Crystal structures of five compounds in the aluminium–ruthenium–silicon system

Kitahara, K.; Takakura, H.; Iwasaki, Y.; Kimura, K.

doi:10.1107/S2056989023008393

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Volume 79| Part 10| October 2023| Pages 946-951

https://doi.org/10.1107/S2056989023008393

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Crystal structures of five compounds in the aluminium–ruthenium–silicon system

Koichi Kitahara,^a,^b ^* Hiroyuki Takakura,^c Yutaka Iwasaki ^d,^b and Kaoru Kimura ^d,^b

^aDepartment of Materials Science and Engineering, School of Electrical and Computer Engineering, National Defense Academy, Yokosuka 239-8686, Japan, ^bDepartment of Advanced Materials Science, Graduate School of Frontier Sciences, The University of Tokyo, Kashiwa 277-8561, Japan, ^cDivision of Applied Physics, Faculty of Engineering, Hokkaido University, Sapporo 060-8628, Japan, and ^dNational Institute for Materials Science (NIMS), Tsukuba 305-0047, Japan
^*Correspondence e-mail: kokitaha@nda.ac.jp

Edited by M. Weil, Vienna University of Technology, Austria (Received 24 July 2023; accepted 25 September 2023; online 29 September 2023)

Single crystals of five compounds with approximate compositions ∼Ru₁₆(Al_0.78Si_0.22)₄₇, (I), ∼Ru₉(Al_0.70Si_0.30)₃₂, (II), ∼Ru₁₀(Al_0.67Si_0.33)₄₁, (III), ∼Ru(Al_0.57Si_0.43)₅, (IV), and ∼Ru₂(Al_0.46Si_0.54)₉, (V), were obtained from polycrystalline lumps mainly composed of the target compounds, and their crystal structures were determined by means of single-crystal X-ray diffraction. The crystal structure of (I) can be related to that of a cubic rational crystalline approximant to an icosahedral quasicrystal through crystallographic shear and then unit-cell twinning. The crystal structure of (II) is isotypic with that of a phase with composition ∼Fe₉(Al,Si)₃₂. The crystal structure of (III) is comprised of edge-sharing Ru(Al,Si)_9–11 polyhedra with disordered chains along edges of polyhedra. The crystal structure of (IV) is of the LiIrSn₄ type. The crystal structure of (V) can be viewed as a crystallographic shear structure derived from that of (IV).

Keywords: crystal structure; aluminium–ruthenium–silicon system; single-crystal X-ray diffraction; isotypism; structural similarity; crystallographic shear; unit-cell twinning; quasicrystal approximant.

CCDC references: 2297119; 2297118; 2297117; 2297116; 2297115

1. Chemical context

Semiconductors with complex crystal structures have attracted attention as thermoelectric materials (Snyder & Toberer, 2008 ; Zhang & Zhao, 2015 ; Liu et al., 2017 ). To facilitate a search for such materials, knowledge on crystal structures is essential because it serves as a basis for understanding how semiconductivity and structural complexity meet in a material. Recently, a semiconducting compound with a complex crystal structure, which is considered a cubic rational crystalline approximant to an icosahedral quasicrystal, was discovered near the composition Al_67.6Ru_23.5Si_8.9 (Iwasaki et al., 2019 ). Following this discovery, phase equilibria in the Al–Ru–Si system at 1200 K were thoroughly investigated, and eleven new ternary phases were identified (Kitahara et al., 2023 ). In the course of these investigations, single crystals of five new compounds with approximate compositions ∼Ru₁₆(Al_0.78Si_0.22)₄₇ (I), ∼Ru₉(Al_0.70Si_0.30)₃₂ (II), ∼Ru₁₀(Al_0.67Si_0.33)₄₁ (III), ∼Ru(Al_0.57Si_0.43)₅ (IV) and ∼Ru₂(Al_0.46Si_0.54)₉ (V) could be obtained from polycrystalline lumps mainly composed of the target compounds. Here we report the crystal structures of these compounds.

2. Structural commentary

The crystal structure of (I) consists of Ru-centred polyhedra with coordination numbers ranging from nine to eleven [Fig. 1(a–e, g–i)] and (Si,Ru)-centred icosahedra [Fig. 1(f)]. Each polyhedron is connected to three, four, five, six or fourteen others through face-sharing. A sensible representation of the crystal packing in (I) is obtained by using large structural units (clusters) [Fig. 2(b)] instead of using coordination polyhedra [Fig. 2(a)].

Figure 1
Coordination environments of (a) Ru1, (b) Ru2, (c) Ru3, (d) Ru4, (e) Ru5, (f) Si/Ru6, (g) Ru7, (h) Ru8 and (i) Ru9 in the crystal structure of (I) with displacement ellipsoids plotted at the 99% probability level. Unlabelled atoms in (a–f), (g) and (h) are related to the corresponding labelled atoms by (iii), (i) and (xix), respectively. Only the major disordered components are shown except for Ru8, Al20 and Al28A, for which two split components with equal occupancy are shown. Colour codes: Al and (Al/Si) (light blue); Ru (light brown); Si, (Si/Al) and (Si/Ru) (blue). [Symmetry codes: (i) x, y, −z + $[{1\over 2}]$ ; (iii) −x, y, z; (v) −x + $[{1\over 2}]$ , −y + $[{1\over 2}]$ , z + $[{1\over 2}]$ ; (vi) −x, −y, −z + 1; (vii) −x + $[{1\over 2}]$ , −y + $[{1\over 2}]$ , −z + 1; (ix) −x + $[{1\over 2}]$ , −y + $[{1\over 2}]$ , −z; (x) −x + $[{1\over 2}]$ , y + $[{1\over 2}]$ , z; (xii) −x, −y + 1, −z; (xiii) −x, −y + 1, z − $[{1\over 2}]$ ; (xiv) x + $[{1\over 2}]$ , y − $[{1\over 2}]$ , −z + $[{1\over 2}]$ ; (xv) x + $[{1\over 2}]$ , y − $[{1\over 2}]$ , z; (xvi) −x + $[{1\over 2}]$ , y − $[{1\over 2}]$ , −z + $[{1\over 2}]$ ; (xvii) −x + $[{1\over 2}]$ , y − $[{1\over 2}]$ , z; (xix) −x + 1, y, z; (xx) −x + $[{1\over 2}]$ , −y + $[{1\over 2}]$ , z − $[{1\over 2}]$ .]

Figure 2
Packing diagrams for (I) based on (a) the coordination polyhedra given in Fig. 1

and (b) larger structural units (clusters).

The crystal structure of (I) can be related to that of a rational crystalline approximant to an icosahedral quasicrystal through crystallographic shear and then unit-cell twinning, as detailed in the following. The crystallographic shear and unit-cell twinning are two of the most important structure building operations by which a recombination structure is derived from a simpler parent structure (Lima-de-Faria et al., 1990 ). In this case, the parent structure is a 1/0 cubic approximant to a Mackay-type icosahedral quasicrystal. Crystal structures of this type are known for the phases with approximate compositions ∼RhAl_2.63 (ICSD 406525; Grin et al., 1997 ), ∼IrAl_2.75 (ICSD 406526; Grin et al., 1997), ∼Al_20.5Ru_5.1Ni_2.9 (ICSD 230569; Simura et al., 2017 ) and ∼Al_5.64Fe_0.96Pd_1.04 (ICSD 45248; Li & Fan, 2019 ). The crystal structure of the semiconducting compound ∼Al_67.6Ru_23.5Si_8.9 is also considered to fall into this type (Iwasaki et al., 2019). Fig. 3(a) shows an idealized crystal structure of this cubic approximant, which can be viewed as a CsCl-type packing of two types of clusters, icosahedral clusters and pseudo-Mackay clusters (Simura et al., 2017). Fig. 3(b) shows a crystallographic shear structure derived from the parent structure. The shear planes are (10 $[\overline{1}]$ ) planes of the parent structure [Fig. 3(a)], and the shear operation was applied at cluster level. Fig. 3(c) shows the crystal structure obtained by applying unit-cell twinning to the sheared structure. The twin planes are (001) planes of the sheared structure [Fig. 3(b)], and the twin operation was applied at the atomic level. Two constituent parts of the twinned structure are related by reflection across the twin planes as the mirror planes. Atoms close to each twin plane were shifted onto the plane prior to the twinning. The twinned structure is comparable to the cluster-based representation of (I) shown in Fig. 2(b). Note that the shear structure shown in Fig. 3(b) can also be obtained through so-called linear phason strain (Yamamoto, 1996 ) instead of crystallographic shear and hence directly relates to an icosahedral quasicrystal as a monoclinic approximant.

Figure 3
The structural units given in Fig. 2

(b) as derived from (a) the parent cubic approximant structure by applying (b) crystallographic shear and then (c) unit-cell twinning. Shear planes [(10 $[\overline{1}]$ ) planes of the parent structure] are indicated by arrows in (a). Twin planes [(001) planes of the sheared structure] are indicated by arrows in (b). Colour codes: icosahedral clusters (blue); pseudo-Mackay clusters (red).

The crystal structure of (II) consists of two types of Ru-centred polyhedra, RuAl₁₂ cuboctahedra [Fig. 4(a)] and Ru(Al,Si)₉ square-face tricapped trigonal prisms [Fig. 4(b, c)]. Each cuboctahedron is surrounded by eight square-face tricapped trigonal prisms sharing its eight triangular faces. Each square-face tricapped trigonal prism is in turn connected to others through edge-sharing.

Figure 4
Coordination environments of (a) Ru1, (b) Ru2 and (c) Ru3 in the crystal structure of (II) with displacement ellipsoids plotted at the 99% probability level. Colour codes: Al and Al/Si (light blue); Ru (light brown); Si (blue). [Symmetry codes: (i) x − y, x, −z + 1; (ii) −x + y, −x, z; (iii) −x, −y, −z + 1; (iv) −y, x − y, z; (v) y, −x + y, −z + 1; (vi) y − $[{2\over 3}]$ , −x + y − $[{1\over 3}]$ , −z + $[{2\over 3}]$ ; (vii) −y + $[{2\over 3}]$ , x − y + $[{1\over 3}]$ , z + $[{1\over 3}]$ ; (viii) x − $[{1\over 3}]$ , y − $[{2\over 3}]$ , z + $[{1\over 3}]$ ; (ix) −x + $[{1\over 3}]$ , −y + $[{2\over 3}]$ , −z + $[{2\over 3}]$ ; (x) x − y + $[{1\over 3}]$ , x − $[{1\over 3}]$ , −z + $[{2\over 3}]$ ; (xi) −x + y − $[{1\over 3}]$ , −x + $[{1\over 3}]$ , z + $[{1\over 3}]$ ; (xii) x − y + $[{2\over 3}]$ , x + $[{1\over 3}]$ , −z + $[{1\over 3}]$ ; (xiii) −x + y + $[{1\over 3}]$ , −x + $[{2\over 3}]$ , z − $[{1\over 3}]$ ; (xiv) −x + $[{2\over 3}]$ , −y + $[{1\over 3}]$ , −z + $[{1\over 3}]$ ; (xv) y, −x + y, −z.]

The crystal structure of (III) is comprised of Ru(Al,Si)₁₀ [Fig. 5(a, b)], Ru(Al,Si)₉ [Fig. 5(c)] and Ru(Al,Si)₁₁ [Fig. 5(d–g)] polyhedra. Unlike the polyhedra in (I) and (II), no faces are shared between these polyhedra. These polyhedra are connected through edge-sharing. As an unusual feature, extensive positional disorder within a chain motif along edges of Ru4- and Ru5-centred polyhedra [Fig. 6(a)] is found in (III). A similar disordered chain structure [Fig. 6(b)] was also reported for the phase with approximate composition ∼Fe₂Al₅ (Burkhardt et al., 1994 ; Vinokur et al., 2019 ).

Figure 5
Coordination environments of (a) Ru1, (b) Ru2, (c) Ru3, (d) Ru4, (e) Ru5, (f) Ru6 and (g) Ru7 in the crystal structure of (III) with displacement ellipsoids plotted at the 99% probability level. Unlabelled atoms in (a–d) are related to the corresponding labelled atoms by (vii). Only the major disordered components are shown. Colour codes: Al and Al/Si (light blue); Ru (light brown); Si (blue). [Symmetry codes: (i) −x + $[{1\over 2}]$ , y − $[{1\over 2}]$ , z + $[{1\over 2}]$ ; (iii) x − $[{1\over 2}]$ , y, −z + $[{3\over 2}]$ ; (iv) x + $[{1\over 2}]$ , y, −z + $[{3\over 2}]$ ; (v) x + $[{1\over 2}]$ , −y + $[{1\over 2}]$ , −z + $[{1\over 2}]$ ; (vi) x + $[{1\over 2}]$ , y, −z + $[{1\over 2}]$ ; (vii) x, −y + $[{1\over 2}]$ , z; (viii) −x + $[{1\over 2}]$ , y − $[{1\over 2}]$ , z − $[{1\over 2}]$ ; (x) −x + $[{1\over 2}]$ , −y, z + $[{1\over 2}]$ ; (xi) −x, y − $[{1\over 2}]$ , −z + 1.]

Figure 6
Disordered chains along polyhedral edges (a) in the crystal structure of (III) and (b) in ∼Fe₂Al₅ (CCDC 1880447; Vinokur et al., 2019

). Colour codes: Al (light blue); Fe (brown); Ru (light brown); Si (blue).

The crystal structures of (IV) and (V) consist of Ru(Al,Si)₁₀ bicapped square antiprisms [Fig. 7(a, b)]. In both crystal structures, the two cap positions of each polyhedron [Al2ⁱ and Al2 in Fig. 7(a); Al6 and Al8^iv in Fig. 7(b)] are occupied solely by Al, and each polyhedron is connected to four others in the (001) plane through edge-sharing. Along the [001] direction, each polyhedron is connected to two others sharing its vertices at the two cap positions in (IV) [Fig. 8(a)], while each polyhedron is connected to one another through vertex-sharing and two others through edge-sharing in (V) [Fig. 8(b)]. The structure of (V) can be viewed as a crystallographic shear structure derived from that of (IV). The corresponding shear planes are (001) planes of (IV) [Fig. 8(a)].

Figure 7
Coordination environments of (a) Ru1 in the crystal structure of (IV) [symmetry codes: (i) −x, y, −z + $[{1\over 2}]$ ; (ii) y − 1, −x, z; (iii) y − $[{1\over 2}]$ , −x + $[{1\over 2}]$ , −z + $[{1\over 2}]$ ; (iv) x, y − 1, z; (v) −x + $[{1\over 2}]$ , −y + $[{1\over 2}]$ , −z + $[{1\over 2}]$ ; (vi) −y + $[{1\over 2}]$ , x − $[{1\over 2}]$ , −z + $[{1\over 2}]$ ; (vii) −y + 1, x, z; (viii) x − $[{1\over 2}]$ , y − $[{1\over 2}]$ , −z + $[{1\over 2}]$ ; (ix) −x, −y + 1, z] and (b) Ru1 in the crystal structure of (V) [symmetry codes: (i) −x + $[{1\over 2}]$ , −y + $[{1\over 2}]$ , z − $[{1\over 2}]$ ; (ii) −x + $[{1\over 2}]$ , y − $[{1\over 2}]$ , z; (iv) −x + $[{1\over 2}]$ , −y + $[{1\over 2}]$ , −z] with displacement ellipsoids plotted at the 99% probability level. Colour codes: Al (light blue); Ru (light brown); Si and Si/Al (blue).

Figure 8
Packing diagrams for the crystal structures (a) of (IV) and (b) of (V). Crystallographic shear planes [(001) planes of (IV)] are indicated by arrows in (a). Colour codes: Al (light blue); Ru (light brown); Si (blue).

3. Database survey

Searches for isotypic crystal structures to those of the five compounds were carried out using the Inorganic Crystal Structure Database (ICSD, version 4.9.0; Zagorac et al., 2019 ). For (I), (III) and (V), queries for structures with the Pearson symbols oS250–254, oP200–204 and oS88, respectively, were made, but no entries for isotypic crystals were found. For (II), a query for hR41 was made, and three nearly identical structures (ICSD 99169; Sugiyama et al., 2004 ; ICSD 423182, 423183; Roger et al., 2011 ) of the crystal ∼Fe₉(Al,Si)₃₂ were found. Although isotypism is indicated between (II) and ∼Fe₉(Al,Si)₃₂, unlike in (II), the centres of the cuboctahedra are not occupied solely by transition-metal atoms in these structures. For (IV), a query for tI24 was made, and some isotypic crystals of the LiIrSn₄ type (ICSD 412252; Wu et al., 2002 ) were found. Limiting the results to Al-containing crystal structures, isotypic crystals in the Al–Fe–Si (ICSD 79709; Gueneau et al., 1995 ; ICSD 4837, 4839; Zhou et al., 2018 ), Al–Fe–Ge (ICSD 235910; Reisinger et al., 2018 ) and Al–Ge–Mn (ICSD 8608; Sasaki et al., 2019 ) systems were found. In these structures and that of (IV), the Li sites of the LiIrSn₄-type structure are occupied solely by Al, whereas the Sn sites are occupied by (Al,Si) or (Al,Ge).

4. Synthesis and crystallization

Polycrystalline samples with the nominal compositions Al_58.0Ru_25.3Si_16.7 for (I) and Al_37.5Ru_17.8Si_44.7 for (V) were prepared from powders of aluminium (Kojundo Chemical Lab., Japan, 99.9%), ruthenium (Tanaka Kikinzoku Kogyo K. K., Japan, 99.90% or purer) and silicon (Kojundo Chemical Lab., Japan, 99.99% or purer) using arc melting in an argon atmosphere (NEV-ACD-05, Nissin Giken Corporation, Japan). Each sample was then wrapped in tantalum foil, sealed in a silica tube filled with argon and annealed in a furnace at 1200 K for approximately 264 h, followed by water quenching. Powders for polycrystalline samples with the nominal compositions Al_55.5Ru_21.7Si_22.8 for (II), Al_55.0Ru_19.2Si_25.8 for (III) and Al_48.0Ru_16.2Si_35.8 for (IV) were mechanically compacted without melting. Each sample was then placed in an aluminium nitride crucible, sealed in a silica tube filled with argon and reacted in a furnace at 1200 K for approximately 160 h or longer, followed by water quenching. Single crystals were selected from crushed fragments of the polycrystalline samples (lumps), which are mainly composed of the target compounds. The compositions of the target compounds in the samples were analysed as described elsewhere (Kitahara et al., 2023) using an energy-dispersive spectrometer (X-Max, Oxford Instruments, UK) equipped in a scanning electron microscope (SU6600, Hitachi High-Technologies Corporation, Japan). Determined compositions for equilibria at 1200 K are Al_58.2 (5)Ru_25.1 (4)Si_16.7 (3) for (I), Al_55.2 (6)Ru_21.6 (4)Si_23.1 (7) for (II), Al_54.1 (5)Ru_19.6 (3)Si_26.3 (4) for (III), Al_47.3 (6)Ru_16.3 (3)Si_36.4 (6) for (IV) and Al_38.0 (5)Ru_17.8 (3)Si_44.2 (6) for (V). These compositions are similar to the nominal compositions and consistent with the approximate single-phase regions [from Al₆₂Ru₂₅Si₁₃ to Al₅₆Ru₂₆Si₁₈ for (I), from Al₅₇Ru₂₂Si₂₁ to Al₅₄Ru₂₂Si₂₄ for (II), from Al₅₅Ru₂₀Si₂₅ to Al₅₄Ru₂₀Si₂₆ for (III), from Al₄₉Ru₁₇Si₃₄ to Al₄₇Ru₁₇Si₃₆ for (IV) and from Al₄₁Ru₁₈Si₄₁ to Al₃₇Ru₁₈Si₄₅ for (V)] (Kitahara et al., 2023).

5. Refinement

Crystal data, data collection and structure refinement details are summarized in Table 1.

Table 1
Experimental details

	(I)	(II)	(III)	(IV)	(V)
Crystal data
Chemical formula	∼Ru₁₆(Al_0.78Si_0.22)₄₇	∼Ru₉(Al_0.70Si_0.30)₃₂	∼Ru₁₀(Al_0.67Si_0.33)₄₁	∼Ru(Al_0.57Si_0.43)₅	∼Ru₂(Al_0.46Si_0.54)₉
M_r	2900.59	1783.65	2122.53	238.38	450.41
Crystal system, space group	Orthorhombic, Cmcm	Trigonal, R $[\overline{3}]$	Orthorhombic, Pnma	Tetragonal, I4/mcm	Orthorhombic, Cmcm
Temperature (K)	301	296	298	297	301
a, b, c (Å)	7.6217 (2), 23.4434 (6), 20.6877 (6)	10.4479 (2), 10.4479 (2), 19.6774 (4)	15.0794 (2), 11.8713 (2), 16.9291 (3)	6.20079 (8), 6.20079 (8), 9.6937 (2)	8.63058 (14), 8.79888 (15), 17.4620 (3)
α, β, γ (°)	90, 90, 90	90, 90, 120	90, 90, 90	90, 90, 90	90, 90, 90
V (Å³)	3696.46 (19)	1860.17 (7)	3030.50 (9)	372.72 (1)	1326.05 (4)
Z	4	3	4	4	8
Radiation type	Mo Kα	Mo Kα	Mo Kα	Mo Kα	Mo Kα
μ (mm⁻¹)	7.59	6.59	6.18	5.32	5.88
Crystal size (mm)	0.04 × 0.02 × 0.02	0.03 × 0.03 × 0.03	0.04 × 0.02 × 0.02	0.05 × 0.03 × 0.02	0.05 × 0.04 × 0.04

Data collection
Diffractometer	XtaLAB Synergy R, HyPix	XtaLAB Synergy R, HyPix	XtaLAB Synergy R, HyPix	XtaLAB Synergy R, HyPix	XtaLAB Synergy R, HyPix
Absorption correction	Gaussian (CrysAlis PRO; Matsumoto et al., 2021 )	Gaussian (CrysAlis PRO; Matsumoto et al., 2021)	Gaussian (CrysAlis PRO; Matsumoto et al., 2021)	Gaussian (CrysAlis PRO; Matsumoto et al., 2021)	Gaussian (CrysAlis PRO; Matsumoto et al., 2021)
T_min, T_max	0.824, 0.924	0.868, 0.879	0.867, 0.929	0.833, 0.906	0.826, 0.868
No. of measured, independent and observed [I > 2σ(I)] reflections	11822, 2616, 2280	14255, 1193, 1127	33654, 5672, 4940	8063, 295, 279	17672, 1029, 1001
R_int	0.020	0.027	0.022	0.029	0.016
(sin θ/λ)_max (Å⁻¹)	0.718	0.720	0.781	0.864	0.719

Refinement
R[F² > 2σ(F²)], wR(F²), S	0.015, 0.032, 1.04	0.013, 0.024, 1.08	0.015, 0.026, 1.01	0.009, 0.021, 1.21	0.011, 0.027, 1.31
No. of reflections	2616	1193	5672	295	1029
No. of parameters	218	66	303	13	61
No. of restraints	5	2	2	2	2
Δρ_max, Δρ_min (e Å⁻³)	0.64, −0.69	0.45, −0.53	0.78, −0.74	0.44, −0.42	0.37, −0.42
Computer programs: CrysAlis PRO (Matsumoto et al., 2021), SHELXT (Sheldrick, 2015a ), SHELXL (Sheldrick, 2015b), VESTA (Momma & Izumi, 2011 ) and publCIF (Westrip, 2010 ).

For (I) and (III), significant residual electron density peaks were found around some sites after routine structure refinement procedures. To account for these peaks, some split sites were introduced for (I) [Ru7B from Ru7A; Ru8 (Wyckoff position changed into 8g from 4c); Al12B from Al12A; Si17B from Al17A; Si26B from Al26A; Al28A (16h from 8f); Al28B and Al28C from Al28A] and (III) [Ru4B from Ru4A; Ru5B from Ru5A; Si9B from Si9A; Al10B from Si10A; Al29B from Al29A; Al30B from Al30A; Al31B and Al31C from Al31A; Al32B from Al32A]. Anisotropic displacement parameters were not introduced for minor split components [Ru7B, Al12B, Si17B, Si26B, Al28B and Al28C in (I); Ru4B, Ru5B, Al10B, Al29B, Al30B, Al31B, Al31C and Al32B in (III)] except for Si9B in (III).

Choices of Al, Si or (Al,Si) mixing were basically based on the site-occupancy factors (SOFs). After routine structure-refinement procedures and adding split sites, the SOF of each site was refined independently one by one. (Al,Si) mixing was introduced for some sites for (I) (Si/Al10, Al/Si14, Al/Si18, Al/Si21 and Al/Si22), (II) (Al/Si6 and Al/Si7), (III) (Al/Si11, Al/Si20, Al/Si21 and Al/Si22), (IV) (Si/Al3) and (V) (Si/Al5 and Si/Al7) because the SOF becomes significantly higher than 1 with Al occupation only and lower than 1 with Si occupation only for these sites. The positions and displacement parameters of mixing components were constrained using EXYZ and EADP instructions of SHELXL (Sheldrick, 2015b ). For split sites, (Al,Si) mixing was not introduced, and Al or Si was chosen for each site so that the sum of the SOFs of the split components are close to 1. Choice of Si for Si/Ru6 in (I) is rather arbitrary, and it may be Al or even a vacancy.

After assigning chemical species to each site, the sum of the SOFs for each group of mixed or split sites was constrained to 1 unless it was significantly lower than 1. Sites with SOFs lower than 1 were found for (I) (Al27) and (III) (Al15), and the SOFs for these sites were freely refined. For sites along disordered chains in (III) [Al31A, Al31B, Al31C, Al32A and Al32B; see also Structural commentary and Fig. 6(a)], there is no a priori expected value for the sum of the SOFs, and therefore the SOFs of these sites were refined without any constraints. For these partially occupied sites, the assignment as Al is by no means justified, and some of them may be occupied by Si.

Since it is generally difficult to distinguish between Al and Si solely from X-ray diffraction data, restraints on the chemical compositions based on the chemical analysis data including their uncertainties (see Synthesis and crystallization) were introduced using SUMP instructions of SHELXL (Sheldrick, 2015b) for the final refinement cycles. The compositions deduced from the final refinement are Al_57.8 (3)Ru_25.6Si_16.6 (3) for (I), Al_54.8 (5)Ru_22.0Si_23.3 (5) for (II), Al_53.6 (3)Ru_19.7Si_26.6 (3) for (III), Al_47.2 (5)Ru_16.7Si_36.1 (5) for (IV) and Al_37.2 (4)Ru_18.2Si_44.6 (4) for (V). These compositions are consistent with the chemical analysis data.

Supporting information

CCDC references: 2297119; 2297118; 2297117; 2297116; 2297115

Crystal structure: contains datablocks I, II, III, IV, V, global. DOI: https://doi.org/10.1107/S2056989023008393/wm5690sup1.cif

Structure factors: contains datablock I. DOI: https://doi.org/10.1107/S2056989023008393/wm5690Isup2.hkl

Structure factors: contains datablock II. DOI: https://doi.org/10.1107/S2056989023008393/wm5690IIsup3.hkl

Structure factors: contains datablock III. DOI: https://doi.org/10.1107/S2056989023008393/wm5690IIIsup4.hkl

Structure factors: contains datablock IV. DOI: https://doi.org/10.1107/S2056989023008393/wm5690IVsup5.hkl

Structure factors: contains datablock V. DOI: https://doi.org/10.1107/S2056989023008393/wm5690Vsup6.hkl

checkCIF report

Computing details top

For all structures, data collection: CrysAlis PRO (Matsumoto et al., 2021); cell refinement: CrysAlis PRO (Matsumoto et al., 2021); data reduction: CrysAlis PRO (Matsumoto et al., 2021); program(s) used to solve structure: SHELXT (Sheldrick, 2015a); program(s) used to refine structure: SHELXL (Sheldrick, 2015b); molecular graphics: VESTA (Momma & Izumi, 2011); software used to prepare material for publication: publCIF (Westrip, 2010).

Hexatriacontaaluminium hexadecaruthenium decasilicon (I) top

Crystal data top

~Ru₁₆(Al_0.78Si_0.22)₄₇	D_x = 5.212 Mg m⁻³
M_r = 2900.59	Mo Kα radiation, λ = 0.71073 Å
Orthorhombic, Cmcm	Cell parameters from 5906 reflections
a = 7.6217 (2) Å	θ = 2.6–30.8°
b = 23.4434 (6) Å	µ = 7.59 mm⁻¹
c = 20.6877 (6) Å	T = 301 K
V = 3696.46 (19) Å³	Prism, metallic light colourless
Z = 4	0.04 × 0.02 × 0.02 mm
F(000) = 5237.80

Data collection top

XtaLAB Synergy R, HyPix diffractometer	2616 independent reflections
Radiation source: micro-focus sealed X-ray tube, Mova (Mo) X-ray Source	2280 reflections with I > 2σ(I)
Mirror monochromator	R_int = 0.020
Detector resolution: 10.0000 pixels mm^-1	θ_max = 30.7°, θ_min = 1.7°
ω scans	h = −9→7
Absorption correction: gaussian (CrysAlisPro; Matsumoto et al., 2021)	k = −32→33
T_min = 0.824, T_max = 0.924	l = −22→27
11822 measured reflections

Refinement top

Refinement on F²	Primary atom site location: dual
Least-squares matrix: full	Secondary atom site location: difference Fourier map
R[F² > 2σ(F²)] = 0.015	w = 1/[σ²(F_o²) + (0.015P)² + 1.7856P] where P = (F_o² + 2F_c²)/3
wR(F²) = 0.032	(Δ/σ)_max = 0.002
S = 1.04	Δρ_max = 0.64 e Å⁻³
2616 reflections	Δρ_min = −0.69 e Å⁻³
218 parameters	Extinction correction: SHELXL-2019/3 (Sheldrick, 2015b), Fc^*=kFc[1+0.001xFc²λ³/sin(2θ)]^-1/4
5 restraints	Extinction coefficient: 0.000036 (4)

Special details top

Geometry. All esds (except the esd in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell esds are taken into account individually in the estimation of esds in distances, angles and torsion angles; correlations between esds in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell esds is used for estimating esds involving l.s. planes.

