inorganic compounds
45Cr7C0.32
of AlaState Key Laboratory of Metastable Materials Science and Technology, Yanshan University, Qinhuangdao 066004, People's Republic of China
*Correspondence e-mail: chzfan@ysu.edu.cn
During a high-pressure sintering (HPS) process of a stoichiometric Al7Cr mixture, the ternary phase Al45Cr7C0.32 (pentatetracontaaluminium heptachromium carbide) was obtained serendipitously. The C atom (occupancy 0.32) is irregularly surrounded by six Al atoms.
CCDC reference: 1816969
Structure description
Phase formation of a quasicrystalline phase in an Al–Cr alloy by ion irradiation of an amorphous film was reported by Lilienfeld et al. (1986). The structure of the binary phase Al45Cr7 (θ-Al7Cr) phase was determined by Cooper (1960) in the C2/m, with a = 25.196, b = 7.574, c = 10.949 Å, β = 128° 43′. This phase is isotypic with Al45V7. In a redetermination of θ-Al7Cr, He et al. (2006) used a different unit-cell setting with a = 20.595, b = 7.574, c = 10.949 Å, β = 107.34°. During a project aimed at formation of quasicrystalline material in the Al–Cr system under high-pressure conditions, we obtained the title compound and learned that light atoms can be incorporated into the Al45Cr7 host structure. We attribute the slight increase in the unit-cell lengths and the decrease in the monoclinic angle in comparison with the values of the binary phase reported by He et al. (2006) (Δa = 0.028 Å, Δb = 0.016 Å, Δc = 0.0136 Å, Δβ = −0.03°) to the presence of partially occupied light atoms that must have been diffused into the during the HPS process, or were present as impurities in the employed metals. In principle, the light atoms could be boron, nitrogen (from the BN crucible), or carbon (from the graphite liner). In fact, we found that the educts were contaminated by small amounts of carbon (see Supplementary information).
The 45Cr7C0.32 comprises of sixteen Al, three Cr and one partially occupied C sites (occupancy 0.32). Since the host structure has been described in detail (Cooper, 1960; He et al., 2006), we discuss here only the role of the additional carbon atom in Al45Cr7C0.32. The position of the C1 atom in the can be seen in Fig. 1. It is located on a site with symmetry m (Wyckoff position 4i) and is connected to six Al atoms that form an irregular polyhedron (Fig. 2). The distances between C1 and Al1, Al3, Al5 and Al7 are 1.878 (16), 2.351 (16), 2.497 (6) and 2.378 (13) Å, respectively.
of AlSynthesis and crystallization
The elements Al (indicated purity 99.8%) and Cr (indicated purity 99.95%) were mixed in the stoichiometric ratio of 7:1 and initially ground in an agate mortar. The blended powders were then placed into a grinding tool with a diameter of 9.6 mm and pressed into a tablet at about 3.5 MPa slowly and continuously for about 5 minutes. A cylindrical block 9.6 mm in diameter and 10.0 mm in height was obtained without any defects such as cracks or deformations. The cylindrical block was then inserted into a six-anvil high-pressure apparatus for HPS experiments, pressurized up to 5 GPa and heated to 1183 K for 30 minutes, cooled to 1033 K and held at that temperature for 2 h, and then rapidly cooled down to room temperature. A fragment 0.05 × 0.04 × 0.02 mm3 in size was selected and mounted on a glass fiber for single-crystal X-ray diffraction measurements.
Refinement
Crystal data, data collection and structure . After consideration of all atoms in the Al45Cr7 structure, we found significant remaining electron density (2.1 e− Å3) that was modelled as a carbon atom with partial occupancy. The site occupation factor was refined freely and converged at 0.160 (11). The C atom was treated with an ISOR command to get a physically reasonable shape. The remaining maximum and minimum electron densities are located 0.88 Å from atom Al6 and 0.48 Å from atom Cr1, respectively.
details are summarized in Table 1Structural data
CCDC reference: 1816969
https://doi.org/10.1107/S2414314618000937/wm4061sup1.cif
contains datablock I. DOI:Structure factors: contains datablock I. DOI: https://doi.org/10.1107/S2414314618000937/wm4061Isup2.hkl
Carbon analysis results. DOI: https://doi.org/10.1107/S2414314618000937/wm4061sup3.pdf
Data collection: APEX3 (Bruker, 2015); cell
SAINT (Bruker, 2015); data reduction: SAINT (Bruker, 2015); program(s) used to solve structure: SHELXT (Sheldrick, 2015a); program(s) used to refine structure: SHELXL2014/7 (Sheldrick, 2015b); molecular graphics: DIAMOND (Brandenburg & Putz, 2017); software used to prepare material for publication: publCIF (Westrip, 2010).C0.32Al45Cr7 | F(000) = 1510 |
Mr = 1581.95 | Dx = 3.207 Mg m−3 |
Monoclinic, C2/m | Mo Kα radiation, λ = 0.71073 Å |
a = 20.623 (2) Å | Cell parameters from 1903 reflections |
b = 7.5900 (9) Å | θ = 2.9–28.4° |
c = 10.9626 (13) Å | µ = 3.46 mm−1 |
β = 107.310 (3)° | T = 293 K |
V = 1638.2 (3) Å3 | Grain, metallic |
Z = 2 | 0.05 × 0.04 × 0.02 mm |
Bruker APEXII Photon 100 CMOS diffractometer | 1903 reflections with I > 2σ(I) |
phi and ω scans | Rint = 0.038 |
Absorption correction: multi-scan (SADABS; Bruker, 2015) | θmax = 28.4°, θmin = 2.9° |
Tmin = 0.553, Tmax = 0.746 | h = −27→27 |
9513 measured reflections | k = −10→9 |
2191 independent reflections | l = −14→14 |
Refinement on F2 | 142 parameters |
Least-squares matrix: full | 6 restraints |
R[F2 > 2σ(F2)] = 0.027 | w = 1/[σ2(Fo2) + (0.0188P)2 + 4.4834P] where P = (Fo2 + 2Fc2)/3 |
wR(F2) = 0.060 | (Δ/σ)max = 0.001 |
S = 1.02 | Δρmax = 0.54 e Å−3 |
2191 reflections | Δρmin = −0.71 e Å−3 |
Geometry. All esds (except the esd in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell esds are taken into account individually in the estimation of esds in distances, angles and torsion angles; correlations between esds in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell esds is used for estimating esds involving l.s. planes. |
x | y | z | Uiso*/Ueq | Occ. (<1) | |
Al1 | 0.09059 (5) | 0.5000 | 0.34230 (10) | 0.0142 (2) | |
Cr1 | 0.0000 | 0.5000 | 0.5000 | 0.00839 (15) | |
C1 | 0.1632 (8) | 0.5000 | 0.2718 (16) | 0.003 (5) | 0.160 (11) |
Al2 | 0.12849 (5) | 0.5000 | 0.61192 (9) | 0.0116 (2) | |
Cr2 | 0.25029 (2) | 0.5000 | 0.73869 (5) | 0.00844 (12) | |
Al3 | 0.22392 (5) | 0.5000 | 0.49039 (9) | 0.0115 (2) | |
Cr3 | 0.58523 (2) | 0.32368 (5) | 0.91792 (3) | 0.00790 (9) | |
