3—Al1103.55 (4)Fe3—Al12—Al14iii115.47 (5)
Fe5—Al3—Al157.82 (3)Fe2—Al12—Al14iii54.52 (3)
Al14iv—Al3—Al1115.32 (4)Al11xx—Al12—Al14iii105.36 (5)
Al15v—Al3—Al1104.45 (4)Fe3xx—Al12—Al14iii139.29 (3)
Fe4—Al3—Al6iii140.65 (5)Al13—Al12—Al14iii106.24 (6)
Fe5—Al3—Al6iii55.84 (3)Al13iii—Al12—Al14iii59.79 (3)
Al14iv—Al3—Al6iii65.04 (4)Al14—Al12—Al14iii77.93 (6)
Al15v—Al3—Al6iii86.19 (5)Fe3—Al12—Al8xxiv54.43 (3)
Al1—Al3—Al6iii61.80 (3)Fe2—Al12—Al8xxiv132.07 (3)
Fe4—Al3—Al5vi75.59 (4)Al11xx—Al12—Al8xxiv90.35 (4)
Fe5—Al3—Al5vi129.35 (5)Fe3xx—Al12—Al8xxiv53.04 (3)
Al14iv—Al3—Al5vi66.92 (5)Al13—Al12—Al8xxiv109.66 (5)
Al15v—Al3—Al5vi60.54 (4)Al13iii—Al12—Al8xxiv58.10 (3)
Al1—Al3—Al5vi163.70 (5)Al14—Al12—Al8xxiv163.95 (6)
Al6iii—Al3—Al5vi108.31 (5)Al14iii—Al12—Al8xxiv95.00 (3)
Fe4—Al3—Fe2v110.81 (4)Fe3—Al12—Al8xiv54.43 (3)
Fe5—Al3—Fe2v99.01 (4)Fe2—Al12—Al8xiv132.07 (3)
Al14iv—Al3—Fe2v53.25 (3)Al11xx—Al12—Al8xiv90.35 (4)
Al15v—Al3—Fe2v54.38 (4)Fe3xx—Al12—Al8xiv53.04 (3)
Al1—Al3—Fe2v113.45 (4)Al13—Al12—Al8xiv58.10 (3)
Al6iii—Al3—Fe2v55.28 (3)Al13iii—Al12—Al8xiv109.66 (5)
Al5vi—Al3—Fe2v53.69 (4)Al14—Al12—Al8xiv95.00 (3)
Fe4—Al3—Al5114.19 (5)Al14iii—Al12—Al8xiv163.95 (6)
Fe5—Al3—Al553.74 (4)Al8xxiv—Al12—Al8xiv88.03 (6)
Al14iv—Al3—Al562.00 (4)Fe3—Al13—Fe4ii149.09 (5)
Al15v—Al3—Al5156.54 (5)Fe3—Al13—Al4ix149.09 (5)
Cu1—Al3—Al599.00 (4)Fe4ii—Al13—Al4ix56.89 (4)
Al1—Al3—Al599.00 (4)Fe3—Al13—Al9xiv65.06 (3)
Al6iii—Al3—Al5104.45 (5)Fe4ii—Al13—Al9xiv135.38 (5)
Al5vi—Al3—Al596.06 (3)Al4ix—Al13—Al9xiv108.87 (5)
Fe2v—Al3—Al5114.79 (4)Fe3—Al13—Fe1xiv101.39 (4)
Fe4—Al3—Al14ii56.83 (3)Fe4ii—Al13—Fe1xiv109.53 (4)
Fe5—Al3—Al14ii115.75 (5)Al4ix—Al13—Fe1xiv57.84 (4)
Al14iv—Al3—Al14ii94.59 (4)Al9xiv—Al13—Fe1xiv54.30 (3)
Al15v—Al3—Al14ii100.92 (5)Fe3—Al13—Al8xiv55.95 (4)
Al1—Al3—Al14ii132.65 (4)Fe4ii—Al13—Al8xiv148.11 (5)
Al6iii—Al3—Al14ii159.63 (5)Al4ix—Al13—Al8xiv93.86 (5)
Al5vi—Al3—Al14ii60.82 (4)Al9xiv—Al13—Al8xiv61.50 (3)
Fe2v—Al3—Al14ii113.85 (4)Fe1xiv—Al13—Al8xiv53.57 (4)
Al5—Al3—Al14ii62.45 (4)Fe3—Al13—Al1254.68 (3)
Fe4—Al3—Al251.32 (3)Fe4ii—Al13—Al12111.35 (5)
Fe5—Al3—Al298.43 (4)Al4ix—Al13—Al12108.33 (5)
Al14iv—Al3—Al2143.85 (5)Al9xiv—Al13—Al12113.25 (5)
Al15v—Al3—Al2106.66 (5)Fe1xiv—Al13—Al12111.38 (4)
Cu1—Al3—Al270.26 (4)Al8xiv—Al13—Al1262.61 (4)
Al1—Al3—Al270.26 (4)Fe3—Al13—Al14114.97 (4)
Al6iii—Al3—Al2132.07 (5)Fe4ii—Al13—Al1457.04 (3)
Al5vi—Al3—Al2118.31 (5)Al4ix—Al13—Al1458.05 (4)
Fe2v—Al3—Al2160.96 (5)Al9xiv—Al13—Al14156.71 (5)
Al5—Al3—Al281.93 (5)Fe1xiv—Al13—Al14105.20 (4)
Al14ii—Al3—Al264.42 (4)Al8xiv—Al13—Al1498.32 (4)
Fe5—Al5—Fe2i159.85 (7)Al12—Al13—Al1460.45 (4)
Fe5—Al5—Al15i142.89 (7)Fe3—Al13—Al10xiv126.27 (5)
Fe2i—Al5—Al15i57.25 (4)Fe4ii—Al13—Al10xiv75.96 (4)
Fe5—Al5—Al3vi121.06 (4)Al4ix—Al13—Al10xiv61.51 (4)
Fe2i—Al5—Al3vi65.15 (4)Al9xiv—Al13—Al10xiv61.79 (4)
Al15i—Al5—Al3vi58.41 (3)Fe1xiv—Al13—Al10xiv51.60 (3)
Fe5—Al5—Al3xxv121.06 (4)Al8xiv—Al13—Al10xiv102.58 (5)
Fe2i—Al5—Al3xxv65.15 (4)Al12—Al13—Al10xiv162.64 (5)
Al15i—Al5—Al3xxv58.41 (3)Al14—Al13—Al10xiv116.75 (5)
Al3vi—Al5—Al3xxv113.47 (7)Fe3—Al13—Al9112.75 (4)
Fe5—Al5—Al4vi61.19 (5)Fe4ii—Al13—Al955.60 (3)
Fe2i—Al5—Al4vi138.96 (7)Al4ix—Al13—Al997.03 (5)
Al15i—Al5—Al4vi81.70 (6)Al9xiv—Al13—Al989.53 (4)
Al3vi—Al5—Al4vi94.91 (5)Fe1xiv—Al13—Al9111.71 (4)
Al3xxv—Al5—Al4vi94.91 (5)Al8xiv—Al13—Al9151.00 (4)