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å²) top

	x	y	z	U_iso*/U_eq	Occ. (<1)
Ru1	0.000000	0.35437 (2)	0.250000	0.00702 (8)
Ru2	0.000000	0.19071 (2)	0.14245 (2)	0.00523 (6)
Ru3	0.000000	0.08703 (2)	0.67676 (2)	0.00497 (6)
Ru4	0.000000	0.46501 (2)	0.06755 (2)	0.00580 (6)
Ru5	0.000000	0.08260 (2)	0.06182 (2)	0.00605 (6)
Si6	0.000000	0.63703 (3)	0.09750 (4)	0.0067 (3)	0.9481 (19)
Ru6	0.000000	0.63703 (3)	0.09750 (4)	0.0067 (3)	0.0519 (19)
Ru7A	0.2872 (5)	0.05250 (15)	0.250000	0.0071 (3)	0.87 (3)
Ru7B	0.308 (2)	0.0461 (8)	0.250000	0.0123 (19)*	0.13 (3)
Ru8	0.4748 (2)	0.24633 (2)	0.250000	0.0057 (4)	0.5
Ru9	0.20167 (2)	0.28208 (2)	0.06561 (2)	0.00560 (5)
Si10	0.000000	0.00419 (5)	0.250000	0.0088 (6)	0.73 (12)
Al10	0.000000	0.00419 (5)	0.250000	0.0088 (6)	0.27 (12)
Al11	0.000000	0.63795 (6)	0.250000	0.0132 (3)
Al12A	0.000000	0.12915 (10)	0.250000	0.0126 (9)	0.856 (12)
Al12B	0.079 (3)	0.1477 (10)	0.250000	0.020 (5)*	0.072 (6)
Si13	0.000000	0.29501 (3)	0.15414 (4)	0.00569 (17)
Al14	0.000000	0.36199 (4)	0.03013 (4)	0.0068 (4)	0.59 (8)
Si14	0.000000	0.36199 (4)	0.03013 (4)	0.0068 (4)	0.41 (8)
Al15	0.000000	0.25809 (4)	0.53285 (5)	0.00662 (19)
Al16	0.000000	0.52766 (5)	0.16337 (5)	0.0189 (2)
Al17A	0.000000	0.19089 (7)	0.63750 (11)	0.0091 (5)	0.908 (9)
Si17B	0.000000	0.1757 (7)	0.6124 (11)	0.012 (4)*	0.092 (9)
Al18	0.32754 (14)	0.33805 (4)	0.250000	0.0126 (5)	0.52 (9)
Si18	0.32754 (14)	0.33805 (4)	0.250000	0.0126 (5)	0.48 (9)
Al19	0.20942 (15)	0.44221 (4)	0.250000	0.0133 (2)
Al20	0.1113 (3)	0.23957 (8)	0.250000	0.0096 (4)	0.5
Al21	0.20919 (10)	0.10789 (3)	0.15319 (3)	0.0089 (3)	0.63 (5)
Si21	0.20919 (10)	0.10789 (3)	0.15319 (3)	0.0089 (3)	0.37 (5)
Al22	0.18810 (10)	0.17255 (3)	0.03759 (4)	0.0119 (3)	0.81 (6)
Si22	0.18810 (10)	0.17255 (3)	0.03759 (4)	0.0119 (3)	0.19 (6)
Al23	0.31517 (10)	0.05413 (3)	0.03152 (3)	0.00897 (14)
Al24	0.31724 (10)	0.49470 (3)	0.13170 (4)	0.01044 (15)
Al25	0.18885 (12)	0.38526 (3)	0.13490 (4)	0.0223 (2)
Al26A	0.3202 (4)	0.21649 (10)	0.1531 (2)	0.0070 (7)	0.593 (13)
Si26B	0.2898 (5)	0.22406 (13)	0.1730 (3)	0.0125 (7)*	0.407 (13)
Al27	0.000000	0.000000	0.000000	0.0161 (6)	0.853 (7)
Al28A	0.0495 (3)	0.10981 (8)	0.55507 (9)	0.0328 (10)	0.445 (3)
Al28B	0.000000	0.0716 (12)	0.5512 (8)	0.008 (6)*	0.064 (7)
Al28C	0.000000	0.0454 (15)	0.5436 (12)	0.011 (9)*	0.046 (7)

Atomic displacement parameters (Å²) top

	U¹¹	U²²	U³³	U¹²	U¹³	U²³
Ru1	0.0119 (2)	0.00458 (16)	0.00454 (16)	0.000	0.000	0.000
Ru2	0.00655 (14)	0.00520 (11)	0.00395 (12)	0.000	0.000	−0.00041 (8)
Ru3	0.00556 (14)	0.00514 (11)	0.00421 (12)	0.000	0.000	0.00000 (9)
Ru4	0.00580 (13)	0.00635 (11)	0.00525 (12)	0.000	0.000	0.00106 (9)
Ru5	0.00665 (14)	0.00574 (11)	0.00577 (12)	0.000	0.000	−0.00051 (9)
Si6	0.0058 (5)	0.0074 (4)	0.0068 (4)	0.000	0.000	0.0002 (3)
Ru6	0.0058 (5)	0.0074 (4)	0.0068 (4)	0.000	0.000	0.0002 (3)
Ru7A	0.0063 (5)	0.0058 (5)	0.0090 (3)	−0.0001 (3)	0.000	0.000
Ru8	0.0052 (11)	0.00544 (18)	0.00647 (19)	0.0004 (2)	0.000	0.000
Ru9	0.00554 (10)	0.00702 (8)	0.00425 (9)	0.00082 (6)	0.00052 (7)	0.00001 (6)
Si10	0.0060 (9)	0.0114 (8)	0.0092 (8)	0.000	0.000	0.000
Al10	0.0060 (9)	0.0114 (8)	0.0092 (8)	0.000	0.000	0.000
Al11	0.0105 (8)	0.0060 (6)	0.0230 (8)	0.000	0.000	0.000
Al12A	0.0192 (17)	0.0135 (11)	0.0053 (9)	0.000	0.000	0.000
Si13	0.0069 (5)	0.0054 (4)	0.0047 (4)	0.000	0.000	−0.0008 (3)
Al14	0.0073 (6)	0.0053 (6)	0.0080 (6)	0.000	0.000	−0.0001 (3)
Si14	0.0073 (6)	0.0053 (6)	0.0080 (6)	0.000	0.000	−0.0001 (3)
Al15	0.0045 (5)	0.0090 (4)	0.0064 (4)	0.000	0.000	0.0019 (3)
Al16	0.0037 (6)	0.0390 (7)	0.0140 (5)	0.000	0.000	−0.0183 (5)
Al17A	0.0124 (7)	0.0060 (7)	0.0090 (10)	0.000	0.000	0.0011 (6)
Al18	0.0091 (7)	0.0167 (6)	0.0120 (6)	0.0067 (4)	0.000	0.000
Si18	0.0091 (7)	0.0167 (6)	0.0120 (6)	0.0067 (4)	0.000	0.000
Al19	0.0138 (6)	0.0084 (5)	0.0178 (5)	−0.0024 (4)	0.000	0.000
Al20	0.0142 (12)	0.0092 (9)	0.0055 (9)	0.0019 (7)	0.000	0.000
Al21	0.0103 (5)	0.0068 (4)	0.0095 (4)	0.0021 (2)	−0.0039 (3)	−0.0005 (2)
Si21	0.0103 (5)	0.0068 (4)	0.0095 (4)	0.0021 (2)	−0.0039 (3)	−0.0005 (2)
Al22	0.0112 (5)	0.0097 (4)	0.0148 (5)	0.0015 (3)	0.0059 (3)	0.0041 (3)
Si22	0.0112 (5)	0.0097 (4)	0.0148 (5)	0.0015 (3)	0.0059 (3)	0.0041 (3)
Al23	0.0091 (4)	0.0088 (3)	0.0090 (3)	0.0011 (2)	0.0030 (3)	0.0015 (2)
Al24	0.0091 (4)	0.0099 (3)	0.0123 (3)	0.0018 (3)	−0.0013 (3)	0.0042 (3)
Al25	0.0262 (5)	0.0121 (4)	0.0285 (5)	−0.0080 (3)	−0.0213 (4)	0.0051 (3)
Al26A	0.0040 (9)	0.0086 (7)	0.0084 (13)	−0.0013 (5)	−0.0024 (8)	0.0017 (7)
Al27	0.0105 (11)	0.0136 (10)	0.0243 (11)	0.000	0.000	−0.0147 (7)
Al28A	0.069 (3)	0.0227 (11)	0.0063 (8)	0.0029 (9)	0.0017 (9)	−0.0007 (6)

Geometric parameters (Å, º) top

Ru1—Si13	2.4228 (9)	Ru9—Si26B	2.690 (3)
Ru1—Si13ⁱ	2.4228 (9)	Ru9—Al17A^xx	2.7899 (10)
Ru1—Si18	2.5255 (10)	Si10—Al19^xxi	2.6487 (13)
Ru1—Al18ⁱⁱ	2.5255 (10)	Si10—Al19^xvi	2.6487 (13)
Ru1—Al19	2.6055 (11)	Si10—Al24^xxi	2.8248 (7)
Ru1—Al19ⁱⁱ	2.6056 (10)	Si10—Al24^xvi	2.8248 (7)
Ru1—Al20ⁱⁱ	2.8218 (19)	Si10—Al24^xvii	2.8248 (7)
Ru1—Al20	2.8218 (19)	Si10—Al24^xxii	2.8248 (7)
Ru1—Al25	2.8750 (10)	Al12A—Al12Bⁱⁱ	0.74 (3)
Ru1—Al25ⁱ	2.8750 (10)	Al12A—Al12B	0.74 (3)
Ru1—Al25ⁱⁱⁱ	2.8750 (10)	Al12A—Al21ⁱⁱⁱ	2.6080 (9)
Ru2—Si26B	2.427 (3)	Al12A—Al21ⁱ	2.6080 (9)
Ru2—Si26Bⁱⁱⁱ	2.427 (3)	Al12A—Al21ⁱⁱ	2.6080 (9)
Ru2—Si13	2.4571 (8)	Al12A—Al21	2.6080 (9)
Ru2—Al12B	2.515 (9)	Al12A—Al20	2.724 (3)
Ru2—Al12Bⁱⁱ	2.515 (9)	Al12A—Al20ⁱⁱ	2.724 (3)
Ru2—Al21ⁱⁱⁱ	2.5221 (7)	Al12B—Al12Bⁱⁱ	1.20 (5)
Ru2—Al21	2.5222 (7)	Al12B—Al20	2.17 (2)
Ru2—Al26Aⁱⁱⁱ	2.524 (2)	Al12B—Al21ⁱ	2.423 (11)
Ru2—Al26A	2.524 (2)	Al12B—Al21	2.423 (11)
Ru2—Al22	2.6349 (7)	Al12B—Al20ⁱⁱ	2.595 (19)
Ru3—Si17B	2.469 (11)	Al12B—Si26Bⁱ	2.89 (2)
Ru3—Al24^iv	2.5456 (7)	Al12B—Si26B	2.89 (2)
Ru3—Al24^v	2.5456 (7)	Si13—Al20ⁱⁱ	2.5183 (14)
Ru3—Al17A	2.5668 (13)	Si13—Al20	2.5183 (14)
Ru3—Al28Aⁱⁱⁱ	2.6011 (18)	Si13—Al25	2.5897 (10)
Ru3—Al28A	2.6011 (18)	Si13—Al25ⁱⁱⁱ	2.5898 (10)
Ru3—Al25^iv	2.6069 (8)	Si13—Si26B	2.793 (4)
Ru3—Al25^v	2.6069 (8)	Si13—Si26Bⁱⁱⁱ	2.793 (4)
Ru3—Si10^vi	2.6207 (11)	Al14—Al25	2.6585 (11)
Ru3—Al28B	2.623 (18)	Al14—Al25ⁱⁱⁱ	2.6585 (11)
Ru3—Al18^vii	2.6662 (9)	Al14—Al23^ix	2.7345 (10)
Ru3—Al18^iv	2.6662 (9)	Al14—Al23^viii	2.7345 (10)
Ru4—Al16	2.4671 (11)	Al14—Al15ⁱ	2.7624 (13)
Ru4—Al23^viii	2.5271 (7)	Al14—Al22^viii	2.8756 (9)
Ru4—Al23^ix	2.5271 (7)	Al14—Al22^ix	2.8756 (9)
Ru4—Al14	2.5361 (9)	Al15—Si17B	2.538 (12)
Ru4—Al23^x	2.6278 (7)	Al15—Al17A	2.6774 (16)
Ru4—Al23^xi	2.6278 (7)	Al15—Al22ⁱⁱ	2.8634 (11)
Ru4—Al25ⁱⁱⁱ	2.7401 (8)	Al15—Al22ⁱ	2.8634 (11)
Ru4—Al25	2.7402 (8)	Al15—Al22^v	2.8818 (9)
Ru4—Al24	2.8446 (8)	Al15—Al22^iv	2.8818 (9)
Ru4—Al24ⁱⁱⁱ	2.8446 (8)	Al16—Al24	2.6216 (8)
Ru5—Al27	2.3207 (2)	Al16—Al24ⁱⁱⁱ	2.6216 (8)
Ru5—Al28Cⁱ	2.35 (2)	Al16—Al21^x	2.9146 (11)
Ru5—Al28Bⁱ	2.352 (16)	Al16—Al21^xi	2.9146 (11)
Ru5—Al28Aⁱⁱ	2.5293 (18)	Al17A—Si17B	0.63 (2)
Ru5—Al28Aⁱ	2.5293 (18)	Al17A—Al28Aⁱⁱⁱ	2.581 (3)
Ru5—Al21	2.5429 (7)	Al17A—Al28A	2.581 (3)
Ru5—Al21ⁱⁱⁱ	2.5429 (7)	Al17A—Al26A^v	2.588 (2)
Ru5—Al23ⁱⁱⁱ	2.5708 (7)	Al17A—Al26A^iv	2.588 (2)
Ru5—Al23	2.5708 (7)	Al17A—Si26B^v	2.661 (3)
Ru5—Al22	2.5988 (7)	Al17A—Si26B^iv	2.661 (3)
Si6—Al26A^x	2.583 (5)	Al17A—Al18^vii	2.7577 (18)
Si6—Al26A^xi	2.583 (5)	Al17A—Al18^iv	2.7577 (18)
Si6—Al21^x	2.5898 (8)	Si17B—Al28Aⁱⁱⁱ	1.98 (2)
Si6—Al21^xi	2.5898 (8)	Si17B—Al28A	1.98 (2)
Si6—Al14^xii	2.6404 (12)	Si17B—Al28B	2.75 (4)
Si6—Al23^xi	2.7613 (9)	Si17B—Al25^iv	2.808 (7)
Si6—Al23^x	2.7613 (9)	Si17B—Al25^v	2.808 (7)
Si6—Al15^xiii	2.7990 (12)	Si18—Al19	2.6026 (14)
Si6—Al22^xi	2.8073 (9)	Si18—Al25	2.8305 (10)
Si6—Al22^x	2.8073 (9)	Si18—Al25ⁱ	2.8305 (9)
Si6—Al16	2.9037 (15)	Si18—Al20	2.837 (2)
Ru7A—Al21	2.460 (3)	Al19—Al25ⁱ	2.7344 (10)
Ru7A—Al21ⁱ	2.460 (3)	Al19—Al25	2.7344 (10)
Ru7A—Si10	2.465 (2)	Al19—Al24	2.8599 (9)
Ru7A—Al16^xiv	2.486 (3)	Al19—Al24ⁱ	2.8599 (9)
Ru7A—Al16^xv	2.486 (3)	Al20—Al20ⁱⁱ	1.696 (4)
Ru7A—Al11^xv	2.5774 (16)	Al20—Si26Bⁱ	2.127 (7)
Ru7A—Al19^xvi	2.586 (4)	Al20—Si26B	2.127 (7)
Ru7A—Al12B	2.74 (2)	Al20—Al26A	2.616 (6)
Ru7A—Al12A	2.832 (5)	Al20—Al26Aⁱ	2.616 (6)
Ru7A—Al24^xvii	2.9086 (11)	Al21—Al26A	2.6828 (18)
Ru7B—Al16^xiv	2.355 (14)	Al21—Al24^xvii	2.6980 (10)
Ru7B—Al16^xv	2.355 (14)	Al21—Si26B	2.822 (3)
Ru7B—Al19^xvi	2.440 (18)	Al21—Al22	2.8362 (10)
Ru7B—Si10	2.543 (13)	Al22—Al28Aⁱ	2.637 (2)
Ru7B—Al21	2.583 (15)	Al22—Al26A	2.791 (4)
Ru7B—Al21ⁱ	2.583 (15)	Al22—Al22ⁱⁱⁱ	2.8673 (15)
Ru7B—Al11^xv	2.604 (11)	Al23—Al24^xvii	2.6935 (10)
Ru7B—Al24^xvii	2.890 (6)	Al23—Al27	2.7939 (7)
Ru7B—Al24^xvi	2.890 (6)	Al23—Al23^xix	2.8174 (15)
Ru7B—Ru7B^xviii	2.93 (4)	Al23—Al23^xxiii	2.8534 (13)
Ru8—Ru8^xviii	0.384 (4)	Al23—Al28Cⁱ	2.868 (13)
Ru8—Si26Bⁱ	2.191 (4)	Al24—Al28C^xx	2.48 (2)
Ru8—Si26B	2.191 (4)	Al24—Al28B^xx	2.670 (16)
Ru8—Si18	2.4257 (13)	Al24—Al25	2.7467 (10)
Ru8—Al26A	2.428 (3)	Al24—Al24^xix	2.7858 (15)
Ru8—Al26Aⁱ	2.428 (3)	Al25—Al28A^xx	2.592 (2)
Ru8—Si26B^xviii	2.455 (3)	Al26A—Si26B	0.503 (2)
Ru8—Si26B^xix	2.455 (3)	Al26A—Al26A^xix	2.741 (6)
Ru8—Al11^xv	2.5478 (14)	Al27—Al28Cⁱ	1.40 (3)
Ru8—Al18^xviii	2.6254 (15)	Al27—Al28C^xxiv	1.40 (3)
Ru8—Al26A^xviii	2.636 (3)	Al27—Al28Bⁱ	1.98 (3)
Ru9—Si13	2.4102 (7)	Al27—Al28B^xxiv	1.98 (3)
Ru9—Al22^ix	2.5287 (7)	Al27—Al28Aⁱ	2.8403 (19)
Ru9—Al14	2.5320 (7)	Al27—Al28A^xxiv	2.8403 (19)
Ru9—Al26A	2.5415 (17)	Al28A—Al28Aⁱⁱⁱ	0.754 (5)
Ru9—Al15^xx	2.5526 (5)	Al28A—Al28B	0.98 (2)
Ru9—Al15ⁱ	2.6130 (8)	Al28A—Al28C	1.57 (4)
Ru9—Al22	2.6343 (7)	Al28B—Al28C	0.63 (2)
Ru9—Si17B^xx	2.662 (6)	Al28C—Al28C^vi	2.79 (7)