Al4 | 0.29353 (3) | 0.68643 (9) | 0.36573 (7) | 0.01277 (15) | |
Al5 | 0.33511 (4) | 0.69296 (10) | 0.64551 (7) | 0.01313 (15) | |
Al6 | 0.37439 (4) | 0.5000 | 0.86551 (9) | 0.00862 (19) | |
Al7 | 0.31030 (3) | 0.18598 (10) | 0.88132 (7) | 0.01337 (16) | |
Al8 | 0.29273 (5) | 0.5000 | 1.01491 (9) | 0.0114 (2) | |
Al9 | 0.5000 | 0.5000 | 1.0000 | 0.0076 (3) | |
Al10 | 0.45400 (3) | 0.19674 (9) | 0.87763 (6) | 0.01182 (15) | |
Al11 | 0.47798 (5) | 0.5000 | 0.74372 (9) | 0.0109 (2) | |
Al12 | 0.43072 (3) | 0.31858 (9) | 0.51014 (7) | 0.01300 (16) | |
Al13 | 0.53571 (3) | 0.18856 (9) | 0.70481 (6) | 0.01140 (15) | |
Al14 | 0.61492 (5) | 0.5000 | 0.72906 (9) | 0.0113 (2) | |
Al15 | 0.68150 (3) | 0.18638 (9) | 0.85428 (6) | 0.01101 (15) | |
Al16 | 0.58033 (5) | 0.0000 | 0.93926 (9) | 0.0111 (2) |
U11 | U22 | U33 | U12 | U13 | U23 | |
Al1 | 0.0138 (5) | 0.0110 (5) | 0.0149 (5) | 0.000 | 0.0000 (4) | 0.000 |
Cr1 | 0.0091 (3) | 0.0064 (4) | 0.0092 (3) | 0.000 | 0.0020 (3) | 0.000 |
C1 | 0.005 (6) | 0.001 (6) | 0.003 (6) | 0.000 | 0.001 (4) | 0.000 |
Al2 | 0.0094 (4) | 0.0112 (5) | 0.0137 (5) | 0.000 | 0.0027 (4) | 0.000 |
Cr2 | 0.0080 (2) | 0.0083 (3) | 0.0091 (2) | 0.000 | 0.00262 (19) | 0.000 |
Al3 | 0.0122 (4) | 0.0102 (5) | 0.0126 (5) | 0.000 | 0.0043 (4) | 0.000 |
Cr3 | 0.00858 (17) | 0.00604 (19) | 0.00929 (17) | −0.00005 (13) | 0.00299 (13) | −0.00042 (13) |
Al4 | 0.0141 (3) | 0.0102 (4) | 0.0153 (3) | 0.0005 (3) | 0.0065 (3) | 0.0020 (3) |
Al5 | 0.0149 (3) | 0.0113 (4) | 0.0140 (3) | −0.0015 (3) | 0.0055 (3) | 0.0013 (3) |
Al6 | 0.0078 (4) | 0.0077 (5) | 0.0097 (4) | 0.000 | 0.0016 (3) | 0.000 |
Al7 | 0.0132 (3) | 0.0118 (4) | 0.0145 (3) | 0.0005 (3) | 0.0030 (3) | 0.0011 (3) |
Al8 | 0.0110 (4) | 0.0088 (5) | 0.0139 (5) | 0.000 | 0.0031 (4) | 0.000 |
Al9 | 0.0067 (6) | 0.0065 (7) | 0.0100 (6) | 0.000 | 0.0031 (5) | 0.000 |
Al10 | 0.0140 (3) | 0.0091 (4) | 0.0133 (3) | −0.0007 (3) | 0.0056 (3) | −0.0007 (3) |
Al11 | 0.0131 (4) | 0.0083 (5) | 0.0116 (4) | 0.000 | 0.0041 (4) | 0.000 |
Al12 | 0.0137 (3) | 0.0114 (4) | 0.0130 (3) | 0.0011 (3) | 0.0026 (3) | −0.0006 (3) |
Al13 | 0.0130 (3) | 0.0090 (4) | 0.0114 (3) | −0.0002 (3) | 0.0024 (3) | −0.0015 (3) |
Al14 | 0.0137 (5) | 0.0080 (5) | 0.0131 (5) | 0.000 | 0.0050 (4) | 0.000 |
Al15 | 0.0113 (3) | 0.0088 (4) | 0.0139 (3) | 0.0006 (3) | 0.0052 (3) | −0.0007 (3) |
Al16 | 0.0146 (5) | 0.0060 (5) | 0.0135 (5) | 0.000 | 0.0054 (4) | 0.000 |
Al1—C1 | 1.878 (16) | Al6—Al7viii | 2.7557 (9) |
Al1—Al3 | 2.7458 (14) | Al6—Al7 | 2.7557 (9) |
Al1—Al10i | 2.7512 (11) | Al6—Al10viii | 2.8073 (9) |
Al1—Al10ii | 2.7512 (11) | Al6—Al10 | 2.8073 (9) |
Al1—Al5iii | 2.7703 (9) | Al6—Al11 | 2.8362 (13) |
Al1—Al5iv | 2.7703 (9) | Al7—C1i | 2.378 (13) |
Al1—Al2 | 2.8235 (14) | Al7—Al15vii | 2.7592 (10) |
Al1—Al13i | 2.8807 (11) | Al7—Cr3x | 2.7848 (8) |
Al1—Al13ii | 2.8807 (11) | Al7—Al7xii | 2.8232 (15) |
Al1—Cr1 | 2.8983 (11) | Al7—Al15x | 2.8528 (10) |
Cr1—Al2 | 2.5674 (10) | Al7—Al8 | 2.8762 (9) |
Cr1—Al2v | 2.5675 (10) | Al7—Al16xiii | 2.8824 (11) |
Cr1—Al13i | 2.5783 (7) | Al7—Al4iv | 2.9101 (10) |
Cr1—Al13vi | 2.5783 (7) | Al7—Al5viii | 2.9284 (10) |
Cr1—Al13vii | 2.5783 (7) | Al7—Al10 | 2.9768 (10) |
Cr1—Al13ii | 2.5783 (7) | Al8—Al15ix | 2.7480 (9) |
Cr1—Al12vii | 2.8275 (8) | Al8—Al15x | 2.7480 (9) |
Cr1—Al12ii | 2.8275 (8) | Al8—Cr3ix | 2.7503 (9) |
Cr1—Al12vi | 2.8275 (7) | Al8—Cr3x | 2.7503 (9) |
Cr1—Al12i | 2.8275 (7) | Al8—Al15vii | 2.8213 (11) |
Cr1—Al1v | 2.8983 (11) | Al8—Al15vi | 2.8213 (11) |
C1—Al1 | 1.878 (16) | Al8—Al7viii | 2.8761 (9) |
C1—Al3 | 2.351 (16) | Al8—Al14ix | 2.8851 (14) |
C1—Al7i | 2.378 (13) | Al9—Al6ix | 2.5712 (9) |
C1—Al7ii | 2.378 (13) | Al9—Cr3viii | 2.5752 (4) |
C1—Al5iii | 2.497 (6) | Al9—Cr3x | 2.5752 (4) |
C1—Al5iv | 2.497 (6) | Al9—Cr3ix | 2.5752 (4) |
Al2—Cr2 | 2.4827 (11) | Al9—Al10 | 2.6908 (7) |
Al2—Al3 | 2.6849 (13) | Al9—Al10ix | 2.6908 (7) |
Al2—Al13vii | 2.8116 (11) | Al9—Al10viii | 2.6908 (7) |
Al2—Al13vi | 2.8116 (11) | Al9—Al10x | 2.6908 (7) |
Al2—Al4iii | 2.8419 (9) | Al9—Al11ix | 2.7093 (10) |
Al2—Al4iv | 2.8419 (9) | Al9—Al11 | 2.7093 (10) |
Al2—Al12i | 2.8558 (9) | Al10—Al1i | 2.7512 (11) |
Al2—Al12ii | 2.8558 (9) | Al10—Al16xiii | 2.7579 (11) |
Al2—Al15vi | 2.9201 (11) | Al10—Cr3x | 2.7722 (8) |
Al2—Al15vii | 2.9201 (11) | Al10—Al10x | 2.7873 (14) |
Cr2—Al6 | 2.5230 (11) | Al10—Al11 | 2.8513 (9) |
Cr2—Al15vii | 2.5863 (8) | Al10—Al13 | 2.8866 (10) |
Cr2—Al15vi | 2.5863 (8) | Al10—Al16 | 2.9028 (11) |
Cr2—Al3 | 2.6123 (11) | Al10—Al10xii | 2.9864 (15) |
Cr2—Al4iv | 2.6787 (8) | Al11—Al13 | 2.7366 (9) |
Cr2—Al4iii | 2.6787 (8) | Al11—Al13viii | 2.7366 (9) |
Cr2—Al5 | 2.7040 (8) | Al11—Cr3viii | 2.7958 (9) |
Cr2—Al5viii | 2.7040 (8) | Al11—Al12 | 2.8139 (11) |
Cr2—Al8 | 2.8910 (11) | Al11—Al12viii | 2.8139 (11) |
Cr2—Al7viii | 2.9165 (8) | Al11—Al10viii | 2.8514 (9) |
Cr2—Al7 | 2.9165 (8) | Al11—Al14 | 2.8758 (14) |
Al3—Al4 | 2.6642 (11) | Al12—Al13 | 2.7326 (10) |
Al3—Al4viii | 2.6642 (11) | Al12—Al12viii | 2.7539 (15) |
Al3—Al5 | 2.8240 (11) | Al12—Al5viii | 2.7998 (10) |
Al3—Al5viii | 2.8240 (11) | Al12—Al4viii | 2.8013 (10) |
Al3—Al5iv | 2.8378 (9) | Al12—Al13xiv | 2.8242 (10) |
Al3—Al5iii | 2.8378 (9) | Al12—Cr1xv | 2.8275 (7) |
Al3—Al4iii | 2.9359 (9) | Al12—Al2i | 2.8559 (9) |
Al3—Al4iv | 2.9359 (9) | Al12—Al14xi | 2.8617 (11) |
Cr3—Al16 | 2.4727 (5) | Al12—Al12xiv | 2.9313 (14) |
Cr3—Al13 | 2.4765 (8) | Al13—Cr1xv | 2.5784 (7) |
Cr3—Al15 | 2.5176 (8) | Al13—Al2xv | 2.8117 (11) |
Cr3—Al9 | 2.5752 (4) | Al13—Al12xiv | 2.8243 (10) |
Cr3—Al6ix | 2.6352 (9) | Al13—Al14 | 2.8404 (9) |
Cr3—Cr3viii | 2.6766 (8) | Al13—Al16 | 2.8448 (11) |
Cr3—Al14 | 2.6845 (9) | Al13—Al13xii | 2.8623 (14) |
Cr3—Al8ix | 2.7503 (9) | Al13—Al1i | 2.8806 (11) |
Cr3—Al10x | 2.7722 (8) | Al13—Al15 | 2.9653 (10) |
Cr3—Al10 | 2.7815 (8) | Al14—Cr3viii | 2.6844 (9) |
Cr3—Al7x | 2.7848 (8) | Al14—Al4xiv | 2.7955 (11) |
Cr3—Al11 | 2.7958 (9) | Al14—Al4xi | 2.7955 (11) |
Al4—Cr2iii | 2.6787 (8) | Al14—Al13viii | 2.8404 (9) |
Al4—Al5iii | 2.7743 (10) | Al14—Al12xiv | 2.8617 (11) |
Al4—Al15xi | 2.7844 (10) | Al14—Al12xi | 2.8617 (11) |
Al4—Al14xi | 2.7955 (11) | Al14—Al15 | 2.8835 (9) |
Al4—Al12viii | 2.8012 (10) | Al14—Al15viii | 2.8835 (9) |
Al4—Al4viii | 2.8300 (15) | Al14—Al8ix | 2.8851 (14) |
Al4—Al2iii | 2.8419 (9) | Al15—Cr2xv | 2.5863 (8) |