Fe5—Al5—Al14x60.26 (3)Al12—Al13—Al9136.79 (5)
Fe2i—Al5—Al14x126.18 (3)Al14—Al13—Al9110.25 (4)
Al15i—Al5—Al14x100.22 (5)Al10xiv—Al13—Al960.50 (4)
Al3vi—Al5—Al14x148.06 (7)Fe3—Al13—Al1053.55 (3)
Al3xxv—Al5—Al14x61.87 (3)Fe4ii—Al13—Al10110.34 (5)
Al4vi—Al5—Al14x56.22 (3)Al4ix—Al13—Al10152.92 (5)
Fe5—Al5—Al14iv60.26 (3)Al9xiv—Al13—Al1061.43 (4)
Fe2i—Al5—Al14iv126.18 (3)Fe1xiv—Al13—Al10115.34 (4)
Al15i—Al5—Al14iv100.22 (5)Al8xiv—Al13—Al10101.55 (5)
Al3vi—Al5—Al14iv61.87 (3)Al12—Al13—Al1098.54 (4)
Al3xxv—Al5—Al14iv148.06 (7)Al14—Al13—Al10139.16 (5)
Al4vi—Al5—Al14iv56.22 (3)Al10xiv—Al13—Al1093.19 (3)
Al14x—Al5—Al14iv104.25 (6)Al9—Al13—Al1059.51 (4)
Fe5—Al5—Al3iii54.52 (4)Fe2—Al14—Fe4ii146.58 (5)
Fe2i—Al5—Al3iii110.94 (5)Fe2—Al14—Al3xxiii67.35 (4)
Al15i—Al5—Al3iii142.30 (3)Fe4ii—Al14—Al3xxiii130.88 (5)
Al3vi—Al5—Al3iii155.12 (6)Fe2—Al14—Al4ix151.93 (6)
Al3xxv—Al5—Al3iii83.93 (3)Fe4ii—Al14—Al4ix56.56 (4)
Al4vi—Al5—Al3iii101.38 (5)Al3xxiii—Al14—Al4ix111.43 (5)
Al14x—Al5—Al3iii55.31 (3)Fe2—Al14—Fe5xxi103.42 (4)
Al14iv—Al5—Al3iii112.77 (6)Fe4ii—Al14—Fe5xxi109.77 (4)
Fe5—Al5—Al354.52 (4)Al3xxiii—Al14—Fe5xxi54.95 (3)
Fe2i—Al5—Al3110.94 (5)Al4ix—Al14—Fe5xxi60.50 (4)
Al15i—Al5—Al3142.30 (3)Cu2—Al14—Al13115.49 (4)
Al3vi—Al5—Al383.93 (3)Fe2—Al14—Al13115.49 (4)
Al3xxv—Al5—Al3155.12 (6)Fe4ii—Al14—Al1355.66 (3)
Al4vi—Al5—Al3101.38 (5)Al3xxiii—Al14—Al13164.61 (5)
Al14x—Al5—Al3112.77 (6)Al4ix—Al14—Al1358.35 (4)
Al14iv—Al5—Al355.31 (3)Fe5xxi—Al14—Al13110.71 (4)
Al3iii—Al5—Al374.56 (6)Cu2—Al14—Al1256.18 (4)
Fe5—Al5—Al14ii113.06 (5)Fe2—Al14—Al1256.18 (4)
Fe2i—Al5—Al14ii52.54 (3)Fe4ii—Al14—Al12109.50 (5)
Al15i—Al5—Al14ii96.26 (5)Al3xxiii—Al14—Al12118.96 (5)
Al3vi—Al5—Al14ii55.04 (3)Al4ix—Al14—Al12108.01 (5)
Al3xxv—Al5—Al14ii115.39 (6)Fe5xxi—Al14—Al12116.70 (5)
Al4vi—Al5—Al14ii143.20 (3)Al13—Al14—Al1259.76 (4)
Al14x—Al5—Al14ii156.89 (6)Fe2—Al14—Al5xxi129.43 (5)
Al14iv—Al5—Al14ii88.51 (3)Fe4ii—Al14—Al5xxi72.10 (4)
Al3iii—Al5—Al14ii102.12 (5)Al3xxiii—Al14—Al5xxi62.69 (5)
Al3—Al5—Al14ii58.95 (4)Al4ix—Al14—Al5xxi61.30 (4)
Fe5—Al5—Al14i113.06 (5)Fe5xxi—Al14—Al5xxi52.17 (3)
Fe2i—Al5—Al14i52.54 (3)Al13—Al14—Al5xxi114.73 (5)
Al15i—Al5—Al14i96.26 (5)Al12—Al14—Al5xxi166.75 (5)
Al3vi—Al5—Al14i115.39 (6)Fe2—Al14—Al3ii112.32 (4)
Al3xxv—Al5—Al14i55.04 (3)Fe4ii—Al14—Al3ii53.16 (3)
Al4vi—Al5—Al14i143.20 (3)Al3xxiii—Al14—Al3ii85.41 (4)
Al14x—Al5—Al14i88.51 (3)Al4ix—Al14—Al3ii95.21 (5)
Al14iv—Al5—Al14i156.89 (6)Fe5xxi—Al14—Al3ii108.64 (4)
Al3iii—Al5—Al14i58.95 (4)Al13—Al14—Al3ii106.17 (4)
Al3—Al5—Al14i102.12 (5)Al12—Al14—Al3ii134.62 (5)
Al14ii—Al5—Al14i73.60 (5)Al5xxi—Al14—Al3ii57.31 (4)
Fe5—Al1—Fe5i180.0Fe2—Al14—Al6xxi57.05 (3)
Fe5—Al1—Al356.71 (2)Fe4ii—Al14—Al6xxi153.47 (5)
Fe5i—Al1—Al3123.29 (2)Al3xxiii—Al14—Al6xxi58.87 (4)
Fe5—Al1—Al3i123.29 (2)Al4ix—Al14—Al6xxi97.32 (5)
Fe5i—Al1—Al3i56.71 (2)Fe5xxi—Al14—Al6xxi51.84 (3)
Al3—Al1—Al3i180.0Al13—Al14—Al6xxi108.91 (4)
Fe5—Al1—Al3iii56.71 (2)Al12—Al14—Al6xxi71.69 (4)
Fe5i—Al1—Al3iii123.29 (2)Al5xxi—Al14—Al6xxi100.84 (5)
Al3—Al1—Al3iii80.93 (5)Al3ii—Al14—Al6xxi144.27 (5)
Al3i—Al1—Al3iii99.07 (5)Fe2—Al14—Al5i54.29 (3)
Fe5—Al1—Al3ii123.29 (2)Fe4ii—Al14—Al5i107.32 (5)
Fe5i—Al1—Al3ii56.71 (2)Al3xxiii—Al14—Al5i58.03 (4)
Al3—Al1—Al3ii99.07 (5)Al4ix—Al14—Al5i150.77 (5)
Al3i—Al1—Al3ii80.93 (5)Fe5xxi—Al14—Al5i112.58 (4)
Al3iii—Al1—Al3ii180.00 (4)Al13—Al14—Al5i136.71 (5)