Si13—Ru1—Si13ⁱ	109.88 (4)	Ru3—Al17A—Al28Aⁱⁱⁱ	60.70 (6)
Si13—Ru1—Si18	85.009 (14)	Si17B—Al17A—Al28A	16.0 (9)
Si13ⁱ—Ru1—Si18	85.008 (14)	Ru3—Al17A—Al28A	60.69 (6)
Si13—Ru1—Al18ⁱⁱ	85.008 (14)	Al28Aⁱⁱⁱ—Al17A—Al28A	16.81 (11)
Si13ⁱ—Ru1—Al18ⁱⁱ	85.008 (14)	Si17B—Al17A—Al26A^v	125.3 (8)
Si18—Ru1—Al18ⁱⁱ	162.57 (5)	Ru3—Al17A—Al26A^v	139.14 (13)
Si13—Ru1—Al19	117.000 (18)	Al28Aⁱⁱⁱ—Al17A—Al26A^v	141.06 (11)
Si13ⁱ—Ru1—Al19	117.001 (18)	Al28A—Al17A—Al26A^v	128.54 (8)
Si18—Ru1—Al19	60.93 (3)	Si17B—Al17A—Al26A^iv	125.3 (8)
Al18ⁱⁱ—Ru1—Al19	136.49 (4)	Ru3—Al17A—Al26A^iv	139.14 (13)
Si13—Ru1—Al19ⁱⁱ	117.000 (18)	Al28Aⁱⁱⁱ—Al17A—Al26A^iv	128.53 (8)
Si13ⁱ—Ru1—Al19ⁱⁱ	117.001 (18)	Al28A—Al17A—Al26A^iv	141.06 (11)
Si18—Ru1—Al19ⁱⁱ	136.49 (4)	Al26A^v—Al17A—Al26A^iv	63.95 (14)
Al18ⁱⁱ—Ru1—Al19ⁱⁱ	60.93 (3)	Si17B—Al17A—Si26B^v	130.6 (7)
Al19—Ru1—Al19ⁱⁱ	75.56 (5)	Ru3—Al17A—Si26B^v	128.58 (15)
Si13—Ru1—Al20ⁱⁱ	56.78 (2)	Al28Aⁱⁱⁱ—Al17A—Si26B^v	145.29 (10)
Si13ⁱ—Ru1—Al20ⁱⁱ	56.78 (2)	Al28A—Al17A—Si26B^v	130.25 (9)
Si18—Ru1—Al20ⁱⁱ	98.78 (5)	Al26A^v—Al17A—Si26B^v	10.89 (5)
Al18ⁱⁱ—Ru1—Al20ⁱⁱ	63.79 (5)	Al26A^iv—Al17A—Si26B^v	69.85 (14)
Al19—Ru1—Al20ⁱⁱ	159.71 (5)	Si17B—Al17A—Si26B^iv	130.6 (7)
Al19ⁱⁱ—Ru1—Al20ⁱⁱ	124.73 (5)	Ru3—Al17A—Si26B^iv	128.58 (15)
Si13—Ru1—Al20	56.78 (2)	Al28Aⁱⁱⁱ—Al17A—Si26B^iv	130.25 (9)
Si13ⁱ—Ru1—Al20	56.78 (2)	Al28A—Al17A—Si26B^iv	145.29 (10)
Si18—Ru1—Al20	63.80 (5)	Al26A^v—Al17A—Si26B^iv	69.85 (14)
Al18ⁱⁱ—Ru1—Al20	98.78 (5)	Al26A^iv—Al17A—Si26B^iv	10.89 (5)
Al19—Ru1—Al20	124.73 (5)	Si26B^v—Al17A—Si26B^iv	74.02 (16)
Al19ⁱⁱ—Ru1—Al20	159.71 (5)	Si17B—Al17A—Al15	70.5 (11)
Al20ⁱⁱ—Ru1—Al20	34.98 (9)	Ru3—Al17A—Al15	144.49 (11)
Si13—Ru1—Al25	57.77 (2)	Al28Aⁱⁱⁱ—Al17A—Al15	84.21 (8)
Si13ⁱ—Ru1—Al25	145.35 (2)	Al28A—Al17A—Al15	84.21 (8)
Si18—Ru1—Al25	62.825 (19)	Al26A^v—Al17A—Al15	66.88 (12)
Al18ⁱⁱ—Ru1—Al25	122.209 (17)	Al26A^iv—Al17A—Al15	66.88 (12)
Al19—Ru1—Al25	59.618 (17)	Si26B^v—Al17A—Al15	77.42 (14)
Al19ⁱⁱ—Ru1—Al25	96.18 (2)	Si26B^iv—Al17A—Al15	77.42 (14)
Al20ⁱⁱ—Ru1—Al25	113.00 (3)	Si17B—Al17A—Al18^vii	123.8 (9)
Al20—Ru1—Al25	95.15 (3)	Ru3—Al17A—Al18^vii	59.97 (3)
Si13—Ru1—Al25ⁱ	145.35 (2)	Al28Aⁱⁱⁱ—Al17A—Al18^vii	116.49 (7)
Si13ⁱ—Ru1—Al25ⁱ	57.78 (2)	Al28A—Al17A—Al18^vii	107.86 (6)
Si18—Ru1—Al25ⁱ	62.825 (19)	Al26A^v—Al17A—Al18^vii	81.29 (14)
Al18ⁱⁱ—Ru1—Al25ⁱ	122.210 (17)	Al26A^iv—Al17A—Al18^vii	110.69 (12)
Al19—Ru1—Al25ⁱ	59.616 (17)	Si26B^v—Al17A—Al18^vii	70.40 (15)
Al19ⁱⁱ—Ru1—Al25ⁱ	96.18 (2)	Si26B^iv—Al17A—Al18^vii	103.80 (13)
Al20ⁱⁱ—Ru1—Al25ⁱ	113.00 (3)	Al15—Al17A—Al18^vii	145.81 (5)
Al20—Ru1—Al25ⁱ	95.15 (3)	Si17B—Al17A—Al18^iv	123.8 (9)
Al25—Ru1—Al25ⁱ	111.83 (3)	Ru3—Al17A—Al18^iv	59.97 (3)
Si13—Ru1—Al25ⁱⁱⁱ	57.77 (2)	Al28Aⁱⁱⁱ—Al17A—Al18^iv	107.86 (6)
Si13ⁱ—Ru1—Al25ⁱⁱⁱ	145.35 (2)	Al28A—Al17A—Al18^iv	116.49 (7)
Si18—Ru1—Al25ⁱⁱⁱ	122.210 (17)	Al26A^v—Al17A—Al18^iv	110.69 (12)
Al18ⁱⁱ—Ru1—Al25ⁱⁱⁱ	62.825 (19)	Al26A^iv—Al17A—Al18^iv	81.29 (14)
Al19—Ru1—Al25ⁱⁱⁱ	96.18 (2)	Si26B^v—Al17A—Al18^iv	103.80 (13)
Al19ⁱⁱ—Ru1—Al25ⁱⁱⁱ	59.616 (17)	Si26B^iv—Al17A—Al18^iv	70.40 (15)
Al20ⁱⁱ—Ru1—Al25ⁱⁱⁱ	95.15 (3)	Al15—Al17A—Al18^iv	145.81 (5)
Al20—Ru1—Al25ⁱⁱⁱ	113.00 (3)	Al18^vii—Al17A—Al18^iv	56.93 (5)
Al25—Ru1—Al25ⁱⁱⁱ	60.08 (3)	Si17B—Al17A—Ru8^vii	175.5 (5)
Al25ⁱ—Ru1—Al25ⁱⁱⁱ	150.82 (3)	Ru3—Al17A—Ru8^vii	103.83 (6)
Si26B—Ru2—Si26Bⁱⁱⁱ	131.1 (3)	Al28Aⁱⁱⁱ—Al17A—Ru8^vii	163.69 (7)
Si26B—Ru2—Si13	69.75 (9)	Al28A—Al17A—Ru8^vii	159.96 (7)
Si26Bⁱⁱⁱ—Ru2—Si13	69.75 (9)	Al26A^v—Al17A—Ru8^vii	53.88 (9)
Si26B—Ru2—Al12B	71.4 (7)	Al26A^iv—Al17A—Ru8^vii	58.94 (9)
Si26Bⁱⁱⁱ—Ru2—Al12B	96.7 (5)	Si26B^v—Al17A—Ru8^vii	47.63 (10)
Si13—Ru2—Al12B	108.2 (5)	Si26B^iv—Al17A—Ru8^vii	53.82 (9)
Si26B—Ru2—Al12Bⁱⁱ	96.7 (5)	Al15—Al17A—Ru8^vii	111.59 (6)
Si26Bⁱⁱⁱ—Ru2—Al12Bⁱⁱ	71.4 (7)	Al18^vii—Al17A—Ru8^vii	52.15 (5)
Si13—Ru2—Al12Bⁱⁱ	108.2 (5)	Al18^iv—Al17A—Ru8^vii	56.82 (6)
Al12B—Ru2—Al12Bⁱⁱ	27.6 (12)	Al17A—Si17B—Al28Aⁱⁱⁱ	159.0 (12)
Si26B—Ru2—Al21ⁱⁱⁱ	143.17 (6)	Al17A—Si17B—Al28A	159.0 (12)
Si26Bⁱⁱⁱ—Ru2—Al21ⁱⁱⁱ	69.49 (9)	Al28Aⁱⁱⁱ—Si17B—Al28A	21.9 (3)
Si13—Ru2—Al21ⁱⁱⁱ	139.236 (17)	Al17A—Si17B—Ru3	91.8 (12)
Al12B—Ru2—Al21ⁱⁱⁱ	76.4 (6)	Al28Aⁱⁱⁱ—Si17B—Ru3	70.5 (5)
Al12Bⁱⁱ—Ru2—Al21ⁱⁱⁱ	57.5 (4)	Al28A—Si17B—Ru3	70.5 (5)
Si26B—Ru2—Al21	69.49 (9)	Al17A—Si17B—Al15	96.0 (12)
Si26Bⁱⁱⁱ—Ru2—Al21	143.17 (6)	Al28Aⁱⁱⁱ—Si17B—Al15	101.8 (8)
Si13—Ru2—Al21	139.237 (17)	Al28A—Si17B—Al15	101.8 (8)
Al12B—Ru2—Al21	57.5 (4)	Ru3—Si17B—Al15	172.2 (12)
Al12Bⁱⁱ—Ru2—Al21	76.4 (6)	Al17A—Si17B—Ru9^iv	95.2 (8)
Al21ⁱⁱⁱ—Ru2—Al21	78.42 (3)	Al28Aⁱⁱⁱ—Si17B—Ru9^iv	84.8 (5)
Si26B—Ru2—Al26Aⁱⁱⁱ	141.3 (2)	Al28A—Si17B—Ru9^iv	103.5 (8)
Si26Bⁱⁱⁱ—Ru2—Al26Aⁱⁱⁱ	11.46 (6)	Ru3—Si17B—Ru9^iv	120.6 (2)
Si13—Ru2—Al26Aⁱⁱⁱ	75.71 (7)	Al15—Si17B—Ru9^iv	58.7 (2)
Al12B—Ru2—Al26Aⁱⁱⁱ	104.4 (5)	Al17A—Si17B—Ru9^v	95.2 (8)
Al12Bⁱⁱ—Ru2—Al26Aⁱⁱⁱ	77.8 (6)	Al28Aⁱⁱⁱ—Si17B—Ru9^v	103.5 (8)
Al21ⁱⁱⁱ—Ru2—Al26Aⁱⁱⁱ	64.24 (6)	Al28A—Si17B—Ru9^v	84.8 (5)
Al21—Ru2—Al26Aⁱⁱⁱ	141.99 (5)	Ru3—Si17B—Ru9^v	120.6 (2)
Si26B—Ru2—Al26A	11.46 (6)	Al15—Si17B—Ru9^v	58.7 (2)
Si26Bⁱⁱⁱ—Ru2—Al26A	141.3 (2)	Ru9^iv—Si17B—Ru9^v	117.3 (4)
Si13—Ru2—Al26A	75.70 (7)	Al17A—Si17B—Al28B	151.9 (13)
Al12B—Ru2—Al26A	77.8 (6)	Al28Aⁱⁱⁱ—Si17B—Al28B	14.9 (3)
Al12Bⁱⁱ—Ru2—Al26A	104.4 (5)	Al28A—Si17B—Al28B	14.9 (3)
Al21ⁱⁱⁱ—Ru2—Al26A	141.99 (4)	Ru3—Si17B—Al28B	60.1 (5)
Al21—Ru2—Al26A	64.24 (6)	Al15—Si17B—Al28B	112.1 (9)
Al26Aⁱⁱⁱ—Ru2—Al26A	150.45 (19)	Ru9^iv—Si17B—Al28B	99.3 (7)
Si26B—Ru2—Al22	76.76 (16)	Ru9^v—Si17B—Al28B	99.3 (7)
Si26Bⁱⁱⁱ—Ru2—Al22	139.60 (14)	Al17A—Si17B—Al25^iv	98.7 (8)
Si13—Ru2—Al22	103.99 (2)	Al28Aⁱⁱⁱ—Si17B—Al25^iv	62.7 (3)
Al12B—Ru2—Al22	122.3 (4)	Al28A—Si17B—Al25^iv	82.1 (6)
Al12Bⁱⁱ—Ru2—Al22	142.5 (6)	Ru3—Si17B—Al25^iv	58.8 (2)
Al21ⁱⁱⁱ—Ru2—Al22	106.99 (2)	Al15—Si17B—Al25^iv	119.7 (3)
Al21—Ru2—Al22	66.69 (2)	Ru9^iv—Si17B—Al25^iv	61.84 (8)
Al26Aⁱⁱⁱ—Ru2—Al22	129.56 (11)	Ru9^v—Si17B—Al25^iv	166.1 (11)
Al26A—Ru2—Al22	65.46 (12)	Al28B—Si17B—Al25^iv	67.9 (4)
Si17B—Ru3—Al24^iv	115.9 (5)	Al17A—Si17B—Al25^v	98.7 (8)
Si17B—Ru3—Al24^v	115.9 (5)	Al28Aⁱⁱⁱ—Si17B—Al25^v	82.1 (6)
Al24^iv—Ru3—Al24^v	66.35 (3)	Al28A—Si17B—Al25^v	62.7 (3)
Si17B—Ru3—Al17A	14.2 (6)	Ru3—Si17B—Al25^v	58.8 (2)
Al24^iv—Ru3—Al17A	126.73 (5)	Al15—Si17B—Al25^v	119.7 (3)
Al24^v—Ru3—Al17A	126.73 (5)	Ru9^iv—Si17B—Al25^v	166.1 (11)
Si17B—Ru3—Al28Aⁱⁱⁱ	46.0 (6)	Ru9^v—Si17B—Al25^v	61.84 (8)
Al24^iv—Ru3—Al28Aⁱⁱⁱ	73.78 (5)	Al28B—Si17B—Al25^v	67.9 (4)
Al24^v—Ru3—Al28Aⁱⁱⁱ	83.07 (5)	Al25^iv—Si17B—Al25^v	115.3 (5)
Al17A—Ru3—Al28Aⁱⁱⁱ	59.93 (7)	Ru8—Si18—Ru1	126.28 (6)
Si17B—Ru3—Al28A	46.0 (6)	Ru8—Si18—Al19	172.67 (7)
Al24^iv—Ru3—Al28A	83.07 (5)	Ru1—Si18—Al19	61.05 (3)
Al24^v—Ru3—Al28A	73.78 (5)	Ru8—Si18—Ru8^xviii	7.45 (7)
Al17A—Ru3—Al28A	59.93 (7)	Ru1—Si18—Ru8^xviii	133.73 (6)
Al28Aⁱⁱⁱ—Ru3—Al28A	16.68 (11)	Al19—Si18—Ru8^xviii	165.22 (6)
Si17B—Ru3—Al25^iv	67.11 (10)	Ru8—Si18—Al18^xviii	62.43 (5)
Al24^iv—Ru3—Al25^iv	64.41 (2)	Ru1—Si18—Al18^xviii	171.29 (2)
Al24^v—Ru3—Al25^iv	124.31 (3)	Al19—Si18—Al18^xviii	110.24 (3)
Al17A—Ru3—Al25^iv	70.03 (2)	Ru8^xviii—Si18—Al18^xviii	54.99 (4)
Al28Aⁱⁱⁱ—Ru3—Al25^iv	59.69 (6)	Ru8—Si18—Ru3^vii	110.84 (5)
Al28A—Ru3—Al25^iv	76.07 (6)	Ru1—Si18—Ru3^vii	112.80 (3)
Si17B—Ru3—Al25^v	67.11 (10)	Al19—Si18—Ru3^vii	63.41 (3)
Al24^iv—Ru3—Al25^v	124.31 (3)	Ru8^xviii—Si18—Ru3^vii	104.87 (4)
Al24^v—Ru3—Al25^v	64.41 (2)	Al18^xviii—Si18—Ru3^vii	60.46 (2)
Al17A—Ru3—Al25^v	70.03 (2)	Ru8—Si18—Ru3^xx	110.84 (5)
Al28Aⁱⁱⁱ—Ru3—Al25^v	76.07 (6)	Ru1—Si18—Ru3^xx	112.80 (3)
Al28A—Ru3—Al25^v	59.69 (6)	Al19—Si18—Ru3^xx	63.41 (3)
Al25^iv—Ru3—Al25^v	130.93 (4)	Ru8^xviii—Si18—Ru3^xx	104.87 (4)
Si17B—Ru3—Si10^vi	177.3 (6)	Al18^xviii—Si18—Ru3^xx	60.46 (2)
Al24^iv—Ru3—Si10^vi	66.27 (2)	Ru3^vii—Si18—Ru3^xx	69.26 (3)
Al24^v—Ru3—Si10^vi	66.27 (2)	Ru8—Si18—Al17A^vii	63.98 (5)
Al17A—Ru3—Si10^vi	163.13 (6)	Ru1—Si18—Al17A^vii	120.56 (3)
Al28Aⁱⁱⁱ—Ru3—Si10^vi	136.65 (5)	Al19—Si18—Al17A^vii	113.31 (5)
Al28A—Ru3—Si10^vi	136.64 (5)	Ru8^xviii—Si18—Al17A^vii	61.64 (5)
Al25^iv—Ru3—Si10^vi	113.29 (2)	Al18^xviii—Si18—Al17A^vii	61.53 (3)
Al25^v—Ru3—Si10^vi	113.29 (2)	Ru3^vii—Si18—Al17A^vii	56.46 (4)
Si17B—Ru3—Al28B	65.3 (8)	Ru3^xx—Si18—Al17A^vii	114.00 (4)
Al24^iv—Ru3—Al28B	62.2 (5)	Ru8—Si18—Al17A^xx	63.98 (5)
Al24^v—Ru3—Al28B	62.2 (5)	Ru1—Si18—Al17A^xx	120.56 (3)
Al17A—Ru3—Al28B	79.5 (6)	Al19—Si18—Al17A^xx	113.31 (5)
Al28Aⁱⁱⁱ—Ru3—Al28B	21.5 (5)	Ru8^xviii—Si18—Al17A^xx	61.64 (5)
Al28A—Ru3—Al28B	21.5 (5)	Al18^xviii—Si18—Al17A^xx	61.53 (3)
Al25^iv—Ru3—Al28B	72.86 (18)	Ru3^vii—Si18—Al17A^xx	114.00 (4)
Al25^v—Ru3—Al28B	72.86 (18)	Ru3^xx—Si18—Al17A^xx	56.46 (4)
Si10^vi—Ru3—Al28B	117.4 (6)	Al17A^vii—Si18—Al17A^xx	115.12 (8)
Si17B—Ru3—Al18^vii	75.6 (5)	Ru8—Si18—Al25	121.29 (3)
Al24^iv—Ru3—Al18^vii	166.84 (2)	Ru1—Si18—Al25	64.64 (3)
Al24^v—Ru3—Al18^vii	115.73 (3)	Al19—Si18—Al25	60.26 (3)
Al17A—Ru3—Al18^vii	63.57 (5)	Ru8^xviii—Si18—Al25	122.31 (3)
Al28Aⁱⁱⁱ—Ru3—Al18^vii	119.09 (5)	Al18^xviii—Si18—Al25	111.93 (3)
Al28A—Ru3—Al18^vii	110.08 (5)	Ru3^vii—Si18—Al25	113.87 (4)
Al25^iv—Ru3—Al18^vii	118.23 (3)	Ru3^xx—Si18—Al25	56.53 (2)
Al25^v—Ru3—Al18^vii	64.92 (3)	Al17A^vii—Si18—Al25	169.79 (5)
Si10^vi—Ru3—Al18^vii	102.06 (2)	Al17A^xx—Si18—Al25	64.16 (5)
Al28B—Ru3—Al18^vii	130.8 (4)	Ru8—Si18—Al25ⁱ	121.29 (3)
Si17B—Ru3—Al18^iv	75.6 (5)	Ru1—Si18—Al25ⁱ	64.64 (3)
Al24^iv—Ru3—Al18^iv	115.73 (3)	Al19—Si18—Al25ⁱ	60.26 (3)
Al24^v—Ru3—Al18^iv	166.84 (2)	Ru8^xviii—Si18—Al25ⁱ	122.31 (3)
Al17A—Ru3—Al18^iv	63.57 (5)	Al18^xviii—Si18—Al25ⁱ	111.93 (3)
Al28Aⁱⁱⁱ—Ru3—Al18^iv	110.07 (5)	Ru3^vii—Si18—Al25ⁱ	56.53 (2)
Al28A—Ru3—Al18^iv	119.09 (5)	Ru3^xx—Si18—Al25ⁱ	113.86 (4)
Al25^iv—Ru3—Al18^iv	64.92 (3)	Al17A^vii—Si18—Al25ⁱ	64.17 (5)
Al25^v—Ru3—Al18^iv	118.23 (3)	Al17A^xx—Si18—Al25ⁱ	169.79 (5)
Si10^vi—Ru3—Al18^iv	102.06 (2)	Al25—Si18—Al25ⁱ	114.54 (5)
Al28B—Ru3—Al18^iv	130.8 (4)	Ru8—Si18—Al20	63.09 (6)
Al18^vii—Ru3—Al18^iv	59.08 (4)	Ru1—Si18—Al20	63.19 (5)
Al16—Ru4—Al23^viii	139.23 (2)	Al19—Si18—Al20	124.24 (6)
Al16—Ru4—Al23^ix	139.23 (2)	Ru8^xviii—Si18—Al20	70.54 (6)
Al23^viii—Ru4—Al23^ix	67.76 (3)	Al18^xviii—Si18—Al20	125.52 (5)
Al16—Ru4—Al14	144.31 (4)	Ru3^vii—Si18—Al20	145.349 (14)
Al23^viii—Ru4—Al14	65.38 (2)	Ru3^xx—Si18—Al20	145.349 (14)
Al23^ix—Ru4—Al14	65.38 (2)	Al17A^vii—Si18—Al20	94.40 (4)
Al16—Ru4—Al23^x	75.80 (3)	Al17A^xx—Si18—Al20	94.40 (4)
Al23^viii—Ru4—Al23^x	102.12 (2)	Al25—Si18—Al20	95.81 (4)
Al23^ix—Ru4—Al23^x	67.19 (3)	Al25ⁱ—Si18—Al20	95.81 (4)
Al14—Ru4—Al23^x	132.11 (2)	Ru7B^xxv—Al19—Ru7A^xxv	3.6 (4)
Al16—Ru4—Al23^xi	75.80 (3)	Ru7B^xxv—Al19—Si18	162.8 (5)
Al23^viii—Ru4—Al23^xi	67.19 (3)	Ru7A^xxv—Al19—Si18	159.20 (10)
Al23^ix—Ru4—Al23^xi	102.12 (2)	Ru7B^xxv—Al19—Ru1	139.2 (5)
Al14—Ru4—Al23^xi	132.11 (2)	Ru7A^xxv—Al19—Ru1	142.79 (9)
Al23^x—Ru4—Al23^xi	64.83 (3)	Si18—Al19—Ru1	58.02 (3)
Al16—Ru4—Al25ⁱⁱⁱ	89.86 (3)	Ru7B^xxv—Al19—Si10^xxvii	59.8 (5)
Al23^viii—Ru4—Al25ⁱⁱⁱ	89.91 (3)	Ru7A^xxv—Al19—Si10^xxvii	56.17 (9)
Al23^ix—Ru4—Al25ⁱⁱⁱ	125.74 (2)	Si18—Al19—Si10^xxvii	103.03 (5)
Al14—Ru4—Al25ⁱⁱⁱ	60.36 (2)	Ru1—Al19—Si10^xxvii	161.04 (5)
Al23^x—Ru4—Al25ⁱⁱⁱ	165.54 (3)	Ru7B^xxv—Al19—Al25ⁱ	118.98 (5)
Al23^xi—Ru4—Al25ⁱⁱⁱ	113.90 (2)	Ru7A^xxv—Al19—Al25ⁱ	119.26 (2)
Al16—Ru4—Al25	89.86 (3)	Si18—Al19—Al25ⁱ	64.00 (3)
Al23^viii—Ru4—Al25	125.74 (2)	Ru1—Al19—Al25ⁱ	65.10 (3)
Al23^ix—Ru4—Al25	89.91 (3)	Si10^xxvii—Al19—Al25ⁱ	108.41 (3)
Al14—Ru4—Al25	60.36 (2)	Ru7B^xxv—Al19—Al25	118.98 (5)
Al23^x—Ru4—Al25	113.90 (2)	Ru7A^xxv—Al19—Al25	119.26 (2)
Al23^xi—Ru4—Al25	165.54 (3)	Si18—Al19—Al25	64.00 (3)
Al25ⁱⁱⁱ—Ru4—Al25	63.37 (4)	Ru1—Al19—Al25	65.10 (3)
Al16—Ru4—Al24	58.633 (16)	Si10^xxvii—Al19—Al25	108.41 (3)
Al23^viii—Ru4—Al24	153.59 (2)	Al25ⁱ—Al19—Al25	121.10 (5)
Al23^ix—Ru4—Al24	87.02 (2)	Ru7B^xxv—Al19—Ru3^vii	106.9 (4)
Al14—Ru4—Al24	112.050 (17)	Ru7A^xxv—Al19—Ru3^vii	103.87 (7)
Al23^x—Ru4—Al24	58.81 (2)	Si18—Al19—Ru3^vii	59.41 (3)
Al23^xi—Ru4—Al24	113.17 (2)	Ru1—Al19—Ru3^vii	107.11 (3)
Al25ⁱⁱⁱ—Ru4—Al24	112.10 (3)	Si10^xxvii—Al19—Ru3^vii	57.80 (3)
Al25—Ru4—Al24	58.89 (2)	Al25ⁱ—Al19—Ru3^vii	56.54 (2)
Al16—Ru4—Al24ⁱⁱⁱ	58.634 (16)	Al25—Al19—Ru3^vii	113.66 (4)
Al23^viii—Ru4—Al24ⁱⁱⁱ	87.02 (2)	Ru7B^xxv—Al19—Ru3^xx	106.9 (4)
Al23^ix—Ru4—Al24ⁱⁱⁱ	153.59 (2)	Ru7A^xxv—Al19—Ru3^xx	103.87 (7)
Al14—Ru4—Al24ⁱⁱⁱ	112.049 (17)	Si18—Al19—Ru3^xx	59.41 (3)
Al23^x—Ru4—Al24ⁱⁱⁱ	113.17 (2)	Ru1—Al19—Ru3^xx	107.11 (3)
Al23^xi—Ru4—Al24ⁱⁱⁱ	58.81 (2)	Si10^xxvii—Al19—Ru3^xx	57.80 (3)
Al25ⁱⁱⁱ—Ru4—Al24ⁱⁱⁱ	58.88 (2)	Al25ⁱ—Al19—Ru3^xx	113.66 (4)
Al25—Ru4—Al24ⁱⁱⁱ	112.10 (3)	Al25—Al19—Ru3^xx	56.54 (2)
Al24—Ru4—Al24ⁱⁱⁱ	116.42 (3)	Ru3^vii—Al19—Ru3^xx	66.33 (3)
Al27—Ru5—Al28Cⁱ	34.8 (9)	Ru7B^xxv—Al19—Al24	65.53 (15)
Al27—Ru5—Al28Bⁱ	50.3 (7)	Ru7A^xxv—Al19—Al24	64.34 (3)
Al28Cⁱ—Ru5—Al28Bⁱ	15.5 (6)	Si18—Al19—Al24	107.72 (3)
Al27—Ru5—Al28Aⁱⁱ	71.55 (4)	Ru1—Al19—Al24	121.07 (2)
Al28Cⁱ—Ru5—Al28Aⁱⁱ	37.4 (9)	Si10^xxvii—Al19—Al24	61.56 (2)
Al28Bⁱ—Ru5—Al28Aⁱⁱ	22.7 (6)	Al25ⁱ—Al19—Al24	166.35 (5)
Al27—Ru5—Al28Aⁱ	71.55 (4)	Al25—Al19—Al24	58.76 (2)
Al28Cⁱ—Ru5—Al28Aⁱ	37.4 (9)	Ru3^vii—Al19—Al24	110.17 (4)
Al28Bⁱ—Ru5—Al28Aⁱ	22.7 (6)	Ru3^xx—Al19—Al24	53.74 (2)
Al28Aⁱⁱ—Ru5—Al28Aⁱ	17.15 (11)	Ru7B^xxv—Al19—Al24ⁱ	65.53 (15)
Al27—Ru5—Al21	127.171 (16)	Ru7A^xxv—Al19—Al24ⁱ	64.34 (3)
Al28Cⁱ—Ru5—Al21	140.96 (9)	Si18—Al19—Al24ⁱ	107.71 (3)
Al28Bⁱ—Ru5—Al21	139.85 (16)	Ru1—Al19—Al24ⁱ	121.07 (2)
Al28Aⁱⁱ—Ru5—Al21	138.19 (5)	Si10^xxvii—Al19—Al24ⁱ	61.56 (2)
Al28Aⁱ—Ru5—Al21	123.94 (6)	Al25ⁱ—Al19—Al24ⁱ	58.76 (2)
Al27—Ru5—Al21ⁱⁱⁱ	127.172 (16)	Al25—Al19—Al24ⁱ	166.35 (5)
Al28Cⁱ—Ru5—Al21ⁱⁱⁱ	140.96 (9)	Ru3^vii—Al19—Al24ⁱ	53.74 (2)
Al28Bⁱ—Ru5—Al21ⁱⁱⁱ	139.85 (16)	Ru3^xx—Al19—Al24ⁱ	110.17 (4)
Al28Aⁱⁱ—Ru5—Al21ⁱⁱⁱ	123.94 (6)	Al24—Al19—Al24ⁱ	117.69 (4)
Al28Aⁱ—Ru5—Al21ⁱⁱⁱ	138.19 (5)	Al20ⁱⁱ—Al20—Si26Bⁱ	129.78 (9)
Al21—Ru5—Al21ⁱⁱⁱ	77.66 (3)	Al20ⁱⁱ—Al20—Si26B	129.78 (9)
Al27—Ru5—Al23ⁱⁱⁱ	69.449 (16)	Si26Bⁱ—Al20—Si26B	97.04 (16)
Al28Cⁱ—Ru5—Al23ⁱⁱⁱ	71.17 (14)	Al20ⁱⁱ—Al20—Al12B	83.4 (7)
Al28Bⁱ—Ru5—Al23ⁱⁱⁱ	74.28 (16)	Si26Bⁱ—Al20—Al12B	84.5 (4)
Al28Aⁱⁱ—Ru5—Al23ⁱⁱⁱ	72.12 (6)	Si26B—Al20—Al12B	84.5 (4)
Al28Aⁱ—Ru5—Al23ⁱⁱⁱ	88.37 (6)	Al20ⁱⁱ—Al20—Si13ⁱ	70.32 (5)
Al21—Ru5—Al23ⁱⁱⁱ	145.86 (2)	Si26Bⁱ—Al20—Si13ⁱ	73.37 (7)
Al21ⁱⁱⁱ—Ru5—Al23ⁱⁱⁱ	69.88 (2)	Si26B—Al20—Si13ⁱ	153.36 (12)
Al27—Ru5—Al23	69.449 (16)	Al12B—Al20—Si13ⁱ	118.3 (3)
Al28Cⁱ—Ru5—Al23	71.17 (14)	Al20ⁱⁱ—Al20—Si13	70.32 (5)
Al28Bⁱ—Ru5—Al23	74.28 (16)	Si26Bⁱ—Al20—Si13	153.36 (12)
Al28Aⁱⁱ—Ru5—Al23	88.38 (6)	Si26B—Al20—Si13	73.37 (7)
Al28Aⁱ—Ru5—Al23	72.12 (6)	Al12B—Al20—Si13	118.3 (3)
Al21—Ru5—Al23	69.88 (2)	Si13ⁱ—Al20—Si13	103.91 (8)
Al21ⁱⁱⁱ—Ru5—Al23	145.86 (2)	Al20ⁱⁱ—Al20—Al12Bⁱⁱ	56.1 (6)
Al23ⁱⁱⁱ—Ru5—Al23	138.27 (3)	Si26Bⁱ—Al20—Al12Bⁱⁱ	102.4 (4)
Al27—Ru5—Al22	124.802 (18)	Si26B—Al20—Al12Bⁱⁱ	102.4 (4)
Al28Cⁱ—Ru5—Al22	97.0 (7)	Al12B—Al20—Al12Bⁱⁱ	27.3 (13)
Al28Bⁱ—Ru5—Al22	84.1 (6)	Si13ⁱ—Al20—Al12Bⁱⁱ	103.9 (4)
Al28Aⁱⁱ—Ru5—Al22	72.13 (5)	Si13—Al20—Al12Bⁱⁱ	103.9 (4)
Al28Aⁱ—Ru5—Al22	61.87 (5)	Al20ⁱⁱ—Al20—Al26A	127.49 (5)
Al21—Ru5—Al22	66.94 (2)	Si26Bⁱ—Al20—Al26A	98.57 (10)
Al21ⁱⁱⁱ—Ru5—Al22	107.46 (2)	Si26B—Al20—Al26A	2.89 (9)
Al23ⁱⁱⁱ—Ru5—Al22	132.77 (2)	Al12B—Al20—Al26A	82.2 (4)
Al23—Ru5—Al22	69.40 (2)	Si13ⁱ—Al20—Al26A	156.21 (10)
Al26A^x—Si6—Al26A^xi	64.09 (6)	Si13—Al20—Al26A	73.05 (3)
Al26A^x—Si6—Al21^x	62.48 (5)	Al12Bⁱⁱ—Al20—Al26A	99.7 (4)
Al26A^xi—Si6—Al21^x	116.49 (5)	Al20ⁱⁱ—Al20—Al26Aⁱ	127.49 (5)
Al26A^x—Si6—Al21^xi	116.49 (5)	Si26Bⁱ—Al20—Al26Aⁱ	2.89 (9)
Al26A^xi—Si6—Al21^xi	62.48 (5)	Si26B—Al20—Al26Aⁱ	98.58 (10)
Al21^x—Si6—Al21^xi	117.71 (4)	Al12B—Al20—Al26Aⁱ	82.2 (4)
Al26A^x—Si6—Al14^xii	116.06 (7)	Si13ⁱ—Al20—Al26Aⁱ	73.05 (3)
Al26A^xi—Si6—Al14^xii	116.06 (7)	Si13—Al20—Al26Aⁱ	156.21 (10)
Al21^x—Si6—Al14^xii	116.56 (2)	Al12Bⁱⁱ—Al20—Al26Aⁱ	99.7 (4)
Al21^xi—Si6—Al14^xii	116.56 (2)	Al26A—Al20—Al26Aⁱ	100.00 (10)
Al26A^x—Si6—Al23^xi	176.81 (7)	Al20ⁱⁱ—Al20—Ru2	71.28 (5)
Al26A^xi—Si6—Al23^xi	117.20 (3)	Si26Bⁱ—Al20—Ru2	139.65 (11)
Al21^x—Si6—Al23^xi	118.09 (3)	Si26B—Al20—Ru2	60.02 (8)
Al21^xi—Si6—Al23^xi	66.27 (2)	Al12B—Al20—Ru2	62.1 (2)
Al14^xii—Si6—Al23^xi	60.78 (3)	Si13ⁱ—Al20—Ru2	141.15 (9)
Al26A^x—Si6—Al23^x	117.20 (3)	Si13—Al20—Ru2	56.80 (3)
Al26A^xi—Si6—Al23^x	176.81 (7)	Al12Bⁱⁱ—Al20—Ru2	57.39 (4)
Al21^x—Si6—Al23^x	66.27 (2)	Al26A—Al20—Ru2	57.36 (4)
Al21^xi—Si6—Al23^x	118.09 (3)	Al26Aⁱ—Al20—Ru2	138.65 (8)
Al14^xii—Si6—Al23^x	60.78 (3)	Al20ⁱⁱ—Al20—Ru2ⁱ	71.28 (5)
Al23^xi—Si6—Al23^x	61.35 (3)	Si26Bⁱ—Al20—Ru2ⁱ	60.03 (8)
Al26A^x—Si6—Al15^xiii	65.13 (7)	Si26B—Al20—Ru2ⁱ	139.65 (11)
Al26A^xi—Si6—Al15^xiii	65.13 (7)	Al12B—Al20—Ru2ⁱ	62.1 (2)
Al21^x—Si6—Al15^xiii	116.38 (2)	Si13ⁱ—Al20—Ru2ⁱ	56.80 (3)
Al21^xi—Si6—Al15^xiii	116.38 (2)	Si13—Al20—Ru2ⁱ	141.15 (9)
Al14^xii—Si6—Al15^xiii	60.96 (3)	Al12Bⁱⁱ—Al20—Ru2ⁱ	57.39 (4)
Al23^xi—Si6—Al15^xiii	112.46 (3)	Al26A—Al20—Ru2ⁱ	138.65 (8)
Al23^x—Si6—Al15^xiii	112.46 (3)	Al26Aⁱ—Al20—Ru2ⁱ	57.36 (4)
Al26A^x—Si6—Al22^xi	115.60 (5)	Ru2—Al20—Ru2ⁱ	114.71 (7)
Al26A^xi—Si6—Al22^xi	62.20 (5)	Al20ⁱⁱ—Al20—Al12A	71.86 (5)
Al21^x—Si6—Al22^xi	178.04 (4)	Si26Bⁱ—Al20—Al12A	92.10 (9)
Al21^xi—Si6—Al22^xi	63.25 (2)	Si26B—Al20—Al12A	92.10 (9)
Al14^xii—Si6—Al22^xi	63.63 (2)	Al12B—Al20—Al12A	11.6 (7)
Al23^xi—Si6—Al22^xi	63.80 (2)	Si13ⁱ—Al20—Al12A	112.68 (6)
Al23^x—Si6—Al22^xi	114.99 (3)	Si13—Al20—Al12A	112.68 (6)
Al15^xiii—Si6—Al22^xi	61.86 (2)	Al12Bⁱⁱ—Al20—Al12A	15.8 (6)
Al26A^x—Si6—Al22^x	62.20 (5)	Al26A—Al20—Al12A	89.59 (6)
Al26A^xi—Si6—Al22^x	115.60 (5)	Al26Aⁱ—Al20—Al12A	89.59 (6)
Al21^x—Si6—Al22^x	63.25 (2)	Ru2—Al20—Al12A	59.21 (4)
Al21^xi—Si6—Al22^x	178.04 (4)	Ru2ⁱ—Al20—Al12A	59.21 (4)
Al14^xii—Si6—Al22^x	63.63 (2)	Al12B—Al21—Ru7A	68.3 (4)
Al23^xi—Si6—Al22^x	114.99 (3)	Al12B—Al21—Ru2	61.1 (4)
Al23^x—Si6—Al22^x	63.80 (2)	Ru7A—Al21—Ru2	129.12 (10)
Al15^xiii—Si6—Al22^x	61.86 (2)	Al12B—Al21—Ru5	116.5 (6)
Al22^xi—Si6—Al22^x	115.73 (4)	Ru7A—Al21—Ru5	129.33 (4)
Al26A^x—Si6—Al16	115.32 (7)	Ru2—Al21—Ru5	73.60 (2)
Al26A^xi—Si6—Al16	115.32 (7)	Al12B—Al21—Ru7B	72.2 (6)
Al21^x—Si6—Al16	63.79 (2)	Ru7A—Al21—Ru7B	4.0 (4)
Al21^xi—Si6—Al16	63.79 (2)	Ru2—Al21—Ru7B	133.1 (4)
Al14^xii—Si6—Al16	118.49 (4)	Ru5—Al21—Ru7B	128.9 (2)
Al23^xi—Si6—Al16	67.08 (3)	Al12B—Al21—Si6^xv	128.1 (7)
Al23^x—Si6—Al16	67.08 (3)	Ru7A—Al21—Si6^xv	107.13 (8)
Al15^xiii—Si6—Al16	179.45 (4)	Ru2—Al21—Si6^xv	107.38 (3)
Al22^xi—Si6—Al16	117.98 (2)	Ru5—Al21—Si6^xv	105.51 (3)
Al22^x—Si6—Al16	117.98 (2)	Ru7B—Al21—Si6^xv	104.1 (4)
Al21—Ru7A—Al21ⁱ	109.01 (17)	Al12B—Al21—Al12A	16.4 (7)
Al21—Ru7A—Si10	91.59 (11)	Ru7A—Al21—Al12A	67.88 (10)
Al21ⁱ—Ru7A—Si10	91.59 (11)	Ru2—Al21—Al12A	62.23 (4)
Al21—Ru7A—Al16^xiv	150.26 (7)	Ru5—Al21—Al12A	103.42 (3)
Al21ⁱ—Ru7A—Al16^xiv	72.21 (3)	Ru7B—Al21—Al12A	71.9 (4)
Si10—Ru7A—Al16^xiv	118.15 (7)	Si6^xv—Al21—Al12A	144.53 (5)
Al21—Ru7A—Al16^xv	72.21 (3)	Al12B—Al21—Al26A	76.4 (6)
Al21ⁱ—Ru7A—Al16^xv	150.26 (7)	Ru7A—Al21—Al26A	115.15 (8)
Si10—Ru7A—Al16^xv	118.15 (7)	Ru2—Al21—Al26A	57.91 (6)
Al16^xiv—Ru7A—Al16^xv	92.25 (16)	Ru5—Al21—Al26A	114.75 (5)
Al21—Ru7A—Al11^xv	75.04 (6)	Ru7B—Al21—Al26A	116.1 (2)
Al21ⁱ—Ru7A—Al11^xv	75.04 (6)	Si6^xv—Al21—Al26A	58.64 (11)
Si10—Ru7A—Al11^xv	156.3 (2)	Al12A—Al21—Al26A	90.67 (13)
Al16^xiv—Ru7A—Al11^xv	76.80 (6)	Al12B—Al21—Al24^xvii	119.0 (6)
Al16^xv—Ru7A—Al11^xv	76.80 (6)	Ru7A—Al21—Al24^xvii	68.48 (6)
Al21—Ru7A—Al19^xvi	122.02 (4)	Ru2—Al21—Al24^xvii	134.06 (3)
Al21ⁱ—Ru7A—Al19^xvi	122.02 (4)	Ru5—Al21—Al24^xvii	66.51 (2)
Si10—Ru7A—Al19^xvi	63.21 (5)	Ru7B—Al21—Al24^xvii	66.3 (3)
Al16^xiv—Ru7A—Al19^xvi	76.07 (12)	Si6^xv—Al21—Al24^xvii	104.48 (3)
Al16^xv—Ru7A—Al19^xvi	76.07 (12)	Al12A—Al21—Al24^xvii	105.60 (6)
Al11^xv—Ru7A—Al19^xvi	140.45 (19)	Al26A—Al21—Al24^xvii	163.10 (12)
Al21—Ru7A—Al12B	55.23 (12)	Al12B—Al21—Si26B	66.3 (6)
Al21ⁱ—Ru7A—Al12B	55.23 (12)	Ru7A—Al21—Si26B	109.80 (10)
Si10—Ru7A—Al12B	81.9 (6)	Ru2—Al21—Si26B	53.66 (7)
Al16^xiv—Ru7A—Al12B	124.7 (3)	Ru5—Al21—Si26B	118.00 (6)
Al16^xv—Ru7A—Al12B	124.7 (3)	Ru7B—Al21—Si26B	111.4 (3)
Al11^xv—Ru7A—Al12B	74.4 (6)	Si6^xv—Al21—Si26B	67.88 (12)
Al19^xvi—Ru7A—Al12B	145.1 (6)	Al12A—Al21—Si26B	80.63 (14)
Al21—Ru7A—Al12A	58.55 (10)	Al26A—Al21—Si26B	10.09 (5)
Al21ⁱ—Ru7A—Al12A	58.55 (10)	Al24^xvii—Al21—Si26B	171.65 (10)
Si10—Ru7A—Al12A	66.73 (11)	Al12B—Al21—Al22	117.9 (4)
Al16^xiv—Ru7A—Al12A	130.76 (9)	Ru7A—Al21—Al22	169.24 (9)
Al16^xv—Ru7A—Al12A	130.76 (9)	Ru2—Al21—Al22	58.56 (2)
Al11^xv—Ru7A—Al12A	89.61 (12)	Ru5—Al21—Al22	57.47 (2)
Al19^xvi—Ru7A—Al12A	129.94 (10)	Ru7B—Al21—Al22	165.9 (4)
Al12B—Ru7A—Al12A	15.2 (6)	Si6^xv—Al21—Al22	62.12 (3)
Al21—Ru7A—Al24^xvii	59.64 (3)	Al12A—Al21—Al22	120.71 (5)
Al21ⁱ—Ru7A—Al24^xvii	149.86 (17)	Al26A—Al21—Al22	60.68 (8)
Si10—Ru7A—Al24^xvii	62.79 (3)	Al24^xvii—Al21—Al22	112.49 (3)
Al16^xiv—Ru7A—Al24^xvii	132.53 (18)	Si26B—Al21—Al22	67.59 (10)
Al16^xv—Ru7A—Al24^xvii	57.51 (4)	Ru9^ix—Al22—Ru5	133.43 (3)
Al11^xv—Ru7A—Al24^xvii	122.30 (3)	Ru9^ix—Al22—Ru9	76.273 (19)
Al19^xvi—Ru7A—Al24^xvii	62.41 (5)	Ru5—Al22—Ru9	140.36 (3)
Al12B—Ru7A—Al24^xvii	102.7 (3)	Ru9^ix—Al22—Ru2	143.89 (3)
Al12A—Ru7A—Al24^xvii	94.82 (10)	Ru5—Al22—Ru2	70.857 (19)
Al16^xiv—Ru7B—Al16^xv	99.1 (8)	Ru9—Al22—Ru2	71.503 (19)
Al16^xiv—Ru7B—Al19^xvi	81.4 (6)	Ru9^ix—Al22—Al28Aⁱ	75.76 (5)
Al16^xv—Ru7B—Al19^xvi	81.4 (6)	Ru5—Al22—Al28Aⁱ	57.77 (5)
Al16^xiv—Ru7B—Si10	120.2 (3)	Ru9—Al22—Al28Aⁱ	136.00 (5)
Al16^xv—Ru7B—Si10	120.2 (3)	Ru2—Al22—Al28Aⁱ	118.07 (6)
Al19^xvi—Ru7B—Si10	64.2 (3)	Ru9^ix—Al22—Al26A	116.62 (6)
Al16^xiv—Ru7B—Al21	150.9 (5)	Ru5—Al22—Al26A	109.46 (5)
Al16^xv—Ru7B—Al21	72.18 (11)	Ru9—Al22—Al26A	55.78 (4)
Al19^xvi—Ru7B—Al21	123.0 (2)	Ru2—Al22—Al26A	55.35 (9)
Si10—Ru7B—Al21	87.1 (5)	Al28Aⁱ—Al22—Al26A	166.65 (6)
Al16^xiv—Ru7B—Al21ⁱ	72.18 (11)	Ru9^ix—Al22—Si6^xv	102.48 (3)
Al16^xv—Ru7B—Al21ⁱ	150.9 (5)	Ru5—Al22—Si6^xv	98.12 (3)
Al19^xvi—Ru7B—Al21ⁱ	123.0 (2)	Ru9—Al22—Si6^xv	99.13 (3)
Si10—Ru7B—Al21ⁱ	87.1 (5)	Ru2—Al22—Si6^xv	98.35 (3)
Al21—Ru7B—Al21ⁱ	101.7 (8)	Al28Aⁱ—Al22—Si6^xv	119.65 (6)
Al16^xiv—Ru7B—Al11^xv	78.6 (3)	Al26A—Al22—Si6^xv	54.96 (8)
Al16^xv—Ru7B—Al11^xv	78.6 (3)	Ru9^ix—Al22—Al21	156.62 (3)
Al19^xvi—Ru7B—Al11^xv	148.8 (10)	Ru5—Al22—Al21	55.59 (2)
Si10—Ru7B—Al11^xv	147.0 (10)	Ru9—Al22—Al21	109.46 (3)
Al21—Ru7B—Al11^xv	72.6 (4)	Ru2—Al22—Al21	54.75 (2)
Al21ⁱ—Ru7B—Al11^xv	72.6 (4)	Al28Aⁱ—Al22—Al21	109.73 (5)
Al16^xiv—Ru7B—Al24^xvii	140.6 (9)	Al26A—Al22—Al21	56.94 (4)
Al16^xv—Ru7B—Al24^xvii	58.93 (16)	Si6^xv—Al22—Al21	54.63 (2)
Al19^xvi—Ru7B—Al24^xvii	64.3 (3)	Ru9^ix—Al22—Al15ⁱ	56.09 (2)
Si10—Ru7B—Al24^xvii	62.3 (2)	Ru5—Al22—Al15ⁱ	112.97 (3)
Al21—Ru7B—Al24^xvii	58.76 (13)	Ru9—Al22—Al15ⁱ	56.57 (2)
Al21ⁱ—Ru7B—Al24^xvii	142.6 (8)	Ru2—Al22—Al15ⁱ	91.92 (3)
Al11^xv—Ru7B—Al24^xvii	122.0 (2)	Al28Aⁱ—Al22—Al15ⁱ	79.64 (5)
Al16^xiv—Ru7B—Al24^xvi	58.93 (16)	Al26A—Al22—Al15ⁱ	110.98 (5)
Al16^xv—Ru7B—Al24^xvi	140.6 (9)	Si6^xv—Al22—Al15ⁱ	148.91 (3)
Al19^xvi—Ru7B—Al24^xvi	64.3 (3)	Al21—Al22—Al15ⁱ	146.28 (3)
Si10—Ru7B—Al24^xvi	62.3 (2)	Ru9^ix—Al22—Al22ⁱⁱⁱ	109.401 (18)
Al21—Ru7B—Al24^xvi	142.6 (8)	Ru5—Al22—Al22ⁱⁱⁱ	56.521 (16)
Al21ⁱ—Ru7B—Al24^xvi	58.76 (13)	Ru9—Al22—Al22ⁱⁱⁱ	92.250 (17)
Al11^xv—Ru7B—Al24^xvi	122.0 (2)	Ru2—Al22—Al22ⁱⁱⁱ	57.038 (17)
Al24^xvii—Ru7B—Al24^xvi	115.8 (4)	Al28Aⁱ—Al22—Al22ⁱⁱⁱ	66.38 (5)
Al16^xiv—Ru7B—Ru7B^xviii	51.5 (3)	Al26A—Al22—Al22ⁱⁱⁱ	111.14 (9)
Al16^xv—Ru7B—Ru7B^xviii	51.5 (3)	Si6^xv—Al22—Al22ⁱⁱⁱ	147.868 (19)
Al19^xvi—Ru7B—Ru7B^xviii	93.1 (4)	Al21—Al22—Al22ⁱⁱⁱ	93.25 (2)
Si10—Ru7B—Ru7B^xviii	157.3 (5)	Al15ⁱ—Al22—Al22ⁱⁱⁱ	59.955 (17)
Al21—Ru7B—Ru7B^xviii	106.9 (3)	Ru9^ix—Al22—Al14^ix	55.43 (2)
Al21ⁱ—Ru7B—Ru7B^xviii	106.9 (3)	Ru5—Al22—Al14^ix	108.75 (3)
Al11^xv—Ru7B—Ru7B^xviii	55.8 (5)	Ru9—Al22—Al14^ix	110.44 (3)
Al24^xvii—Ru7B—Ru7B^xviii	109.2 (4)	Ru2—Al22—Al14^ix	153.68 (4)
Al24^xvi—Ru7B—Ru7B^xviii	109.2 (4)	Al28Aⁱ—Al22—Al14^ix	79.63 (6)
Ru8^xviii—Ru8—Si26Bⁱ	130.06 (17)	Al26A—Al22—Al14^ix	102.89 (9)
Ru8^xviii—Ru8—Si26B	130.06 (17)	Si6^xv—Al22—Al14^ix	55.36 (3)
Si26Bⁱ—Ru8—Si26B	93.3 (3)	Al21—Al22—Al14^ix	102.32 (3)
Ru8^xviii—Ru8—Si18	117.55 (5)	Al15ⁱ—Al22—Al14^ix	111.30 (3)
Si26Bⁱ—Ru8—Si18	85.04 (12)	Al22ⁱⁱⁱ—Al22—Al14^ix	145.76 (2)
Si26B—Ru8—Si18	85.03 (12)	Ru4^ix—Al23—Ru5	139.89 (3)
Ru8^xviii—Ru8—Al26A	119.05 (12)	Ru4^ix—Al23—Ru4^xv	77.88 (2)
Si26Bⁱ—Ru8—Al26A	102.7 (2)	Ru5—Al23—Ru4^xv	129.65 (3)
Si26B—Ru8—Al26A	11.05 (8)	Ru4^ix—Al23—Al24^xvii	137.82 (3)
Si18—Ru8—Al26A	91.76 (9)	Ru5—Al23—Al24^xvii	66.20 (2)
Ru8^xviii—Ru8—Al26Aⁱ	119.05 (12)	Ru4^xv—Al23—Al24^xvii	64.62 (2)
Si26Bⁱ—Ru8—Al26Aⁱ	11.05 (8)	Ru4^ix—Al23—Al14^ix	57.47 (2)
Si26B—Ru8—Al26Aⁱ	102.7 (2)	Ru5—Al23—Al14^ix	114.11 (3)
Si18—Ru8—Al26Aⁱ	91.76 (9)	Ru4^xv—Al23—Al14^ix	115.33 (3)
Al26A—Ru8—Al26Aⁱ	111.25 (18)	Al24^xvii—Al23—Al14^ix	157.49 (4)
Ru8^xviii—Ru8—Si26B^xviii	43.07 (15)	Ru4^ix—Al23—Si6^xv	103.97 (3)
Si26Bⁱ—Ru8—Si26B^xviii	87.0 (3)	Ru5—Al23—Si6^xv	99.99 (2)
Si26B—Ru8—Si26B^xviii	153.06 (14)	Ru4^xv—Al23—Si6^xv	98.39 (3)
Si18—Ru8—Si26B^xviii	121.78 (6)	Al24^xvii—Al23—Si6^xv	100.07 (3)
Al26A—Ru8—Si26B^xviii	146.00 (8)	Al14^ix—Al23—Si6^xv	57.43 (3)
Al26Aⁱ—Ru8—Si26B^xviii	76.0 (3)	Ru4^ix—Al23—Al27	102.08 (2)
Ru8^xviii—Ru8—Si26B^xix	43.07 (15)	Ru5—Al23—Al27	51.056 (15)
Si26Bⁱ—Ru8—Si26B^xix	153.05 (14)	Ru4^xv—Al23—Al27	99.56 (2)
Si26B—Ru8—Si26B^xix	87.0 (3)	Al24^xvii—Al23—Al27	67.82 (2)
Si18—Ru8—Si26B^xix	121.78 (6)	Al14^ix—Al23—Al27	131.35 (3)
Al26A—Ru8—Si26B^xix	76.0 (3)	Si6^xv—Al23—Al27	150.89 (3)
Al26Aⁱ—Ru8—Si26B^xix	146.00 (8)	Ru4^ix—Al23—Al23^xix	56.121 (17)
Si26B^xviii—Ru8—Si26B^xix	80.9 (3)	Ru5—Al23—Al23^xix	159.133 (17)
Ru8^xviii—Ru8—Al11^xv	85.69 (4)	Ru4^xv—Al23—Al23^xix	57.583 (16)
Si26Bⁱ—Ru8—Al11^xv	79.09 (8)	Al24^xvii—Al23—Al23^xix	112.01 (2)
Si26B—Ru8—Al11^xv	79.10 (8)	Al14^ix—Al23—Al23^xix	58.992 (18)
Si18—Ru8—Al11^xv	156.75 (8)	Si6^xv—Al23—Al23^xix	59.325 (17)
Al26A—Ru8—Al11^xv	75.48 (5)	Al27—Al23—Al23^xix	149.293 (14)
Al26Aⁱ—Ru8—Al11^xv	75.48 (5)	Ru4^ix—Al23—Al23^xxiii	58.09 (2)
Si26B^xviii—Ru8—Al11^xv	74.51 (7)	Ru5—Al23—Al23^xxiii	110.021 (16)
Si26B^xix—Ru8—Al11^xv	74.51 (7)	Ru4^xv—Al23—Al23^xxiii	54.723 (19)
Ru8^xviii—Ru8—Al18^xviii	54.98 (4)	Al24^xvii—Al23—Al23^xxiii	83.77 (3)
Si26Bⁱ—Ru8—Al18^xviii	124.37 (8)	Al14^ix—Al23—Al23^xxiii	115.24 (4)
Si26B—Ru8—Al18^xviii	124.36 (8)	Si6^xv—Al23—Al23^xxiii	148.424 (19)
Si18—Ru8—Al18^xviii	62.58 (5)	Al27—Al23—Al23^xxiii	59.293 (14)
Al26A—Ru8—Al18^xviii	120.97 (5)	Al23^xix—Al23—Al23^xxiii	90.0
Al26Aⁱ—Ru8—Al18^xviii	120.97 (5)	Ru4^ix—Al23—Al28Cⁱ	90.8 (4)
Si26B^xviii—Ru8—Al18^xviii	75.82 (12)	Ru5—Al23—Al28Cⁱ	50.8 (4)
Si26B^xix—Ru8—Al18^xviii	75.82 (12)	Ru4^xv—Al23—Al28Cⁱ	123.1 (7)
Al11^xv—Ru8—Al18^xviii	140.67 (8)	Al24^xvii—Al23—Al28Cⁱ	93.8 (6)
Ru8^xviii—Ru8—Al26A^xviii	53.64 (11)	Al14^ix—Al23—Al28Cⁱ	103.3 (7)
Si26Bⁱ—Ru8—Al26A^xviii	76.4 (3)	Si6^xv—Al23—Al28Cⁱ	138.2 (7)
Si26B—Ru8—Al26A^xviii	150.61 (9)	Al27—Al23—Al28Cⁱ	28.5 (7)
Si18—Ru8—Al26A^xviii	120.64 (4)	Al23^xix—Al23—Al28Cⁱ	146.9 (4)
Al26A—Ru8—Al26A^xviii	147.02 (8)	Al23^xxiii—Al23—Al28Cⁱ	71.9 (6)
Al26Aⁱ—Ru8—Al26A^xviii	65.4 (2)	Ru4^ix—Al23—Al21	158.01 (3)
Si26B^xviii—Ru8—Al26A^xviii	10.60 (7)	Ru5—Al23—Al21	54.62 (2)
Si26B^xix—Ru8—Al26A^xviii	90.2 (2)	Ru4^xv—Al23—Al21	104.25 (3)