Al4—Al7ii | 2.9101 (10) | Al15—Al8ix | 2.7480 (9) |
Al4—Al5 | 2.9292 (10) | Al15—Al7xvi | 2.7592 (10) |
Al4—Al3iii | 2.9359 (9) | Al15—Al4xi | 2.7844 (10) |
Al5—C1iii | 2.497 (6) | Al15—Al8xv | 2.8214 (11) |
Al5—Al6 | 2.7304 (10) | Al15—Al15xii | 2.8293 (14) |
Al5—Al1iii | 2.7704 (9) | Al15—Al7x | 2.8528 (10) |
Al5—Al4iii | 2.7742 (10) | Al15—Al16 | 2.8947 (11) |
Al5—Al12viii | 2.7998 (10) | Al15—Al2xv | 2.9201 (11) |
Al5—Al3iii | 2.8378 (9) | Al16—Cr3xii | 2.4727 (5) |
Al5—Al7viii | 2.9285 (10) | Al16—Al10x | 2.7579 (11) |
Al5—Al5viii | 2.9291 (15) | Al16—Al10xiii | 2.7579 (11) |
Al6—Al9 | 2.5712 (9) | Al16—Al13xii | 2.8448 (11) |
Al6—Cr3ix | 2.6352 (9) | Al16—Al7x | 2.8824 (11) |
Al6—Cr3x | 2.6352 (9) | Al16—Al7xiii | 2.8824 (11) |
Al6—Al8 | 2.6757 (13) | Al16—Al15xii | 2.8946 (11) |
Al6—Al5viii | 2.7304 (11) | Al16—Al10xii | 2.9028 (11) |
C1—Al1—Al3 | 57.5 (5) | Al15x—Al7—Al16xiii | 60.62 (3) |
C1—Al1—Al10i | 74.8 (4) | Al8—Al7—Al16xiii | 104.47 (3) |
Al3—Al1—Al10i | 122.20 (4) | C1i—Al7—Al4iv | 66.7 (4) |
C1—Al1—Al10ii | 74.8 (4) | Al6—Al7—Al4iv | 100.04 (3) |
Al3—Al1—Al10ii | 122.20 (4) | Al15vii—Al7—Al4iv | 58.76 (2) |
Al10i—Al1—Al10ii | 65.74 (4) | Cr3x—Al7—Al4iv | 156.49 (3) |
C1—Al1—Al5iii | 61.49 (15) | Al7xii—Al7—Al4iv | 90.07 (2) |
Al3—Al1—Al5iii | 61.92 (2) | Al15x—Al7—Al4iv | 138.62 (3) |
Al10i—Al1—Al5iii | 122.32 (4) | Al8—Al7—Al4iv | 107.67 (3) |
Al10ii—Al1—Al5iii | 67.76 (2) | Al16xiii—Al7—Al4iv | 147.71 (3) |
C1—Al1—Al5iv | 61.49 (15) | C1i—Al7—Cr2 | 104.9 (3) |
Al3—Al1—Al5iv | 61.92 (2) | Al6—Al7—Cr2 | 52.73 (2) |
Al10i—Al1—Al5iv | 67.76 (2) | Al15vii—Al7—Cr2 | 54.13 (2) |
Al10ii—Al1—Al5iv | 122.32 (4) | Cr3x—Al7—Cr2 | 102.83 (3) |
Al5iii—Al1—Al5iv | 114.53 (5) | Al7xii—Al7—Cr2 | 144.809 (17) |
C1—Al1—Al2 | 115.1 (5) | Al15x—Al7—Cr2 | 115.55 (3) |
Al3—Al1—Al2 | 57.62 (3) | Al8—Al7—Cr2 | 59.87 (3) |
Al10i—Al1—Al2 | 146.47 (2) | Al16xiii—Al7—Cr2 | 152.52 (3) |
Al10ii—Al1—Al2 | 146.47 (2) | Al4iv—Al7—Cr2 | 54.74 (2) |
Al5iii—Al1—Al2 | 88.43 (3) | C1i—Al7—Al5viii | 55.0 (2) |
Al5iv—Al1—Al2 | 88.43 (3) | Al6—Al7—Al5viii | 57.32 (3) |
C1—Al1—Al13i | 135.6 (4) | Al15vii—Al7—Al5viii | 102.15 (3) |
Al3—Al1—Al13i | 143.03 (3) | Cr3x—Al7—Al5viii | 106.42 (3) |
Al10i—Al1—Al13i | 61.62 (3) | Al7xii—Al7—Al5viii | 108.29 (2) |
Al10ii—Al1—Al13i | 93.67 (4) | Al15x—Al7—Al5viii | 157.44 (3) |
Al5iii—Al1—Al13i | 152.15 (3) | Al8—Al7—Al5viii | 105.73 (3) |
Al5iv—Al1—Al13i | 92.77 (2) | Al16xiii—Al7—Al5viii | 116.70 (3) |
Al2—Al1—Al13i | 98.14 (4) | Al4iv—Al7—Al5viii | 56.74 (2) |
C1—Al1—Al13ii | 135.6 (4) | Cr2—Al7—Al5viii | 55.11 (2) |
Al3—Al1—Al13ii | 143.03 (3) | C1i—Al7—Al10 | 64.4 (4) |
Al10i—Al1—Al13ii | 93.67 (4) | Al6—Al7—Al10 | 58.49 (2) |
Al10ii—Al1—Al13ii | 61.62 (3) | Al15vii—Al7—Al10 | 156.82 (3) |
Al5iii—Al1—Al13ii | 92.77 (2) | Cr3x—Al7—Al10 | 57.41 (2) |
Al5iv—Al1—Al13ii | 152.15 (3) | Al7xii—Al7—Al10 | 91.572 (19) |
Al2—Al1—Al13ii | 98.14 (4) | Al15x—Al7—Al10 | 104.80 (3) |
Al13i—Al1—Al13ii | 59.58 (4) | Al8—Al7—Al10 | 105.13 (3) |
C1—Al1—Cr1 | 168.4 (5) | Al16xiii—Al7—Al10 | 56.13 (3) |
Al3—Al1—Cr1 | 110.92 (4) | Al4iv—Al7—Al10 | 116.56 (3) |
Al10i—Al1—Cr1 | 114.59 (3) | Cr2—Al7—Al10 | 103.63 (3) |
Al10ii—Al1—Cr1 | 114.59 (3) | Al5viii—Al7—Al10 | 62.82 (2) |
Al5iii—Al1—Cr1 | 114.62 (3) | Al6—Al8—Al15ix | 105.08 (3) |
Al5iv—Al1—Cr1 | 114.62 (3) | Al6—Al8—Al15x | 105.08 (3) |
Al2—Al1—Cr1 | 53.30 (3) | Al15ix—Al8—Al15x | 120.04 (5) |
Al13i—Al1—Cr1 | 52.99 (2) | Al6—Al8—Cr3ix | 58.09 (3) |
Al13ii—Al1—Cr1 | 52.99 (2) | Al15ix—Al8—Cr3ix | 54.50 (2) |
Al2—Cr1—Al2v | 180.0 | Al15x—Al8—Cr3ix | 105.21 (3) |
Al2—Cr1—Al13i | 113.76 (2) | Al6—Al8—Cr3x | 58.09 (3) |
Al2v—Cr1—Al13i | 66.24 (2) | Al15ix—Al8—Cr3x | 105.21 (3) |
Al2—Cr1—Al13vi | 66.24 (2) | Al15x—Al8—Cr3x | 54.50 (2) |
Al2v—Cr1—Al13vi | 113.76 (2) | Cr3ix—Al8—Cr3x | 58.24 (3) |
Al13i—Cr1—Al13vi | 180.0 | Al6—Al8—Al15vii | 99.26 (4) |
Al2—Cr1—Al13vii | 66.24 (2) | Al15ix—Al8—Al15vii | 139.03 (4) |
Al2v—Cr1—Al13vii | 113.76 (2) | Al15x—Al8—Al15vii | 83.48 (2) |
Al13i—Cr1—Al13vii | 112.57 (3) | Cr3ix—Al8—Al15vii | 156.98 (4) |
Al13vi—Cr1—Al13vii | 67.43 (3) | Cr3x—Al8—Al15vii | 115.62 (2) |
Al2—Cr1—Al13ii | 113.76 (2) | Al6—Al8—Al15vi | 99.26 (4) |
Al2v—Cr1—Al13ii | 66.24 (2) | Al15ix—Al8—Al15vi | 83.48 (2) |
Al13i—Cr1—Al13ii | 67.43 (3) | Al15x—Al8—Al15vi | 139.03 (4) |
Al13vi—Cr1—Al13ii | 112.57 (3) | Cr3ix—Al8—Al15vi | 115.62 (2) |
Al13vii—Cr1—Al13ii | 180.0 | Cr3x—Al8—Al15vi | 156.98 (4) |
Al2—Cr1—Al12vii | 116.291 (16) | Al15vii—Al8—Al15vi | 60.19 (4) |
Al2v—Cr1—Al12vii | 63.709 (16) | Al6—Al8—Al7viii | 59.39 (2) |
Al13i—Cr1—Al12vii | 62.79 (2) | Al15ix—Al8—Al7viii | 60.91 (2) |
Al13vi—Cr1—Al12vii | 117.21 (2) | Al15x—Al8—Al7viii | 161.70 (4) |
Al13vii—Cr1—Al12vii | 60.52 (2) | Cr3ix—Al8—Al7viii | 59.28 (2) |
Al13ii—Cr1—Al12vii | 119.48 (2) | Cr3x—Al8—Al7viii | 107.20 (3) |
Al2—Cr1—Al12ii | 63.709 (16) | Al15vii—Al8—Al7viii | 107.45 (4) |
Al2v—Cr1—Al12ii | 116.292 (16) | Al15vi—Al8—Al7viii | 57.92 (2) |
Al13i—Cr1—Al12ii | 117.21 (2) | Al6—Al8—Al7 | 59.39 (2) |
Al13vi—Cr1—Al12ii | 62.79 (2) | Al15ix—Al8—Al7 | 161.70 (4) |
Al13vii—Cr1—Al12ii | 119.48 (2) | Al15x—Al8—Al7 | 60.91 (2) |
Al13ii—Cr1—Al12ii | 60.52 (2) | Cr3ix—Al8—Al7 | 107.20 (3) |
Al12vii—Cr1—Al12ii | 180.0 | Cr3x—Al8—Al7 | 59.28 (2) |
Al2—Cr1—Al12vi | 116.291 (16) | Al15vii—Al8—Al7 | 57.92 (2) |
Al2v—Cr1—Al12vi | 63.709 (16) | Al15vi—Al8—Al7 | 107.45 (4) |
Al13i—Cr1—Al12vi | 119.48 (2) | Al7viii—Al8—Al7 | 111.93 (4) |
Al13vi—Cr1—Al12vi | 60.52 (2) | Al6—Al8—Al14ix | 104.00 (4) |
Al13vii—Cr1—Al12vi | 117.21 (2) | Al15ix—Al8—Al14ix | 61.52 (2) |
Al13ii—Cr1—Al12vi | 62.79 (2) | Al15x—Al8—Al14ix | 61.52 (2) |
Al12vii—Cr1—Al12vi | 117.56 (3) | Cr3ix—Al8—Al14ix | 56.83 (2) |
Al12ii—Cr1—Al12vi | 62.44 (3) | Cr3x—Al8—Al14ix | 56.83 (2) |
Al2—Cr1—Al12i | 63.709 (16) | Al15vii—Al8—Al14ix | 141.81 (3) |
Al2v—Cr1—Al12i | 116.291 (16) | Al15vi—Al8—Al14ix | 141.81 (3) |
Al13i—Cr1—Al12i | 60.52 (2) | Al7viii—Al8—Al14ix | 110.40 (3) |
Al13vi—Cr1—Al12i | 119.48 (2) | Al7—Al8—Al14ix | 110.40 (3) |
Al13vii—Cr1—Al12i | 62.79 (2) | Al6—Al8—Cr2 | 53.73 (3) |
Al13ii—Cr1—Al12i | 117.21 (2) | Al15ix—Al8—Cr2 | 119.86 (2) |
Al12vii—Cr1—Al12i | 62.44 (3) | Al15x—Al8—Cr2 | 119.86 (2) |
Al12ii—Cr1—Al12i | 117.56 (3) | Cr3ix—Al8—Cr2 | 104.37 (3) |
Al12vi—Cr1—Al12i | 180.0 | Cr3x—Al8—Cr2 | 104.37 (3) |