Fe5—Al1—Al654.96 (2)Al12—Al14—Al5i100.31 (4)
Fe5i—Al1—Al6125.04 (2)Al5xxi—Al14—Al5i91.49 (3)
Al3—Al1—Al6111.58 (3)Al3ii—Al14—Al5i58.60 (4)
Al3i—Al1—Al668.42 (3)Al6xxi—Al14—Al5i98.27 (4)
Al3iii—Al1—Al660.17 (3)Al11xxvii—Al15—Fe2172.31 (7)
Al3ii—Al1—Al6119.83 (3)Al11xxvii—Al15—Cu2172.31 (7)
Fe5—Al1—Al6i125.04 (2)Al11xxvii—Al15—Al15xxii125.05 (9)
Fe5i—Al1—Al6i54.96 (2)Fe2—Al15—Al15xxii62.65 (6)
Al3—Al1—Al6i68.42 (3)Al11xxvii—Al15—Fe4xxiii58.39 (4)
Al3i—Al1—Al6i111.58 (3)Fe2—Al15—Fe4xxiii116.38 (4)
Al3iii—Al1—Al6i119.83 (3)Al15xxii—Al15—Fe4xxiii139.47 (3)
Al3ii—Al1—Al6i60.17 (3)Al11xxvii—Al15—Fe4xxiv58.39 (4)
Al6—Al1—Al6i180.0Fe2—Al15—Fe4xxiv116.38 (4)
Fe5—Al1—Al6ii125.04 (2)Al15xxii—Al15—Fe4xxiv139.47 (3)
Fe5i—Al1—Al6ii54.96 (2)Fe4xxiii—Al15—Fe4xxiv79.73 (4)
Al3—Al1—Al6ii119.83 (3)Al11xxvii—Al15—Fe2xxii66.65 (5)
Al3i—Al1—Al6ii60.17 (3)Fe2—Al15—Fe2xxii121.04 (5)
Al3iii—Al1—Al6ii68.42 (3)Al15xxii—Al15—Fe2xxii58.40 (5)
Al3ii—Al1—Al6ii111.58 (3)Fe4xxiii—Al15—Fe2xxii107.89 (4)
Al6—Al1—Al6ii96.39 (4)Fe4xxiv—Al15—Fe2xxii107.89 (4)
Al6i—Al1—Al6ii83.62 (4)Al11xxvii—Al15—Al3xxiii110.88 (4)
Fe5—Al1—Al6iii54.96 (2)Fe2—Al15—Al3xxiii66.27 (3)
Fe5i—Al1—Al6iii125.04 (2)Al15xxii—Al15—Al3xxiii95.53 (5)
Al3—Al1—Al6iii60.17 (3)Fe4xxiii—Al15—Al3xxiii55.25 (3)
Al3i—Al1—Al6iii119.83 (3)Fe4xxiv—Al15—Al3xxiii122.08 (6)
Al3iii—Al1—Al6iii111.58 (3)Fe2xxii—Al15—Al3xxiii118.62 (3)
Al3ii—Al1—Al6iii68.42 (3)Al11xxvii—Al15—Al3xxiv110.88 (4)
Al6—Al1—Al6iii83.61 (4)Fe2—Al15—Al3xxiv66.26 (3)
Al6i—Al1—Al6iii96.38 (4)Al15xxii—Al15—Al3xxiv95.53 (5)
Al6ii—Al1—Al6iii180.0Fe4xxiii—Al15—Al3xxiv122.08 (6)
Fe5—Cu1—Fe5i180.0Fe4xxiv—Al15—Al3xxiv55.25 (3)
Fe5—Cu1—Al356.71 (2)Fe2xxii—Al15—Al3xxiv118.62 (3)
Fe5i—Cu1—Al3123.29 (2)Al3xxiii—Al15—Al3xxiv118.38 (7)
Fe5—Cu1—Al3i123.29 (2)Al11xxvii—Al15—Al5i115.05 (7)
Fe5i—Cu1—Al3i56.71 (2)Fe2—Al15—Al5i57.26 (4)
Al3—Cu1—Al3i180.0Al15xxii—Al15—Al5i119.91 (8)
Fe5—Cu1—Al3iii56.71 (2)Fe4xxiii—Al15—Al5i73.37 (4)
Fe5i—Cu1—Al3iii123.29 (2)Fe4xxiv—Al15—Al5i73.37 (4)
Al3—Cu1—Al3iii80.93 (5)Fe2xxii—Al15—Al5i178.30 (7)
Al3i—Cu1—Al3iii99.07 (5)Al3xxiii—Al15—Al5i61.05 (3)
Fe5—Cu1—Al3ii123.29 (2)Al3xxiv—Al15—Al5i61.05 (3)
Fe5i—Cu1—Al3ii56.71 (2)Al11xxvii—Al15—Al6xxviii60.97 (4)
Al3—Cu1—Al3ii99.07 (5)Fe2—Al15—Al6xxviii122.12 (4)
Al3i—Cu1—Al3ii80.93 (5)Al15xxii—Al15—Al6xxviii88.17 (5)
Al3iii—Cu1—Al3ii180.00 (4)Fe4xxiii—Al15—Al6xxviii56.87 (3)
Fe5—Cu1—Al654.96 (2)Fe4xxiv—Al15—Al6xxviii117.61 (5)
Fe5i—Cu1—Al6125.04 (2)Fe2xxii—Al15—Al6xxviii57.27 (3)
Al3—Cu1—Al6111.58 (3)Al3xxiii—Al15—Al6xxviii68.65 (3)
Al3i—Cu1—Al668.42 (3)Al3xxiv—Al15—Al6xxviii171.54 (6)
Al3iii—Cu1—Al660.17 (3)Al5i—Al15—Al6xxviii123.31 (4)
Al3ii—Cu1—Al6119.83 (3)Al11xxvii—Al15—Al6xii60.97 (4)
Fe5—Cu1—Al6i125.04 (2)Fe2—Al15—Al6xii122.12 (4)
Fe5i—Cu1—Al6i54.96 (2)Al15xxii—Al15—Al6xii88.17 (5)
Al3—Cu1—Al6i68.42 (3)Fe4xxiii—Al15—Al6xii117.61 (5)
Al3i—Cu1—Al6i111.58 (3)Fe4xxiv—Al15—Al6xii56.87 (3)
Al3iii—Cu1—Al6i119.83 (3)Fe2xxii—Al15—Al6xii57.27 (3)
Al3ii—Cu1—Al6i60.17 (3)Al3xxiii—Al15—Al6xii171.54 (6)
Al6—Cu1—Al6i180.0Al3xxiv—Al15—Al6xii68.65 (3)
Fe5—Cu1—Al6ii125.04 (2)Al5i—Al15—Al6xii123.31 (4)
Fe5i—Cu1—Al6ii54.96 (2)Al6xxviii—Al15—Al6xii103.96 (6)
Al3—Cu1—Al6ii119.83 (3)Al2—Fe4—Al374.52 (5)
Al3i—Cu1—Al6ii60.17 (3)Al2—Fe4—Al4133.36 (5)
Al3iii—Cu1—Al6ii68.42 (3)Al3—Fe4—Al4112.44 (4)
Al3ii—Cu1—Al6ii111.58 (3)Al2—Fe4—Al11viii131.51 (5)