Al11^xv—Ru8—Al26A^xviii	71.98 (4)	Al24^xvii—Al23—Al21	57.17 (2)
Al18^xviii—Ru8—Al26A^xviii	82.95 (9)	Al14^ix—Al23—Al21	103.50 (3)
Si13—Ru9—Al22^ix	143.18 (3)	Si6^xv—Al23—Al21	54.05 (2)
Si13—Ru9—Al14	74.93 (3)	Al27—Al23—Al21	99.14 (3)
Al22^ix—Ru9—Al14	69.25 (2)	Al23^xix—Al23—Al21	106.01 (2)
Si13—Ru9—Al26A	76.19 (12)	Al23^xxiii—Al23—Al21	140.86 (4)
Al22^ix—Ru9—Al26A	137.56 (11)	Al28Cⁱ—Al23—Al21	105.4 (4)
Al14—Ru9—Al26A	150.45 (13)	Ru4^ix—Al23—Al22	112.68 (3)
Si13—Ru9—Al15^xx	144.71 (3)	Ru5—Al23—Al22	55.75 (2)
Al22^ix—Ru9—Al15^xx	68.60 (3)	Ru4^xv—Al23—Al22	156.11 (3)
Al14—Ru9—Al15^xx	137.45 (3)	Al24^xvii—Al23—Al22	109.38 (3)
Al26A—Ru9—Al15^xx	69.48 (11)	Al14^ix—Al23—Al22	60.73 (2)
Si13—Ru9—Al15ⁱ	104.138 (19)	Si6^xv—Al23—Al22	58.86 (2)
Al22^ix—Ru9—Al15ⁱ	68.15 (2)	Al27—Al23—Al22	98.94 (3)
Al14—Ru9—Al15ⁱ	64.92 (3)	Al23^xix—Al23—Al22	109.21 (2)
Al26A—Ru9—Al15ⁱ	129.36 (6)	Al23^xxiii—Al23—Al22	149.15 (4)
Al15^xx—Ru9—Al15ⁱ	103.749 (11)	Al28Cⁱ—Al23—Al22	79.3 (7)
Si13—Ru9—Al22	105.35 (3)	Al21—Al23—Al22	57.77 (2)
Al22^ix—Ru9—Al22	103.725 (19)	Al28C^xx—Al24—Ru3^xx	71.1 (7)
Al14—Ru9—Al22	129.31 (2)	Al28C^xx—Al24—Al16	144.5 (3)
Al26A—Ru9—Al22	65.23 (9)	Ru3^xx—Al24—Al16	129.42 (4)
Al15^xx—Ru9—Al22	67.48 (2)	Al28C^xx—Al24—Al28B^xx	13.5 (6)
Al15ⁱ—Ru9—Al22	66.15 (3)	Ru3^xx—Al24—Al28B^xx	60.3 (5)
Si13—Ru9—Si17B^xx	102.8 (4)	Al16—Al24—Al28B^xx	144.0 (2)
Al22^ix—Ru9—Si17B^xx	82.4 (5)	Al28C^xx—Al24—Al23^x	80.9 (7)
Al14—Ru9—Si17B^xx	110.4 (4)	Ru3^xx—Al24—Al23^x	151.18 (4)
Al26A—Ru9—Si17B^xx	70.2 (5)	Al16—Al24—Al23^x	72.20 (4)
Al15^xx—Ru9—Si17B^xx	58.2 (2)	Al28B^xx—Al24—Al23^x	90.9 (5)
Al15ⁱ—Ru9—Si17B^xx	150.0 (5)	Al28C^xx—Al24—Al21^x	122.4 (8)
Al22—Ru9—Si17B^xx	118.4 (3)	Ru3^xx—Al24—Al21^x	136.11 (3)
Si13—Ru9—Si26B	66.13 (13)	Al16—Al24—Al21^x	66.43 (3)
Al22^ix—Ru9—Si26B	145.78 (11)	Al28B^xx—Al24—Al21^x	135.6 (5)
Al14—Ru9—Si26B	139.92 (13)	Al23^x—Al24—Al21^x	65.80 (3)
Al26A—Ru9—Si26B	10.56 (5)	Al28C^xx—Al24—Al25	82.2 (8)
Al15^xx—Ru9—Si26B	79.06 (13)	Ru3^xx—Al24—Al25	58.88 (2)
Al15ⁱ—Ru9—Si26B	132.98 (6)	Al16—Al24—Al25	86.60 (4)
Al22—Ru9—Si26B	72.46 (10)	Al28B^xx—Al24—Al25	70.0 (5)
Si17B^xx—Ru9—Si26B	71.0 (6)	Al23^x—Al24—Al25	111.61 (3)
Si13—Ru9—Al17A^xx	94.94 (4)	Al21^x—Al24—Al25	152.63 (4)
Al22^ix—Ru9—Al17A^xx	94.80 (5)	Al28C^xx—Al24—Al24^xix	55.8 (3)
Al14—Ru9—Al17A^xx	118.76 (4)	Ru3^xx—Al24—Al24^xix	56.826 (17)
Al26A—Ru9—Al17A^xx	57.86 (6)	Al16—Al24—Al24^xix	157.27 (3)
Al15^xx—Ru9—Al17A^xx	59.96 (3)	Al28B^xx—Al24—Al24^xix	58.6 (2)
Al15ⁱ—Ru9—Al17A^xx	160.71 (4)	Al23^x—Al24—Al24^xix	112.00 (2)
Al22—Ru9—Al17A^xx	111.76 (4)	Al21^x—Al24—Al24^xix	94.28 (2)
Si17B^xx—Ru9—Al17A^xx	13.0 (5)	Al25—Al24—Al24^xix	110.87 (3)
Si26B—Ru9—Al17A^xx	58.07 (8)	Al28C^xx—Al24—Si10^xxvii	112.9 (4)
Ru7Aⁱⁱ—Si10—Ru7A	125.3 (2)	Ru3^xx—Al24—Si10^xxvii	58.14 (3)
Ru7Aⁱⁱ—Si10—Ru7Bⁱⁱ	4.6 (4)	Al16—Al24—Si10^xxvii	102.42 (3)
Ru7A—Si10—Ru7Bⁱⁱ	129.9 (6)	Al28B^xx—Al24—Si10^xxvii	109.2 (3)
Ru7Aⁱⁱ—Si10—Ru7B	129.9 (6)	Al23^x—Al24—Si10^xxvii	144.16 (4)
Ru7A—Si10—Ru7B	4.6 (4)	Al21^x—Al24—Si10^xxvii	79.43 (4)
Ru7Bⁱⁱ—Si10—Ru7B	134.5 (10)	Al25—Al24—Si10^xxvii	103.20 (4)
Ru7Aⁱⁱ—Si10—Ru3^xxiv	112.02 (9)	Al24^xix—Al24—Si10^xxvii	60.455 (15)
Ru7A—Si10—Ru3^xxiv	112.02 (9)	Al28C^xx—Al24—Ru4	92.4 (3)
Ru7Bⁱⁱ—Si10—Ru3^xxiv	108.4 (4)	Ru3^xx—Al24—Ru4	116.86 (3)
Ru7B—Si10—Ru3^xxiv	108.4 (4)	Al16—Al24—Ru4	53.47 (3)
Ru7Aⁱⁱ—Si10—Ru3^vi	112.02 (9)	Al28B^xx—Al24—Ru4	90.57 (19)
Ru7A—Si10—Ru3^vi	112.02 (9)	Al23^x—Al24—Ru4	56.57 (2)
Ru7Bⁱⁱ—Si10—Ru3^vi	108.4 (4)	Al21^x—Al24—Ru4	104.72 (3)
Ru7B—Si10—Ru3^vi	108.4 (4)	Al25—Al24—Ru4	58.66 (2)
Ru3^xxiv—Si10—Ru3^vi	70.63 (3)	Al24^xix—Al24—Ru4	148.210 (16)
Ru7Aⁱⁱ—Si10—Al19^xxi	60.62 (11)	Si10^xxvii—Al24—Ru4	147.42 (3)
Ru7A—Si10—Al19^xxi	174.09 (12)	Al28C^xx—Al24—Al19	128.9 (8)
Ru7Bⁱⁱ—Si10—Al19^xxi	56.0 (5)	Ru3^xx—Al24—Al19	61.31 (3)
Ru7B—Si10—Al19^xxi	169.5 (5)	Al16—Al24—Al19	69.38 (4)
Ru3^xxiv—Si10—Al19^xxi	63.41 (3)	Al28B^xx—Al24—Al19	115.7 (5)
Ru3^vi—Si10—Al19^xxi	63.41 (3)	Al23^x—Al24—Al19	140.66 (4)
Ru7Aⁱⁱ—Si10—Al19^xvi	174.09 (12)	Al21^x—Al24—Al19	105.11 (3)
Ru7A—Si10—Al19^xvi	60.62 (11)	Al25—Al24—Al19	58.34 (3)
Ru7Bⁱⁱ—Si10—Al19^xvi	169.5 (5)	Al24^xix—Al24—Al19	106.70 (3)
Ru7B—Si10—Al19^xvi	56.0 (5)	Si10^xxvii—Al24—Al19	55.54 (3)
Ru3^xxiv—Si10—Al19^xvi	63.41 (3)	Ru4—Al24—Al19	92.85 (3)
Ru3^vi—Si10—Al19^xvi	63.41 (3)	Al28C^xx—Al24—Ru5^xxvii	68.3 (8)
Al19^xxi—Si10—Al19^xvi	113.47 (6)	Ru3^xx—Al24—Ru5^xxvii	117.27 (3)
Ru7Aⁱⁱ—Si10—Al24^xxi	66.31 (4)	Al16—Al24—Ru5^xxvii	111.16 (4)
Ru7A—Si10—Al24^xxi	118.30 (3)	Al28B^xx—Al24—Ru5^xxvii	81.4 (5)
Ru7Bⁱⁱ—Si10—Al24^xxi	64.89 (15)	Al23^x—Al24—Ru5^xxvii	54.85 (2)
Ru7B—Si10—Al24^xxi	119.03 (7)	Al21^x—Al24—Ru5^xxvii	54.16 (2)
Ru3^xxiv—Si10—Al24^xxi	55.588 (19)	Al25—Al24—Ru5^xxvii	148.62 (4)
Ru3^vi—Si10—Al24^xxi	115.89 (4)	Al24^xix—Al24—Ru5^xxvii	61.040 (15)
Al19^xxi—Si10—Al24^xxi	62.902 (19)	Si10^xxvii—Al24—Ru5^xxvii	98.06 (3)
Al19^xvi—Si10—Al24^xxi	111.66 (3)	Ru4—Al24—Ru5^xxvii	110.63 (2)
Ru7Aⁱⁱ—Si10—Al24^xvi	118.31 (3)	Al19—Al24—Ru5^xxvii	151.32 (3)
Ru7A—Si10—Al24^xvi	66.31 (4)	Si13—Al25—Al28A^xx	124.19 (6)
Ru7Bⁱⁱ—Si10—Al24^xvi	119.03 (7)	Si13—Al25—Ru3^xx	131.16 (3)
Ru7B—Si10—Al24^xvi	64.90 (15)	Al28A^xx—Al25—Ru3^xx	60.04 (5)
Ru3^xxiv—Si10—Al24^xvi	115.89 (4)	Si13—Al25—Al14	69.92 (3)
Ru3^vi—Si10—Al24^xvi	55.588 (19)	Al28A^xx—Al25—Al14	84.62 (5)
Al19^xxi—Si10—Al24^xvi	111.66 (3)	Ru3^xx—Al25—Al14	144.54 (4)
Al19^xvi—Si10—Al24^xvi	62.902 (18)	Si13—Al25—Al19	107.28 (4)
Al24^xxi—Si10—Al24^xvi	170.96 (6)	Al28A^xx—Al25—Al19	119.27 (6)
Ru7Aⁱⁱ—Si10—Al24^xvii	118.31 (3)	Ru3^xx—Al25—Al19	62.41 (3)
Ru7A—Si10—Al24^xvii	66.31 (4)	Al14—Al25—Al19	147.27 (5)
Ru7Bⁱⁱ—Si10—Al24^xvii	119.03 (7)	Si13—Al25—Ru4	110.10 (3)
Ru7B—Si10—Al24^xvii	64.90 (15)	Al28A^xx—Al25—Ru4	92.85 (5)
Ru3^xxiv—Si10—Al24^xvii	55.588 (19)	Ru3^xx—Al25—Ru4	118.47 (3)
Ru3^vi—Si10—Al24^xvii	115.89 (4)	Al14—Al25—Ru4	56.01 (2)
Al19^xxi—Si10—Al24^xvii	111.66 (3)	Al19—Al25—Ru4	98.03 (3)
Al19^xvi—Si10—Al24^xvii	62.902 (19)	Si13—Al25—Al24	164.76 (5)
Al24^xxi—Si10—Al24^xvii	59.09 (3)	Al28A^xx—Al25—Al24	70.66 (5)
Al24^xvi—Si10—Al24^xvii	120.09 (3)	Ru3^xx—Al25—Al24	56.71 (2)
Ru7Aⁱⁱ—Si10—Al24^xxii	66.31 (4)	Al14—Al25—Al24	111.40 (4)
Ru7A—Si10—Al24^xxii	118.30 (3)	Al19—Al25—Al24	62.90 (3)
Ru7Bⁱⁱ—Si10—Al24^xxii	64.89 (15)	Ru4—Al25—Al24	62.46 (2)
Ru7B—Si10—Al24^xxii	119.03 (7)	Si13—Al25—Si17B^xx	94.5 (4)
Ru3^xxiv—Si10—Al24^xxii	115.89 (4)	Al28A^xx—Al25—Si17B^xx	42.9 (5)
Ru3^vi—Si10—Al24^xxii	55.588 (19)	Ru3^xx—Al25—Si17B^xx	54.1 (2)
Al19^xxi—Si10—Al24^xxii	62.902 (19)	Al14—Al25—Si17B^xx	102.6 (3)
Al19^xvi—Si10—Al24^xxii	111.66 (3)	Al19—Al25—Si17B^xx	110.1 (3)
Al24^xxi—Si10—Al24^xxii	120.09 (3)	Ru4—Al25—Si17B^xx	135.0 (5)
Al24^xvi—Si10—Al24^xxii	59.09 (3)	Al24—Al25—Si17B^xx	99.8 (3)
Al24^xvii—Si10—Al24^xxii	170.96 (6)	Si13—Al25—Ru9	52.79 (2)
Ru8^xxv—Al11—Ru8^xi	8.64 (8)	Al28A^xx—Al25—Ru9	71.76 (5)
Ru8^xxv—Al11—Ru7A^xi	145.33 (12)	Ru3^xx—Al25—Ru9	110.61 (3)
Ru8^xi—Al11—Ru7A^xi	136.69 (12)	Al14—Al25—Ru9	55.04 (2)
Ru8^xxv—Al11—Ru7A^xxv	136.69 (12)	Al19—Al25—Ru9	149.49 (4)
Ru8^xi—Al11—Ru7A^xxv	145.33 (12)	Ru4—Al25—Ru9	110.23 (3)
Ru7A^xi—Al11—Ru7A^xxv	78.0 (2)	Al24—Al25—Ru9	141.11 (4)
Ru8^xxv—Al11—Ru7B^xi	150.1 (5)	Si17B^xx—Al25—Ru9	56.5 (2)
Ru8^xi—Al11—Ru7B^xi	141.4 (5)	Si13—Al25—Si18	76.05 (3)
Ru7A^xi—Al11—Ru7B^xi	4.7 (4)	Al28A^xx—Al25—Si18	105.43 (6)
Ru7A^xxv—Al11—Ru7B^xi	73.2 (6)	Ru3^xx—Al25—Si18	58.55 (3)
Ru8^xxv—Al11—Ru7B^xxv	141.4 (5)	Al14—Al25—Si18	143.89 (4)
Ru8^xi—Al11—Ru7B^xxv	150.1 (5)	Al19—Al25—Si18	55.73 (3)
Ru7A^xi—Al11—Ru7B^xxv	73.2 (6)	Ru4—Al25—Si18	152.96 (4)
Ru7A^xxv—Al11—Ru7B^xxv	4.7 (4)	Al24—Al25—Si18	104.62 (4)
Ru7B^xi—Al11—Ru7B^xxv	68.5 (10)	Si17B^xx—Al25—Si18	68.0 (5)
Al12Bⁱⁱ—Al12A—Al12B	108 (3)	Ru9—Al25—Si18	94.56 (3)
Al12Bⁱⁱ—Al12A—Al21ⁱⁱⁱ	67.5 (8)	Si26B—Al26A—Ru8	56.5 (4)
Al12B—Al12A—Al21ⁱⁱⁱ	127.4 (4)	Si26B—Al26A—Ru2	73.2 (4)
Al12Bⁱⁱ—Al12A—Al21ⁱ	127.4 (4)	Ru8—Al26A—Ru2	127.6 (2)
Al12B—Al12A—Al21ⁱ	67.5 (8)	Si26B—Al26A—Ru9	101.8 (4)
Al21ⁱⁱⁱ—Al12A—Al21ⁱ	157.96 (11)	Ru8—Al26A—Ru9	125.89 (10)
Al12Bⁱⁱ—Al12A—Al21ⁱⁱ	67.5 (8)	Ru2—Al26A—Ru9	74.86 (4)
Al12B—Al12A—Al21ⁱⁱ	127.4 (4)	Si26B—Al26A—Si6^xv	149.4 (4)
Al21ⁱⁱⁱ—Al12A—Al21ⁱⁱ	100.34 (4)	Ru8—Al26A—Si6^xv	108.54 (8)
Al21ⁱ—Al12A—Al21ⁱⁱ	75.37 (3)	Ru2—Al26A—Si6^xv	107.54 (11)
Al12Bⁱⁱ—Al12A—Al21	127.4 (4)	Ru9—Al26A—Si6^xv	107.90 (18)
Al12B—Al12A—Al21	67.5 (8)	Si26B—Al26A—Al17A^xx	92.8 (4)
Al21ⁱⁱⁱ—Al12A—Al21	75.37 (3)	Ru8—Al26A—Al17A^xx	66.69 (7)
Al21ⁱ—Al12A—Al21	100.34 (4)	Ru2—Al26A—Al17A^xx	134.59 (9)
Al21ⁱⁱ—Al12A—Al21	157.96 (11)	Ru9—Al26A—Al17A^xx	65.89 (6)
Al12Bⁱⁱ—Al12A—Ru2ⁱ	71.4 (7)	Si6^xv—Al26A—Al17A^xx	105.56 (15)
Al12B—Al12A—Ru2ⁱ	71.4 (7)	Si26B—Al26A—Al20	12.3 (4)
Al21ⁱⁱⁱ—Al12A—Ru2ⁱ	138.44 (5)	Ru8—Al26A—Al20	66.65 (14)
Al21ⁱ—Al12A—Ru2ⁱ	57.296 (18)	Ru2—Al26A—Al20	61.85 (11)
Al21ⁱⁱ—Al12A—Ru2ⁱ	57.296 (18)	Ru9—Al26A—Al20	101.79 (13)
Al21—Al12A—Ru2ⁱ	138.44 (5)	Si6^xv—Al26A—Al20	144.43 (8)
Al12Bⁱⁱ—Al12A—Ru2	71.4 (7)	Al17A^xx—Al26A—Al20	104.15 (16)
Al12B—Al12A—Ru2	71.4 (7)	Si26B—Al26A—Ru8^xviii	63.8 (4)
Al21ⁱⁱⁱ—Al12A—Ru2	57.297 (18)	Ru8—Al26A—Ru8^xviii	7.31 (7)
Al21ⁱ—Al12A—Ru2	138.44 (5)	Ru2—Al26A—Ru8^xviii	134.7 (2)
Al21ⁱⁱ—Al12A—Ru2	138.44 (5)	Ru9—Al26A—Ru8^xviii	126.28 (8)
Al21—Al12A—Ru2	57.298 (18)	Si6^xv—Al26A—Ru8^xviii	102.45 (8)
Ru2ⁱ—Al12A—Ru2	114.07 (9)	Al17A^xx—Al26A—Ru8^xviii	63.79 (7)
Al12Bⁱⁱ—Al12A—Al20	72.2 (15)	Al20—Al26A—Ru8^xviii	73.95 (14)
Al12B—Al12A—Al20	35.9 (15)	Si26B—Al26A—Al21	100.9 (4)
Al21ⁱⁱⁱ—Al12A—Al20	111.84 (7)	Ru8—Al26A—Al21	115.23 (8)
Al21ⁱ—Al12A—Al20	89.50 (5)	Ru2—Al26A—Al21	57.85 (3)
Al21ⁱⁱ—Al12A—Al20	111.84 (7)	Ru9—Al26A—Al21	117.54 (9)
Al21—Al12A—Al20	89.50 (5)	Si6^xv—Al26A—Al21	58.88 (8)
Ru2ⁱ—Al12A—Al20	58.86 (4)	Al17A^xx—Al26A—Al21	164.4 (2)
Ru2—Al12A—Al20	58.86 (4)	Al20—Al26A—Al21	90.24 (11)
Al12Bⁱⁱ—Al12A—Al20ⁱⁱ	35.9 (15)	Ru8^xviii—Al26A—Al21	116.01 (7)
Al12B—Al12A—Al20ⁱⁱ	72.2 (15)	Si26B—Al26A—Al26A^xix	117.3 (4)
Al21ⁱⁱⁱ—Al12A—Al20ⁱⁱ	89.50 (5)	Ru8—Al26A—Al26A^xix	60.96 (12)
Al21ⁱ—Al12A—Al20ⁱⁱ	111.84 (7)	Ru2—Al26A—Al26A^xix	165.22 (9)
Al21ⁱⁱ—Al12A—Al20ⁱⁱ	89.50 (5)	Ru9—Al26A—Al26A^xix	110.82 (8)
Al21—Al12A—Al20ⁱⁱ	111.84 (7)	Si6^xv—Al26A—Al26A^xix	57.95 (3)
Ru2ⁱ—Al12A—Al20ⁱⁱ	58.86 (4)	Al17A^xx—Al26A—Al26A^xix	58.02 (7)
Ru2—Al12A—Al20ⁱⁱ	58.86 (4)	Al20—Al26A—Al26A^xix	127.49 (5)
Al20—Al12A—Al20ⁱⁱ	36.28 (10)	Ru8^xviii—Al26A—Al26A^xix	53.64 (11)
Al12Bⁱⁱ—Al12A—Ru7A	176.6 (15)	Al21—Al26A—Al26A^xix	108.38 (7)
Al12B—Al12A—Ru7A	75.3 (15)	Al26A—Si26B—Al20	164.8 (5)
Al21ⁱⁱⁱ—Al12A—Ru7A	110.57 (6)	Al26A—Si26B—Ru8	112.4 (4)
Al21ⁱ—Al12A—Ru7A	53.57 (3)	Al20—Si26B—Ru8	80.0 (2)
Al21ⁱⁱ—Al12A—Ru7A	110.57 (6)	Al26A—Si26B—Ru2	95.3 (4)
Al21—Al12A—Ru7A	53.57 (3)	Al20—Si26B—Ru2	70.59 (14)
Ru2ⁱ—Al12A—Ru7A	110.196 (14)	Ru8—Si26B—Ru2	148.4 (3)
Ru2—Al12A—Ru7A	110.197 (14)	Al26A—Si26B—Ru8^xviii	105.6 (4)
Al20—Al12A—Ru7A	111.24 (6)	Al20—Si26B—Ru8^xviii	86.8 (2)
Al20ⁱⁱ—Al12A—Ru7A	147.52 (8)	Ru8—Si26B—Ru8^xviii	6.87 (7)
Al12A—Al12B—Al12Bⁱⁱ	36.0 (15)	Ru2—Si26B—Ru8^xviii	154.5 (3)
Al12A—Al12B—Al20	133 (2)	Al26A—Si26B—Al17A^xx	76.3 (4)
Al12Bⁱⁱ—Al12B—Al20	96.6 (7)	Al20—Si26B—Al17A^xx	117.6 (2)
Al12A—Al12B—Al21ⁱ	96.1 (10)	Ru8—Si26B—Al17A^xx	68.57 (8)
Al12Bⁱⁱ—Al12B—Al21ⁱ	114.2 (6)	Ru2—Si26B—Al17A^xx	135.85 (12)
Al20—Al12B—Al21ⁱ	109.6 (8)	Ru8^xviii—Si26B—Al17A^xx	65.16 (8)
Al12A—Al12B—Al21	96.1 (10)	Al26A—Si26B—Ru9	67.6 (4)
Al12Bⁱⁱ—Al12B—Al21	114.2 (6)	Al20—Si26B—Ru9	111.86 (15)
Al20—Al12B—Al21	109.6 (8)	Ru8—Si26B—Ru9	129.86 (10)
Al21ⁱ—Al12B—Al21	111.5 (8)	Ru2—Si26B—Ru9	73.78 (8)
Al12A—Al12B—Ru2ⁱ	92.4 (10)	Ru8^xviii—Si26B—Ru9	127.65 (10)
Al12Bⁱⁱ—Al12B—Ru2ⁱ	76.2 (6)	Al17A^xx—Si26B—Ru9	62.85 (9)
Al20—Al12B—Ru2ⁱ	68.2 (5)	Al26A—Si26B—Si13	117.4 (4)
Al21ⁱ—Al12B—Ru2ⁱ	61.39 (6)	Al20—Si26B—Si13	59.77 (13)
Al21—Al12B—Ru2ⁱ	169.5 (12)	Ru8—Si26B—Si13	117.9 (2)
Al12A—Al12B—Ru2	92.4 (10)	Ru2—Si26B—Si13	55.64 (7)
Al12Bⁱⁱ—Al12B—Ru2	76.2 (6)	Ru8^xviii—Si26B—Si13	122.8 (2)
Al20—Al12B—Ru2	68.2 (5)	Al17A^xx—Si26B—Si13	89.50 (8)
Al21ⁱ—Al12B—Ru2	169.5 (12)	Ru9—Si26B—Si13	52.12 (5)
Al21—Al12B—Ru2	61.39 (6)	Al26A—Si26B—Al21	69.0 (4)
Ru2ⁱ—Al12B—Ru2	124.4 (8)	Al20—Si26B—Al21	97.72 (13)
Al12A—Al12B—Al20ⁱⁱ	92.1 (17)	Ru8—Si26B—Al21	118.41 (9)
Al12Bⁱⁱ—Al12B—Al20ⁱⁱ	56.1 (6)	Ru2—Si26B—Al21	56.84 (6)
Al20—Al12B—Al20ⁱⁱ	40.5 (3)	Ru8^xviii—Si26B—Al21	117.29 (9)
Al21ⁱ—Al12B—Al20ⁱⁱ	123.3 (4)	Al17A^xx—Si26B—Al21	144.5 (3)
Al21—Al12B—Al20ⁱⁱ	123.3 (4)	Ru9—Si26B—Al21	108.29 (15)
Ru2ⁱ—Al12B—Al20ⁱⁱ	62.3 (4)	Si13—Si26B—Al21	112.48 (9)
Ru2—Al12B—Al20ⁱⁱ	62.3 (4)	Al26A—Si26B—Al12B	119.2 (5)
Al12A—Al12B—Ru7A	89.5 (16)	Al20—Si26B—Al12B	48.4 (3)
Al12Bⁱⁱ—Al12B—Ru7A	125.5 (6)	Ru8—Si26B—Al12B	96.0 (4)
Al20—Al12B—Ru7A	138.0 (12)	Ru2—Si26B—Al12B	55.7 (4)
Al21ⁱ—Al12B—Ru7A	56.5 (4)	Ru8^xviii—Si26B—Al12B	100.4 (4)
Al21—Al12B—Ru7A	56.5 (4)	Al17A^xx—Si26B—Al12B	162.3 (4)
Ru2ⁱ—Al12B—Ru7A	117.7 (4)	Ru9—Si26B—Al12B	129.1 (4)
Ru2—Al12B—Ru7A	117.7 (4)	Si13—Si26B—Al12B	90.3 (4)
Al20ⁱⁱ—Al12B—Ru7A	178.5 (12)	Al21—Si26B—Al12B	50.2 (3)
Al12A—Al12B—Si26Bⁱ	144.6 (7)	Al28Cⁱ—Al27—Al28C^xxiv	180 (3)
Al12Bⁱⁱ—Al12B—Si26Bⁱ	123.9 (4)	Al28Cⁱ—Al27—Al28Bⁱ	8.0 (11)
Al20—Al12B—Si26Bⁱ	47.2 (5)	Al28C^xxiv—Al27—Al28Bⁱ	172.0 (11)
Al21ⁱ—Al12B—Si26Bⁱ	63.5 (4)	Al28Cⁱ—Al27—Al28B^xxiv	172.0 (11)
Al21—Al12B—Si26Bⁱ	117.8 (10)	Al28C^xxiv—Al27—Al28B^xxiv	8.0 (11)
Ru2ⁱ—Al12B—Si26Bⁱ	52.9 (3)	Al28Bⁱ—Al27—Al28B^xxiv	180.0 (13)
Ru2—Al12B—Si26Bⁱ	111.9 (9)	Al28Cⁱ—Al27—Ru5^xxviii	106.3 (11)
Al20ⁱⁱ—Al12B—Si26Bⁱ	78.3 (6)	Al28C^xxiv—Al27—Ru5^xxviii	73.7 (11)
Ru7A—Al12B—Si26Bⁱ	100.5 (7)	Al28Bⁱ—Al27—Ru5^xxviii	114.3 (5)
Al12A—Al12B—Si26B	144.6 (7)	Al28B^xxiv—Al27—Ru5^xxviii	65.7 (5)
Al12Bⁱⁱ—Al12B—Si26B	123.9 (4)	Al28Cⁱ—Al27—Ru5	73.7 (11)
Al20—Al12B—Si26B	47.2 (5)	Al28C^xxiv—Al27—Ru5	106.3 (11)
Al21ⁱ—Al12B—Si26B	117.8 (10)	Al28Bⁱ—Al27—Ru5	65.7 (5)
Al21—Al12B—Si26B	63.5 (4)	Al28B^xxiv—Al27—Ru5	114.3 (5)
Ru2ⁱ—Al12B—Si26B	111.9 (9)	Ru5^xxviii—Al27—Ru5	180.0
Ru2—Al12B—Si26B	52.9 (3)	Al28Cⁱ—Al27—Al23^xxviii	101.3 (5)
Al20ⁱⁱ—Al12B—Si26B	78.3 (6)	Al28C^xxiv—Al27—Al23^xxviii	78.7 (5)
Ru7A—Al12B—Si26B	100.5 (7)	Al28Bⁱ—Al27—Al23^xxviii	105.0 (2)
Si26Bⁱ—Al12B—Si26B	67.0 (6)	Al28B^xxiv—Al27—Al23^xxviii	75.0 (2)
Ru9—Si13—Ru9ⁱⁱⁱ	79.25 (3)	Ru5^xxviii—Al27—Al23^xxviii	59.495 (14)
Ru9—Si13—Ru1	133.97 (2)	Ru5—Al27—Al23^xxviii	120.505 (14)
Ru9ⁱⁱⁱ—Si13—Ru1	133.97 (2)	Al28Cⁱ—Al27—Al23ⁱⁱⁱ	78.7 (5)
Ru9—Si13—Ru2	78.47 (2)	Al28C^xxiv—Al27—Al23ⁱⁱⁱ	101.3 (5)
Ru9ⁱⁱⁱ—Si13—Ru2	78.46 (2)	Al28Bⁱ—Al27—Al23ⁱⁱⁱ	75.0 (2)
Ru1—Si13—Ru2	130.71 (4)	Al28B^xxiv—Al27—Al23ⁱⁱⁱ	105.0 (2)
Ru9—Si13—Al20ⁱⁱ	138.45 (5)	Ru5^xxviii—Al27—Al23ⁱⁱⁱ	120.505 (14)
Ru9ⁱⁱⁱ—Si13—Al20ⁱⁱ	108.59 (4)	Ru5—Al27—Al23ⁱⁱⁱ	59.495 (14)
Ru1—Si13—Al20ⁱⁱ	69.62 (4)	Al23^xxviii—Al27—Al23ⁱⁱⁱ	61.41 (3)
Ru2—Si13—Al20ⁱⁱ	64.15 (4)	Al28Cⁱ—Al27—Al23^xxiii	101.3 (5)
Ru9—Si13—Al20	108.59 (4)	Al28C^xxiv—Al27—Al23^xxiii	78.7 (5)
Ru9ⁱⁱⁱ—Si13—Al20	138.44 (5)	Al28Bⁱ—Al27—Al23^xxiii	105.0 (2)
Ru1—Si13—Al20	69.62 (4)	Al28B^xxiv—Al27—Al23^xxiii	75.0 (2)
Ru2—Si13—Al20	64.15 (4)	Ru5^xxviii—Al27—Al23^xxiii	59.495 (14)
Al20ⁱⁱ—Si13—Al20	39.36 (10)	Ru5—Al27—Al23^xxiii	120.505 (14)
Ru9—Si13—Al25	68.38 (3)	Al23^xxviii—Al27—Al23^xxiii	118.59 (3)
Ru9ⁱⁱⁱ—Si13—Al25	109.91 (4)	Al23ⁱⁱⁱ—Al27—Al23^xxiii	180.00 (4)
Ru1—Si13—Al25	69.91 (3)	Al28Cⁱ—Al27—Al23	78.7 (5)
Ru2—Si13—Al25	142.93 (3)	Al28C^xxiv—Al27—Al23	101.3 (5)
Al20ⁱⁱ—Si13—Al25	136.87 (5)	Al28Bⁱ—Al27—Al23	75.0 (2)
Al20—Si13—Al25	110.82 (5)	Al28B^xxiv—Al27—Al23	105.0 (2)
Ru9—Si13—Al25ⁱⁱⁱ	109.91 (4)	Ru5^xxviii—Al27—Al23	120.505 (14)
Ru9ⁱⁱⁱ—Si13—Al25ⁱⁱⁱ	68.38 (3)	Ru5—Al27—Al23	59.495 (14)
Ru1—Si13—Al25ⁱⁱⁱ	69.91 (3)	Al23^xxviii—Al27—Al23	180.0
Ru2—Si13—Al25ⁱⁱⁱ	142.93 (3)	Al23ⁱⁱⁱ—Al27—Al23	118.59 (3)
Al20ⁱⁱ—Si13—Al25ⁱⁱⁱ	110.82 (5)	Al23^xxiii—Al27—Al23	61.41 (3)
Al20—Si13—Al25ⁱⁱⁱ	136.87 (5)	Al28Cⁱ—Al27—Al28Aⁱ	18.1 (10)
Al25—Si13—Al25ⁱⁱⁱ	67.53 (4)	Al28C^xxiv—Al27—Al28Aⁱ	161.9 (10)
Ru9—Si13—Si26B	61.75 (12)	Al28Bⁱ—Al27—Al28Aⁱ	11.3 (4)
Ru9ⁱⁱⁱ—Si13—Si26B	122.39 (11)	Al28B^xxiv—Al27—Al28Aⁱ	168.7 (4)
Ru1—Si13—Si26B	103.17 (11)	Ru5^xxviii—Al27—Al28Aⁱ	122.36 (4)
Ru2—Si13—Si26B	54.62 (6)	Ru5—Al27—Al28Aⁱ	57.64 (4)
Al20ⁱⁱ—Si13—Si26B	81.32 (11)	Al23^xxviii—Al27—Al28Aⁱ	115.61 (5)
Al20—Si13—Si26B	46.86 (13)	Al23ⁱⁱⁱ—Al27—Al28Aⁱ	78.24 (5)
Al25—Si13—Si26B	93.92 (6)	Al23^xxiii—Al27—Al28Aⁱ	101.76 (5)
Al25ⁱⁱⁱ—Si13—Si26B	161.39 (6)	Al23—Al27—Al28Aⁱ	64.39 (5)
Ru9—Si13—Si26Bⁱⁱⁱ	122.39 (11)	Al28Cⁱ—Al27—Al28A^xxiv	161.9 (10)
Ru9ⁱⁱⁱ—Si13—Si26Bⁱⁱⁱ	61.75 (12)	Al28C^xxiv—Al27—Al28A^xxiv	18.1 (10)
Ru1—Si13—Si26Bⁱⁱⁱ	103.17 (11)	Al28Bⁱ—Al27—Al28A^xxiv	168.7 (4)
Ru2—Si13—Si26Bⁱⁱⁱ	54.62 (6)	Al28B^xxiv—Al27—Al28A^xxiv	11.3 (4)
Al20ⁱⁱ—Si13—Si26Bⁱⁱⁱ	46.86 (13)	Ru5^xxviii—Al27—Al28A^xxiv	57.64 (4)
Al20—Si13—Si26Bⁱⁱⁱ	81.32 (11)	Ru5—Al27—Al28A^xxiv	122.36 (4)
Al25—Si13—Si26Bⁱⁱⁱ	161.40 (6)	Al23^xxviii—Al27—Al28A^xxiv	64.39 (5)
Al25ⁱⁱⁱ—Si13—Si26Bⁱⁱⁱ	93.93 (6)	Al23ⁱⁱⁱ—Al27—Al28A^xxiv	101.76 (5)
Si26B—Si13—Si26Bⁱⁱⁱ	104.56 (11)	Al23^xxiii—Al27—Al28A^xxiv	78.24 (5)
Ru9—Al14—Ru9ⁱⁱⁱ	74.75 (2)	Al23—Al27—Al28A^xxiv	115.61 (5)
Ru9—Al14—Ru4	128.03 (3)	Al28Aⁱ—Al27—Al28A^xxiv	180.00 (7)
Ru9ⁱⁱⁱ—Al14—Ru4	128.03 (3)	Al28Aⁱⁱⁱ—Al28A—Al28B	67.3 (6)
Ru9—Al14—Si6^xii	107.23 (3)	Al28Aⁱⁱⁱ—Al28A—Al28C	76.1 (3)
Ru9ⁱⁱⁱ—Al14—Si6^xii	107.23 (3)	Al28B—Al28A—Al28C	9.6 (7)
Ru4—Al14—Si6^xii	107.28 (4)	Al28Aⁱⁱⁱ—Al28A—Si17B	79.04 (15)
Ru9—Al14—Al25	65.59 (2)	Al28B—Al28A—Si17B	133.7 (9)
Ru9ⁱⁱⁱ—Al14—Al25	104.13 (4)	Al28C—Al28A—Si17B	142.3 (8)
Ru4—Al14—Al25	63.62 (3)	Al28Aⁱⁱⁱ—Al28A—Ru5ⁱ	81.43 (6)
Si6^xii—Al14—Al25	144.44 (3)	Al28B—Al28A—Ru5ⁱ	68.4 (9)
Ru9—Al14—Al25ⁱⁱⁱ	104.13 (4)	Al28C—Al28A—Ru5ⁱ	65.1 (8)
Ru9ⁱⁱⁱ—Al14—Al25ⁱⁱⁱ	65.60 (2)	Si17B—Al28A—Ru5ⁱ	137.7 (4)
Ru4—Al14—Al25ⁱⁱⁱ	63.62 (3)	Al28Aⁱⁱⁱ—Al28A—Al17A	81.59 (5)
Si6^xii—Al14—Al25ⁱⁱⁱ	144.44 (3)	Al28B—Al28A—Al17A	132.4 (9)
Al25—Al14—Al25ⁱⁱⁱ	65.56 (5)	Al28C—Al28A—Al17A	140.4 (8)
Ru9—Al14—Al23^ix	110.764 (16)	Si17B—Al28A—Al17A	5.0 (4)
Ru9ⁱⁱⁱ—Al14—Al23^ix	168.52 (4)	Ru5ⁱ—Al28A—Al17A	142.71 (9)
Ru4—Al14—Al23^ix	57.15 (2)	Al28Aⁱⁱⁱ—Al28A—Al25^v	140.30 (5)
Si6^xii—Al14—Al23^ix	61.80 (3)	Al28B—Al28A—Al25^v	113.0 (7)
Al25—Al14—Al23^ix	87.35 (3)	Al28C—Al28A—Al25^v	108.9 (6)
Al25ⁱⁱⁱ—Al14—Al23^ix	120.77 (4)	Si17B—Al28A—Al25^v	74.4 (3)
Ru9—Al14—Al23^viii	168.52 (4)	Ru5ⁱ—Al28A—Al25^v	137.33 (10)
Ru9ⁱⁱⁱ—Al14—Al23^viii	110.764 (16)	Al17A—Al28A—Al25^v	70.04 (6)
Ru4—Al14—Al23^viii	57.15 (2)	Al28Aⁱⁱⁱ—Al28A—Ru3	81.66 (5)
Si6^xii—Al14—Al23^viii	61.80 (3)	Al28B—Al28A—Ru3	80.5 (9)
Al25—Al14—Al23^viii	120.77 (4)	Al28C—Al28A—Ru3	85.1 (9)
Al25ⁱⁱⁱ—Al14—Al23^viii	87.35 (3)	Si17B—Al28A—Ru3	63.5 (4)
Al23^ix—Al14—Al23^viii	62.02 (4)	Ru5ⁱ—Al28A—Ru3	148.43 (9)
Ru9—Al14—Al15ⁱ	58.96 (2)	Al17A—Al28A—Ru3	59.38 (5)
Ru9ⁱⁱⁱ—Al14—Al15ⁱ	58.95 (2)	Al25^v—Al28A—Ru3	60.26 (5)
Ru4—Al14—Al15ⁱ	169.63 (4)	Al28Aⁱⁱⁱ—Al28A—Al22ⁱ	113.62 (5)
Si6^xii—Al14—Al15ⁱ	62.36 (3)	Al28B—Al28A—Al22ⁱ	127.4 (10)
Al25—Al14—Al15ⁱ	124.44 (3)	Al28C—Al28A—Al22ⁱ	121.4 (8)
Al25ⁱⁱⁱ—Al14—Al15ⁱ	124.44 (3)	Si17B—Al28A—Al22ⁱ	94.4 (3)
Al23^ix—Al14—Al15ⁱ	114.47 (4)	Ru5ⁱ—Al28A—Al22ⁱ	60.36 (4)
Al23^viii—Al14—Al15ⁱ	114.46 (4)	Al17A—Al28A—Al22ⁱ	97.35 (7)
Ru9—Al14—Al22^viii	115.76 (3)	Al25^v—Al28A—Al22ⁱ	97.47 (8)
Ru9ⁱⁱⁱ—Al14—Al22^viii	55.318 (17)	Ru3—Al28A—Al22ⁱ	151.18 (9)
Ru4—Al14—Al22^viii	114.64 (2)	Al28Aⁱⁱⁱ—Al28A—Al27^xxix	82.37 (5)
Si6^xii—Al14—Al22^viii	61.01 (2)	Al28B—Al28A—Al27^xxix	23.5 (9)
Al25—Al14—Al22^viii	154.49 (4)	Al28C—Al28A—Al27^xxix	15.9 (8)
Al25ⁱⁱⁱ—Al14—Al22^viii	90.42 (3)	Si17B—Al28A—Al27^xxix	157.0 (2)
Al23^ix—Al14—Al22^viii	113.65 (4)	Ru5ⁱ—Al28A—Al27^xxix	50.81 (4)
Al23^viii—Al14—Al22^viii	63.22 (2)	Al17A—Al28A—Al27^xxix	155.92 (9)
Al15ⁱ—Al14—Al22^viii	61.44 (2)	Al25^v—Al28A—Al27^xxix	113.47 (8)
Ru9—Al14—Al22^ix	55.319 (17)	Ru3—Al28A—Al27^xxix	100.54 (6)
Ru9ⁱⁱⁱ—Al14—Al22^ix	115.76 (3)	Al22ⁱ—Al28A—Al27^xxix	105.50 (6)
Ru4—Al14—Al22^ix	114.64 (2)	Al28C—Al28B—Al28A	155.5 (14)
Si6^xii—Al14—Al22^ix	61.01 (2)	Al28C—Al28B—Al28Aⁱⁱⁱ	155.5 (14)
Al25—Al14—Al22^ix	90.42 (3)	Al28A—Al28B—Al28Aⁱⁱⁱ	45.5 (13)
Al25ⁱⁱⁱ—Al14—Al22^ix	154.49 (4)	Al28C—Al28B—Al27^xxix	18 (2)
Al23^ix—Al14—Al22^ix	63.22 (2)	Al28A—Al28B—Al27^xxix	145.2 (11)
Al23^viii—Al14—Al22^ix	113.65 (4)	Al28Aⁱⁱⁱ—Al28B—Al27^xxix	145.2 (11)
Al15ⁱ—Al14—Al22^ix	61.44 (2)	Al28C—Al28B—Ru5ⁱ	82 (3)
Al22^viii—Al14—Al22^ix	111.52 (4)	Al28A—Al28B—Ru5ⁱ	88.9 (10)
Si17B—Al15—Ru9^iv	63.07 (3)	Al28Aⁱⁱⁱ—Al28B—Ru5ⁱ	88.9 (10)
Si17B—Al15—Ru9^v	63.07 (3)	Al27^xxix—Al28B—Ru5ⁱ	64.0 (6)
Ru9^iv—Al15—Ru9^v	125.94 (4)	Al28C—Al28B—Ru3	112 (3)
Si17B—Al15—Ru9ⁱⁱ	132.0 (4)	Al28A—Al28B—Ru3	78.0 (11)
Ru9^iv—Al15—Ru9ⁱⁱ	76.250 (11)	Al28Aⁱⁱⁱ—Al28B—Ru3	78.0 (11)
Ru9^v—Al15—Ru9ⁱⁱ	144.13 (4)	Al27^xxix—Al28B—Ru3	130.2 (10)
Si17B—Al15—Ru9ⁱ	132.0 (4)	Ru5ⁱ—Al28B—Ru3	165.8 (12)
Ru9^iv—Al15—Ru9ⁱ	144.13 (4)	Al28C—Al28B—Al24^v	66 (2)
Ru9^v—Al15—Ru9ⁱ	76.250 (11)	Al28A—Al28B—Al24^v	106.4 (7)
Ru9ⁱⁱ—Al15—Ru9ⁱ	72.07 (3)	Al28Aⁱⁱⁱ—Al28B—Al24^v	133.2 (14)
Si17B—Al15—Al17A	13.5 (5)	Al27^xxix—Al28B—Al24^v	80.8 (8)
Ru9^iv—Al15—Al17A	64.43 (2)	Ru5ⁱ—Al28B—Al24^v	133.1 (8)
Ru9^v—Al15—Al17A	64.43 (2)	Ru3—Al28B—Al24^v	57.5 (3)
Ru9ⁱⁱ—Al15—Al17A	139.19 (3)	Al28C—Al28B—Al24^iv	66 (2)
Ru9ⁱ—Al15—Al17A	139.19 (3)	Al28A—Al28B—Al24^iv	133.2 (14)
Si17B—Al15—Al14ⁱ	167.7 (6)	Al28Aⁱⁱⁱ—Al28B—Al24^iv	106.4 (7)
Ru9^iv—Al15—Al14ⁱ	116.772 (19)	Al27^xxix—Al28B—Al24^iv	80.8 (8)
Ru9^v—Al15—Al14ⁱ	116.772 (19)	Ru5ⁱ—Al28B—Al24^iv	133.1 (8)
Ru9ⁱⁱ—Al15—Al14ⁱ	56.12 (2)	Ru3—Al28B—Al24^iv	57.5 (3)
Ru9ⁱ—Al15—Al14ⁱ	56.12 (2)	Al24^v—Al28B—Al24^iv	62.9 (4)
Al17A—Al15—Al14ⁱ	154.18 (7)	Al28C—Al28B—Si17B	167 (3)
Si17B—Al15—Si6^xxvi	111.0 (6)	Al28A—Al28B—Si17B	31.4 (8)
Ru9^iv—Al15—Si6^xxvi	101.37 (2)	Al28Aⁱⁱⁱ—Al28B—Si17B	31.4 (8)
Ru9^v—Al15—Si6^xxvi	101.37 (2)	Al27^xxix—Al28B—Si17B	175.2 (9)
Ru9ⁱⁱ—Al15—Si6^xxvi	100.57 (3)	Ru5ⁱ—Al28B—Si17B	111.1 (9)
Ru9ⁱ—Al15—Si6^xxvi	100.57 (3)	Ru3—Al28B—Si17B	54.6 (6)
Al17A—Al15—Si6^xxvi	97.50 (6)	Al24^v—Al28B—Si17B	103.3 (6)
Al14ⁱ—Al15—Si6^xxvi	56.68 (3)	Al24^iv—Al28B—Si17B	103.3 (6)
Si17B—Al15—Al22ⁱⁱ	78.3 (5)	Al28C—Al28B—Al23ⁱⁱ	74.0 (15)
Ru9^iv—Al15—Al22ⁱⁱ	55.306 (19)	Al28A—Al28B—Al23ⁱⁱ	119.0 (11)
Ru9^v—Al15—Al22ⁱⁱ	108.83 (3)	Al28Aⁱⁱⁱ—Al28B—Al23ⁱⁱ	82.0 (5)
Ru9ⁱⁱ—Al15—Al22ⁱⁱ	57.28 (2)	Al27^xxix—Al28B—Al23ⁱⁱ	65.0 (4)
Ru9ⁱ—Al15—Al22ⁱⁱ	92.78 (3)	Ru5ⁱ—Al28B—Al23ⁱⁱ	56.2 (3)
Al17A—Al15—Al22ⁱⁱ	89.97 (5)	Ru3—Al28B—Al23ⁱⁱ	126.0 (3)
Al14ⁱ—Al15—Al22ⁱⁱ	112.18 (4)	Al24^v—Al28B—Al23ⁱⁱ	134.4 (9)
Si6^xxvi—Al15—Al22ⁱⁱ	149.13 (2)	Al24^iv—Al28B—Al23ⁱⁱ	81.8 (3)
Si17B—Al15—Al22ⁱ	78.3 (5)	Si17B—Al28B—Al23ⁱⁱ	112.8 (6)
Ru9^iv—Al15—Al22ⁱ	108.83 (3)	Al28C—Al28B—Al23ⁱ	74.0 (15)
Ru9^v—Al15—Al22ⁱ	55.306 (19)	Al28A—Al28B—Al23ⁱ	82.0 (5)
Ru9ⁱⁱ—Al15—Al22ⁱ	92.78 (3)	Al28Aⁱⁱⁱ—Al28B—Al23ⁱ	119.0 (11)
Ru9ⁱ—Al15—Al22ⁱ	57.28 (2)	Al27^xxix—Al28B—Al23ⁱ	65.0 (4)
Al17A—Al15—Al22ⁱ	89.97 (5)	Ru5ⁱ—Al28B—Al23ⁱ	56.2 (3)
Al14ⁱ—Al15—Al22ⁱ	112.18 (4)	Ru3—Al28B—Al23ⁱ	126.0 (3)
Si6^xxvi—Al15—Al22ⁱ	149.13 (2)	Al24^v—Al28B—Al23ⁱ	81.8 (3)
Al22ⁱⁱ—Al15—Al22ⁱ	60.09 (3)	Al24^iv—Al28B—Al23ⁱ	134.4 (9)
Si17B—Al15—Al22^v	114.0 (3)	Si17B—Al28B—Al23ⁱ	112.8 (6)
Ru9^iv—Al15—Al22^v	159.05 (4)	Al23ⁱⁱ—Al28B—Al23ⁱ	107.6 (6)
Ru9^v—Al15—Al22^v	57.609 (15)	Al28B—Al28C—Al27^xxix	154 (4)
Ru9ⁱⁱ—Al15—Al22^v	112.97 (3)	Al28B—Al28C—Al28A	14.9 (8)
Ru9ⁱ—Al15—Al22^v	54.534 (18)	Al27^xxix—Al28C—Al28A	146.0 (16)
Al17A—Al15—Al22^v	107.73 (4)	Al28B—Al28C—Al28Aⁱⁱⁱ	14.9 (8)
Al14ⁱ—Al15—Al22^v	61.21 (2)	Al27^xxix—Al28C—Al28Aⁱⁱⁱ	146.0 (16)
Si6^xxvi—Al15—Al22^v	59.21 (2)	Al28A—Al28C—Al28Aⁱⁱⁱ	27.7 (7)
Al22ⁱⁱ—Al15—Al22^v	145.63 (3)	Al28B—Al28C—Ru5ⁱ	83 (3)
Al22ⁱ—Al15—Al22^v	89.97 (2)	Al27^xxix—Al28C—Ru5ⁱ	71.5 (10)
Si17B—Al15—Al22^iv	114.0 (3)	Al28A—Al28C—Ru5ⁱ	77.5 (11)
Ru9^iv—Al15—Al22^iv	57.609 (15)	Al28Aⁱⁱⁱ—Al28C—Ru5ⁱ	77.5 (11)
Ru9^v—Al15—Al22^iv	159.05 (4)	Al28B—Al28C—Al24^v	101 (2)
Ru9ⁱⁱ—Al15—Al22^iv	54.534 (18)	Al27^xxix—Al28C—Al24^v	100.7 (14)
Ru9ⁱ—Al15—Al22^iv	112.97 (3)	Al28A—Al28C—Al24^v	96.8 (10)
Al17A—Al15—Al22^iv	107.73 (4)	Al28Aⁱⁱⁱ—Al28C—Al24^v	112.8 (14)
Al14ⁱ—Al15—Al22^iv	61.21 (2)	Ru5ⁱ—Al28C—Al24^v	145.4 (4)
Si6^xxvi—Al15—Al22^iv	59.21 (2)	Al28B—Al28C—Al24^iv	101 (2)
Al22ⁱⁱ—Al15—Al22^iv	89.97 (2)	Al27^xxix—Al28C—Al24^iv	100.7 (14)
Al22ⁱ—Al15—Al22^iv	145.63 (3)	Al28A—Al28C—Al24^iv	112.8 (14)
Al22^v—Al15—Al22^iv	111.16 (4)	Al28Aⁱⁱⁱ—Al28C—Al24^iv	96.8 (10)
Ru7B^xxv—Al16—Ru7B^xi	77.0 (6)	Ru5ⁱ—Al28C—Al24^iv	145.4 (4)
Ru7B^xxv—Al16—Ru4	136.1 (2)	Al24^v—Al28C—Al24^iv	68.4 (6)
Ru7B^xi—Al16—Ru4	136.1 (2)	Al28B—Al28C—Al28C^vi	154 (4)
Ru7B^xxv—Al16—Ru7A^xxv	4.1 (4)	Al27^xxix—Al28C—Al28C^vi	0.0 (8)
Ru7B^xi—Al16—Ru7A^xxv	79.3 (3)	Al28A—Al28C—Al28C^vi	146.0 (16)
Ru4—Al16—Ru7A^xxv	135.94 (4)	Al28Aⁱⁱⁱ—Al28C—Al28C^vi	146.0 (16)
Ru7B^xxv—Al16—Ru7A^xi	79.3 (3)	Ru5ⁱ—Al28C—Al28C^vi	71.5 (10)
Ru7B^xi—Al16—Ru7A^xi	4.1 (4)	Al24^v—Al28C—Al28C^vi	100.7 (14)
Ru4—Al16—Ru7A^xi	135.94 (4)	Al24^iv—Al28C—Al28C^vi	100.7 (14)
Ru7A^xxv—Al16—Ru7A^xi	81.43 (11)	Al28B—Al28C—Al23ⁱⁱ	93.7 (16)
Ru7B^xxv—Al16—Al24	70.8 (3)	Al27^xxix—Al28C—Al23ⁱⁱ	72.8 (7)
Ru7B^xi—Al16—Al24	144.9 (4)	Al28A—Al28C—Al23ⁱⁱ	102.4 (11)
Ru4—Al16—Al24	67.90 (3)	Al28Aⁱⁱⁱ—Al28C—Al23ⁱⁱ	79.2 (6)
Ru7A^xxv—Al16—Al24	69.37 (4)	Ru5ⁱ—Al28C—Al23ⁱⁱ	58.0 (4)
Ru7A^xi—Al16—Al24	148.30 (9)	Al24^v—Al28C—Al23ⁱⁱ	153.6 (10)
Ru7B^xxv—Al16—Al24ⁱⁱⁱ	144.9 (4)	Al24^iv—Al28C—Al23ⁱⁱ	87.4 (2)
Ru7B^xi—Al16—Al24ⁱⁱⁱ	70.8 (3)	Al28C^vi—Al28C—Al23ⁱⁱ	72.8 (7)
Ru4—Al16—Al24ⁱⁱⁱ	67.90 (3)	Al28B—Al28C—Al23ⁱ	93.7 (16)
Ru7A^xxv—Al16—Al24ⁱⁱⁱ	148.30 (9)	Al27^xxix—Al28C—Al23ⁱ	72.8 (7)
Ru7A^xi—Al16—Al24ⁱⁱⁱ	69.37 (4)	Al28A—Al28C—Al23ⁱ	79.2 (6)
Al24—Al16—Al24ⁱⁱⁱ	134.53 (5)	Al28Aⁱⁱⁱ—Al28C—Al23ⁱ	102.4 (11)
Ru7B^xxv—Al16—Si6	101.2 (5)	Ru5ⁱ—Al28C—Al23ⁱ	58.0 (4)
Ru7B^xi—Al16—Si6	101.2 (5)	Al24^v—Al28C—Al23ⁱ	87.4 (2)
Ru4—Al16—Si6	98.54 (4)	Al24^iv—Al28C—Al23ⁱ	153.6 (10)
Ru7A^xxv—Al16—Si6	97.56 (9)	Al28C^vi—Al28C—Al23ⁱ	72.8 (7)
Ru7A^xi—Al16—Si6	97.56 (9)	Al23ⁱⁱ—Al28C—Al23ⁱ	113.7 (8)
Al24—Al16—Si6	98.22 (3)	Al28B—Al28C—Ru3	56 (3)
Al24ⁱⁱⁱ—Al16—Si6	98.22 (3)	Al27^xxix—Al28C—Ru3	149.8 (17)
Ru7B^xxv—Al16—Al21^x	57.5 (5)	Al28A—Al28C—Ru3	62.5 (10)
Ru7B^xi—Al16—Al21^x	114.2 (3)	Al28Aⁱⁱⁱ—Al28C—Ru3	62.5 (10)
Ru4—Al16—Al21^x	109.03 (3)	Ru5ⁱ—Al28C—Ru3	138.7 (15)
Ru7A^xxv—Al16—Al21^x	53.48 (9)	Al24^v—Al28C—Ru3	55.5 (5)
Ru7A^xi—Al16—Al21^x	113.39 (5)	Al24^iv—Al28C—Ru3	55.5 (5)
Al24—Al16—Al21^x	58.04 (2)	Al28C^vi—Al28C—Ru3	149.8 (17)
Al24ⁱⁱⁱ—Al16—Al21^x	150.87 (5)	Al23ⁱⁱ—Al28C—Ru3	119.1 (7)
Si6—Al16—Al21^x	52.86 (3)	Al23ⁱ—Al28C—Ru3	119.1 (7)
Ru7B^xxv—Al16—Al21^xi	114.2 (3)	Al28B—Al28C—Ru5^xxix	159 (3)
Ru7B^xi—Al16—Al21^xi	57.5 (5)	Al27^xxix—Al28C—Ru5^xxix	47.4 (10)
Ru4—Al16—Al21^xi	109.03 (3)	Al28A—Al28C—Ru5^xxix	158.9 (10)
Ru7A^xxv—Al16—Al21^xi	113.39 (5)	Al28Aⁱⁱⁱ—Al28C—Ru5^xxix	158.9 (10)
Ru7A^xi—Al16—Al21^xi	53.48 (9)	Ru5ⁱ—Al28C—Ru5^xxix	118.9 (13)
Al24—Al16—Al21^xi	150.87 (5)	Al24^v—Al28C—Ru5^xxix	62.1 (7)
Al24ⁱⁱⁱ—Al16—Al21^xi	58.04 (2)	Al24^iv—Al28C—Ru5^xxix	62.1 (7)
Si6—Al16—Al21^xi	52.86 (3)	Al28C^vi—Al28C—Ru5^xxix	47.4 (10)
Al21^x—Al16—Al21^xi	99.01 (5)	Al23ⁱⁱ—Al28C—Ru5^xxix	97.9 (8)
Si17B—Al17A—Ru3	74.0 (11)	Al23ⁱ—Al28C—Ru5^xxix	97.9 (8)
Si17B—Al17A—Al28Aⁱⁱⁱ	16.0 (9)	Ru3—Al28C—Ru5^xxix	102.3 (7)