Al2—Cr1—Al1v | 118.14 (3) | Al15vii—Al8—Cr2 | 53.82 (2) |
Al2v—Cr1—Al1v | 61.86 (3) | Al15vi—Al8—Cr2 | 53.82 (2) |
Al13i—Cr1—Al1v | 116.85 (2) | Al7viii—Al8—Cr2 | 60.75 (2) |
Al13vi—Cr1—Al1v | 63.15 (2) | Al7—Al8—Cr2 | 60.75 (2) |
Al13vii—Cr1—Al1v | 63.15 (2) | Al14ix—Al8—Cr2 | 157.73 (4) |
Al13ii—Cr1—Al1v | 116.85 (2) | Al6—Al9—Al6ix | 180.00 (4) |
Al12vii—Cr1—Al1v | 63.491 (16) | Al6—Al9—Cr3 | 118.398 (19) |
Al12ii—Cr1—Al1v | 116.509 (16) | Al6ix—Al9—Cr3 | 61.602 (19) |
Al12vi—Cr1—Al1v | 63.491 (16) | Al6—Al9—Cr3viii | 118.399 (19) |
Al12i—Cr1—Al1v | 116.509 (16) | Al6ix—Al9—Cr3viii | 61.601 (19) |
Al2—Cr1—Al1 | 61.86 (3) | Cr3—Al9—Cr3viii | 62.622 (17) |
Al2v—Cr1—Al1 | 118.14 (3) | Al6—Al9—Cr3x | 61.601 (19) |
Al13i—Cr1—Al1 | 63.15 (2) | Al6ix—Al9—Cr3x | 118.399 (19) |
Al13vi—Cr1—Al1 | 116.85 (2) | Cr3—Al9—Cr3x | 117.378 (17) |
Al13vii—Cr1—Al1 | 116.85 (2) | Cr3viii—Al9—Cr3x | 180.0 |
Al13ii—Cr1—Al1 | 63.15 (2) | Al6—Al9—Cr3ix | 61.601 (19) |
Al12vii—Cr1—Al1 | 116.509 (16) | Al6ix—Al9—Cr3ix | 118.399 (19) |
Al12ii—Cr1—Al1 | 63.491 (16) | Cr3—Al9—Cr3ix | 180.0 |
Al12vi—Cr1—Al1 | 116.509 (16) | Cr3viii—Al9—Cr3ix | 117.378 (17) |
Al12i—Cr1—Al1 | 63.491 (16) | Cr3x—Al9—Cr3ix | 62.622 (17) |
Al1v—Cr1—Al1 | 180.0 | Al6—Al9—Al10 | 64.439 (17) |
Al1—C1—Al3 | 80.1 (6) | Al6ix—Al9—Al10 | 115.561 (16) |
Al1—C1—Al7i | 132.0 (6) | Cr3—Al9—Al10 | 63.724 (17) |
Al3—C1—Al7i | 123.7 (6) | Cr3viii—Al9—Al10 | 116.514 (17) |
Al1—C1—Al7ii | 132.0 (6) | Cr3x—Al9—Al10 | 63.486 (17) |
Al3—C1—Al7ii | 123.7 (6) | Cr3ix—Al9—Al10 | 116.276 (18) |
Al7i—C1—Al7ii | 72.8 (5) | Al6—Al9—Al10ix | 115.562 (16) |
Al1—C1—Al5iii | 77.1 (4) | Al6ix—Al9—Al10ix | 64.438 (17) |
Al3—C1—Al5iii | 71.6 (4) | Cr3—Al9—Al10ix | 116.274 (18) |
Al7i—C1—Al5iii | 146.0 (6) | Cr3viii—Al9—Al10ix | 63.485 (17) |
Al7ii—C1—Al5iii | 73.79 (13) | Cr3x—Al9—Al10ix | 116.515 (17) |
Al1—C1—Al5iv | 77.1 (4) | Cr3ix—Al9—Al10ix | 63.726 (17) |
Al3—C1—Al5iv | 71.6 (4) | Al10—Al9—Al10ix | 180.0 |
Al7i—C1—Al5iv | 73.79 (13) | Al6—Al9—Al10viii | 64.438 (16) |
Al7ii—C1—Al5iv | 146.0 (6) | Al6ix—Al9—Al10viii | 115.562 (17) |
Al5iii—C1—Al5iv | 137.9 (7) | Cr3—Al9—Al10viii | 116.515 (17) |
Cr2—Al2—Cr1 | 174.84 (4) | Cr3viii—Al9—Al10viii | 63.726 (17) |
Cr2—Al2—Al3 | 60.58 (3) | Cr3x—Al9—Al10viii | 116.274 (17) |
Cr1—Al2—Al3 | 124.58 (4) | Cr3ix—Al9—Al10viii | 63.485 (17) |
Cr2—Al2—Al13vii | 118.78 (4) | Al10—Al9—Al10viii | 117.61 (3) |
Cr1—Al2—Al13vii | 57.07 (2) | Al10ix—Al9—Al10viii | 62.39 (3) |
Al3—Al2—Al13vii | 149.091 (19) | Al6—Al9—Al10x | 115.562 (17) |
Cr2—Al2—Al13vi | 118.78 (4) | Al6ix—Al9—Al10x | 64.438 (16) |
Cr1—Al2—Al13vi | 57.07 (2) | Cr3—Al9—Al10x | 63.485 (17) |
Al3—Al2—Al13vi | 149.091 (19) | Cr3viii—Al9—Al10x | 116.274 (17) |
Al13vii—Al2—Al13vi | 61.20 (3) | Cr3x—Al9—Al10x | 63.726 (17) |
Cr2—Al2—Al1 | 120.32 (4) | Cr3ix—Al9—Al10x | 116.515 (17) |
Cr1—Al2—Al1 | 64.84 (3) | Al10—Al9—Al10x | 62.39 (3) |
Al3—Al2—Al1 | 59.74 (4) | Al10ix—Al9—Al10x | 117.61 (3) |
Al13vii—Al2—Al1 | 111.89 (4) | Al10viii—Al9—Al10x | 180.0 |
Al13vi—Al2—Al1 | 111.89 (4) | Al6—Al9—Al11ix | 115.09 (3) |
Cr2—Al2—Al4iii | 59.96 (2) | Al6ix—Al9—Al11ix | 64.91 (3) |
Cr1—Al2—Al4iii | 121.22 (2) | Cr3—Al9—Al11ix | 116.175 (18) |
Al3—Al2—Al4iii | 64.10 (2) | Cr3viii—Al9—Al11ix | 116.174 (18) |
Al13vii—Al2—Al4iii | 145.46 (4) | Cr3x—Al9—Al11ix | 63.825 (18) |
Al13vi—Al2—Al4iii | 88.34 (2) | Cr3ix—Al9—Al11ix | 63.825 (18) |
Al1—Al2—Al4iii | 93.64 (3) | Al10—Al9—Al11ix | 116.259 (16) |
Cr2—Al2—Al4iv | 59.96 (2) | Al10ix—Al9—Al11ix | 63.742 (16) |
Cr1—Al2—Al4iv | 121.22 (2) | Al10viii—Al9—Al11ix | 116.258 (16) |
Al3—Al2—Al4iv | 64.10 (2) | Al10x—Al9—Al11ix | 63.742 (16) |
Al13vii—Al2—Al4iv | 88.34 (2) | Al6—Al9—Al11 | 64.91 (3) |
Al13vi—Al2—Al4iv | 145.46 (4) | Al6ix—Al9—Al11 | 115.09 (3) |
Al1—Al2—Al4iv | 93.64 (3) | Cr3—Al9—Al11 | 63.824 (18) |
Al4iii—Al2—Al4iv | 113.74 (4) | Cr3viii—Al9—Al11 | 63.824 (18) |
Cr2—Al2—Al12i | 118.85 (2) | Cr3x—Al9—Al11 | 116.176 (19) |
Cr1—Al2—Al12i | 62.58 (2) | Cr3ix—Al9—Al11 | 116.176 (18) |
Al3—Al2—Al12i | 92.40 (3) | Al10—Al9—Al11 | 63.742 (16) |
Al13vii—Al2—Al12i | 59.77 (2) | Al10ix—Al9—Al11 | 116.258 (16) |
Al13vi—Al2—Al12i | 111.01 (4) | Al10viii—Al9—Al11 | 63.742 (16) |
Al1—Al2—Al12i | 64.08 (2) | Al10x—Al9—Al11 | 116.258 (16) |
Al4iii—Al2—Al12i | 154.36 (4) | Al11ix—Al9—Al11 | 180.0 |
Al4iv—Al2—Al12i | 58.90 (2) | Al9—Al10—Al1i | 151.34 (3) |
Cr2—Al2—Al12ii | 118.85 (2) | Al9—Al10—Al16xiii | 103.24 (3) |
Cr1—Al2—Al12ii | 62.58 (2) | Al1i—Al10—Al16xiii | 104.64 (3) |
Al3—Al2—Al12ii | 92.40 (3) | Al9—Al10—Cr3x | 56.225 (16) |
Al13vii—Al2—Al12ii | 111.01 (4) | Al1i—Al10—Cr3x | 142.69 (3) |
Al13vi—Al2—Al12ii | 59.77 (2) | Al16xiii—Al10—Cr3x | 53.119 (19) |
Al1—Al2—Al12ii | 64.08 (2) | Al9—Al10—Cr3 | 56.114 (16) |
Al4iii—Al2—Al12ii | 58.90 (2) | Al1i—Al10—Cr3 | 112.51 (3) |
Al4iv—Al2—Al12ii | 154.36 (4) | Al16xiii—Al10—Cr3 | 121.35 (3) |
Al12i—Al2—Al12ii | 115.71 (4) | Cr3x—Al10—Cr3 | 104.80 (3) |
Cr2—Al2—Al15vi | 56.50 (2) | Al9—Al10—Al10x | 58.807 (15) |
Cr1—Al2—Al15vi | 119.25 (3) | Al1i—Al10—Al10x | 142.92 (3) |
Al3—Al2—Al15vi | 108.67 (4) | Al16xiii—Al10—Al10x | 63.13 (3) |
Al13vii—Al2—Al15vi | 91.60 (3) | Cr3x—Al10—Al10x | 60.04 (2) |
Al13vi—Al2—Al15vi | 62.28 (3) | Cr3—Al10—Al10x | 59.71 (2) |
Al1—Al2—Al15vi | 149.83 (2) | Al9—Al10—Al6 | 55.71 (2) |
Al4iii—Al2—Al15vi | 57.78 (2) | Al1i—Al10—Al6 | 111.43 (3) |
Al4iv—Al2—Al15vi | 106.15 (4) | Al16xiii—Al10—Al6 | 101.84 (3) |
Al12i—Al2—Al15vi | 145.96 (3) | Cr3x—Al10—Al6 | 56.36 (2) |
Al12ii—Al2—Al15vi | 90.47 (2) | Cr3—Al10—Al6 | 104.55 (3) |
Cr2—Al2—Al15vii | 56.50 (2) | Al10x—Al10—Al6 | 105.46 (3) |
Cr1—Al2—Al15vii | 119.25 (3) | Al9—Al10—Al11 | 58.45 (2) |
Al3—Al2—Al15vii | 108.67 (4) | Al1i—Al10—Al11 | 92.92 (3) |
Al13vii—Al2—Al15vii | 62.28 (3) | Al16xiii—Al10—Al11 | 158.95 (3) |
Al13vi—Al2—Al15vii | 91.60 (3) | Cr3x—Al10—Al11 | 105.83 (3) |
Al1—Al2—Al15vii | 149.83 (2) | Cr3—Al10—Al11 | 59.50 (2) |
Al4iii—Al2—Al15vii | 106.15 (4) | Al10x—Al10—Al11 | 108.84 (3) |
Al4iv—Al2—Al15vii | 57.78 (2) | Al6—Al10—Al11 | 60.15 (3) |
Al12i—Al2—Al15vii | 90.47 (2) | Al9—Al10—Al13 | 99.06 (3) |
Al12ii—Al2—Al15vii | 145.96 (3) | Al1i—Al10—Al13 | 61.40 (3) |
Al15vi—Al2—Al15vii | 57.95 (3) | Al16xiii—Al10—Al13 | 142.42 (3) |
Al2—Cr2—Al6 | 179.44 (4) | Cr3x—Al10—Al13 | 154.94 (3) |