Al6—Cu1—Al6ii96.39 (4)Al3—Fe4—Al11viii119.51 (4)
Al6i—Cu1—Al6ii83.62 (4)Al4—Fe4—Al11viii86.96 (4)
Fe5—Cu1—Al6iii54.96 (2)Al2—Fe4—Al9ii75.25 (5)
Fe5i—Cu1—Al6iii125.04 (2)Al3—Fe4—Al9ii136.09 (4)
Al3—Cu1—Al6iii60.17 (3)Al4—Fe4—Al9ii111.46 (4)
Al3i—Cu1—Al6iii119.83 (3)Al11viii—Fe4—Al9ii63.48 (4)
Al3iii—Cu1—Al6iii111.58 (3)Al2—Fe4—Al13ii77.16 (5)
Al3ii—Cu1—Al6iii68.42 (3)Al3—Fe4—Al13ii132.64 (4)
Al6—Cu1—Al6iii83.61 (4)Al4—Fe4—Al13ii64.73 (4)
Al6i—Cu1—Al6iii96.38 (4)Al11viii—Fe4—Al13ii107.72 (4)
Al6ii—Cu1—Al6iii180.0Al9ii—Fe4—Al13ii68.30 (3)
Fe1—Al7—Fe5162.97 (7)Al2—Fe4—Al14ii77.54 (5)
Fe1—Al7—Al4vi132.34 (7)Al3—Fe4—Al14ii70.01 (4)
Fe5—Al7—Al4vi64.70 (5)Al4—Fe4—Al14ii63.89 (4)
Fe1—Al7—Fe1xiii71.01 (4)Al11viii—Fe4—Al14ii150.05 (4)
Fe5—Al7—Fe1xiii126.02 (6)Al9ii—Fe4—Al14ii131.78 (4)
Al4vi—Al7—Fe1xiii61.32 (5)Al13ii—Fe4—Al14ii67.30 (3)
Fe1—Al7—Al955.27 (3)Al2—Fe4—Al6i77.69 (5)
Fe5—Al7—Al9112.48 (5)Al3—Fe4—Al6i75.42 (4)
Al4vi—Al7—Al9142.52 (3)Al4—Fe4—Al6i148.71 (4)
Fe1xiii—Al7—Al9109.81 (5)Al11viii—Fe4—Al6i64.15 (4)
Fe1—Al7—Al9iii55.27 (3)Al9ii—Fe4—Al6i67.56 (3)
Fe5—Al7—Al9iii112.48 (5)Al13ii—Fe4—Al6i133.29 (4)
Al4vi—Al7—Al9iii142.52 (3)Al14ii—Fe4—Al6i141.63 (4)
Fe1xiii—Al7—Al9iii109.81 (5)Al2—Fe4—Al15v128.80 (5)
Al9—Al7—Al9iii74.70 (5)Al3—Fe4—Al15v63.69 (4)
Fe1—Al7—Al6114.77 (5)Al4—Fe4—Al15v90.95 (4)
Fe5—Al7—Al654.07 (3)Al11viii—Fe4—Al15v59.11 (4)
Al4vi—Al7—Al6100.82 (5)Al9ii—Fe4—Al15v116.35 (4)
Fe1xiii—Al7—Al6137.51 (3)Al13ii—Fe4—Al15v153.92 (4)
Al9—Al7—Al6106.24 (5)Al14ii—Fe4—Al15v111.77 (4)
Al9iii—Al7—Al659.53 (3)Al6i—Fe4—Al15v64.64 (4)
Fe1—Al7—Al6iii114.77 (5)Al5—Fe5—Al6iii130.42 (3)
Fe5—Al7—Al6iii54.07 (3)Al5—Fe5—Al6130.42 (3)
Al4vi—Al7—Al6iii100.82 (5)Al6iii—Fe5—Al698.57 (5)
Fe1xiii—Al7—Al6iii137.51 (3)Al5—Fe5—Al3iii71.73 (4)
Al9—Al7—Al6iii59.53 (3)Al6iii—Fe5—Al3iii133.91 (4)
Al9iii—Al7—Al6iii106.24 (5)Al6—Fe5—Al3iii67.84 (4)
Al6—Al7—Al6iii80.85 (6)Al5—Fe5—Al371.73 (4)
Fe1—Al7—Al8xiii54.92 (3)Al6iii—Fe5—Al367.84 (4)
Fe5—Al7—Al8xiii132.33 (3)Al6—Fe5—Al3133.91 (4)
Al4vi—Al7—Al8xiii94.27 (4)Al3iii—Fe5—Al389.87 (5)
Fe1xiii—Al7—Al8xiii54.06 (3)Al5—Fe5—Al7125.88 (6)
Al9—Al7—Al8xiii109.39 (5)Al6iii—Fe5—Al771.19 (3)
Al9iii—Al7—Al8xiii58.81 (3)Al6—Fe5—Al771.18 (3)
Al6—Al7—Al8xiii93.18 (3)Al3iii—Fe5—Al7134.27 (3)
Al6iii—Al7—Al8xiii164.56 (6)Al3—Fe5—Al7134.27 (3)
Fe1—Al7—Al854.92 (3)Al5—Fe5—Al1117.81 (4)
Fe5—Al7—Al8132.33 (3)Al6iii—Fe5—Al168.57 (3)
Al4vi—Al7—Al894.27 (4)Al6—Fe5—Al168.57 (3)
Fe1xiii—Al7—Al854.06 (3)Al3iii—Fe5—Al165.47 (3)
Al9—Al7—Al858.81 (3)Al3—Fe5—Al165.47 (3)
Al9iii—Al7—Al8109.39 (5)Al7—Fe5—Al1116.31 (4)
Al6—Al7—Al8164.56 (6)Al5—Fe5—Cu1117.81 (4)
Al6iii—Al7—Al893.18 (3)Al6iii—Fe5—Cu168.57 (3)
Al8xiii—Al7—Al888.94 (6)Al6—Fe5—Cu168.57 (3)
Fe5—Al6—Fe4i141.86 (5)Al3iii—Fe5—Cu165.47 (3)
Fe5—Al6—Fe2x106.68 (4)Al3—Fe5—Cu165.47 (3)
Fe4i—Al6—Fe2x110.67 (4)Al7—Fe5—Cu1116.31 (4)
Fe5—Al6—Al11xi153.57 (6)Al5—Fe5—Al14iv67.57 (3)
Fe4i—Al6—Al11xi56.88 (4)Al6iii—Fe5—Al14iv68.77 (3)
Fe2x—Al6—Al11xi64.89 (4)Al6—Fe5—Al14iv155.74 (4)
Fe5—Al6—Al3iii56.32 (3)Al3iii—Fe5—Al14iv135.91 (4)
Fe4i—Al6—Al3iii137.44 (5)Al3—Fe5—Al14iv62.05 (3)
Fe2x—Al6—Al3iii64.48 (3)Al7—Fe5—Al14iv84.94 (3)
Al11xi—Al6—Al3iii128.18 (5)Al1—Fe5—Al14iv121.24 (2)
Fe5—Al6—Al15xii144.22 (5)Al5—Fe5—Al14x67.57 (3)
Fe4i—Al6—Al15xii58.49 (4)Al6iii—Fe5—Al14x155.74 (4)
Fe2x—Al6—Al15xii58.80 (4)Al6—Fe5—Al14x68.77 (3)