Symmetry codes: (i) x, y, −z+1/2; (ii) −x, y, −z+1/2; (iii) −x, y, z; (iv) x−1/2, −y+1/2, z+1/2; (v) −x+1/2, −y+1/2, z+1/2; (vi) −x, −y, −z+1; (vii) −x+1/2, −y+1/2, −z+1; (viii) x−1/2, −y+1/2, −z; (ix) −x+1/2, −y+1/2, −z; (x) −x+1/2, y+1/2, z; (xi) x−1/2, y+1/2, z; (xii) −x, −y+1, −z; (xiii) −x, −y+1, z−1/2; (xiv) x+1/2, y−1/2, −z+1/2; (xv) x+1/2, y−1/2, z; (xvi) −x+1/2, y−1/2, −z+1/2; (xvii) −x+1/2, y−1/2, z; (xviii) −x+1, y, −z+1/2; (xix) −x+1, y, z; (xx) −x+1/2, −y+1/2, z−1/2; (xxi) x−1/2, y−1/2, z; (xxii) x−1/2, y−1/2, −z+1/2; (xxiii) x, −y, −z; (xxiv) −x, −y, z−1/2; (xxv) −x+1/2, y+1/2, −z+1/2; (xxvi) −x, −y+1, z+1/2; (xxvii) x+1/2, y+1/2, z; (xxviii) −x, −y, −z; (xxix) −x, −y, z+1/2.