Al2—Cr2—Al15vii | 70.31 (3) | Cr3—Al10—Al13 | 51.77 (2) |
Al6—Cr2—Al15vii | 110.14 (3) | Al10x—Al10—Al13 | 105.58 (4) |
Al2—Cr2—Al15vi | 70.31 (3) | Al6—Al10—Al13 | 115.72 (3) |
Al6—Cr2—Al15vi | 110.14 (3) | Al11—Al10—Al13 | 56.97 (2) |
Al15vii—Cr2—Al15vi | 66.32 (3) | Al9—Al10—Al16 | 99.50 (3) |
Al2—Cr2—Al3 | 63.54 (3) | Al1i—Al10—Al16 | 88.14 (3) |
Al6—Cr2—Al3 | 115.90 (3) | Al16xiii—Al10—Al16 | 87.65 (3) |
Al15vii—Cr2—Al3 | 122.41 (3) | Cr3x—Al10—Al16 | 116.63 (3) |
Al15vi—Cr2—Al3 | 122.41 (3) | Cr3—Al10—Al16 | 51.518 (19) |
Al2—Cr2—Al4iv | 66.693 (19) | Al10x—Al10—Al16 | 57.94 (3) |
Al6—Cr2—Al4iv | 113.164 (19) | Al6—Al10—Al16 | 154.76 (3) |
Al15vii—Cr2—Al4iv | 63.83 (2) | Al11—Al10—Al16 | 104.71 (3) |
Al15vi—Cr2—Al4iv | 122.06 (3) | Al13—Al10—Al16 | 58.86 (3) |
Al3—Cr2—Al4iv | 67.392 (19) | Al9—Al10—Al7 | 102.79 (3) |
Al2—Cr2—Al4iii | 66.693 (19) | Al1i—Al10—Al7 | 85.56 (3) |
Al6—Cr2—Al4iii | 113.164 (19) | Al16xiii—Al10—Al7 | 60.20 (3) |
Al15vii—Cr2—Al4iii | 122.06 (3) | Cr3x—Al10—Al7 | 57.82 (2) |
Al15vi—Cr2—Al4iii | 63.83 (2) | Cr3—Al10—Al7 | 158.89 (3) |
Al3—Cr2—Al4iii | 67.392 (19) | Al10x—Al10—Al7 | 112.47 (4) |
Al4iv—Cr2—Al4iii | 125.37 (4) | Al6—Al10—Al7 | 56.81 (2) |
Al2—Cr2—Al5 | 116.68 (3) | Al11—Al10—Al7 | 110.80 (3) |
Al6—Cr2—Al5 | 62.87 (3) | Al13—Al10—Al7 | 141.83 (3) |
Al15vii—Cr2—Al5 | 172.81 (3) | Al16—Al10—Al7 | 144.18 (3) |
Al15vi—Cr2—Al5 | 113.55 (2) | Al9—Al10—Al10xii | 148.807 (15) |
Al3—Cr2—Al5 | 64.15 (2) | Al1i—Al10—Al10xii | 57.129 (19) |
Al4iv—Cr2—Al5 | 119.58 (3) | Al16xiii—Al10—Al10xii | 57.218 (19) |
Al4iii—Cr2—Al5 | 62.05 (2) | Cr3x—Al10—Al10xii | 110.336 (17) |
Al2—Cr2—Al5viii | 116.68 (3) | Cr3—Al10—Al10xii | 110.268 (17) |
Al6—Cr2—Al5viii | 62.87 (2) | Al10x—Al10—Al10xii | 90.0 |
Al15vii—Cr2—Al5viii | 113.55 (2) | Al6—Al10—Al10xii | 145.07 (2) |
Al15vi—Cr2—Al5viii | 172.81 (3) | Al11—Al10—Al10xii | 143.83 (2) |
Al3—Cr2—Al5viii | 64.15 (2) | Al13—Al10—Al10xii | 88.77 (2) |
Al4iv—Cr2—Al5viii | 62.05 (2) | Al16—Al10—Al10xii | 59.044 (17) |
Al4iii—Cr2—Al5viii | 119.58 (3) | Al7—Al10—Al10xii | 88.427 (19) |
Al5—Cr2—Al5viii | 65.59 (3) | Al9—Al11—Al13 | 102.43 (3) |
Al2—Cr2—Al8 | 121.79 (3) | Al9—Al11—Al13viii | 102.43 (3) |
Al6—Cr2—Al8 | 58.77 (3) | Al13—Al11—Al13viii | 119.49 (4) |
Al15vii—Cr2—Al8 | 61.71 (2) | Al9—Al11—Cr3 | 55.75 (2) |
Al15vi—Cr2—Al8 | 61.71 (2) | Al13—Al11—Cr3 | 53.17 (2) |
Al3—Cr2—Al8 | 174.67 (3) | Al13viii—Al11—Cr3 | 103.15 (3) |
Al4iv—Cr2—Al8 | 113.958 (19) | Al9—Al11—Cr3viii | 55.75 (2) |
Al4iii—Cr2—Al8 | 113.958 (19) | Al13—Al11—Cr3viii | 103.15 (3) |
Al5—Cr2—Al8 | 111.55 (3) | Al13viii—Al11—Cr3viii | 53.17 (2) |
Al5viii—Cr2—Al8 | 111.55 (3) | Cr3—Al11—Cr3viii | 57.20 (2) |
Al2—Cr2—Al7viii | 119.827 (19) | Al9—Al11—Al12 | 148.15 (2) |
Al6—Cr2—Al7viii | 60.363 (18) | Al13—Al11—Al12 | 58.97 (2) |
Al15vii—Cr2—Al7viii | 113.04 (3) | Al13viii—Al11—Al12 | 109.26 (4) |
Al15vi—Cr2—Al7viii | 59.83 (2) | Cr3—Al11—Al12 | 112.14 (2) |
Al3—Cr2—Al7viii | 118.832 (19) | Cr3viii—Al11—Al12 | 147.70 (4) |
Al4iv—Cr2—Al7viii | 172.12 (3) | Al9—Al11—Al12viii | 148.15 (2) |
Al4iii—Cr2—Al7viii | 62.51 (2) | Al13—Al11—Al12viii | 109.26 (4) |
Al5—Cr2—Al7viii | 62.67 (2) | Al13viii—Al11—Al12viii | 58.97 (2) |
Al5viii—Cr2—Al7viii | 115.22 (3) | Cr3—Al11—Al12viii | 147.70 (4) |
Al8—Cr2—Al7viii | 59.370 (18) | Cr3viii—Al11—Al12viii | 112.14 (2) |
Al2—Cr2—Al7 | 119.827 (19) | Al12—Al11—Al12viii | 58.60 (4) |
Al6—Cr2—Al7 | 60.363 (18) | Al9—Al11—Al6 | 55.19 (3) |
Al15vii—Cr2—Al7 | 59.83 (2) | Al13—Al11—Al6 | 119.79 (2) |
Al15vi—Cr2—Al7 | 113.04 (3) | Al13viii—Al11—Al6 | 119.80 (2) |
Al3—Cr2—Al7 | 118.831 (19) | Cr3—Al11—Al6 | 103.42 (3) |
Al4iv—Cr2—Al7 | 62.51 (2) | Cr3viii—Al11—Al6 | 103.42 (3) |
Al4iii—Cr2—Al7 | 172.13 (3) | Al12—Al11—Al6 | 108.84 (4) |
Al5—Cr2—Al7 | 115.22 (3) | Al12viii—Al11—Al6 | 108.84 (4) |
Al5viii—Cr2—Al7 | 62.67 (2) | Al9—Al11—Al10 | 57.81 (2) |
Al8—Cr2—Al7 | 59.371 (18) | Al13—Al11—Al10 | 62.17 (2) |
Al7viii—Cr2—Al7 | 109.62 (3) | Al13viii—Al11—Al10 | 158.08 (4) |
C1—Al3—Cr2 | 160.9 (4) | Cr3—Al11—Al10 | 59.01 (2) |
C1—Al3—Al4 | 71.5 (3) | Cr3viii—Al11—Al10 | 104.95 (3) |
Cr2—Al3—Al4 | 123.89 (4) | Al12—Al11—Al10 | 90.42 (2) |
C1—Al3—Al4viii | 71.5 (3) | Al12viii—Al11—Al10 | 142.88 (4) |
Cr2—Al3—Al4viii | 123.89 (4) | Al6—Al11—Al10 | 59.15 (2) |
Al4—Al3—Al4viii | 64.16 (4) | Al9—Al11—Al10viii | 57.81 (2) |
C1—Al3—Al2 | 105.0 (4) | Al13—Al11—Al10viii | 158.08 (4) |
Cr2—Al3—Al2 | 55.88 (3) | Al13viii—Al11—Al10viii | 62.17 (2) |
Al4—Al3—Al2 | 147.24 (2) | Cr3—Al11—Al10viii | 104.95 (3) |
Al4viii—Al3—Al2 | 147.24 (2) | Cr3viii—Al11—Al10viii | 59.01 (2) |
C1—Al3—Al1 | 42.4 (4) | Al12—Al11—Al10viii | 142.88 (4) |
Cr2—Al3—Al1 | 118.52 (4) | Al12viii—Al11—Al10viii | 90.42 (2) |
Al4—Al3—Al1 | 107.12 (4) | Al6—Al11—Al10viii | 59.15 (2) |
Al4viii—Al3—Al1 | 107.12 (4) | Al10—Al11—Al10viii | 107.66 (4) |
Al2—Al3—Al1 | 62.64 (4) | Al9—Al11—Al14 | 101.16 (4) |
C1—Al3—Al5 | 134.8 (3) | Al13—Al11—Al14 | 60.75 (2) |
Cr2—Al3—Al5 | 59.50 (3) | Al13viii—Al11—Al14 | 60.75 (2) |
Al4—Al3—Al5 | 64.44 (3) | Cr3—Al11—Al14 | 56.48 (3) |
Al4viii—Al3—Al5 | 96.86 (4) | Cr3viii—Al11—Al14 | 56.48 (3) |
Al2—Al3—Al5 | 106.56 (4) | Al12—Al11—Al14 | 91.67 (3) |
Al1—Al3—Al5 | 147.88 (2) | Al12viii—Al11—Al14 | 91.67 (3) |
C1—Al3—Al5viii | 134.8 (3) | Al6—Al11—Al14 | 156.35 (5) |
Cr2—Al3—Al5viii | 59.50 (3) | Al10—Al11—Al14 | 110.64 (3) |
Al4—Al3—Al5viii | 96.86 (4) | Al10viii—Al11—Al14 | 110.64 (3) |
Al4viii—Al3—Al5viii | 64.44 (3) | Al13—Al12—Al12viii | 111.17 (2) |
Al2—Al3—Al5viii | 106.56 (4) | Al13—Al12—Al5viii | 95.39 (3) |
Al1—Al3—Al5viii | 147.88 (2) | Al12viii—Al12—Al5viii | 91.79 (2) |
Al5—Al3—Al5viii | 62.48 (4) | Al13—Al12—Al4viii | 150.32 (4) |
C1—Al3—Al5iv | 56.60 (8) | Al12viii—Al12—Al4viii | 90.78 (2) |
Cr2—Al3—Al5iv | 118.09 (2) | Al5viii—Al12—Al4viii | 63.06 (3) |
Al4—Al3—Al5iv | 112.29 (4) | Al13—Al12—Al11 | 59.11 (2) |
Al4viii—Al3—Al5iv | 60.46 (2) | Al12viii—Al12—Al11 | 60.703 (18) |
Al2—Al3—Al5iv | 89.84 (3) | Al5viii—Al12—Al11 | 68.95 (3) |
Al1—Al3—Al5iv | 59.46 (2) | Al4viii—Al12—Al11 | 122.62 (3) |
Al5—Al3—Al5iv | 152.46 (3) | Al13—Al12—Al13xiv | 101.04 (3) |
Al5viii—Al3—Al5iv | 92.00 (2) | Al12viii—Al12—Al13xiv | 110.45 (2) |
C1—Al3—Al5iii | 56.60 (8) | Al5viii—Al12—Al13xiv | 144.83 (3) |
Cr2—Al3—Al5iii | 118.09 (2) | Al4viii—Al12—Al13xiv | 88.90 (3) |