Al11xi—Al6—Al15xii55.08 (4)Al3iii—Fe5—Al14x62.05 (3)
Al3iii—Al6—Al15xii89.14 (5)Al3—Fe5—Al14x135.91 (4)
Fe5—Al6—Cu156.47 (3)Al7—Fe5—Al14x84.94 (3)
Fe4i—Al6—Cu197.80 (4)Al1—Fe5—Al14x121.24 (2)
Al11xi—Al6—Cu1149.96 (5)Al14iv—Fe5—Al14x114.34 (5)
Al3iii—Al6—Cu158.03 (3)Al5—Fe5—Al4vi66.44 (5)
Al15xii—Al6—Cu199.33 (4)Al6iii—Fe5—Al4vi108.92 (4)
Fe5—Al6—Al156.47 (3)Al6—Fe5—Al4vi108.92 (4)
Fe4i—Al6—Al197.80 (4)Al3iii—Fe5—Al4vi117.16 (4)
Fe2x—Al6—Al1118.47 (4)Al3—Fe5—Al4vi117.17 (4)
Al11xi—Al6—Al1149.96 (5)Al7—Fe5—Al4vi59.44 (5)
Al3iii—Al6—Al158.03 (3)Al1—Fe5—Al4vi175.75 (4)
Al15xii—Al6—Al199.33 (4)Al14iv—Fe5—Al4vi59.64 (3)
Fe5—Al6—Al9iii113.21 (5)Al14x—Fe5—Al4vi59.64 (3)
Fe4i—Al6—Al9iii55.27 (3)Al10—Fe1—Al7123.94 (6)
Fe2x—Al6—Al9iii116.33 (5)Al10—Fe1—Al9iii70.63 (4)
Al11xi—Al6—Al9iii57.12 (4)Al7—Fe1—Al9iii69.73 (4)
Al3iii—Al6—Al9iii167.13 (5)Al10—Fe1—Al970.63 (4)
Al15xii—Al6—Al9iii102.22 (5)Al7—Fe1—Al969.73 (4)
Al1—Al6—Al9iii124.69 (4)Al9iii—Fe1—Al987.66 (5)
Fe5—Al6—Al754.74 (4)Al10—Fe1—Al8xiii126.02 (2)
Fe4i—Al6—Al7108.88 (4)Al7—Fe1—Al8xiii70.88 (2)
Fe2x—Al6—Al7121.37 (5)Al9iii—Fe1—Al8xiii68.63 (3)
Al11xi—Al6—Al7106.48 (5)Al9—Fe1—Al8xiii139.09 (4)
Al3iii—Al6—Al7108.37 (5)Al10—Fe1—Al8126.02 (2)
Al15xii—Al6—Al7160.87 (5)Al7—Fe1—Al870.88 (2)
Cu1—Al6—Al796.58 (4)Al9iii—Fe1—Al8139.09 (4)
Al1—Al6—Al796.58 (4)Al9—Fe1—Al868.62 (3)
Al9iii—Al6—Al759.60 (4)Al8xiii—Fe1—Al8107.96 (5)
Fe5—Al6—Al14x59.39 (3)Al10—Fe1—Al7xiii127.08 (5)
Fe4i—Al6—Al14x156.65 (5)Al7—Fe1—Al7xiii108.99 (4)
Fe2x—Al6—Al14x53.11 (3)Al9iii—Fe1—Al7xiii135.32 (3)
Al11xi—Al6—Al14x99.81 (5)Al9—Fe1—Al7xiii135.32 (3)
Al3iii—Al6—Al14x56.09 (3)Al8xiii—Fe1—Al7xiii69.19 (2)
Al15xii—Al6—Al14x111.41 (5)Al8—Fe1—Al7xiii69.19 (2)
Al1—Al6—Al14x104.89 (4)Al10—Fe1—Al4xviii67.80 (5)
Al9iii—Al6—Al14x113.16 (5)Al7—Fe1—Al4xviii168.26 (5)
Al7—Al6—Al14x74.26 (4)Al9iii—Fe1—Al4xviii117.90 (4)
Fe3v—Al8—Fe3xiv71.20 (5)Al9—Fe1—Al4xviii117.90 (4)
Fe3v—Al8—Fe1xiii108.862 (18)Al8xiii—Fe1—Al4xviii102.79 (3)
Fe3xiv—Al8—Fe1xiii172.76 (2)Al8—Fe1—Al4xviii102.79 (3)
Fe3v—Al8—Fe1172.76 (2)Al7xiii—Fe1—Al4xviii59.28 (5)
Fe3xiv—Al8—Fe1108.861 (18)Al10—Fe1—Al13xvi66.00 (3)
Fe1xiii—Al8—Fe172.04 (5)Al7—Fe1—Al13xvi122.50 (2)
Fe3v—Al8—Al13iv56.06 (3)Al9iii—Fe1—Al13xvi61.80 (3)
Fe3xiv—Al8—Al13iv113.68 (5)Al9—Fe1—Al13xvi132.99 (4)
Fe1xiii—Al8—Al13iv62.23 (3)Al8xiii—Fe1—Al13xvi64.19 (3)
Fe1—Al8—Al13iv128.44 (5)Al8—Fe1—Al13xvi155.93 (4)
Fe3v—Al8—Al13xiv113.68 (5)Al7xiii—Fe1—Al13xvi86.96 (3)
Fe3xiv—Al8—Al13xiv56.06 (3)Al4xviii—Fe1—Al13xvi60.01 (3)
Fe1xiii—Al8—Al13xiv128.44 (5)Al10—Fe1—Al13xiv66.00 (3)
Fe1—Al8—Al13xiv62.23 (3)Al7—Fe1—Al13xiv122.50 (2)
Al13iv—Al8—Al13xiv168.94 (7)Al9iii—Fe1—Al13xiv132.99 (4)
Fe3v—Al8—Al9128.48 (5)Al9—Fe1—Al13xiv61.80 (3)
Fe3xiv—Al8—Al963.36 (3)Al8xiii—Fe1—Al13xiv155.93 (3)
Fe1xiii—Al8—Al9113.21 (5)Al8—Fe1—Al13xiv64.19 (3)
Fe1—Al8—Al955.45 (3)Al7xiii—Fe1—Al13xiv86.96 (3)
Al13iv—Al8—Al9123.90 (3)Al4xviii—Fe1—Al13xiv60.01 (2)
Al13xiv—Al8—Al957.51 (3)Al13xvi—Fe1—Al13xiv112.93 (5)
Fe3v—Al8—Al9xv63.36 (3)Al10—Fe1—Fe1xiii179.91 (5)
Fe3xiv—Al8—Al9xv128.48 (5)Al7—Fe1—Fe1xiii56.16 (4)
Fe1xiii—Al8—Al9xv55.45 (3)Al9iii—Fe1—Fe1xiii109.43 (3)
Fe1—Al8—Al9xv113.21 (5)Al9—Fe1—Fe1xiii109.43 (3)
Al13iv—Al8—Al9xv57.51 (3)Al8xiii—Fe1—Fe1xiii53.98 (2)
Al13xiv—Al8—Al9xv123.90 (3)Al8—Fe1—Fe1xiii53.98 (2)
Al9—Al8—Al9xv167.72 (7)Al7xiii—Fe1—Fe1xiii52.83 (4)