Docosaaluminium nonaruthenium decasilicon (II) top

Crystal data top

~Ru₉(Al_0.70Si_0.30)₃₂	D_x = 4.777 Mg m⁻³
M_r = 1783.65	Mo Kα radiation, λ = 0.71073 Å
Trigonal, R3	Cell parameters from 10605 reflections
a = 10.4479 (2) Å	θ = 3.9–30.7°
c = 19.6774 (4) Å	µ = 6.59 mm⁻¹
V = 1860.17 (7) Å³	T = 296 K
Z = 3	Irregular, metallic light silver
F(000) = 2436.84	0.03 × 0.03 × 0.03 mm

Data collection top

XtaLAB Synergy R, HyPix diffractometer	1193 independent reflections
Radiation source: micro-focus sealed X-ray tube, Mova (Mo) X-ray Source	1127 reflections with I > 2σ(I)
Mirror monochromator	R_int = 0.027
Detector resolution: 10.0000 pixels mm^-1	θ_max = 30.8°, θ_min = 3.9°
ω scans	h = −14→14
Absorption correction: gaussian (CrysAlisPro; Matsumoto et al., 2021)	k = −14→14
T_min = 0.868, T_max = 0.879	l = −27→28
14255 measured reflections

Refinement top

Refinement on F²	Primary atom site location: dual
Least-squares matrix: full	w = 1/[σ²(F_o²) + (0.0111P)² + 0.5812P] where P = (F_o² + 2F_c²)/3
R[F² > 2σ(F²)] = 0.013	(Δ/σ)_max = 0.002
wR(F²) = 0.024	Δρ_max = 0.45 e Å⁻³
S = 1.08	Δρ_min = −0.53 e Å⁻³
1193 reflections	Extinction correction: SHELXL-2019/3 (Sheldrick, 2015b), Fc^*=kFc[1+0.001xFc²λ³/sin(2θ)]^-1/4
66 parameters	Extinction coefficient: 0.000262 (16)
2 restraints

Special details top

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å²) top

	x	y	z	U_iso*/U_eq	Occ. (<1)
Ru1	0.000000	0.000000	0.500000	0.00463 (7)
Ru2	0.000000	0.000000	0.28833 (2)	0.00519 (6)
Ru3	0.24368 (2)	0.24916 (2)	0.09171 (2)	0.00467 (5)
Al4	0.000000	0.000000	0.12554 (5)	0.01068 (17)
Si5	0.06845 (5)	0.25394 (5)	0.29541 (2)	0.00880 (9)
Al6	0.22915 (5)	0.16512 (5)	0.21432 (2)	0.0079 (2)	0.58 (4)
Si6	0.22915 (5)	0.16512 (5)	0.21432 (2)	0.0079 (2)	0.42 (4)
Al7	0.00143 (5)	0.21088 (5)	0.03958 (2)	0.0076 (2)	0.82 (4)
Si7	0.00143 (5)	0.21088 (5)	0.03958 (2)	0.0076 (2)	0.18 (4)
Al8	0.16504 (5)	0.12448 (5)	0.39021 (2)	0.00948 (10)
Al9	0.12627 (6)	0.37148 (6)	0.16275 (2)	0.01084 (11)

Atomic displacement parameters (Å²) top

	U¹¹	U²²	U³³	U¹²	U¹³	U²³
Ru1	0.00464 (9)	0.00464 (9)	0.00459 (13)	0.00232 (5)	0.000	0.000
Ru2	0.00444 (7)	0.00444 (7)	0.00667 (10)	0.00222 (4)	0.000	0.000
Ru3	0.00486 (7)	0.00394 (7)	0.00529 (7)	0.00224 (5)	0.00054 (4)	0.00006 (4)
Al4	0.0066 (2)	0.0066 (2)	0.0189 (4)	0.00329 (12)	0.000	0.000
Si5	0.0109 (2)	0.0054 (2)	0.0101 (2)	0.00405 (18)	−0.00401 (16)	−0.00003 (16)
Al6	0.0076 (3)	0.0096 (3)	0.0073 (3)	0.0048 (2)	0.00127 (16)	0.00249 (17)
Si6	0.0076 (3)	0.0096 (3)	0.0073 (3)	0.0048 (2)	0.00127 (16)	0.00249 (17)
Al7	0.0059 (3)	0.0102 (3)	0.0061 (3)	0.0036 (2)	0.00001 (16)	−0.00019 (17)
Si7	0.0059 (3)	0.0102 (3)	0.0061 (3)	0.0036 (2)	0.00001 (16)	−0.00019 (17)
Al8	0.0074 (2)	0.0088 (2)	0.0076 (2)	0.00063 (19)	−0.00180 (18)	−0.00055 (17)
Al9	0.0098 (2)	0.0097 (2)	0.0121 (2)	0.0042 (2)	0.00506 (18)	−0.00117 (19)

Geometric parameters (Å, º) top

Ru1—Al8ⁱ	2.6625 (5)	Ru3—Al7^xv	2.6119 (5)
Ru1—Al8ⁱⁱ	2.6625 (5)	Ru3—Al4	2.6597 (3)
Ru1—Al8ⁱⁱⁱ	2.6625 (5)	Ru3—Al7ⁱⁱ	2.6643 (5)
Ru1—Al8^iv	2.6626 (5)	Al4—Al6^iv	2.7622 (7)
Ru1—Al8^v	2.6626 (5)	Al4—Al6ⁱⁱ	2.7622 (7)
Ru1—Al8	2.6626 (5)	Al4—Al6	2.7622 (7)
Ru1—Al9^vi	2.7432 (5)	Al4—Al7	2.7718 (7)
Ru1—Al9^vii	2.7432 (5)	Al4—Al7^iv	2.7718 (7)
Ru1—Al9^viii	2.7432 (5)	Al4—Al7ⁱⁱ	2.7718 (7)
Ru1—Al9^ix	2.7432 (5)	Si5—Si5^ix	2.4056 (9)
Ru1—Al9^x	2.7433 (5)	Si5—Al8^ix	2.6749 (6)
Ru1—Al9^xi	2.7433 (5)	Si5—Al6^iv	2.7560 (6)
Ru2—Si5ⁱⁱ	2.3817 (4)	Si5—Al8	2.7736 (6)
Ru2—Si5	2.3817 (4)	Si5—Al6	2.7899 (6)
Ru2—Si5^iv	2.3817 (4)	Si5—Al9	2.8188 (7)
Ru2—Al8	2.5380 (5)	Si5—Al8^iv	2.8319 (7)
Ru2—Al8ⁱⁱ	2.5380 (5)	Al6—Al7^xii	2.6531 (6)
Ru2—Al8^iv	2.5381 (5)	Al6—Al9^xii	2.8394 (7)
Ru2—Al6ⁱⁱ	2.5880 (5)	Al6—Al6^xiv	2.8614 (9)
Ru2—Al6^iv	2.5880 (5)	Al7—Al7^xvi	2.6922 (6)
Ru2—Al6	2.5881 (5)	Al7—Al7^xv	2.6922 (6)
Ru3—Si5^xii	2.4214 (4)	Al7—Al9	2.8639 (7)
Ru3—Al8^xiii	2.5175 (5)	Al8—Al9^vii	2.6172 (7)
Ru3—Al6	2.5459 (5)	Al8—Al8ⁱⁱ	2.6956 (8)
Ru3—Al7	2.5702 (5)	Al8—Al8^iv	2.6957 (8)
Ru3—Al9^xii	2.5708 (5)	Al8—Al9^ix	2.7562 (7)
Ru3—Al9	2.5806 (5)	Al9—Al9^xii	2.7465 (5)
Ru3—Al6^xiv	2.6110 (5)	Al9—Al9^xvii	2.7465 (5)

Al8ⁱ—Ru1—Al8ⁱⁱ	180.0	Si5^ix—Si5—Al8^ix	65.93 (2)
Al8ⁱ—Ru1—Al8ⁱⁱⁱ	60.824 (17)	Ru3^xvii—Si5—Al8^ix	58.956 (14)
Al8ⁱⁱ—Ru1—Al8ⁱⁱⁱ	119.176 (17)	Ru2—Si5—Al6^iv	59.969 (14)
Al8ⁱ—Ru1—Al8^iv	119.176 (17)	Si5^ix—Si5—Al6^iv	177.02 (3)
Al8ⁱⁱ—Ru1—Al8^iv	60.824 (17)	Ru3^xvii—Si5—Al6^iv	60.159 (14)
Al8ⁱⁱⁱ—Ru1—Al8^iv	119.176 (17)	Al8^ix—Si5—Al6^iv	115.87 (2)
Al8ⁱ—Ru1—Al8^v	60.824 (17)	Ru2—Si5—Al8	58.394 (14)
Al8ⁱⁱ—Ru1—Al8^v	119.176 (17)	Si5^ix—Si5—Al8	61.71 (2)
Al8ⁱⁱⁱ—Ru1—Al8^v	60.824 (17)	Ru3^xvii—Si5—Al8	159.94 (2)
Al8^iv—Ru1—Al8^v	180.000 (12)	Al8^ix—Si5—Al8	127.637 (19)
Al8ⁱ—Ru1—Al8	119.177 (17)	Al6^iv—Si5—Al8	116.45 (2)
Al8ⁱⁱ—Ru1—Al8	60.823 (17)	Ru2—Si5—Al6	59.434 (14)
Al8ⁱⁱⁱ—Ru1—Al8	179.999 (12)	Si5^ix—Si5—Al6	97.84 (3)
Al8^iv—Ru1—Al8	60.824 (17)	Ru3^xvii—Si5—Al6	119.201 (19)
Al8^v—Ru1—Al8	119.176 (17)	Al8^ix—Si5—Al6	109.51 (2)
Al8ⁱ—Ru1—Al9^vi	89.014 (15)	Al6^iv—Si5—Al6	83.85 (2)
Al8ⁱⁱ—Ru1—Al9^vi	90.986 (15)	Al8—Si5—Al6	78.242 (18)
Al8ⁱⁱⁱ—Ru1—Al9^vi	57.891 (14)	Ru2—Si5—Al9	108.102 (19)
Al8^iv—Ru1—Al9^vi	61.286 (14)	Si5^ix—Si5—Al9	110.55 (3)
Al8^v—Ru1—Al9^vi	118.714 (14)	Ru3^xvii—Si5—Al9	58.171 (14)
Al8—Ru1—Al9^vi	122.110 (14)	Al8^ix—Si5—Al9	60.157 (17)
Al8ⁱ—Ru1—Al9^vii	90.986 (15)	Al6^iv—Si5—Al9	72.378 (18)
Al8ⁱⁱ—Ru1—Al9^vii	89.014 (15)	Al8—Si5—Al9	141.66 (2)
Al8ⁱⁱⁱ—Ru1—Al9^vii	122.109 (14)	Al6—Si5—Al9	65.278 (17)
Al8^iv—Ru1—Al9^vii	118.714 (14)	Ru2—Si5—Al8^iv	57.488 (14)
Al8^v—Ru1—Al9^vii	61.286 (14)	Si5^ix—Si5—Al8^iv	99.22 (3)
Al8—Ru1—Al9^vii	57.890 (14)	Ru3^xvii—Si5—Al8^iv	103.669 (19)
Al9^vi—Ru1—Al9^vii	180.0	Al8^ix—Si5—Al8^iv	134.55 (2)
Al8ⁱ—Ru1—Al9^viii	122.109 (14)	Al6^iv—Si5—Al8^iv	77.825 (18)
Al8ⁱⁱ—Ru1—Al9^viii	57.891 (14)	Al8—Si5—Al8^iv	57.48 (2)
Al8ⁱⁱⁱ—Ru1—Al9^viii	61.285 (14)	Al6—Si5—Al8^iv	115.13 (2)
Al8^iv—Ru1—Al9^viii	89.013 (15)	Al9—Si5—Al8^iv	150.02 (2)
Al8^v—Ru1—Al9^viii	90.987 (15)	Ru3—Al6—Ru2	129.707 (19)
Al8—Ru1—Al9^viii	118.714 (14)	Ru3—Al6—Ru3^xiv	112.612 (17)
Al9^vi—Ru1—Al9^viii	60.077 (1)	Ru2—Al6—Ru3^xiv	106.091 (16)
Al9^vii—Ru1—Al9^viii	119.923 (1)	Ru3—Al6—Al7^xii	116.69 (2)
Al8ⁱ—Ru1—Al9^ix	57.891 (14)	Ru2—Al6—Al7^xii	109.655 (19)
Al8ⁱⁱ—Ru1—Al9^ix	122.109 (14)	Ru3^xiv—Al6—Al7^xii	60.806 (14)
Al8ⁱⁱⁱ—Ru1—Al9^ix	118.715 (14)	Ru3—Al6—Si5ⁱⁱ	143.99 (2)
Al8^iv—Ru1—Al9^ix	90.987 (15)	Ru2—Al6—Si5ⁱⁱ	52.818 (13)
Al8^v—Ru1—Al9^ix	89.013 (15)	Ru3^xiv—Al6—Si5ⁱⁱ	53.554 (13)
Al8—Ru1—Al9^ix	61.286 (14)	Al7^xii—Al6—Si5ⁱⁱ	86.919 (19)
Al9^vi—Ru1—Al9^ix	119.923 (1)	Ru3—Al6—Al4	59.976 (17)
Al9^vii—Ru1—Al9^ix	60.077 (1)	Ru2—Al6—Al4	73.471 (19)
Al9^viii—Ru1—Al9^ix	180.0	Ru3^xiv—Al6—Al4	119.885 (18)
Al8ⁱ—Ru1—Al9^x	118.713 (14)	Al7^xii—Al6—Al4	176.66 (3)
Al8ⁱⁱ—Ru1—Al9^x	61.287 (14)	Si5ⁱⁱ—Al6—Al4	96.03 (2)
Al8ⁱⁱⁱ—Ru1—Al9^x	89.012 (15)	Ru3—Al6—Si5	111.671 (19)
Al8^iv—Ru1—Al9^x	122.111 (14)	Ru2—Al6—Si5	52.410 (13)
Al8^v—Ru1—Al9^x	57.889 (14)	Ru3^xiv—Al6—Si5	133.10 (2)
Al8—Ru1—Al9^x	90.987 (15)	Al7^xii—Al6—Si5	85.969 (18)
Al9^vi—Ru1—Al9^x	119.921 (1)	Si5ⁱⁱ—Al6—Si5	95.90 (2)
Al9^vii—Ru1—Al9^x	60.079 (1)	Al4—Al6—Si5	95.257 (19)
Al9^viii—Ru1—Al9^x	60.079 (1)	Ru3—Al6—Al9^xii	56.713 (13)
Al9^ix—Ru1—Al9^x	119.921 (1)	Ru2—Al6—Al9^xii	144.13 (2)
Al8ⁱ—Ru1—Al9^xi	61.287 (14)	Ru3^xiv—Al6—Al9^xii	99.795 (18)
Al8ⁱⁱ—Ru1—Al9^xi	118.713 (14)	Al7^xii—Al6—Al9^xii	62.748 (17)
Al8ⁱⁱⁱ—Ru1—Al9^xi	90.988 (15)	Si5ⁱⁱ—Al6—Al9^xii	148.12 (2)
Al8^iv—Ru1—Al9^xi	57.889 (14)	Al4—Al6—Al9^xii	114.07 (2)
Al8^v—Ru1—Al9^xi	122.111 (14)	Si5—Al6—Al9^xii	91.741 (19)
Al8—Ru1—Al9^xi	89.013 (15)	Ru3—Al6—Al6^xiv	57.391 (15)
Al9^vi—Ru1—Al9^xi	60.079 (1)	Ru2—Al6—Al6^xiv	145.22 (3)
Al9^vii—Ru1—Al9^xi	119.921 (1)	Ru3^xiv—Al6—Al6^xiv	55.221 (15)
Al9^viii—Ru1—Al9^xi	119.921 (1)	Al7^xii—Al6—Al6^xiv	87.39 (2)
Al9^ix—Ru1—Al9^xi	60.079 (1)	Si5ⁱⁱ—Al6—Al6^xiv	100.23 (2)
Al9^x—Ru1—Al9^xi	180.0	Al4—Al6—Al6^xiv	90.54 (2)
Si5ⁱⁱ—Ru2—Si5	119.661 (2)	Si5—Al6—Al6^xiv	162.19 (3)
Si5ⁱⁱ—Ru2—Si5^iv	119.662 (2)	Al9^xii—Al6—Al6^xiv	70.54 (2)
Si5—Ru2—Si5^iv	119.659 (2)	Ru3—Al7—Ru3^xvi	117.649 (18)
Si5ⁱⁱ—Ru2—Al8	70.202 (16)	Ru3—Al7—Al6^xvii	116.63 (2)
Si5—Ru2—Al8	68.549 (15)	Ru3^xvi—Al7—Al6^xvii	119.15 (2)
Si5^iv—Ru2—Al8	124.453 (17)	Ru3—Al7—Ru3^iv	116.862 (18)
Si5ⁱⁱ—Ru2—Al8ⁱⁱ	68.549 (15)	Ru3^xvi—Al7—Ru3^iv	114.346 (17)
Si5—Ru2—Al8ⁱⁱ	124.452 (17)	Al6^xvii—Al7—Ru3^iv	58.818 (14)
Si5^iv—Ru2—Al8ⁱⁱ	70.202 (16)	Ru3—Al7—Al7^xvi	134.381 (13)
Al8—Ru2—Al8ⁱⁱ	64.153 (18)	Ru3^xvi—Al7—Al7^xvi	57.944 (19)
Si5ⁱⁱ—Ru2—Al8^iv	124.453 (17)	Al6^xvii—Al7—Al7^xvi	99.12 (2)
Si5—Ru2—Al8^iv	70.202 (16)	Ru3^iv—Al7—Al7^xvi	58.365 (12)
Si5^iv—Ru2—Al8^iv	68.548 (15)	Ru3—Al7—Al7^xv	59.461 (12)
Al8—Ru2—Al8^iv	64.153 (18)	Ru3^xvi—Al7—Al7^xv	60.283 (19)
Al8ⁱⁱ—Ru2—Al8^iv	64.152 (18)	Al6^xvii—Al7—Al7^xv	168.67 (2)
Si5ⁱⁱ—Ru2—Al6ⁱⁱ	68.158 (15)	Ru3^iv—Al7—Al7^xv	132.432 (13)
Si5—Ru2—Al6ⁱⁱ	149.111 (17)	Al7^xvi—Al7—Al7^xv	89.88 (2)
Si5^iv—Ru2—Al6ⁱⁱ	67.213 (15)	Ru3—Al7—Al4	59.578 (10)
Al8—Ru2—Al6ⁱⁱ	135.530 (15)	Ru3^xvi—Al7—Al4	135.92 (2)
Al8ⁱⁱ—Ru2—Al6ⁱⁱ	86.437 (15)	Al6^xvii—Al7—Al4	94.86 (2)
Al8^iv—Ru2—Al6ⁱⁱ	132.991 (15)	Ru3^iv—Al7—Al4	58.545 (10)
Si5ⁱⁱ—Ru2—Al6^iv	149.112 (17)	Al7^xvi—Al7—Al4	91.721 (15)
Si5—Ru2—Al6^iv	67.211 (15)	Al7^xv—Al7—Al4	91.721 (15)
Si5^iv—Ru2—Al6^iv	68.157 (15)	Ru3—Al7—Al9	56.394 (14)
Al8—Ru2—Al6^iv	132.990 (15)	Ru3^xvi—Al7—Al9	142.61 (2)
Al8ⁱⁱ—Ru2—Al6^iv	135.529 (15)	Al6^xvii—Al7—Al9	61.810 (17)
Al8^iv—Ru2—Al6^iv	86.436 (15)	Ru3^iv—Al7—Al9	97.917 (17)
Al6ⁱⁱ—Ru2—Al6^iv	91.441 (15)	Al7^xvi—Al7—Al9	156.03 (3)
Si5ⁱⁱ—Ru2—Al6	67.213 (15)	Al7^xv—Al7—Al9	111.07 (2)
Si5—Ru2—Al6	68.157 (15)	Al4—Al7—Al9	76.65 (2)
Si5^iv—Ru2—Al6	149.112 (17)	Ru3^vii—Al8—Ru2	143.54 (2)
Al8—Ru2—Al6	86.435 (15)	Ru3^vii—Al8—Al9^vii	60.306 (15)
Al8ⁱⁱ—Ru2—Al6	132.991 (15)	Ru2—Al8—Al9^vii	145.45 (2)
Al8^iv—Ru2—Al6	135.529 (15)	Ru3^vii—Al8—Ru1	109.918 (17)
Al6ⁱⁱ—Ru2—Al6	91.442 (15)	Ru2—Al8—Ru1	106.409 (17)
Al6^iv—Ru2—Al6	91.441 (15)	Al9^vii—Al8—Ru1	62.599 (15)
Si5^xii—Ru3—Al8^xiii	65.551 (15)	Ru3^vii—Al8—Si5^ix	55.492 (14)
Si5^xii—Ru3—Al6	120.406 (15)	Ru2—Al8—Si5^ix	104.439 (19)
Al8^xiii—Ru3—Al6	124.414 (16)	Al9^vii—Al8—Si5^ix	109.63 (2)
Si5^xii—Ru3—Al7	122.217 (15)	Ru1—Al8—Si5^ix	117.12 (2)
Al8^xiii—Ru3—Al7	73.932 (16)	Ru3^vii—Al8—Al8ⁱⁱ	149.08 (3)
Al6—Ru3—Al7	116.122 (15)	Ru2—Al8—Al8ⁱⁱ	57.924 (9)
Si5^xii—Ru3—Al9^xii	68.678 (16)	Al9^vii—Al8—Al8ⁱⁱ	91.00 (2)
Al8^xiii—Ru3—Al9^xii	65.586 (16)	Ru1—Al8—Al8ⁱⁱ	59.587 (8)
Al6—Ru3—Al9^xii	67.410 (16)	Si5^ix—Al8—Al8ⁱⁱ	155.06 (3)
Al7—Ru3—Al9^xii	127.455 (16)	Ru3^vii—Al8—Al8^iv	143.73 (3)
Si5^xii—Ru3—Al9	119.665 (16)	Ru2—Al8—Al8^iv	57.925 (9)
Al8^xiii—Ru3—Al9	61.760 (16)	Al9^vii—Al8—Al8^iv	122.187 (15)
Al6—Ru3—Al9	72.324 (16)	Ru1—Al8—Al8^iv	59.588 (8)
Al7—Ru3—Al9	67.560 (16)	Si5^ix—Al8—Al8^iv	96.24 (3)
Al9^xii—Ru3—Al9	64.436 (17)	Al8ⁱⁱ—Al8—Al8^iv	60.0
Si5^xii—Ru3—Al6^xiv	66.289 (14)	Ru3^vii—Al8—Al9^ix	58.136 (15)
Al8^xiii—Ru3—Al6^xiv	127.640 (16)	Ru2—Al8—Al9^ix	145.13 (2)
Al6—Ru3—Al6^xiv	67.389 (17)	Al9^vii—Al8—Al9^ix	61.411 (12)
Al7—Ru3—Al6^xiv	153.459 (16)	Ru1—Al8—Al9^ix	60.799 (14)
Al9^xii—Ru3—Al6^xiv	78.881 (16)	Si5^ix—Al8—Al9^ix	62.510 (18)
Al9—Ru3—Al6^xiv	133.370 (16)	Al8ⁱⁱ—Al8—Al9^ix	120.386 (14)
Si5^xii—Ru3—Al7^xv	71.465 (15)	Al8^iv—Al8—Al9^ix	90.01 (2)
Al8^xiii—Ru3—Al7^xv	80.729 (15)	Ru3^vii—Al8—Si5	104.754 (19)
Al6—Ru3—Al7^xv	154.440 (16)	Ru2—Al8—Si5	53.057 (13)
Al7—Ru3—Al7^xv	62.594 (14)	Al9^vii—Al8—Si5	161.49 (2)
Al9^xii—Ru3—Al7^xv	135.585 (16)	Ru1—Al8—Si5	118.64 (2)
Al9—Ru3—Al7^xv	123.870 (16)	Si5^ix—Al8—Si5	52.363 (19)
Al6^xiv—Ru3—Al7^xv	102.325 (15)	Al8ⁱⁱ—Al8—Si5	105.493 (16)
Si5^xii—Ru3—Al4	156.665 (16)	Al8^iv—Al8—Si5	62.348 (19)
Al8^xiii—Ru3—Al4	133.431 (13)	Al9^ix—Al8—Si5	102.09 (2)
Al6—Ru3—Al4	64.05 (2)	Ru3^vii—Al8—Si5ⁱⁱ	111.11 (2)
Al7—Ru3—Al4	63.982 (15)	Ru2—Al8—Si5ⁱⁱ	52.311 (13)
Al9^xii—Ru3—Al4	127.93 (2)	Al9^vii—Al8—Si5ⁱⁱ	101.04 (2)
Al9—Ru3—Al4	83.669 (15)	Ru1—Al8—Si5ⁱⁱ	116.598 (19)
Al6^xiv—Ru3—Al4	98.593 (12)	Si5^ix—Al8—Si5ⁱⁱ	125.72 (2)
Al7^xv—Ru3—Al4	96.13 (2)	Al8ⁱⁱ—Al8—Si5ⁱⁱ	60.177 (19)
Si5^xii—Ru3—Al7ⁱⁱ	93.941 (15)	Al8^iv—Al8—Si5ⁱⁱ	103.902 (16)
Al8^xiii—Ru3—Al7ⁱⁱ	141.416 (15)	Al9^ix—Al8—Si5ⁱⁱ	162.00 (2)
Al6—Ru3—Al7ⁱⁱ	94.038 (15)	Si5—Al8—Si5ⁱⁱ	94.55 (2)
Al7—Ru3—Al7ⁱⁱ	93.18 (2)	Ru3^xvii—Al9—Ru3	147.99 (2)
Al9^xii—Ru3—Al7ⁱⁱ	139.245 (16)	Ru3^xvii—Al9—Al8^xiii	148.40 (2)
Al9—Ru3—Al7ⁱⁱ	146.275 (16)	Ru3—Al9—Al8^xiii	57.934 (15)
Al6^xiv—Ru3—Al7ⁱⁱ	60.377 (15)	Ru3^xvii—Al9—Ru1^xviii	105.884 (17)
Al7^xv—Ru3—Al7ⁱⁱ	61.353 (14)	Ru3—Al9—Ru1^xviii	105.607 (17)
Al4—Ru3—Al7ⁱⁱ	62.748 (15)	Al8^xiii—Al9—Ru1^xviii	59.509 (15)
Ru3—Al4—Ru3^iv	113.957 (15)	Ru3^xvii—Al9—Al9^xii	138.86 (3)
Ru3—Al4—Ru3ⁱⁱ	113.956 (15)	Ru3—Al9—Al9^xii	57.609 (18)
Ru3^iv—Al4—Ru3ⁱⁱ	113.956 (15)	Al8^xiii—Al9—Al9^xii	61.789 (18)
Ru3—Al4—Al6^iv	109.230 (14)	Ru1^xviii—Al9—Al9^xii	59.959 (1)
Ru3^iv—Al4—Al6^iv	55.974 (11)	Ru3^xvii—Al9—Al9^xvii	57.955 (19)
Ru3ⁱⁱ—Al4—Al6^iv	134.84 (2)	Ru3—Al9—Al9^xvii	148.22 (3)
Ru3—Al4—Al6ⁱⁱ	134.84 (2)	Al8^xiii—Al9—Al9^xvii	91.89 (2)
Ru3^iv—Al4—Al6ⁱⁱ	109.230 (14)	Ru1^xviii—Al9—Al9^xvii	60.0
Ru3ⁱⁱ—Al4—Al6ⁱⁱ	55.974 (11)	Al9^xii—Al9—Al9^xvii	119.687 (4)
Al6^iv—Al4—Al6ⁱⁱ	84.26 (3)	Ru3^xvii—Al9—Al8^ix	56.276 (14)
Ru3—Al4—Al6	55.973 (11)	Ru3—Al9—Al8^ix	143.01 (2)
Ru3^iv—Al4—Al6	134.84 (2)	Al8^xiii—Al9—Al8^ix	117.42 (3)
Ru3ⁱⁱ—Al4—Al6	109.231 (14)	Ru1^xviii—Al9—Al8^ix	57.913 (14)
Al6^iv—Al4—Al6	84.26 (3)	Al9^xii—Al9—Al8^ix	87.05 (2)
Al6ⁱⁱ—Al4—Al6	84.26 (3)	Al9^xvii—Al9—Al8^ix	56.799 (18)
Ru3—Al4—Al7	56.440 (13)	Ru3^xvii—Al9—Si5	53.152 (13)
Ru3^iv—Al4—Al7	58.708 (14)	Ru3—Al9—Si5	109.71 (2)
Ru3ⁱⁱ—Al4—Al7	127.88 (3)	Al8^xiii—Al9—Si5	154.89 (3)
Al6^iv—Al4—Al7	87.091 (13)	Ru1^xviii—Al9—Si5	109.909 (19)
Al6ⁱⁱ—Al4—Al7	167.862 (14)	Al9^xii—Al9—Si5	93.10 (3)
Al6—Al4—Al7	103.356 (14)	Al9^xvii—Al9—Si5	102.00 (3)
Ru3—Al4—Al7^iv	127.88 (3)	Al8^ix—Al9—Si5	57.332 (16)
Ru3^iv—Al4—Al7^iv	56.439 (13)	Ru3^xvii—Al9—Al6^xvii	55.877 (14)
Ru3ⁱⁱ—Al4—Al7^iv	58.708 (14)	Ru3—Al9—Al6^xvii	110.10 (2)
Al6^iv—Al4—Al7^iv	103.357 (14)	Al8^xiii—Al9—Al6^xvii	105.54 (2)
Al6ⁱⁱ—Al4—Al7^iv	87.091 (13)	Ru1^xviii—Al9—Al6^xvii	121.90 (2)
Al6—Al4—Al7^iv	167.862 (14)	Al9^xii—Al9—Al6^xvii	165.26 (3)
Al7—Al4—Al7^iv	86.64 (2)	Al9^xvii—Al9—Al6^xvii	65.56 (2)
Ru3—Al4—Al7ⁱⁱ	58.708 (14)	Al8^ix—Al9—Al6^xvii	106.35 (2)
Ru3^iv—Al4—Al7ⁱⁱ	127.88 (3)	Si5—Al9—Al6^xvii	99.26 (2)
Ru3ⁱⁱ—Al4—Al7ⁱⁱ	56.439 (13)	Ru3^xvii—Al9—Al7	108.93 (2)
Al6^iv—Al4—Al7ⁱⁱ	167.862 (14)	Ru3—Al9—Al7	56.047 (14)
Al6ⁱⁱ—Al4—Al7ⁱⁱ	103.357 (14)	Al8^xiii—Al9—Al7	67.695 (18)
Al6—Al4—Al7ⁱⁱ	87.091 (13)	Ru1^xviii—Al9—Al7	123.68 (2)
Al7—Al4—Al7ⁱⁱ	86.64 (2)	Al9^xii—Al9—Al7	110.49 (3)
Al7^iv—Al4—Al7ⁱⁱ	86.64 (2)	Al9^xvii—Al9—Al7	105.97 (3)
Ru2—Si5—Si5^ix	118.81 (3)	Al8^ix—Al9—Al7	160.85 (2)
Ru2—Si5—Ru3^xvii	119.762 (18)	Si5—Al9—Al7	126.36 (2)
Si5^ix—Si5—Ru3^xvii	120.64 (3)	Al6^xvii—Al9—Al7	55.443 (16)
Ru2—Si5—Al8^ix	167.65 (2)