Al4—Al3—Al5iii | 60.46 (2) | Al11—Al12—Al13xiv | 145.66 (4) |
Al4viii—Al3—Al5iii | 112.29 (4) | Al13—Al12—Cr1xv | 55.22 (2) |
Al2—Al3—Al5iii | 89.84 (3) | Al12viii—Al12—Cr1xv | 148.779 (15) |
Al1—Al3—Al5iii | 59.46 (2) | Al5viii—Al12—Cr1xv | 115.97 (3) |
Al5—Al3—Al5iii | 92.00 (2) | Al4viii—Al12—Cr1xv | 113.79 (3) |
Al5viii—Al3—Al5iii | 152.46 (3) | Al11—Al12—Cr1xv | 114.33 (3) |
Al5iv—Al3—Al5iii | 110.41 (4) | Al13xiv—Al12—Cr1xv | 54.284 (19) |
C1—Al3—Al4iii | 115.75 (18) | Al13—Al12—Al2i | 100.90 (3) |
Cr2—Al3—Al4iii | 57.38 (2) | Al12viii—Al12—Al2i | 147.85 (2) |
Al4—Al3—Al4iii | 90.91 (2) | Al5viii—Al12—Al2i | 87.22 (3) |
Al4viii—Al3—Al4iii | 151.28 (3) | Al4viii—Al12—Al2i | 60.30 (3) |
Al2—Al3—Al4iii | 60.55 (2) | Al11—Al12—Al2i | 145.56 (3) |
Al1—Al3—Al4iii | 93.23 (3) | Al13xiv—Al12—Al2i | 59.34 (3) |
Al5—Al3—Al4iii | 57.55 (2) | Cr1xv—Al12—Al2i | 53.71 (2) |
Al5viii—Al3—Al4iii | 107.71 (4) | Al13—Al12—Al14xi | 149.04 (4) |
Al5iv—Al3—Al4iii | 147.76 (4) | Al12viii—Al12—Al14xi | 61.237 (17) |
Al5iii—Al3—Al4iii | 60.95 (2) | Al5viii—Al12—Al14xi | 114.16 (3) |
C1—Al3—Al4iv | 115.75 (18) | Al4viii—Al12—Al14xi | 59.15 (3) |
Cr2—Al3—Al4iv | 57.38 (2) | Al11—Al12—Al14xi | 121.93 (3) |
Al4—Al3—Al4iv | 151.28 (3) | Al13xiv—Al12—Al14xi | 59.94 (2) |
Al4viii—Al3—Al4iv | 90.91 (2) | Cr1xv—Al12—Al14xi | 114.06 (3) |
Al2—Al3—Al4iv | 60.55 (2) | Al2i—Al12—Al14xi | 89.99 (3) |
Al1—Al3—Al4iv | 93.23 (3) | Al13—Al12—Al12xiv | 59.70 (3) |
Al5—Al3—Al4iv | 107.71 (4) | Al12viii—Al12—Al12xiv | 90.0 |
Al5viii—Al3—Al4iv | 57.55 (2) | Al5viii—Al12—Al12xiv | 153.67 (4) |
Al5iv—Al3—Al4iv | 60.95 (2) | Al4viii—Al12—Al12xiv | 143.19 (4) |
Al5iii—Al3—Al4iv | 147.76 (4) | Al11—Al12—Al12xiv | 89.28 (3) |
Al4iii—Al3—Al4iv | 108.32 (4) | Al13xiv—Al12—Al12xiv | 56.65 (3) |
Al16—Cr3—Al13 | 70.17 (3) | Cr1xv—Al12—Al12xiv | 58.779 (15) |
Al16—Cr3—Al15 | 70.90 (3) | Al2i—Al12—Al12xiv | 104.77 (3) |
Al13—Cr3—Al15 | 72.84 (2) | Al14xi—Al12—Al12xiv | 89.59 (3) |
Al16—Cr3—Al9 | 115.59 (3) | Cr3—Al13—Cr1xv | 169.15 (3) |
Al13—Cr3—Al9 | 114.33 (2) | Cr3—Al13—Al12 | 126.57 (3) |
Al15—Cr3—Al9 | 171.29 (2) | Cr1xv—Al13—Al12 | 64.26 (2) |
Al16—Cr3—Al6ix | 115.48 (3) | Cr3—Al13—Al11 | 64.64 (3) |
Al13—Cr3—Al6ix | 172.43 (3) | Cr1xv—Al13—Al11 | 126.19 (3) |
Al15—Cr3—Al6ix | 113.33 (3) | Al12—Al13—Al11 | 61.93 (3) |
Al9—Cr3—Al6ix | 59.13 (2) | Cr3—Al13—Al2xv | 114.73 (3) |
Al16—Cr3—Cr3viii | 173.47 (2) | Cr1xv—Al13—Al2xv | 56.69 (2) |
Al13—Cr3—Cr3viii | 114.464 (19) | Al12—Al13—Al2xv | 111.56 (3) |
Al15—Cr3—Cr3viii | 114.450 (18) | Al11—Al13—Al2xv | 150.53 (3) |
Al9—Cr3—Cr3viii | 58.689 (9) | Cr3—Al13—Al12xiv | 120.51 (3) |
Al6ix—Cr3—Cr3viii | 59.480 (13) | Cr1xv—Al13—Al12xiv | 62.92 (2) |
Al16—Cr3—Al14 | 126.40 (3) | Al12—Al13—Al12xiv | 63.65 (3) |
Al13—Cr3—Al14 | 66.64 (3) | Al11—Al13—Al12xiv | 93.11 (3) |
Al15—Cr3—Al14 | 67.23 (2) | Al2xv—Al13—Al12xiv | 60.89 (2) |
Al9—Cr3—Al14 | 110.27 (2) | Cr3—Al13—Al14 | 60.19 (3) |
Al6ix—Cr3—Al14 | 110.99 (2) | Cr1xv—Al13—Al14 | 123.42 (3) |
Cr3viii—Cr3—Al14 | 60.097 (13) | Al12—Al13—Al14 | 94.16 (3) |
Al16—Cr3—Al8ix | 121.20 (3) | Al11—Al13—Al14 | 62.05 (3) |
Al13—Cr3—Al8ix | 122.80 (3) | Al2xv—Al13—Al14 | 91.33 (3) |
Al15—Cr3—Al8ix | 62.70 (2) | Al12xiv—Al13—Al14 | 60.69 (3) |
Al9—Cr3—Al8ix | 108.60 (2) | Cr3—Al13—Al16 | 54.85 (2) |
Al6ix—Cr3—Al8ix | 59.54 (3) | Cr1xv—Al13—Al16 | 116.06 (3) |
Cr3viii—Cr3—Al8ix | 60.882 (13) | Al12—Al13—Al16 | 148.81 (4) |
Al14—Cr3—Al8ix | 64.12 (3) | Al11—Al13—Al16 | 109.42 (3) |
Al16—Cr3—Al10x | 63.14 (3) | Al2xv—Al13—Al16 | 89.95 (3) |
Al13—Cr3—Al10x | 118.76 (3) | Al12xiv—Al13—Al16 | 146.70 (3) |
Al15—Cr3—Al10x | 121.61 (3) | Al14—Al13—Al16 | 108.16 (3) |
Al9—Cr3—Al10x | 60.291 (17) | Cr3—Al13—Al13xii | 114.465 (19) |
Al6ix—Cr3—Al10x | 62.49 (2) | Cr1xv—Al13—Al13xii | 56.284 (16) |
Cr3viii—Cr3—Al10x | 110.339 (17) | Al12—Al13—Al13xii | 111.17 (2) |
Al14—Cr3—Al10x | 170.12 (2) | Al11—Al13—Al13xii | 149.75 (2) |
Al8ix—Cr3—Al10x | 114.62 (3) | Al2xv—Al13—Al13xii | 59.401 (17) |
Al16—Cr3—Al10 | 66.77 (3) | Al12xiv—Al13—Al13xii | 110.45 (2) |
Al13—Cr3—Al10 | 66.30 (2) | Al14—Al13—Al13xii | 146.32 (2) |
Al15—Cr3—Al10 | 128.53 (3) | Al16—Al13—Al13xii | 59.797 (17) |
Al9—Cr3—Al10 | 60.162 (18) | Cr3—Al13—Al1i | 118.16 (3) |
Al6ix—Cr3—Al10 | 110.53 (3) | Cr1xv—Al13—Al1i | 63.85 (2) |
Cr3viii—Cr3—Al10 | 110.268 (17) | Al12—Al13—Al1i | 64.87 (3) |
Al14—Cr3—Al10 | 118.99 (3) | Al11—Al13—Al1i | 92.58 (3) |
Al8ix—Cr3—Al10 | 168.72 (3) | Al2xv—Al13—Al1i | 111.01 (3) |
Al10x—Cr3—Al10 | 60.25 (3) | Al12xiv—Al13—Al1i | 117.19 (3) |
Al16—Cr3—Al7x | 66.18 (3) | Al14—Al13—Al1i | 153.42 (3) |
Al13—Cr3—Al7x | 126.51 (3) | Al16—Al13—Al1i | 86.80 (3) |
Al15—Cr3—Al7x | 64.87 (2) | Al13xii—Al13—Al1i | 60.211 (18) |
Al9—Cr3—Al7x | 111.52 (2) | Cr3—Al13—Al10 | 61.93 (2) |
Al6ix—Cr3—Al7x | 61.04 (2) | Cr1xv—Al13—Al10 | 120.81 (3) |
Cr3viii—Cr3—Al7x | 112.042 (17) | Al12—Al13—Al10 | 91.33 (3) |
Al14—Cr3—Al7x | 119.75 (3) | Al11—Al13—Al10 | 60.87 (3) |
Al8ix—Cr3—Al7x | 62.61 (2) | Al2xv—Al13—Al10 | 147.32 (3) |
Al10x—Cr3—Al7x | 64.78 (2) | Al12xiv—Al13—Al10 | 151.16 (3) |
Al10—Cr3—Al7x | 118.87 (3) | Al14—Al13—Al10 | 110.64 (3) |
Al16—Cr3—Al11 | 119.60 (3) | Al16—Al13—Al10 | 60.85 (3) |
Al13—Cr3—Al11 | 62.19 (2) | Al13xii—Al13—Al10 | 91.23 (2) |
Al15—Cr3—Al11 | 122.52 (3) | Al1i—Al13—Al10 | 56.99 (3) |
Al9—Cr3—Al11 | 60.42 (2) | Cr3—Al13—Al15 | 54.22 (2) |
Al6ix—Cr3—Al11 | 110.24 (2) | Cr1xv—Al13—Al15 | 117.26 (3) |
Cr3viii—Cr3—Al11 | 61.401 (12) | Al12—Al13—Al15 | 150.58 (3) |
Al14—Cr3—Al11 | 63.26 (3) | Al11—Al13—Al15 | 109.59 (3) |
Al8ix—Cr3—Al11 | 115.14 (2) | Al2xv—Al13—Al15 | 60.66 (3) |
Al10x—Cr3—Al11 | 110.90 (3) | Al12xiv—Al13—Al15 | 90.17 (3) |
Al10—Cr3—Al11 | 61.49 (2) | Al14—Al13—Al15 | 59.51 (3) |
Al7x—Cr3—Al11 | 171.19 (3) | Al16—Al13—Al15 | 59.72 (3) |
Al3—Al4—Cr2iii | 121.76 (3) | Al13xii—Al13—Al15 | 89.680 (19) |
Al3—Al4—Al5iii | 62.87 (3) | Al1i—Al13—Al15 | 144.13 (3) |
Cr2iii—Al4—Al5iii | 59.42 (2) | Al10—Al13—Al15 | 109.35 (3) |
Al3—Al4—Al15xi | 153.53 (4) | Cr3viii—Al14—Cr3 | 59.81 (3) |
Cr2iii—Al4—Al15xi | 56.47 (2) | Cr3viii—Al14—Al4xiv | 111.63 (2) |
Al5iii—Al4—Al15xi | 105.54 (3) | Cr3—Al14—Al4xiv | 150.84 (4) |
Al3—Al4—Al14xi | 116.65 (3) | Cr3viii—Al14—Al4xi | 150.84 (4) |
Cr2iii—Al4—Al14xi | 118.04 (3) | Cr3—Al14—Al4xi | 111.63 (2) |
Al5iii—Al4—Al14xi | 153.28 (4) | Al4xiv—Al14—Al4xi | 60.82 (3) |