Fe3v—Al8—Al7xiii117.58 (3)Al4xviii—Fe1—Fe1xiii112.11 (4)
Fe3xiv—Al8—Al7xiii132.55 (3)Al13xvi—Fe1—Fe1xiii113.96 (3)
Fe1xiii—Al8—Al7xiii54.20 (4)Al13xiv—Fe1—Fe1xiii113.96 (3)
Fe1—Al8—Al7xiii56.75 (4)Al10—Fe3—Al12123.53 (6)
Al13iv—Al8—Al7xiii107.52 (4)Al10—Fe3—Al1166.23 (5)
Al13xiv—Al8—Al7xiii80.44 (4)Al12—Fe3—Al11170.24 (6)
Al9—Al8—Al7xiii110.75 (5)Al10—Fe3—Al8xxiv125.58 (2)
Al9xv—Al8—Al7xiii59.73 (4)Al12—Fe3—Al8xxiv72.15 (2)
Fe3v—Al8—Al7132.55 (3)Al11—Fe3—Al8xxiv102.61 (3)
Fe3xiv—Al8—Al7117.58 (3)Al10—Fe3—Al8xiv125.58 (2)
Fe1xiii—Al8—Al756.75 (4)Al12—Fe3—Al8xiv72.15 (2)
Fe1—Al8—Al754.20 (4)Al11—Fe3—Al8xiv102.61 (3)
Al13iv—Al8—Al780.44 (4)Al8xxiv—Fe3—Al8xiv108.80 (5)
Al13xiv—Al8—Al7107.52 (4)Al10—Fe3—Al13iii71.29 (4)
Al9—Al8—Al759.73 (4)Al12—Fe3—Al13iii69.48 (4)
Al9xv—Al8—Al7110.75 (5)Al11—Fe3—Al13iii116.75 (4)
Al7xiii—Al8—Al791.06 (6)Al8xxiv—Fe3—Al13iii67.99 (3)
Fe3v—Al8—Al12v53.42 (4)Al8xiv—Fe3—Al13iii140.41 (4)
Fe3xiv—Al8—Al12v57.72 (4)Al10—Fe3—Al1371.29 (4)
Fe1xiii—Al8—Al12v116.18 (3)Al12—Fe3—Al1369.48 (4)
Fe1—Al8—Al12v133.06 (3)Al11—Fe3—Al13116.75 (4)
Al13iv—Al8—Al12v59.29 (4)Al8xxiv—Fe3—Al13140.41 (4)
Al13xiv—Al8—Al12v112.13 (5)Al8xiv—Fe3—Al1367.99 (3)
Al9—Al8—Al12v81.49 (4)Al13iii—Fe3—Al1389.56 (5)
Al9xv—Al8—Al12v107.25 (4)Al10—Fe3—Al12xx125.76 (5)
Al7xiii—Al8—Al12v166.33 (4)Al12—Fe3—Al12xx110.71 (4)
Al7—Al8—Al12v90.10 (3)Al11—Fe3—Al12xx59.53 (5)
Fe3v—Al8—Al12xiv57.72 (4)Al8xxiv—Fe3—Al12xx69.24 (2)
Fe3xiv—Al8—Al12xiv53.42 (4)Al8xiv—Fe3—Al12xx69.24 (2)
Fe1xiii—Al8—Al12xiv133.06 (3)Al13iii—Fe3—Al12xx134.53 (3)
Fe1—Al8—Al12xiv116.18 (3)Al13—Fe3—Al12xx134.53 (3)
Al13iv—Al8—Al12xiv112.13 (5)Al10—Fe3—Al9xvi65.51 (3)
Al13xiv—Al8—Al12xiv59.29 (4)Al12—Fe3—Al9xvi122.33 (2)
Al9—Al8—Al12xiv107.25 (4)Al11—Fe3—Al9xvi59.82 (2)
Al9xv—Al8—Al12xiv81.49 (4)Al8xxiv—Fe3—Al9xvi63.74 (3)
Al7xiii—Al8—Al12xiv90.10 (3)Al8xiv—Fe3—Al9xvi155.76 (4)
Al7—Al8—Al12xiv166.33 (4)Al13iii—Fe3—Al9xvi60.83 (3)
Al12v—Al8—Al12xiv91.97 (6)Al13—Fe3—Al9xvi133.31 (4)
Fe1—Al9—Fe4ii151.13 (5)Al12xx—Fe3—Al9xvi86.83 (3)
Fe1—Al9—Al11xiv146.65 (5)Al10—Fe3—Al9xiv65.51 (3)
Fe4ii—Al9—Al11xiv58.23 (4)Al12—Fe3—Al9xiv122.33 (2)
Fe1—Al9—Al13xiv63.91 (3)Al11—Fe3—Al9xiv59.82 (2)
Fe4ii—Al9—Al13xiv136.48 (5)Al8xxiv—Fe3—Al9xiv155.76 (4)
Al11xiv—Al9—Al13xiv105.24 (5)Al8xiv—Fe3—Al9xiv63.74 (3)
Fe1—Al9—Fe3xiv100.39 (4)Al13iii—Fe3—Al9xiv133.31 (4)
Fe4ii—Al9—Fe3xiv108.44 (4)Al13—Fe3—Al9xiv60.83 (3)
Al11xiv—Al9—Fe3xiv54.24 (4)Al12xx—Fe3—Al9xiv86.83 (3)
Al13xiv—Al9—Fe3xiv54.11 (3)Al9xvi—Fe3—Al9xiv112.78 (5)
Fe1—Al9—Al855.93 (4)Al10—Fe3—Fe3xx178.25 (5)
Fe4ii—Al9—Al8145.71 (5)Al12—Fe3—Fe3xx58.22 (4)
Al11xiv—Al9—Al890.89 (5)Al11—Fe3—Fe3xx112.02 (5)
Al13xiv—Al9—Al860.99 (3)Al8xxiv—Fe3—Fe3xx54.40 (2)
Fe3xiv—Al9—Al852.90 (4)Al8xiv—Fe3—Fe3xx54.40 (2)
Fe1—Al9—Al6iii115.83 (5)Al13iii—Fe3—Fe3xx109.88 (3)
Fe4ii—Al9—Al6iii57.17 (3)Al13—Fe3—Fe3xx109.88 (3)
Al11xiv—Al9—Al6iii59.01 (4)Al12xx—Fe3—Fe3xx52.49 (4)
Al13xiv—Al9—Al6iii153.12 (5)Al9xvi—Fe3—Fe3xx113.77 (3)
Fe3xiv—Al9—Al6iii102.03 (4)Al9xiv—Fe3—Fe3xx113.77 (3)
Al8—Al9—Al6iii95.65 (4)Al14iii—Fe2—Al1492.50 (5)
Fe1—Al9—Al755.00 (4)Al14iii—Fe2—Al1269.30 (3)
Fe4ii—Al9—Al7111.69 (5)Al14—Fe2—Al1269.30 (3)
Al11xiv—Al9—Al7109.06 (5)Al14iii—Fe2—Al15116.82 (3)
Al13xiv—Al9—Al7111.81 (5)Al14—Fe2—Al15116.82 (3)
Fe3xiv—Al9—Al7109.71 (4)Al12—Fe2—Al15170.01 (5)