Symmetry codes: (i) x−y, x, −z+1; (ii) −x+y, −x, z; (iii) −x, −y, −z+1; (iv) −y, x−y, z; (v) y, −x+y, −z+1; (vi) y−2/3, −x+y−1/3, −z+2/3; (vii) −y+2/3, x−y+1/3, z+1/3; (viii) x−1/3, y−2/3, z+1/3; (ix) −x+1/3, −y+2/3, −z+2/3; (x) x−y+1/3, x−1/3, −z+2/3; (xi) −x+y−1/3, −x+1/3, z+1/3; (xii) x−y+2/3, x+1/3, −z+1/3; (xiii) −x+y+1/3, −x+2/3, z−1/3; (xiv) −x+2/3, −y+1/3, −z+1/3; (xv) y, −x+y, −z; (xvi) x−y, x, −z; (xvii) y−1/3, −x+y+1/3, −z+1/3; (xviii) x+1/3, y+2/3, z−1/3.

Heptacosaaluminium decaruthenium tridecasilicon (III) top

Crystal data top

~Ru₁₀(Al_0.67Si_0.33)₄₁	D_x = 4.652 Mg m⁻³
M_r = 2122.53	Mo Kα radiation, λ = 0.71073 Å
Orthorhombic, Pnma	Cell parameters from 16783 reflections
a = 15.0794 (2) Å	θ = 3.4–33.8°
b = 11.8713 (2) Å	µ = 6.18 mm⁻¹
c = 16.9291 (3) Å	T = 298 K
V = 3030.50 (9) Å³	Irregular, metallic light silver
Z = 4	0.04 × 0.02 × 0.02 mm
F(000) = 3888.20

Data collection top

XtaLAB Synergy R, HyPix diffractometer	5672 independent reflections
Radiation source: micro-focus sealed X-ray tube, Mova (Mo) X-ray Source	4940 reflections with I > 2σ(I)
Mirror monochromator	R_int = 0.022
Detector resolution: 10.0000 pixels mm^-1	θ_max = 33.7°, θ_min = 3.2°
ω scans	h = −23→21
Absorption correction: gaussian (CrysAlisPro; Matsumoto et al., 2021)	k = −17→18
T_min = 0.867, T_max = 0.929	l = −25→24
33654 measured reflections

Refinement top

Refinement on F²	Primary atom site location: dual
Least-squares matrix: full	Secondary atom site location: difference Fourier map
R[F² > 2σ(F²)] = 0.015	w = 1/[σ²(F_o²) + (0.0093P)² + 1.1293P] where P = (F_o² + 2F_c²)/3
wR(F²) = 0.026	(Δ/σ)_max = 0.003
S = 1.01	Δρ_max = 0.78 e Å⁻³
5672 reflections	Δρ_min = −0.74 e Å⁻³
303 parameters	Extinction correction: SHELXL-2019/3 (Sheldrick, 2015b), Fc^*=kFc[1+0.001xFc²λ³/sin(2θ)]^-1/4
2 restraints	Extinction coefficient: 0.000039 (4)

Special details top

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å²) top

	x	y	z	U_iso*/U_eq	Occ. (<1)
Ru1	0.15195 (2)	0.250000	0.76146 (2)	0.00513 (3)
Ru2	0.41069 (2)	0.250000	0.87752 (2)	0.00474 (3)
Ru3	0.45013 (2)	0.250000	0.16946 (2)	0.00542 (3)
Ru4A	0.1834 (2)	0.250000	0.02174 (3)	0.00665 (15)	0.933 (16)
Ru4B	0.1655 (15)	0.250000	0.0209 (4)	0.0036 (13)*	0.067 (16)
Ru5A	0.42722 (8)	0.0630 (2)	0.38435 (7)	0.00501 (13)	0.74 (2)
Ru5B	0.4253 (3)	0.0509 (5)	0.3844 (2)	0.0052 (4)*	0.26 (2)
Ru6	0.17223 (2)	0.06068 (2)	0.25159 (2)	0.00500 (3)
Ru7	0.15518 (2)	0.05637 (2)	0.52078 (2)	0.00672 (3)
Si8	0.20752 (4)	0.250000	0.31440 (3)	0.00625 (11)
Si9A	0.37913 (7)	0.250000	0.62569 (5)	0.0103 (3)	0.727 (3)
Si9B	0.43672 (17)	0.250000	0.59893 (13)	0.0095 (7)	0.273 (3)
Si10A	0.3512 (4)	0.250000	0.38677 (9)	0.0081 (6)	0.85 (2)
Al10B	0.3758 (16)	0.250000	0.3830 (5)	0.0082 (18)*	0.15 (2)
Al11	0.19544 (4)	0.250000	0.47722 (4)	0.0089 (3)	0.65 (6)
Si11	0.19544 (4)	0.250000	0.47722 (4)	0.0089 (3)	0.35 (6)
Al12	0.48579 (4)	0.250000	0.74245 (4)	0.00666 (12)
Al13	0.16461 (4)	0.250000	0.16972 (4)	0.00748 (12)
Al14	0.08651 (5)	0.250000	0.60711 (4)	0.01395 (15)
Al15	0.33501 (5)	0.250000	0.07842 (5)	0.0183 (3)	0.950 (4)
Si16	0.05763 (3)	0.56298 (4)	0.31273 (2)	0.00608 (8)
Si17	0.41912 (3)	0.56490 (4)	0.26431 (2)	0.00638 (8)
Si18	0.19988 (3)	0.62931 (4)	0.45426 (2)	0.00859 (8)
Si19	0.02383 (3)	0.14871 (4)	0.21915 (2)	0.00739 (8)
Al20	0.21386 (3)	0.63959 (4)	0.30297 (3)	0.0109 (2)	0.55 (5)
Si20	0.21386 (3)	0.63959 (4)	0.30297 (3)	0.0109 (2)	0.45 (5)
Al21	0.42109 (3)	0.04580 (4)	0.12868 (3)	0.0072 (2)	0.64 (5)
Si21	0.42109 (3)	0.04580 (4)	0.12868 (3)	0.0072 (2)	0.36 (5)
Al22	0.33859 (3)	0.11923 (4)	0.51409 (3)	0.0115 (2)	0.67 (5)
Si22	0.33859 (3)	0.11923 (4)	0.51409 (3)	0.0115 (2)	0.33 (5)
Al23	0.33880 (3)	0.12822 (4)	0.25123 (3)	0.00721 (9)
Al24	0.25334 (3)	0.04455 (4)	0.38472 (3)	0.00724 (9)
Al25	0.07288 (3)	0.54572 (4)	0.15156 (3)	0.00777 (9)
Al26	0.08203 (3)	0.13043 (4)	0.38371 (3)	0.00734 (9)
Al27	0.21669 (3)	0.06506 (4)	0.09349 (3)	0.01224 (10)
Al28	0.02308 (3)	0.59649 (5)	0.46632 (3)	0.01334 (10)
Al29A	0.3572 (3)	0.64190 (10)	0.3938 (2)	0.0077 (5)	0.79 (2)
Al29B	0.3742 (7)	0.6377 (5)	0.4074 (7)	0.0109 (11)*	0.21 (2)
Al30A	0.28629 (14)	0.6034 (3)	0.16459 (9)	0.0188 (6)	0.754 (11)
Al30B	0.2701 (3)	0.6380 (5)	0.1547 (2)	0.0136 (8)*	0.246 (11)
Al31A	0.01771 (7)	0.250000	0.07942 (7)	0.0153 (5)	0.728 (5)
Al31B	0.0308 (4)	0.1965 (6)	0.0529 (4)	0.015 (2)*	0.104 (3)
Al31C	0.0457 (8)	0.1351 (13)	0.0372 (7)	0.016 (4)*	0.047 (3)
Al32A	0.06370 (5)	0.06801 (7)	0.01653 (4)	0.0151 (3)	0.716 (3)
Al32B	0.0186 (3)	0.0224 (4)	0.0048 (3)	0.0129 (15)*	0.121 (3)

Atomic displacement parameters (Å²) top

	U¹¹	U²²	U³³	U¹²	U¹³	U²³
Ru1	0.00431 (7)	0.00457 (8)	0.00651 (7)	0.000	−0.00060 (6)	0.000
Ru2	0.00433 (7)	0.00403 (7)	0.00587 (7)	0.000	−0.00033 (5)	0.000
Ru3	0.00414 (7)	0.00694 (8)	0.00517 (7)	0.000	−0.00026 (6)	0.000
Ru4A	0.0081 (5)	0.00790 (13)	0.00392 (11)	0.000	0.00035 (13)	0.000
Ru5A	0.00401 (16)	0.0042 (3)	0.00676 (16)	−0.00089 (18)	0.00098 (7)	−0.00108 (17)
Ru6	0.00449 (5)	0.00601 (6)	0.00452 (5)	−0.00090 (4)	−0.00053 (4)	0.00048 (4)
Ru7	0.00645 (5)	0.00859 (6)	0.00513 (5)	0.00172 (4)	−0.00042 (4)	−0.00090 (4)
Si8	0.0067 (3)	0.0055 (3)	0.0065 (3)	0.000	−0.0001 (2)	0.000
Si9A	0.0154 (5)	0.0066 (4)	0.0088 (4)	0.000	−0.0050 (3)	0.000
Si9B	0.0144 (15)	0.0052 (11)	0.0091 (11)	0.000	−0.0036 (9)	0.000
Si10A	0.0098 (14)	0.0055 (4)	0.0090 (4)	0.000	−0.0013 (4)	0.000
Al11	0.0091 (4)	0.0069 (4)	0.0108 (4)	0.000	−0.0005 (2)	0.000
Si11	0.0091 (4)	0.0069 (4)	0.0108 (4)	0.000	−0.0005 (2)	0.000
Al12	0.0060 (3)	0.0063 (3)	0.0076 (3)	0.000	0.0008 (2)	0.000
Al13	0.0108 (3)	0.0065 (3)	0.0051 (3)	0.000	0.0012 (2)	0.000
Al14	0.0090 (3)	0.0204 (4)	0.0124 (3)	0.000	0.0002 (3)	0.000
Al15	0.0172 (5)	0.0158 (5)	0.0219 (5)	0.000	−0.0147 (3)	0.000
Si16	0.00579 (18)	0.00568 (19)	0.00676 (18)	0.00030 (15)	−0.00049 (14)	−0.00084 (14)
Si17	0.00719 (18)	0.00518 (19)	0.00678 (18)	0.00049 (15)	0.00114 (14)	0.00033 (14)
Si18	0.0088 (2)	0.0083 (2)	0.00861 (19)	0.00025 (16)	−0.00109 (15)	0.00063 (15)
Si19	0.00649 (18)	0.0067 (2)	0.00891 (19)	0.00029 (16)	0.00037 (14)	−0.00100 (15)
Al20	0.0094 (3)	0.0074 (3)	0.0159 (3)	−0.00202 (17)	0.00544 (17)	−0.00150 (17)
Si20	0.0094 (3)	0.0074 (3)	0.0159 (3)	−0.00202 (17)	0.00544 (17)	−0.00150 (17)
Al21	0.0072 (3)	0.0072 (3)	0.0072 (3)	−0.00030 (17)	0.00040 (15)	−0.00223 (16)
Si21	0.0072 (3)	0.0072 (3)	0.0072 (3)	−0.00030 (17)	0.00040 (15)	−0.00223 (16)
Al22	0.0143 (3)	0.0126 (3)	0.0075 (3)	−0.00185 (19)	−0.00166 (17)	0.00134 (17)
Si22	0.0143 (3)	0.0126 (3)	0.0075 (3)	−0.00185 (19)	−0.00166 (17)	0.00134 (17)
Al23	0.0067 (2)	0.0077 (2)	0.0072 (2)	0.00081 (17)	0.00118 (16)	0.00033 (16)
Al24	0.0070 (2)	0.0080 (2)	0.0068 (2)	−0.00033 (17)	−0.00041 (16)	0.00027 (16)
Al25	0.0073 (2)	0.0074 (2)	0.0086 (2)	−0.00030 (17)	0.00002 (16)	0.00109 (17)
Al26	0.0060 (2)	0.0076 (2)	0.0085 (2)	−0.00025 (17)	−0.00033 (16)	0.00000 (16)
Al27	0.0154 (2)	0.0077 (2)	0.0135 (2)	−0.0003 (2)	0.00641 (19)	−0.00069 (18)
Al28	0.0115 (2)	0.0150 (3)	0.0135 (2)	−0.0029 (2)	0.00047 (18)	0.00552 (19)
Al29A	0.0139 (8)	0.0046 (4)	0.0047 (6)	0.0026 (3)	0.0010 (6)	−0.0011 (3)
Al30A	0.0182 (6)	0.0278 (11)	0.0103 (4)	−0.0093 (7)	0.0000 (4)	−0.0088 (5)
Al31A	0.0090 (5)	0.0215 (9)	0.0155 (6)	0.000	−0.0021 (4)	0.000
Al32A	0.0167 (5)	0.0181 (5)	0.0105 (4)	0.0000 (3)	0.0052 (3)	0.0019 (3)

Geometric parameters (Å, º) top

Ru1—Si17ⁱ	2.4453 (4)	Si9B—Al25ⁱⁱ	2.5876 (10)
Ru1—Si17ⁱⁱ	2.4453 (4)	Si9B—Al25ⁱ	2.5876 (10)
Ru1—Al12ⁱⁱⁱ	2.5063 (7)	Si10A—Al31A^vi	2.576 (5)
Ru1—Al20ⁱⁱ	2.5113 (5)	Si10A—Al22^vii	2.6631 (16)
Ru1—Al20ⁱ	2.5113 (5)	Si10A—Al22	2.6631 (16)
Ru1—Al30Bⁱ	2.534 (3)	Si10A—Al23^vii	2.7183 (11)
Ru1—Al30Bⁱⁱ	2.534 (3)	Si10A—Al23	2.7183 (11)
Ru1—Al30Aⁱ	2.5661 (12)	Si10A—Al11	2.803 (5)
Ru1—Al30Aⁱⁱ	2.5661 (12)	Al10B—Al31A^vi	2.23 (2)
Ru1—Al29Aⁱⁱ	2.585 (4)	Al10B—Al31B^v	2.65 (2)
Ru1—Al29Aⁱ	2.585 (4)	Al10B—Al31B^vi	2.65 (2)
Ru1—Al14	2.7932 (7)	Al10B—Al23^vii	2.716 (7)
Ru2—Si16ⁱ	2.5220 (4)	Al10B—Al23	2.716 (7)
Ru2—Si16ⁱⁱ	2.5220 (4)	Al10B—Al22^vii	2.766 (10)
Ru2—Al12	2.5516 (6)	Al10B—Al22	2.766 (10)
Ru2—Si18ⁱ	2.5536 (5)	Al11—Al26^vii	2.7287 (7)
Ru2—Si18ⁱⁱ	2.5536 (4)	Al11—Al26	2.7288 (7)
Ru2—Al28ⁱⁱ	2.5649 (5)	Al11—Al22^vii	2.7310 (7)
Ru2—Al28ⁱ	2.5649 (5)	Al11—Al22	2.7310 (7)
Ru2—Al20ⁱ	2.6150 (5)	Al11—Al14	2.7447 (9)
Ru2—Al20ⁱⁱ	2.6150 (5)	Al12—Si16ⁱⁱ	2.6025 (5)
Ru2—Al14^iv	2.6640 (7)	Al12—Si16ⁱ	2.6025 (5)
Ru3—Al15	2.3213 (8)	Al12—Si17^xii	2.6263 (6)
Ru3—Si19^v	2.4975 (4)	Al12—Si17^xiii	2.6263 (6)
Ru3—Si19^vi	2.4975 (4)	Al12—Al14^iv	2.9652 (10)
Ru3—Al21^vii	2.5582 (5)	Al13—Si19^vii	2.5792 (7)
Ru3—Al21	2.5582 (5)	Al13—Si19	2.5793 (7)
Ru3—Al26^v	2.6041 (5)	Al13—Al27	2.6650 (6)
Ru3—Al26^vi	2.6041 (5)	Al13—Al27^vii	2.6650 (6)
Ru3—Al23^vii	2.6124 (5)	Al13—Al31A	2.6914 (12)
Ru3—Al23	2.6124 (5)	Al13—Al31B	2.896 (6)
Ru4A—Al31B	2.445 (6)	Al13—Al31B^vii	2.896 (6)
Ru4A—Al31B^vii	2.445 (6)	Al14—Al30Bⁱⁱ	2.663 (3)
Ru4A—Al15	2.479 (3)	Al14—Al30Bⁱ	2.663 (3)
Ru4A—Al31C^vii	2.498 (12)	Al14—Al28^xi	2.7563 (7)
Ru4A—Al31C	2.498 (12)	Al14—Al28^xiv	2.7563 (7)
Ru4A—Al29B^viii	2.505 (6)	Al14—Al30Aⁱⁱ	2.7665 (17)
Ru4A—Al29B^ix	2.505 (6)	Al14—Al30Aⁱ	2.7665 (16)
Ru4A—Al13	2.5211 (8)	Al15—Si18^viii	2.5976 (8)
Ru4A—Si18^ix	2.541 (2)	Al15—Si18^ix	2.5976 (8)
Ru4A—Si18^viii	2.541 (2)	Al15—Al27^vii	2.8406 (7)
Ru4A—Al27	2.5588 (9)	Al15—Al27	2.8406 (7)
Ru4A—Al27^vii	2.5588 (9)	Al15—Al21	2.8784 (6)
Ru4B—Al31B	2.20 (2)	Al15—Al21^vii	2.8784 (6)
Ru4B—Al31B^vii	2.20 (2)	Si16—Si17^xv	2.4623 (6)
Ru4B—Al31C^vii	2.28 (2)	Si16—Al20	2.5307 (6)
Ru4B—Al31C	2.28 (2)	Si16—Al26^vii	2.6175 (6)
Ru4B—Al29B^viii	2.413 (11)	Si16—Al21^xvi	2.6250 (6)
Ru4B—Al29B^ix	2.413 (11)	Si16—Al28	2.6816 (6)
Ru4B—Al31A	2.44 (2)	Si16—Al25	2.7456 (6)
Ru4B—Al13	2.520 (7)	Si17—Al29A	2.5512 (15)
Ru4B—Al29A^viii	2.529 (7)	Si17—Al23^vii	2.6024 (6)
Ru4B—Al29A^ix	2.529 (7)	Si17—Al21^vii	2.6456 (6)
Ru4B—Al27	2.632 (8)	Si17—Al30A	2.659 (3)
Ru4B—Al27^vii	2.632 (8)	Si17—Al29B	2.660 (8)
Ru5A—Al10B	2.352 (9)	Si17—Al25^vi	2.7306 (6)
Ru5A—Al32B^vi	2.377 (5)	Si18—Al24^vii	2.5092 (6)
Ru5A—Al31C^vi	2.385 (12)	Si18—Al20	2.5727 (6)
Ru5A—Al32B^x	2.419 (5)	Si18—Al29A	2.589 (3)
Ru5A—Al31B^vi	2.466 (6)	Si18—Al28	2.7022 (7)
Ru5A—Si19^vi	2.4958 (19)	Si18—Al29B	2.748 (7)
Ru5A—Si10A	2.499 (4)	Si18—Al27^xvii	2.7785 (6)
Ru5A—Si17^vii	2.5395 (19)	Si19—Si19^vii	2.4048 (9)
Ru5A—Al29B^vii	2.543 (7)	Si19—Al31A	2.6552 (12)
Ru5A—Al25^v	2.6190 (16)	Si19—Al25^vii	2.6803 (6)
Ru5A—Al24	2.6311 (14)	Si19—Al23^xv	2.8453 (6)
Ru5A—Al29A^vii	2.656 (4)	Si19—Al31B	2.874 (6)
Ru5B—Al32B^vi	2.368 (6)	Al20—Al30A	2.6202 (10)
Ru5B—Al32B^x	2.372 (6)	Al20—Al20^xviii	2.6215 (10)
Ru5B—Al29B^vii	2.400 (9)	Al20—Al30B	2.650 (3)
Ru5B—Si17^vii	2.456 (5)	Al20—Al29A	2.653 (6)
Ru5B—Al31C^vi	2.460 (13)	Al20—Al24^vii	2.6549 (7)
Ru5B—Al10B	2.479 (9)	Al20—Al29B	2.996 (14)
Ru5B—Al29A^vii	2.513 (7)	Al21—Al23	2.6080 (6)
Ru5B—Si19^vi	2.575 (5)	Al21—Al26^vi	2.6350 (6)
Ru5B—Al25^v	2.576 (4)	Al21—Al30A^vii	2.764 (3)
Ru5B—Al31B^vi	2.578 (8)	Al21—Al28^v	2.7938 (7)
Ru5B—Al24	2.594 (4)	Al21—Al28^viii	2.9369 (7)
Ru5B—Si10A	2.615 (6)	Al22—Al32A^x	2.6670 (10)
Ru6—Si16^vii	2.4926 (4)	Al22—Al24	2.6898 (6)
Ru6—Si19	2.5300 (4)	Al22—Al27^x	2.6996 (7)
Ru6—Si8	2.5426 (3)	Al22—Al32B^x	2.737 (5)
Ru6—Al24	2.5715 (5)	Al23—Al24	2.7846 (6)
Ru6—Al25^vii	2.5898 (5)	Al24—Al29A^vii	2.716 (3)
Ru6—Al20^vii	2.6083 (5)	Al24—Al26	2.7772 (6)
Ru6—Al23	2.6367 (5)	Al25—Al32A^vii	2.6586 (8)
Ru6—Al13	2.6429 (4)	Al25—Al27^vii	2.7200 (7)
Ru6—Al26	2.7455 (5)	Al25—Al32B^vii	2.738 (4)
Ru6—Al27	2.7596 (5)	Al26—Al26^vii	2.8388 (10)
Ru6—Al30A^vii	2.987 (2)	Al27—Al30A^vii	2.5594 (16)
Ru7—Al21^x	2.4760 (5)	Al27—Al32A	2.6497 (10)
Ru7—Al11	2.4892 (3)	Al27—Al30B^vii	2.744 (4)
Ru7—Si18^vii	2.5655 (5)	Al28—Al28^xiv	2.6519 (10)
Ru7—Al30Aⁱ	2.6492 (8)	Al29A—Al32A^xvii	2.551 (5)
Ru7—Al27^x	2.7068 (5)	Al29A—Al29A^xviii	2.567 (2)
Ru7—Al30Bⁱ	2.711 (3)	Al29A—Al29B^xviii	2.639 (6)
Ru7—Al26	2.7156 (5)	Al29B—Al32A^xvii	2.229 (14)
Ru7—Al28^xi	2.7385 (5)	Al29B—Al31C^xvii	2.507 (19)
Ru7—Al24	2.7416 (5)	Al29B—Al29B^xviii	2.666 (12)
Ru7—Al28^vii	2.8479 (5)	Al29B—Al32B^xvii	2.684 (15)
Ru7—Al22	2.8669 (5)	Al30A—Al30B	0.507 (4)
Si8—Si10A	2.489 (5)	Al30B—Al30B^xviii	2.659 (12)
Si8—Al13	2.5334 (8)	Al31A—Al31B^vii	0.802 (8)
Si8—Al26^vii	2.6404 (7)	Al31A—Al31B	0.802 (8)
Si8—Al26	2.6404 (7)	Al31A—Al31C	1.596 (16)
Si8—Al23^vii	2.6744 (7)	Al31A—Al31C^vii	1.596 (16)
Si8—Al23	2.6744 (7)	Al31A—Al32A^vii	2.5064 (11)
Si8—Al11	2.7624 (9)	Al31A—Al32A	2.5064 (11)
Si8—Al10B	2.79 (2)	Al31B—Al31C	0.808 (15)
Si8—Al24^vii	2.8005 (5)	Al31B—Al31B^vii	1.269 (15)
Si9A—Si9B	0.979 (3)	Al31B—Al32A	1.718 (8)
Si9A—Al22^vii	2.5205 (8)	Al31B—Al31C^vii	2.028 (19)
Si9A—Al22	2.5205 (8)	Al31B—Al32B	2.229 (9)
Si9A—Al12	2.5484 (10)	Al31C—Al32A	0.912 (16)
Si9A—Al25ⁱⁱ	2.5683 (6)	Al31C—Al32B	1.503 (16)
Si9A—Al25ⁱ	2.5683 (6)	Al31C—Al32B^xix	2.223 (15)
Si9A—Al30Bⁱ	2.659 (7)	Al31C—Al31C^vii	2.73 (3)
Si9A—Al30Bⁱⁱ	2.659 (7)	Al32A—Al32B	0.892 (4)
Si9B—Al12	2.540 (2)	Al32A—Al32B^xix	1.680 (5)
Si9B—Al22^vii	2.5812 (19)	Al32A—Al32A^xix	2.5713 (17)
Si9B—Al22	2.5812 (19)	Al32B—Al32B^xix	0.790 (9)