Al15xi—Al4—Al14xi | 62.23 (3) | Cr3viii—Al14—Al13viii | 53.171 (19) |
Al3—Al4—Al12viii | 108.10 (3) | Cr3—Al14—Al13viii | 103.32 (3) |
Cr2iii—Al4—Al12viii | 114.15 (3) | Al4xiv—Al14—Al13viii | 88.69 (2) |
Al5iii—Al4—Al12viii | 145.21 (3) | Al4xi—Al14—Al13viii | 145.05 (4) |
Al15xi—Al4—Al12viii | 94.49 (3) | Cr3viii—Al14—Al13 | 103.32 (3) |
Al14xi—Al4—Al12viii | 61.50 (3) | Cr3—Al14—Al13 | 53.170 (19) |
Al3—Al4—Al4viii | 57.920 (19) | Al4xiv—Al14—Al13 | 145.05 (4) |
Cr2iii—Al4—Al4viii | 152.682 (18) | Al4xi—Al14—Al13 | 88.69 (2) |
Al5iii—Al4—Al4viii | 109.27 (2) | Al13viii—Al14—Al13 | 112.65 (4) |
Al15xi—Al4—Al4viii | 110.29 (2) | Cr3viii—Al14—Al12xiv | 149.13 (4) |
Al14xi—Al4—Al4viii | 59.591 (18) | Cr3—Al14—Al12xiv | 112.24 (2) |
Al12viii—Al4—Al4viii | 89.22 (2) | Al4xiv—Al14—Al12xiv | 88.70 (3) |
Al3—Al4—Al2iii | 141.08 (4) | Al4xi—Al14—Al12xiv | 59.35 (3) |
Cr2iii—Al4—Al2iii | 53.35 (2) | Al13viii—Al14—Al12xiv | 106.95 (4) |
Al5iii—Al4—Al2iii | 103.69 (3) | Al13—Al14—Al12xiv | 59.38 (2) |
Al15xi—Al4—Al2iii | 62.52 (3) | Cr3viii—Al14—Al12xi | 112.24 (2) |
Al14xi—Al4—Al2iii | 91.63 (3) | Cr3—Al14—Al12xi | 149.13 (4) |
Al12viii—Al4—Al2iii | 60.80 (3) | Al4xiv—Al14—Al12xi | 59.35 (3) |
Al4viii—Al4—Al2iii | 146.87 (2) | Al4xi—Al14—Al12xi | 88.70 (3) |
Al3—Al4—Al7ii | 96.73 (3) | Al13viii—Al14—Al12xi | 59.38 (2) |
Cr2iii—Al4—Al7ii | 62.75 (2) | Al13—Al14—Al12xi | 106.95 (4) |
Al5iii—Al4—Al7ii | 61.96 (2) | Al12xiv—Al14—Al12xi | 57.52 (3) |
Al15xi—Al4—Al7ii | 57.91 (2) | Cr3viii—Al14—Al11 | 60.26 (3) |
Al14xi—Al4—Al7ii | 92.57 (3) | Cr3—Al14—Al11 | 60.26 (3) |
Al12viii—Al4—Al7ii | 149.96 (3) | Al4xiv—Al14—Al11 | 143.50 (3) |
Al4viii—Al4—Al7ii | 89.93 (2) | Al4xi—Al14—Al11 | 143.50 (3) |
Al2iii—Al4—Al7ii | 108.79 (3) | Al13viii—Al14—Al11 | 57.20 (2) |
Al3—Al4—Al5 | 60.42 (3) | Al13—Al14—Al11 | 57.20 (2) |
Cr2iii—Al4—Al5 | 112.88 (3) | Al12xiv—Al14—Al11 | 89.46 (3) |
Al5iii—Al4—Al5 | 91.09 (3) | Al12xi—Al14—Al11 | 89.46 (3) |
Al15xi—Al4—Al5 | 146.01 (3) | Cr3viii—Al14—Al15 | 103.30 (3) |
Al14xi—Al4—Al5 | 112.22 (3) | Cr3—Al14—Al15 | 53.621 (19) |
Al12viii—Al4—Al5 | 58.44 (2) | Al4xiv—Al14—Al15 | 108.43 (4) |
Al4viii—Al4—Al5 | 90.970 (19) | Al4xi—Al14—Al15 | 58.70 (2) |
Al2iii—Al4—Al5 | 85.05 (3) | Al13viii—Al14—Al15 | 155.61 (4) |
Al7ii—Al4—Al5 | 151.60 (3) | Al13—Al14—Al15 | 62.40 (2) |
Al3—Al4—Al3iii | 89.09 (2) | Al12xiv—Al14—Al15 | 91.10 (2) |
Cr2iii—Al4—Al3iii | 55.23 (2) | Al12xi—Al14—Al15 | 144.45 (3) |
Al5iii—Al4—Al3iii | 59.20 (3) | Al11—Al14—Al15 | 108.05 (3) |
Al15xi—Al4—Al3iii | 105.55 (3) | Cr3viii—Al14—Al15viii | 53.621 (19) |
Al14xi—Al4—Al3iii | 144.52 (3) | Cr3—Al14—Al15viii | 103.30 (3) |
Al12viii—Al4—Al3iii | 88.39 (3) | Al4xiv—Al14—Al15viii | 58.70 (2) |
Al4viii—Al4—Al3iii | 144.16 (2) | Al4xi—Al14—Al15viii | 108.43 (4) |
Al2iii—Al4—Al3iii | 55.35 (3) | Al13viii—Al14—Al15viii | 62.40 (2) |
Al7ii—Al4—Al3iii | 109.09 (3) | Al13—Al14—Al15viii | 155.60 (4) |
Al5—Al4—Al3iii | 57.87 (3) | Al12xiv—Al14—Al15viii | 144.45 (3) |
C1iii—Al5—Cr2 | 108.0 (4) | Al12xi—Al14—Al15viii | 91.10 (2) |
C1iii—Al5—Al6 | 102.2 (4) | Al11—Al14—Al15viii | 108.05 (3) |
Cr2—Al5—Al6 | 55.32 (3) | Al15—Al14—Al15viii | 111.28 (4) |
C1iii—Al5—Al1iii | 41.4 (4) | Cr3viii—Al14—Al8ix | 59.05 (3) |
Cr2—Al5—Al1iii | 148.01 (3) | Cr3—Al14—Al8ix | 59.05 (3) |
Al6—Al5—Al1iii | 113.21 (3) | Al4xiv—Al14—Al8ix | 92.19 (3) |
C1iii—Al5—Al4iii | 67.6 (4) | Al4xi—Al14—Al8ix | 92.19 (3) |
Cr2—Al5—Al4iii | 58.53 (2) | Al13viii—Al14—Al8ix | 106.61 (3) |
Al6—Al5—Al4iii | 104.16 (3) | Al13—Al14—Al8ix | 106.61 (3) |
Al1iii—Al5—Al4iii | 103.44 (3) | Al12xiv—Al14—Al8ix | 146.44 (3) |
C1iii—Al5—Al12viii | 106.6 (4) | Al12xi—Al14—Al8ix | 146.44 (3) |
Cr2—Al5—Al12viii | 145.09 (3) | Al11—Al14—Al8ix | 108.70 (4) |
Al6—Al5—Al12viii | 112.38 (3) | Al15—Al14—Al8ix | 56.90 (2) |
Al1iii—Al5—Al12viii | 65.49 (3) | Al15viii—Al14—Al8ix | 56.90 (2) |
Al4iii—Al5—Al12viii | 143.29 (3) | Cr3—Al15—Cr2xv | 162.72 (3) |
C1iii—Al5—Al3 | 128.6 (4) | Cr3—Al15—Al8ix | 62.79 (3) |
Cr2—Al5—Al3 | 56.35 (3) | Cr2xv—Al15—Al8ix | 132.88 (3) |
Al6—Al5—Al3 | 103.18 (3) | Cr3—Al15—Al7xvi | 129.66 (3) |
Al1iii—Al5—Al3 | 143.48 (4) | Cr2xv—Al15—Al7xvi | 66.04 (2) |
Al4iii—Al5—Al3 | 63.25 (3) | Al8ix—Al15—Al7xvi | 67.00 (3) |
Al12viii—Al5—Al3 | 103.79 (3) | Cr3—Al15—Al4xi | 117.44 (3) |
C1iii—Al5—Al3iii | 51.8 (4) | Cr2xv—Al15—Al4xi | 59.70 (2) |
Cr2—Al5—Al3iii | 114.74 (3) | Al8ix—Al15—Al4xi | 95.44 (3) |
Al6—Al5—Al3iii | 150.74 (4) | Al7xvi—Al15—Al4xi | 63.33 (3) |
Al1iii—Al5—Al3iii | 58.61 (3) | Cr3—Al15—Al8xv | 126.60 (3) |
Al4iii—Al5—Al3iii | 56.67 (3) | Cr2xv—Al15—Al8xv | 64.47 (3) |
Al12viii—Al5—Al3iii | 90.41 (3) | Al8ix—Al15—Al8xv | 96.52 (2) |
Al3—Al5—Al3iii | 88.00 (2) | Al7xvi—Al15—Al8xv | 62.03 (3) |
C1iii—Al5—Al7viii | 51.2 (4) | Al4xi—Al15—Al8xv | 112.89 (3) |
Cr2—Al5—Al7viii | 62.22 (2) | Cr3—Al15—Al15xii | 114.451 (18) |
Al6—Al5—Al7viii | 58.16 (2) | Cr2xv—Al15—Al15xii | 56.841 (17) |
Al1iii—Al5—Al7viii | 86.15 (3) | Al8ix—Al15—Al15xii | 150.02 (2) |
Al4iii—Al5—Al7viii | 61.30 (2) | Al7xvi—Al15—Al15xii | 110.55 (2) |
Al12viii—Al5—Al7viii | 144.42 (3) | Al4xi—Al15—Al15xii | 110.29 (2) |
Al3—Al5—Al7viii | 111.74 (3) | Al8xv—Al15—Al15xii | 59.907 (18) |
Al3iii—Al5—Al7viii | 92.60 (3) | Cr3—Al15—Al7x | 62.10 (2) |
C1iii—Al5—Al5viii | 159.0 (4) | Cr2xv—Al15—Al7x | 128.46 (3) |
Cr2—Al5—Al5viii | 57.205 (17) | Al8ix—Al15—Al7x | 61.76 (3) |
Al6—Al5—Al5viii | 57.562 (19) | Al7xvi—Al15—Al7x | 97.30 (3) |
Al1iii—Al5—Al5viii | 147.27 (2) | Al4xi—Al15—Al7x | 155.52 (3) |
Al4iii—Al5—Al5viii | 109.27 (2) | Al8xv—Al15—Al7x | 64.78 (3) |
Al12viii—Al5—Al5viii | 88.21 (2) | Al15xii—Al15—Al7x | 89.94 (2) |
Al3—Al5—Al5viii | 58.761 (18) | Cr3—Al15—Al14 | 59.14 (3) |
Al3iii—Al5—Al5viii | 145.21 (2) | Cr2xv—Al15—Al14 | 118.11 (3) |
Al7viii—Al5—Al5viii | 108.29 (2) | Al8ix—Al15—Al14 | 61.58 (3) |
C1iii—Al5—Al4 | 111.4 (4) | Al7xvi—Al15—Al14 | 93.91 (3) |
Cr2—Al5—Al4 | 111.45 (3) | Al4xi—Al15—Al14 | 59.07 (3) |
Al6—Al5—Al4 | 146.44 (3) | Al8xv—Al15—Al14 | 153.46 (3) |
Al1iii—Al5—Al4 | 92.87 (3) | Al15xii—Al15—Al14 | 145.64 (2) |
Al4iii—Al5—Al4 | 88.91 (3) | Al7x—Al15—Al14 | 111.13 (3) |
Al12viii—Al5—Al4 | 58.49 (2) | Cr3—Al15—Al16 | 53.826 (19) |
Al3—Al5—Al4 | 55.14 (3) | Cr2xv—Al15—Al16 | 116.32 (3) |
Al3iii—Al5—Al4 | 61.18 (3) | Al8ix—Al15—Al16 | 107.54 (3) |