Al8—Al9—Al761.47 (4)Al14iii—Fe2—Al5i73.17 (4)
Al6iii—Al9—Al760.87 (4)Al14—Fe2—Al5i73.17 (4)
Fe1—Al9—Al13114.71 (4)Al12—Fe2—Al5i124.50 (5)
Fe4ii—Al9—Al1356.10 (3)Al15—Fe2—Al5i65.49 (5)
Al11xiv—Al9—Al1396.02 (5)Al14iii—Fe2—Al6xxix69.83 (3)
Al13xiv—Al9—Al1390.47 (4)Al14—Fe2—Al6xxix150.51 (4)
Fe3xiv—Al9—Al13110.70 (4)Al12—Fe2—Al6xxix82.17 (3)
Al8—Al9—Al13151.44 (4)Al15—Fe2—Al6xxix92.49 (3)
Al6iii—Al9—Al13111.67 (4)Al5i—Fe2—Al6xxix120.56 (3)
Al7—Al9—Al13139.54 (5)Al14iii—Fe2—Al6xxi150.52 (4)
Fe1—Al9—Al1053.78 (4)Al14—Fe2—Al6xxi69.83 (3)
Fe4ii—Al9—Al10112.26 (5)Al12—Fe2—Al6xxi82.17 (3)
Al11xiv—Al9—Al10151.50 (5)Al15—Fe2—Al6xxi92.49 (3)
Al13xiv—Al9—Al1061.46 (4)Al5i—Fe2—Al6xxi120.56 (3)
Fe3xiv—Al9—Al10115.11 (4)Al6xxix—Fe2—Al6xxi114.53 (5)
Al8—Al9—Al10102.02 (5)Al14iii—Fe2—Al15xxii132.97 (3)
Al6iii—Al9—Al10142.43 (5)Al14—Fe2—Al15xxii132.97 (3)
Al7—Al9—Al1099.43 (4)Al12—Fe2—Al15xxii111.05 (5)
Al13—Al9—Al1061.11 (4)Al15—Fe2—Al15xxii58.96 (5)
Fe1—Al9—Al10xiv126.00 (5)Al5i—Fe2—Al15xxii124.44 (5)
Fe4ii—Al9—Al10xiv75.74 (4)Al6xxix—Fe2—Al15xxii63.93 (3)
Al11xiv—Al9—Al10xiv58.55 (4)Al6xxi—Fe2—Al15xxii63.93 (3)
Al13xiv—Al9—Al10xiv62.57 (4)Al14iii—Fe2—Al11xx107.31 (3)
Fe3xiv—Al9—Al10xiv51.36 (3)Al14—Fe2—Al11xx107.31 (3)
Al8—Al9—Al10xiv101.98 (5)Al12—Fe2—Al11xx56.22 (4)
Al6iii—Al9—Al10xiv114.86 (5)Al15—Fe2—Al11xx113.79 (5)
Al7—Al9—Al10xiv160.66 (5)Al5i—Fe2—Al11xx179.28 (5)
Al13—Al9—Al10xiv59.66 (4)Al6xxix—Fe2—Al11xx59.29 (3)
Al10—Al9—Al10xiv93.66 (3)Al6xxi—Fe2—Al11xx59.29 (3)
Fe1—Al9—Al2i101.02 (4)Al15xxii—Fe2—Al11xx54.83 (4)
Fe4ii—Al9—Al2i50.12 (3)Al14iii—Fe2—Al3xxiii131.08 (4)
Al11xiv—Al9—Al2i104.35 (4)Al14—Fe2—Al3xxiii59.40 (3)
Al13xiv—Al9—Al2i142.15 (5)Al12—Fe2—Al3xxiii123.62 (3)
Fe3xiv—Al9—Al2i158.17 (4)Al15—Fe2—Al3xxiii59.35 (3)
Al8—Al9—Al2i141.03 (5)Al5i—Fe2—Al3xxiii61.16 (3)
Al6iii—Al9—Al2i64.45 (4)Al6xxix—Fe2—Al3xxiii149.49 (4)
Al7—Al9—Al2i79.61 (4)Al6xxi—Fe2—Al3xxiii60.24 (3)
Al13—Al9—Al2i63.36 (4)Al15xxii—Fe2—Al3xxiii89.55 (3)
Al10—Al9—Al2i81.42 (5)Al11xx—Fe2—Al3xxiii118.56 (3)
Al10xiv—Al9—Al2i116.65 (5)Al14iii—Fe2—Al3xxiv59.40 (3)
Fe1—Al10—Fe3165.79 (8)Al14—Fe2—Al3xxiv131.08 (4)
Fe1—Al10—Al11136.67 (7)Al12—Fe2—Al3xxiv123.62 (3)
Fe3—Al10—Al1157.54 (4)Al15—Fe2—Al3xxiv59.35 (3)
Fe1—Al10—Al4xviii59.48 (5)Al5i—Fe2—Al3xxiv61.16 (3)
Fe3—Al10—Al4xviii134.73 (7)Al6xxix—Fe2—Al3xxiv60.24 (3)
Al11—Al10—Al4xviii77.19 (6)Al6xxi—Fe2—Al3xxiv149.49 (4)
Fe1—Al10—Al13xiv62.40 (3)Al15xxii—Fe2—Al3xxiv89.55 (3)
Fe3—Al10—Al13xiv122.55 (4)Al11xx—Fe2—Al3xxiv118.56 (3)
Al11—Al10—Al13xiv95.06 (5)Al3xxiii—Fe2—Al3xxiv107.65 (5)
Al4xviii—Al10—Al13xiv56.79 (3)Al14iii—Cu2—Al1492.50 (5)
Fe1—Al10—Al13xvi62.40 (3)Al14iii—Cu2—Al1269.30 (3)
Fe3—Al10—Al13xvi122.55 (4)Al14—Cu2—Al1269.30 (3)
Al11—Al10—Al13xvi95.06 (5)Al14iii—Cu2—Al15116.82 (3)
Al4xviii—Al10—Al13xvi56.79 (3)Al14—Cu2—Al15116.82 (3)
Al13xiv—Al10—Al13xvi107.92 (6)Al12—Cu2—Al15170.01 (5)
Fe1—Al10—Al9iii55.59 (4)Al14iii—Cu2—Al5i73.17 (4)
Fe3—Al10—Al9iii114.23 (5)Al14—Cu2—Al5i73.17 (4)
Al11—Al10—Al9iii142.71 (3)Al12—Cu2—Al5i124.50 (5)
Al4xviii—Al10—Al9iii101.28 (5)Al15—Cu2—Al5i65.49 (5)
Al13xiv—Al10—Al9iii115.53 (6)Al14iii—Cu2—Al6xxix69.83 (3)
Al13xvi—Al10—Al9iii56.75 (3)Al14—Cu2—Al6xxix150.51 (4)
Fe1—Al10—Al955.59 (4)Al12—Cu2—Al6xxix82.17 (3)
Fe3—Al10—Al9114.23 (5)Al15—Cu2—Al6xxix92.49 (3)
Al11—Al10—Al9142.71 (3)Al5i—Cu2—Al6xxix120.56 (3)
Al4xviii—Al10—Al9101.28 (5)Al14iii—Cu2—Al6xxi150.52 (4)
Al13xiv—Al10—Al956.75 (3)Al14—Cu2—Al6xxi69.83 (3)
Al13xvi—Al10—Al9115.53 (6)Al12—Cu2—Al6xxi82.17 (3)
Al9iii—Al10—Al974.54 (6)Al15—Cu2—Al6xxi92.49 (3)
Fe1—Al10—Al9xvi121.76 (4)Al5i—Cu2—Al6xxi120.56 (3)
Fe3—Al10—Al9xvi63.13 (3)Al6xxix—Cu2—Al6xxi114.53 (5)
Al11—Al10—Al9xvi56.91 (3)Al14iii—Cu2—Al15xxii132.97 (3)
Al4xviii—Al10—Al9xvi93.59 (4)Al14—Cu2—Al15xxii132.97 (3)
Al13xiv—Al10—Al9xvi144.87 (7)Al12—Cu2—Al15xxii111.05 (5)
Al13xvi—Al10—Al9xvi59.84 (3)Al15—Cu2—Al15xxii58.96 (5)
Al9iii—Al10—Al9xvi86.34 (3)Al5i—Cu2—Al15xxii124.44 (5)
Al9—Al10—Al9xvi157.66 (6)Al6xxix—Cu2—Al15xxii63.93 (3)
Fe1—Al10—Al9xiv121.76 (4)Al6xxi—Cu2—Al15xxii63.93 (3)
Fe3—Al10—Al9xiv63.13 (3)Al14iii—Cu2—Al11xx107.31 (3)
Al11—Al10—Al9xiv56.91 (3)Al14—Cu2—Al11xx107.31 (3)
Al4xviii—Al10—Al9xiv93.59 (4)Al12—Cu2—Al11xx56.22 (4)
Al13xiv—Al10—Al9xiv59.84 (3)Al15—Cu2—Al11xx113.79 (5)
Al13xvi—Al10—Al9xiv144.87 (7)Al5i—Cu2—Al11xx179.28 (5)
Al9iii—Al10—Al9xiv157.66 (6)Al6xxix—Cu2—Al11xx59.29 (3)
Al9—Al10—Al9xiv86.34 (3)Al6xxi—Cu2—Al11xx59.29 (3)
Al9xvi—Al10—Al9xiv109.45 (6)Al15xxii—Cu2—Al11xx54.83 (4)
Fe1—Al10—Al13iii114.78 (5)Al14iii—Cu2—Al3xxiii131.08 (4)
Fe3—Al10—Al13iii55.16 (3)Al14—Cu2—Al3xxiii59.40 (3)
Al11—Al10—Al13iii99.00 (5)Al12—Cu2—Al3xxiii123.62 (3)
Al4xviii—Al10—Al13iii142.36 (3)Al15—Cu2—Al3xxiii59.35 (3)
Al13xiv—Al10—Al13iii158.67 (6)Al5i—Cu2—Al3xxiii61.16 (3)
Al13xvi—Al10—Al13iii86.81 (3)Al6xxix—Cu2—Al3xxiii149.49 (4)
Al9iii—Al10—Al13iii59.38 (4)Al6xxi—Cu2—Al3xxiii60.24 (3)
Al9—Al10—Al13iii103.29 (6)Al15xxii—Cu2—Al3xxiii89.55 (3)
Al9xvi—Al10—Al13iii56.00 (3)Al11xx—Cu2—Al3xxiii118.56 (3)
Al9xiv—Al10—Al13iii115.94 (6)Al14iii—Cu2—Al3xxiv59.40 (3)
Fe1—Al10—Al13114.78 (5)Al14—Cu2—Al3xxiv131.08 (4)
Fe3—Al10—Al1355.16 (3)Al12—Cu2—Al3xxiv123.62 (3)
Al11—Al10—Al1399.00 (5)Al15—Cu2—Al3xxiv59.35 (3)
Al4xviii—Al10—Al13142.36 (3)Al5i—Cu2—Al3xxiv61.16 (3)
Al13xiv—Al10—Al1386.81 (3)Al6xxix—Cu2—Al3xxiv60.24 (3)
Al13xvi—Al10—Al13158.67 (6)Al6xxi—Cu2—Al3xxiv149.49 (4)
Al9iii—Al10—Al13103.29 (6)Al15xxii—Cu2—Al3xxiv89.55 (3)
Al9—Al10—Al1359.38 (4)Al11xx—Cu2—Al3xxiv118.56 (3)
Al9xvi—Al10—Al13115.94 (6)Al3xxiii—Cu2—Al3xxiv107.65 (5)
Al9xiv—Al10—Al1356.00 (3)
Symmetry codes: (i) −x+1, −y+1, −z+1; (ii) −x+1, y, −z+1; (iii) x, −y+1, z; (iv) x+1/2, −y+3/2, z; (v) x+1/2, y+1/2, z; (vi) −x+3/2, −y+3/2, −z+1; (vii) x, −y+2, z; (viii) x+1/2, y+1/2, z+1; (ix) −x+1, −y+2, −z+1; (x) x+1/2, y−1/2, z; (xi) −x+1/2, −y+1/2, −z; (xii) −x+1/2, −y+1/2, −z+1; (xiii) −x+1, −y+1, −z; (xiv) −x+1/2, −y+3/2, −z; (xv) −x+1, y, −z; (xvi) −x+1/2, y−1/2, −z; (xvii) x−1/2, −y+3/2, z−1; (xviii) x−1/2, y−1/2, z−1; (xix) x, y, z−1; (xx) −x, −y+1, −z; (xxi) x−1/2, y+1/2, z; (xxii) −x, −y+1, −z+1; (xxiii) x−1/2, −y+3/2, z; (xxiv) x−1/2, y−1/2, z; (xxv) −x+3/2, y−1/2, −z+1; (xxvi) −x+1/2, y+1/2, −z; (xxvii) x, y, z+1; (xxviii) −x+1/2, y+1/2, −z+1; (xxix) x−1/2, −y+1/2, z.
 

Acknowledgements

We greatly acknowledge the financial support from the Hebei Province Youth Top-notch Talent Program (2013–2018).

References

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This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.

Journal logoIUCrDATA
ISSN: 2414-3146
Volume 3| Part 3| March 2018| x180363
https://doi.org/10.1107/S2414314618003632
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