Al7viii—Al5—Al4 | 148.87 (3) | Al7xvi—Al15—Al16 | 154.16 (4) |
Al5viii—Al5—Al4 | 89.031 (19) | Al4xi—Al15—Al16 | 141.72 (3) |
Cr2—Al6—Al9 | 178.55 (4) | Al8xv—Al15—Al16 | 94.83 (3) |
Cr2—Al6—Cr3ix | 119.55 (3) | Al15xii—Al15—Al16 | 60.744 (17) |
Al9—Al6—Cr3ix | 59.27 (2) | Al7x—Al15—Al16 | 60.20 (3) |
Cr2—Al6—Cr3x | 119.55 (3) | Al14—Al15—Al16 | 105.66 (3) |
Al9—Al6—Cr3x | 59.27 (2) | Cr3—Al15—Al2xv | 109.88 (3) |
Cr3ix—Al6—Cr3x | 61.04 (3) | Cr2xv—Al15—Al2xv | 53.18 (2) |
Cr2—Al6—Al8 | 67.50 (3) | Al8ix—Al15—Al2xv | 148.91 (3) |
Al9—Al6—Al8 | 111.05 (4) | Al7xvi—Al15—Al2xv | 110.84 (3) |
Cr3ix—Al6—Al8 | 62.37 (3) | Al4xi—Al15—Al2xv | 59.70 (2) |
Cr3x—Al6—Al8 | 62.37 (3) | Al8xv—Al15—Al2xv | 109.86 (3) |
Cr2—Al6—Al5 | 61.81 (3) | Al15xii—Al15—Al2xv | 61.023 (17) |
Al9—Al6—Al5 | 119.34 (3) | Al7x—Al15—Al2xv | 144.77 (3) |
Cr3ix—Al6—Al5 | 117.04 (2) | Al14—Al15—Al2xv | 88.31 (3) |
Cr3x—Al6—Al5 | 177.94 (3) | Al16—Al15—Al2xv | 86.87 (3) |
Al8—Al6—Al5 | 117.73 (4) | Cr3—Al15—Al13 | 52.94 (2) |
Cr2—Al6—Al5viii | 61.81 (3) | Cr2xv—Al15—Al13 | 110.25 (3) |
Al9—Al6—Al5viii | 119.34 (3) | Al8ix—Al15—Al13 | 106.88 (3) |
Cr3ix—Al6—Al5viii | 177.94 (3) | Al7xvi—Al15—Al13 | 147.44 (3) |
Cr3x—Al6—Al5viii | 117.035 (19) | Al4xi—Al15—Al13 | 86.44 (3) |
Al8—Al6—Al5viii | 117.73 (4) | Al8xv—Al15—Al13 | 148.22 (3) |
Al5—Al6—Al5viii | 64.88 (4) | Al15xii—Al15—Al13 | 90.319 (19) |
Cr2—Al6—Al7viii | 66.91 (2) | Al7x—Al15—Al13 | 107.77 (3) |
Al9—Al6—Al7viii | 112.59 (2) | Al14—Al15—Al13 | 58.09 (3) |
Cr3ix—Al6—Al7viii | 62.16 (2) | Al16—Al15—Al13 | 58.07 (3) |
Cr3x—Al6—Al7viii | 114.30 (3) | Al2xv—Al15—Al13 | 57.07 (2) |
Al8—Al6—Al7viii | 63.93 (2) | Cr3xii—Al16—Cr3 | 166.95 (5) |
Al5—Al6—Al7viii | 64.52 (2) | Cr3xii—Al16—Al10x | 129.30 (4) |
Al5viii—Al6—Al7viii | 119.85 (4) | Cr3—Al16—Al10x | 63.74 (2) |
Cr2—Al6—Al7 | 66.91 (2) | Cr3xii—Al16—Al10xiii | 63.74 (2) |
Al9—Al6—Al7 | 112.59 (2) | Cr3—Al16—Al10xiii | 129.30 (4) |
Cr3ix—Al6—Al7 | 114.30 (3) | Al10x—Al16—Al10xiii | 65.56 (4) |
Cr3x—Al6—Al7 | 62.16 (2) | Cr3xii—Al16—Al13 | 115.20 (4) |
Al8—Al6—Al7 | 63.93 (2) | Cr3—Al16—Al13 | 54.98 (2) |
Al5—Al6—Al7 | 119.85 (4) | Al10x—Al16—Al13 | 107.53 (3) |
Al5viii—Al6—Al7 | 64.52 (2) | Al10xiii—Al16—Al13 | 147.77 (4) |
Al7viii—Al6—Al7 | 119.74 (4) | Cr3xii—Al16—Al13xii | 54.98 (2) |
Cr2—Al6—Al10viii | 120.60 (2) | Cr3—Al16—Al13xii | 115.20 (4) |
Al9—Al6—Al10viii | 59.85 (2) | Al10x—Al16—Al13xii | 147.77 (4) |
Cr3ix—Al6—Al10viii | 61.15 (2) | Al10xiii—Al16—Al13xii | 107.53 (3) |
Cr3x—Al6—Al10viii | 110.50 (3) | Al13—Al16—Al13xii | 60.41 (3) |
Al8—Al6—Al10viii | 115.89 (3) | Cr3xii—Al16—Al7x | 120.36 (4) |
Al5—Al6—Al10viii | 67.52 (2) | Cr3—Al16—Al7x | 62.11 (2) |
Al5viii—Al6—Al10viii | 119.82 (4) | Al10x—Al16—Al7x | 63.66 (3) |
Al7viii—Al6—Al10viii | 64.69 (2) | Al10xiii—Al16—Al7x | 94.97 (4) |
Al7—Al6—Al10viii | 172.24 (4) | Al13—Al16—Al7x | 110.32 (3) |
Cr2—Al6—Al10 | 120.60 (2) | Al13xii—Al16—Al7x | 147.13 (4) |
Al9—Al6—Al10 | 59.85 (2) | Cr3xii—Al16—Al7xiii | 62.11 (2) |
Cr3ix—Al6—Al10 | 110.50 (3) | Cr3—Al16—Al7xiii | 120.36 (4) |
Cr3x—Al6—Al10 | 61.15 (2) | Al10x—Al16—Al7xiii | 94.97 (4) |
Al8—Al6—Al10 | 115.89 (3) | Al10xiii—Al16—Al7xiii | 63.66 (3) |
Al5—Al6—Al10 | 119.82 (4) | Al13—Al16—Al7xiii | 147.13 (4) |
Al5viii—Al6—Al10 | 67.52 (2) | Al13xii—Al16—Al7xiii | 110.32 (3) |
Al7viii—Al6—Al10 | 172.24 (4) | Al7x—Al16—Al7xiii | 58.65 (4) |
Al7—Al6—Al10 | 64.69 (2) | Cr3xii—Al16—Al15xii | 55.27 (2) |
Al10viii—Al6—Al10 | 110.15 (4) | Cr3—Al16—Al15xii | 113.67 (3) |
Cr2—Al6—Al11 | 121.55 (4) | Al10x—Al16—Al15xii | 149.83 (4) |
Al9—Al6—Al11 | 59.90 (3) | Al10xiii—Al16—Al15xii | 109.59 (3) |
Cr3ix—Al6—Al11 | 110.11 (3) | Al13—Al16—Al15xii | 91.46 (3) |
Cr3x—Al6—Al11 | 110.11 (3) | Al13xii—Al16—Al15xii | 62.21 (3) |
Al8—Al6—Al11 | 170.95 (5) | Al7x—Al16—Al15xii | 88.07 (3) |
Al5—Al6—Al11 | 69.59 (3) | Al7xiii—Al16—Al15xii | 59.18 (3) |
Al5viii—Al6—Al11 | 69.59 (3) | Cr3xii—Al16—Al15 | 113.67 (3) |
Al7viii—Al6—Al11 | 118.17 (2) | Cr3—Al16—Al15 | 55.27 (2) |
Al7—Al6—Al11 | 118.17 (2) | Al10x—Al16—Al15 | 109.59 (3) |
Al10viii—Al6—Al11 | 60.69 (2) | Al10xiii—Al16—Al15 | 149.83 (4) |
Al10—Al6—Al11 | 60.69 (2) | Al13—Al16—Al15 | 62.21 (3) |
C1i—Al7—Al6 | 104.7 (3) | Al13xii—Al16—Al15 | 91.46 (3) |
C1i—Al7—Al15vii | 123.3 (4) | Al7x—Al16—Al15 | 59.18 (3) |
Al6—Al7—Al15vii | 98.86 (3) | Al7xiii—Al16—Al15 | 88.07 (3) |
C1i—Al7—Cr3x | 119.6 (4) | Al15xii—Al16—Al15 | 58.51 (3) |
Al6—Al7—Cr3x | 56.80 (2) | Cr3xii—Al16—Al10 | 123.24 (4) |
Al15vii—Al7—Cr3x | 116.53 (3) | Cr3—Al16—Al10 | 61.71 (2) |
C1i—Al7—Al7xii | 53.6 (2) | Al10x—Al16—Al10 | 58.93 (3) |
Al6—Al7—Al7xii | 149.87 (2) | Al10xiii—Al16—Al10 | 92.35 (3) |
Al15vii—Al7—Al7xii | 110.56 (2) | Al13—Al16—Al10 | 60.28 (2) |
Cr3x—Al7—Al7xii | 112.042 (17) | Al13xii—Al16—Al10 | 91.25 (3) |
C1i—Al7—Al15x | 139.6 (3) | Al7x—Al16—Al10 | 111.89 (3) |
Al6—Al7—Al15x | 100.28 (3) | Al7xiii—Al16—Al10 | 151.23 (4) |
Al15vii—Al7—Al15x | 82.70 (3) | Al15xii—Al16—Al10 | 149.25 (4) |
Cr3x—Al7—Al15x | 53.03 (2) | Al15—Al16—Al10 | 110.90 (3) |
Al7xii—Al7—Al15x | 90.06 (2) | Cr3xii—Al16—Al10xii | 61.71 (2) |
C1i—Al7—Al8 | 160.3 (2) | Cr3—Al16—Al10xii | 123.24 (4) |
Al6—Al7—Al8 | 56.68 (3) | Al10x—Al16—Al10xii | 92.35 (3) |
Al15vii—Al7—Al8 | 60.04 (3) | Al10xiii—Al16—Al10xii | 58.93 (3) |
Cr3x—Al7—Al8 | 58.11 (3) | Al13—Al16—Al10xii | 91.25 (3) |
Al7xii—Al7—Al8 | 145.96 (2) | Al13xii—Al16—Al10xii | 60.29 (2) |
Al15x—Al7—Al8 | 57.33 (3) | Al7x—Al16—Al10xii | 151.23 (4) |
C1i—Al7—Al16xiii | 83.9 (4) | Al7xiii—Al16—Al10xii | 111.89 (3) |
Al6—Al7—Al16xiii | 100.02 (3) | Al15xii—Al16—Al10xii | 110.90 (3) |
Al15vii—Al7—Al16xiii | 141.08 (4) | Al15—Al16—Al10xii | 149.25 (4) |
Cr3x—Al7—Al16xiii | 51.703 (18) | Al10—Al16—Al10xii | 61.91 (3) |
Al7xii—Al7—Al16xiii | 60.678 (18) |
Symmetry codes: (i) −x+1/2, −y+1/2, −z+1; (ii) −x+1/2, y+1/2, −z+1; (iii) −x+1/2, −y+3/2, −z+1; (iv) −x+1/2, y−1/2, −z+1; (v) −x, −y+1, −z+1; (vi) x−1/2, y+1/2, z; (vii) x−1/2, −y+1/2, z; (viii) x, −y+1, z; (ix) −x+1, −y+1, −z+2; (x) −x+1, y, −z+2; (xi) −x+1, −y+1, −z+1; (xii) x, −y, z; (xiii) −x+1, −y, −z+2; (xiv) −x+1, y, −z+1; (xv) x+1/2, y−1/2, z; (xvi) x+1/2, −y+1/2, z. |
Funding information
We greatly acknowledge financial support from the Hebei Province Youth Top-notch Talent Program (2013–2018).
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