Si17ⁱ—Ru1—Si17ⁱⁱ	127.96 (2)	Ru2^ix—Si18—Al15ⁱⁱ	88.28 (2)
Si17ⁱ—Ru1—Al12ⁱⁱⁱ	64.049 (11)	Ru7^vii—Si18—Al15ⁱⁱ	93.755 (17)
Si17ⁱⁱ—Ru1—Al12ⁱⁱⁱ	64.049 (11)	Al20—Si18—Al15ⁱⁱ	142.75 (2)
Si17ⁱ—Ru1—Al20ⁱⁱ	144.754 (15)	Al29A—Si18—Al15ⁱⁱ	118.30 (8)
Si17ⁱⁱ—Ru1—Al20ⁱⁱ	83.029 (15)	Al24^vii—Si18—Al28	103.52 (2)
Al12ⁱⁱⁱ—Ru1—Al20ⁱⁱ	144.381 (13)	Ru4Aⁱⁱ—Si18—Al28	136.96 (5)
Si17ⁱ—Ru1—Al20ⁱ	83.029 (15)	Ru2^ix—Si18—Al28	58.339 (14)
Si17ⁱⁱ—Ru1—Al20ⁱ	144.754 (15)	Ru7^vii—Si18—Al28	65.395 (15)
Al12ⁱⁱⁱ—Ru1—Al20ⁱ	144.381 (14)	Al20—Si18—Al28	99.38 (2)
Al20ⁱⁱ—Ru1—Al20ⁱ	62.92 (2)	Al29A—Si18—Al28	160.49 (10)
Si17ⁱ—Ru1—Al30Bⁱ	75.28 (17)	Al15ⁱⁱ—Si18—Al28	79.54 (2)
Si17ⁱⁱ—Ru1—Al30Bⁱ	133.55 (13)	Al24^vii—Si18—Ru4Bⁱⁱ	112.7 (3)
Al12ⁱⁱⁱ—Ru1—Al30Bⁱ	116.43 (11)	Ru4Aⁱⁱ—Si18—Ru4Bⁱⁱ	4.2 (3)
Al20ⁱⁱ—Ru1—Al30Bⁱ	95.71 (13)	Ru2^ix—Si18—Ru4Bⁱⁱ	113.67 (18)
Al20ⁱ—Ru1—Al30Bⁱ	63.37 (8)	Ru7^vii—Si18—Ru4Bⁱⁱ	117.73 (11)
Si17ⁱ—Ru1—Al30Bⁱⁱ	133.55 (13)	Al20—Si18—Ru4Bⁱⁱ	109.0 (2)
Si17ⁱⁱ—Ru1—Al30Bⁱⁱ	75.28 (17)	Al29A—Si18—Ru4Bⁱⁱ	56.7 (3)
Al12ⁱⁱⁱ—Ru1—Al30Bⁱⁱ	116.43 (11)	Al15ⁱⁱ—Si18—Ru4Bⁱⁱ	61.8 (3)
Al20ⁱⁱ—Ru1—Al30Bⁱⁱ	63.37 (8)	Al28—Si18—Ru4Bⁱⁱ	141.1 (3)
Al20ⁱ—Ru1—Al30Bⁱⁱ	95.71 (13)	Al24^vii—Si18—Al29B	65.62 (12)
Al30Bⁱ—Ru1—Al30Bⁱⁱ	63.3 (3)	Ru4Aⁱⁱ—Si18—Al29B	56.4 (2)
Si17ⁱ—Ru1—Al30Aⁱ	64.04 (9)	Ru2^ix—Si18—Al29B	117.2 (3)
Si17ⁱⁱ—Ru1—Al30Aⁱ	141.35 (6)	Ru7^vii—Si18—Al29B	114.16 (19)
Al12ⁱⁱⁱ—Ru1—Al30Aⁱ	110.24 (6)	Al20—Si18—Al29B	68.5 (3)
Al20ⁱⁱ—Ru1—Al30Aⁱ	103.90 (7)	Al29A—Si18—Al29B	6.68 (19)
Al20ⁱ—Ru1—Al30Aⁱ	62.12 (2)	Al15ⁱⁱ—Si18—Al29B	114.0 (2)
Al30Bⁱ—Ru1—Al30Aⁱ	11.38 (9)	Al28—Si18—Al29B	166.2 (2)
Al30Bⁱⁱ—Ru1—Al30Aⁱ	74.4 (3)	Ru4Bⁱⁱ—Si18—Al29B	52.3 (4)
Si17ⁱ—Ru1—Al30Aⁱⁱ	141.35 (6)	Al24^vii—Si18—Al27^xvii	91.53 (2)
Si17ⁱⁱ—Ru1—Al30Aⁱⁱ	64.04 (9)	Ru4Aⁱⁱ—Si18—Al27^xvii	57.299 (16)
Al12ⁱⁱⁱ—Ru1—Al30Aⁱⁱ	110.24 (6)	Ru2^ix—Si18—Al27^xvii	151.80 (2)
Al20ⁱⁱ—Ru1—Al30Aⁱⁱ	62.12 (2)	Ru7^vii—Si18—Al27^xvii	60.707 (14)
Al20ⁱ—Ru1—Al30Aⁱⁱ	103.90 (7)	Al20—Si18—Al27^xvii	145.13 (2)
Al30Bⁱ—Ru1—Al30Aⁱⁱ	74.4 (3)	Al29A—Si18—Al27^xvii	86.36 (11)
Al30Bⁱⁱ—Ru1—Al30Aⁱⁱ	11.38 (9)	Al15ⁱⁱ—Si18—Al27^xvii	63.69 (2)
Al30Aⁱ—Ru1—Al30Aⁱⁱ	85.39 (18)	Al28—Si18—Al27^xvii	110.06 (2)
Si17ⁱ—Ru1—Al29Aⁱⁱ	113.93 (8)	Ru4Bⁱⁱ—Si18—Al27^xvii	57.10 (11)
Si17ⁱⁱ—Ru1—Al29Aⁱⁱ	60.88 (3)	Al29B—Si18—Al27^xvii	79.7 (3)
Al12ⁱⁱⁱ—Ru1—Al29Aⁱⁱ	88.24 (10)	Si19^vii—Si19—Ru5A^xv	114.07 (6)
Al20ⁱⁱ—Ru1—Al29Aⁱⁱ	62.72 (10)	Si19^vii—Si19—Ru3^xv	61.220 (10)
Al20ⁱ—Ru1—Al29Aⁱⁱ	93.44 (7)	Ru5A^xv—Si19—Ru3^xv	117.82 (4)
Al30Bⁱ—Ru1—Al29Aⁱⁱ	154.64 (12)	Si19^vii—Si19—Ru6	114.396 (10)
Al30Bⁱⁱ—Ru1—Al29Aⁱⁱ	112.49 (16)	Ru5A^xv—Si19—Ru6	120.02 (5)
Al30Aⁱ—Ru1—Al29Aⁱⁱ	155.48 (6)	Ru3^xv—Si19—Ru6	115.378 (16)
Al30Aⁱⁱ—Ru1—Al29Aⁱⁱ	103.68 (10)	Si19^vii—Si19—Ru5B^xv	116.81 (12)
Si17ⁱ—Ru1—Al29Aⁱ	60.88 (3)	Ru5A^xv—Si19—Ru5B^xv	2.78 (10)
Si17ⁱⁱ—Ru1—Al29Aⁱ	113.93 (8)	Ru3^xv—Si19—Ru5B^xv	118.33 (8)
Al12ⁱⁱⁱ—Ru1—Al29Aⁱ	88.24 (10)	Ru6—Si19—Ru5B^xv	118.15 (10)
Al20ⁱⁱ—Ru1—Al29Aⁱ	93.44 (7)	Si19^vii—Si19—Al13	62.212 (12)
Al20ⁱ—Ru1—Al29Aⁱ	62.72 (10)	Ru5A^xv—Si19—Al13	116.28 (4)
Al30Bⁱ—Ru1—Al29Aⁱ	112.49 (15)	Ru3^xv—Si19—Al13	112.756 (19)
Al30Bⁱⁱ—Ru1—Al29Aⁱ	154.64 (12)	Ru6—Si19—Al13	62.290 (14)
Al30Aⁱ—Ru1—Al29Aⁱ	103.68 (10)	Ru5B^xv—Si19—Al13	117.66 (10)
Al30Aⁱⁱ—Ru1—Al29Aⁱ	155.48 (6)	Si19^vii—Si19—Al31A	63.073 (15)
Al29Aⁱⁱ—Ru1—Al29Aⁱ	59.54 (7)	Ru5A^xv—Si19—Al31A	62.54 (5)
Si17ⁱ—Ru1—Al14	82.158 (12)	Ru3^xv—Si19—Al31A	116.05 (2)
Si17ⁱⁱ—Ru1—Al14	82.158 (12)	Ru6—Si19—Al31A	114.28 (3)
Al12ⁱⁱⁱ—Ru1—Al14	67.80 (2)	Ru5B^xv—Si19—Al31A	65.01 (12)
Al20ⁱⁱ—Ru1—Al14	123.122 (17)	Al13—Si19—Al31A	61.86 (3)
Al20ⁱ—Ru1—Al14	123.122 (17)	Si19^vii—Si19—Al25^vii	149.448 (13)
Al30Bⁱ—Ru1—Al14	59.76 (8)	Ru5A^xv—Si19—Al25^vii	60.67 (5)
Al30Bⁱⁱ—Ru1—Al14	59.76 (8)	Ru3^xv—Si19—Al25^vii	149.29 (2)
Al30Aⁱ—Ru1—Al14	61.99 (3)	Ru6—Si19—Al25^vii	59.526 (14)
Al30Aⁱⁱ—Ru1—Al14	61.99 (3)	Ru5B^xv—Si19—Al25^vii	58.67 (10)
Al29Aⁱⁱ—Ru1—Al14	142.33 (5)	Al13—Si19—Al25^vii	92.054 (18)
Al29Aⁱ—Ru1—Al14	142.33 (5)	Al31A—Si19—Al25^vii	91.10 (2)
Si16ⁱ—Ru2—Si16ⁱⁱ	123.36 (2)	Si19^vii—Si19—Al23^xv	94.905 (13)
Si16ⁱ—Ru2—Al12	61.718 (10)	Ru5A^xv—Si19—Al23^xv	61.08 (3)
Si16ⁱⁱ—Ru2—Al12	61.718 (10)	Ru3^xv—Si19—Al23^xv	58.108 (13)
Si16ⁱ—Ru2—Si18ⁱ	81.434 (14)	Ru6—Si19—Al23^xv	142.54 (2)
Si16ⁱⁱ—Ru2—Si18ⁱ	147.022 (15)	Ru5B^xv—Si19—Al23^xv	61.03 (8)
Al12—Ru2—Si18ⁱ	138.220 (13)	Al13—Si19—Al23^xv	154.71 (2)
Si16ⁱ—Ru2—Si18ⁱⁱ	147.022 (15)	Al31A—Si19—Al23^xv	99.30 (3)
Si16ⁱⁱ—Ru2—Si18ⁱⁱ	81.434 (14)	Al25^vii—Si19—Al23^xv	105.80 (2)
Al12—Ru2—Si18ⁱⁱ	138.220 (13)	Si19^vii—Si19—Al31B	78.60 (16)
Si18ⁱ—Ru2—Si18ⁱⁱ	68.26 (2)	Ru5A^xv—Si19—Al31B	54.13 (13)
Si16ⁱ—Ru2—Al28ⁱⁱ	143.769 (17)	Ru3^xv—Si19—Al31B	131.36 (16)
Si16ⁱⁱ—Ru2—Al28ⁱⁱ	63.620 (15)	Ru6—Si19—Al31B	105.19 (13)
Al12—Ru2—Al28ⁱⁱ	110.636 (16)	Ru5B^xv—Si19—Al31B	56.15 (17)
Si18ⁱ—Ru2—Al28ⁱⁱ	110.775 (16)	Al13—Si19—Al31B	63.90 (11)
Si18ⁱⁱ—Ru2—Al28ⁱⁱ	63.730 (15)	Al31A—Si19—Al31B	16.07 (16)
Si16ⁱ—Ru2—Al28ⁱ	63.620 (15)	Al25^vii—Si19—Al31B	75.04 (16)
Si16ⁱⁱ—Ru2—Al28ⁱ	143.769 (17)	Al23^xv—Si19—Al31B	103.02 (11)
Al12—Ru2—Al28ⁱ	110.636 (16)	Ru1^ix—Al20—Si16	162.93 (2)
Si18ⁱ—Ru2—Al28ⁱ	63.730 (15)	Ru1^ix—Al20—Si18	111.67 (2)
Si18ⁱⁱ—Ru2—Al28ⁱ	110.775 (16)	Si16—Al20—Si18	80.894 (18)
Al28ⁱⁱ—Ru2—Al28ⁱ	90.55 (2)	Ru1^ix—Al20—Ru6^vii	125.197 (19)
Si16ⁱ—Ru2—Al20ⁱ	58.997 (14)	Si16—Al20—Ru6^vii	58.004 (14)
Si16ⁱⁱ—Ru2—Al20ⁱ	111.555 (15)	Si18—Al20—Ru6^vii	105.61 (2)
Al12—Ru2—Al20ⁱ	83.470 (17)	Ru1^ix—Al20—Ru2^ix	116.882 (18)
Si18ⁱ—Ru2—Al20ⁱ	59.691 (15)	Si16—Al20—Ru2^ix	58.669 (14)
Si18ⁱⁱ—Ru2—Al20ⁱ	93.313 (15)	Si18—Al20—Ru2^ix	58.968 (14)
Al28ⁱⁱ—Ru2—Al20ⁱ	156.733 (17)	Ru6^vii—Al20—Ru2^ix	116.420 (18)
Al28ⁱ—Ru2—Al20ⁱ	101.912 (16)	Ru1^ix—Al20—Al30A	59.97 (3)
Si16ⁱ—Ru2—Al20ⁱⁱ	111.555 (15)	Si16—Al20—Al30A	112.80 (3)
Si16ⁱⁱ—Ru2—Al20ⁱⁱ	58.997 (14)	Si18—Al20—Al30A	156.41 (9)
Al12—Ru2—Al20ⁱⁱ	83.470 (17)	Ru6^vii—Al20—Al30A	69.68 (6)
Si18ⁱ—Ru2—Al20ⁱⁱ	93.313 (15)	Ru2^ix—Al20—Al30A	144.39 (9)
Si18ⁱⁱ—Ru2—Al20ⁱⁱ	59.691 (15)	Ru1^ix—Al20—Al20^xviii	58.538 (11)
Al28ⁱⁱ—Ru2—Al20ⁱⁱ	101.912 (16)	Si16—Al20—Al20^xviii	111.059 (14)
Al28ⁱ—Ru2—Al20ⁱⁱ	156.733 (17)	Si18—Al20—Al20^xviii	92.718 (15)
Al20ⁱ—Ru2—Al20ⁱⁱ	60.16 (2)	Ru6^vii—Al20—Al20^xviii	155.712 (11)
Si16ⁱ—Ru2—Al14^iv	81.602 (12)	Ru2^ix—Al20—Al20^xviii	59.918 (10)
Si16ⁱⁱ—Ru2—Al14^iv	81.602 (12)	Al30A—Al20—Al20^xviii	99.43 (8)
Al12—Ru2—Al14^iv	69.26 (2)	Ru1^ix—Al20—Al30B	58.73 (7)
Si18ⁱ—Ru2—Al14^iv	126.881 (15)	Si16—Al20—Al30B	110.92 (8)
Si18ⁱⁱ—Ru2—Al14^iv	126.881 (15)	Si18—Al20—Al30B	165.71 (13)
Al28ⁱⁱ—Ru2—Al14^iv	63.592 (15)	Ru6^vii—Al20—Al30B	75.79 (10)
Al28ⁱ—Ru2—Al14^iv	63.592 (15)	Ru2^ix—Al20—Al30B	133.67 (16)
Al20ⁱ—Ru2—Al14^iv	139.634 (15)	Al30A—Al20—Al30B	11.01 (8)
Al20ⁱⁱ—Ru2—Al14^iv	139.634 (15)	Al20^xviii—Al20—Al30B	90.41 (13)
Al15—Ru3—Si19^v	146.524 (15)	Ru1^ix—Al20—Al29A	60.00 (3)
Al15—Ru3—Si19^vi	146.524 (15)	Si16—Al20—Al29A	136.44 (3)
Si19^v—Ru3—Si19^vi	57.56 (2)	Si18—Al20—Al29A	59.37 (3)
Al15—Ru3—Al21^vii	72.113 (11)	Ru6^vii—Al20—Al29A	113.50 (3)
Si19^v—Ru3—Al21^vii	79.846 (14)	Ru2^ix—Al20—Al29A	107.50 (3)
Si19^vi—Ru3—Al21^vii	137.403 (15)	Al30A—Al20—Al29A	100.36 (6)
Al15—Ru3—Al21	72.112 (11)	Al20^xviii—Al20—Al29A	89.41 (3)
Si19^v—Ru3—Al21	137.404 (15)	Al30B—Al20—Al29A	106.75 (11)
Si19^vi—Ru3—Al21	79.847 (14)	Ru1^ix—Al20—Al24^vii	113.26 (2)
Al21^vii—Ru3—Al21	142.73 (2)	Si16—Al20—Al24^vii	83.043 (19)
Al15—Ru3—Al26^v	109.98 (2)	Si18—Al20—Al24^vii	57.344 (17)
Si19^v—Ru3—Al26^v	70.039 (14)	Ru6^vii—Al20—Al24^vii	58.487 (14)
Si19^vi—Ru3—Al26^v	100.573 (15)	Ru2^ix—Al20—Al24^vii	108.797 (19)
Al21^vii—Ru3—Al26^v	61.378 (15)	Al30A—Al20—Al24^vii	103.75 (9)
Al21—Ru3—Al26^v	123.640 (16)	Al20^xviii—Al20—Al24^vii	145.427 (14)
Al15—Ru3—Al26^vi	109.98 (2)	Al30B—Al20—Al24^vii	114.60 (16)
Si19^v—Ru3—Al26^vi	100.573 (15)	Al29A—Al20—Al24^vii	61.56 (3)
Si19^vi—Ru3—Al26^vi	70.039 (14)	Ru1^ix—Al20—Al29B	61.22 (13)
Al21^vii—Ru3—Al26^vi	123.640 (16)	Si16—Al20—Al29B	135.26 (13)
Al21—Ru3—Al26^vi	61.378 (15)	Si18—Al20—Al29B	58.55 (11)
Al26^v—Ru3—Al26^vi	66.06 (2)	Ru6^vii—Al20—Al29B	112.61 (11)
Al15—Ru3—Al23^vii	82.61 (2)	Ru2^ix—Al20—Al29B	107.37 (10)
Si19^v—Ru3—Al23^vii	67.631 (14)	Al30A—Al20—Al29B	100.96 (12)
Si19^vi—Ru3—Al23^vii	98.759 (15)	Al20^xviii—Al20—Al29B	90.42 (11)
Al21^vii—Ru3—Al23^vii	60.570 (14)	Al30B—Al20—Al29B	107.52 (16)
Al21—Ru3—Al23^vii	123.873 (15)	Al29A—Al20—Al29B	1.27 (13)
Al26^v—Ru3—Al23^vii	111.863 (15)	Al24^vii—Al20—Al29B	60.35 (12)
Al26^vi—Ru3—Al23^vii	167.327 (15)	Ru7^xx—Al21—Ru3	137.97 (2)
Al15—Ru3—Al23	82.61 (2)	Ru7^xx—Al21—Al23	123.35 (2)
Si19^v—Ru3—Al23	98.760 (15)	Ru3—Al21—Al23	60.742 (15)
Si19^vi—Ru3—Al23	67.632 (14)	Ru7^xx—Al21—Si16^v	113.707 (19)
Al21^vii—Ru3—Al23	123.873 (16)	Ru3—Al21—Si16^v	103.294 (18)
Al21—Ru3—Al23	60.570 (14)	Al23—Al21—Si16^v	104.90 (2)
Al26^v—Ru3—Al23	167.328 (15)	Ru7^xx—Al21—Al26^vi	123.77 (2)
Al26^vi—Ru3—Al23	111.862 (15)	Ru3—Al21—Al26^vi	60.167 (15)
Al23^vii—Ru3—Al23	67.20 (2)	Al23—Al21—Al26^vi	111.01 (2)
Al31B—Ru4A—Al31B^vii	30.1 (4)	Si16^v—Al21—Al26^vi	59.684 (17)
Al31B—Ru4A—Al15	141.68 (13)	Ru7^xx—Al21—Si17^vii	113.06 (2)
Al31B^vii—Ru4A—Al15	141.68 (13)	Ru3—Al21—Si17^vii	103.791 (18)
Al31B—Ru4A—Al31C^vii	48.4 (5)	Al23—Al21—Si17^vii	59.380 (16)
Al31B^vii—Ru4A—Al31C^vii	18.8 (3)	Si16^v—Al21—Si17^vii	55.701 (16)
Al15—Ru4A—Al31C^vii	136.5 (3)	Al26^vi—Al21—Si17^vii	105.59 (2)
Al31B—Ru4A—Al31C	18.8 (3)	Ru7^xx—Al21—Al30A^vii	60.44 (5)
Al31B^vii—Ru4A—Al31C	48.4 (5)	Ru3—Al21—Al30A^vii	132.37 (5)
Al15—Ru4A—Al31C	136.5 (3)	Al23—Al21—Al30A^vii	73.48 (6)
Al31C^vii—Ru4A—Al31C	66.2 (7)	Si16^v—Al21—Al30A^vii	100.28 (3)
Al31B—Ru4A—Al29B^viii	72.6 (4)	Al26^vi—Al21—Al30A^vii	159.92 (3)
Al31B^vii—Ru4A—Al29B^viii	88.7 (3)	Si17^vii—Al21—Al30A^vii	58.84 (3)
Al15—Ru4A—Al29B^viii	128.2 (2)	Ru7^xx—Al21—Al28^v	62.275 (15)
Al31C^vii—Ru4A—Al29B^viii	94.8 (3)	Ru3—Al21—Al28^v	129.35 (2)
Al31C—Ru4A—Al29B^viii	60.1 (4)	Al23—Al21—Al28^v	161.21 (2)
Al31B—Ru4A—Al29B^ix	88.7 (3)	Si16^v—Al21—Al28^v	59.224 (16)
Al31B^vii—Ru4A—Al29B^ix	72.6 (4)	Al26^vi—Al21—Al28^v	71.198 (18)
Al15—Ru4A—Al29B^ix	128.2 (2)	Si17^vii—Al21—Al28^v	101.86 (2)
Al31C^vii—Ru4A—Al29B^ix	60.1 (4)	Al30A^vii—Al21—Al28^v	98.28 (5)
Al31C—Ru4A—Al29B^ix	94.8 (3)	Ru7^xx—Al21—Al15	89.143 (19)
Al29B^viii—Ru4A—Al29B^ix	64.3 (3)	Ru3—Al21—Al15	50.129 (15)
Al31B—Ru4A—Al13	71.34 (15)	Al23—Al21—Al15	72.82 (2)
Al31B^vii—Ru4A—Al13	71.34 (15)	Si16^v—Al21—Al15	151.61 (2)
Al15—Ru4A—Al13	73.69 (5)	Al26^vi—Al21—Al15	94.05 (2)
Al31C^vii—Ru4A—Al13	78.6 (3)	Si17^vii—Al21—Al15	132.05 (3)
Al31C—Ru4A—Al13	78.6 (3)	Al30A^vii—Al21—Al15	105.85 (3)
Al29B^viii—Ru4A—Al13	136.8 (3)	Al28^v—Al21—Al15	125.96 (3)
Al29B^ix—Ru4A—Al13	136.8 (3)	Ru7^xx—Al21—Al28^viii	62.811 (15)
Al31B—Ru4A—Si18^ix	153.56 (16)	Ru3—Al21—Al28^viii	90.535 (18)
Al31B^vii—Ru4A—Si18^ix	127.1 (2)	Al23—Al21—Al28^viii	143.52 (2)
Al15—Ru4A—Si18^ix	62.31 (7)	Si16^v—Al21—Al28^viii	103.27 (2)
Al31C^vii—Ru4A—Si18^ix	108.4 (4)	Al26^vi—Al21—Al28^viii	65.378 (17)
Al31C—Ru4A—Si18^ix	158.6 (3)	Si17^vii—Al21—Al28^viii	156.51 (2)
Al29B^viii—Ru4A—Si18^ix	101.1 (3)	Al30A^vii—Al21—Al28^viii	123.23 (5)
Al29B^ix—Ru4A—Si18^ix	66.0 (2)	Al28^v—Al21—Al28^viii	55.06 (2)
Al13—Ru4A—Si18^ix	121.64 (8)	Al15—Al21—Al28^viii	71.34 (2)
Al31B—Ru4A—Si18^viii	127.1 (2)	Si9A—Al22—Si9B	22.09 (6)
Al31B^vii—Ru4A—Si18^viii	153.56 (16)	Si9A—Al22—Ru5A	130.73 (6)
Al15—Ru4A—Si18^viii	62.31 (7)	Si9B—Al22—Ru5A	108.84 (7)
Al31C^vii—Ru4A—Si18^viii	158.6 (3)	Si9A—Al22—Si10A	103.32 (3)
Al31C—Ru4A—Si18^viii	108.4 (4)	Si9B—Al22—Si10A	93.38 (8)
Al29B^viii—Ru4A—Si18^viii	66.0 (2)	Ru5A—Al22—Si10A	56.05 (10)
Al29B^ix—Ru4A—Si18^viii	101.1 (3)	Si9A—Al22—Al32A^x	111.57 (3)
Al13—Ru4A—Si18^viii	121.64 (8)	Si9B—Al22—Al32A^x	100.13 (4)
Si18^ix—Ru4A—Si18^viii	68.65 (6)	Ru5A—Al22—Al32A^x	61.66 (6)
Al31B—Ru4A—Al27	81.93 (16)	Si10A—Al22—Al32A^x	117.32 (9)
Al31B^vii—Ru4A—Al27	107.8 (2)	Si9A—Al22—Ru5B	132.98 (12)
Al15—Ru4A—Al27	68.62 (6)	Si9B—Al22—Ru5B	110.98 (13)
Al31C^vii—Ru4A—Al27	125.6 (4)	Ru5A—Al22—Ru5B	3.10 (10)
Al31C—Ru4A—Al27	69.2 (3)	Si10A—Al22—Ru5B	58.60 (13)
Al29B^viii—Ru4A—Al27	88.75 (18)	Al32A^x—Al22—Ru5B	59.40 (10)
Al29B^ix—Ru4A—Al27	153.02 (17)	Si9A—Al22—Al24	158.31 (3)
Al13—Ru4A—Al27	63.279 (16)	Si9B—Al22—Al24	157.71 (5)
Si18^ix—Ru4A—Al27	124.15 (11)	Ru5A—Al22—Al24	58.96 (3)
Si18^viii—Ru4A—Al27	66.03 (4)	Si10A—Al22—Al24	64.35 (6)
Al31B—Ru4A—Al27^vii	107.8 (2)	Al32A^x—Al22—Al24	90.11 (2)
Al31B^vii—Ru4A—Al27^vii	81.93 (16)	Ru5B—Al22—Al24	57.77 (10)
Al15—Ru4A—Al27^vii	68.62 (6)	Si9A—Al22—Al27^x	101.59 (2)
Al31C^vii—Ru4A—Al27^vii	69.2 (3)	Si9B—Al22—Al27^x	112.79 (4)
Al31C—Ru4A—Al27^vii	125.6 (4)	Ru5A—Al22—Al27^x	111.30 (7)
Al29B^viii—Ru4A—Al27^vii	153.02 (17)	Si10A—Al22—Al27^x	153.82 (6)
Al29B^ix—Ru4A—Al27^vii	88.75 (18)	Al32A^x—Al22—Al27^x	59.17 (2)
Al13—Ru4A—Al27^vii	63.280 (16)	Ru5B—Al22—Al27^x	108.24 (13)
Si18^ix—Ru4A—Al27^vii	66.03 (4)	Al24—Al22—Al27^x	89.47 (2)
Si18^viii—Ru4A—Al27^vii	124.15 (11)	Si9A—Al22—Al11	90.74 (3)
Al27—Ru4A—Al27^vii	118.19 (6)	Si9B—Al22—Al11	103.79 (4)
Al31B—Ru4B—Al31B^vii	33.6 (5)	Ru5A—Al22—Al11	110.59 (4)
Al31B—Ru4B—Al31C^vii	53.9 (7)	Si10A—Al22—Al11	62.61 (12)
Al31B^vii—Ru4B—Al31C^vii	20.7 (4)	Al32A^x—Al22—Al11	156.05 (3)
Al31B—Ru4B—Al31C	20.7 (4)	Ru5B—Al22—Al11	111.75 (8)
Al31B^vii—Ru4B—Al31C	53.9 (7)	Al24—Al22—Al11	67.886 (18)
Al31C^vii—Ru4B—Al31C	73.5 (10)	Al27^x—Al22—Al11	109.29 (2)
Al31B—Ru4B—Al29B^viii	78.9 (6)	Si9A—Al22—Al32B^x	103.33 (10)
Al31B^vii—Ru4B—Al29B^viii	97.3 (8)	Si9B—Al22—Al32B^x	87.15 (11)
Al31C^vii—Ru4B—Al29B^viii	103.3 (8)	Ru5A—Al22—Al32B^x	53.28 (10)
Al31C—Ru4B—Al29B^viii	64.5 (6)	Si10A—Al22—Al32B^x	104.81 (14)
Al31B—Ru4B—Al29B^ix	97.3 (8)	Al32A^x—Al22—Al32B^x	18.94 (9)
Al31B^vii—Ru4B—Al29B^ix	78.9 (6)	Ru5B—Al22—Al32B^x	51.91 (12)
Al31C^vii—Ru4B—Al29B^ix	64.5 (6)	Al24—Al22—Al32B^x	97.29 (10)
Al31C—Ru4B—Al29B^ix	103.3 (8)	Al27^x—Al22—Al32B^x	76.92 (10)
Al29B^viii—Ru4B—Al29B^ix	67.1 (5)	Al11—Al22—Al32B^x	163.34 (9)
Al31B—Ru4B—Al31A	19.0 (3)	Si9A—Al22—Al10B	101.92 (15)
Al31B^vii—Ru4B—Al31A	19.0 (3)	Si9B—Al22—Al10B	89.6 (3)
Al31C^vii—Ru4B—Al31A	39.4 (5)	Ru5A—Al22—Al10B	51.4 (3)
Al31C—Ru4B—Al31A	39.4 (5)	Si10A—Al22—Al10B	7.7 (4)
Al29B^viii—Ru4B—Al31A	95.5 (7)	Al32A^x—Al22—Al10B	111.6 (4)
Al29B^ix—Ru4B—Al31A	95.5 (7)	Ru5B—Al22—Al10B	54.1 (3)
Al31B—Ru4B—Al13	75.4 (4)	Al24—Al22—Al10B	68.2 (3)
Al31B^vii—Ru4B—Al13	75.4 (4)	Al27^x—Al22—Al10B	156.49 (16)
Al31C^vii—Ru4B—Al13	82.8 (5)	Al11—Al22—Al10B	70.0 (5)
Al31C—Ru4B—Al13	82.8 (5)	Al32B^x—Al22—Al10B	98.0 (4)
Al29B^viii—Ru4B—Al13	142.6 (5)	Si17^vii—Al23—Al21	61.029 (17)
Al29B^ix—Ru4B—Al13	142.6 (5)	Si17^vii—Al23—Ru3	103.499 (18)
Al31A—Ru4B—Al13	65.7 (3)	Al21—Al23—Ru3	58.687 (14)
Al31B—Ru4B—Al29A^viii	86.4 (6)	Si17^vii—Al23—Ru6	100.099 (19)
Al31B^vii—Ru4B—Al29A^viii	103.4 (8)	Al21—Al23—Ru6	109.94 (2)
Al31C^vii—Ru4B—Al29A^viii	107.4 (8)	Ru3—Al23—Ru6	141.414 (19)
Al31C—Ru4B—Al29A^viii	72.1 (5)	Si17^vii—Al23—Si8	141.88 (2)
Al29B^viii—Ru4B—Al29A^viii	7.6 (2)	Al21—Al23—Si8	150.82 (2)
Al29B^ix—Ru4B—Al29A^viii	64.5 (3)	Ru3—Al23—Si8	112.858 (19)
Al31A—Ru4B—Al29A^viii	102.8 (7)	Ru6—Al23—Si8	57.201 (13)
Al13—Ru4B—Al29A^viii	148.2 (3)	Si17^vii—Al23—Al10B	107.7 (3)
Al31B—Ru4B—Al29A^ix	103.4 (8)	Al21—Al23—Al10B	139.1 (5)
Al31B^vii—Ru4B—Al29A^ix	86.4 (6)	Ru3—Al23—Al10B	90.5 (4)
Al31C^vii—Ru4B—Al29A^ix	72.1 (5)	Ru6—Al23—Al10B	110.8 (5)
Al31C—Ru4B—Al29A^ix	107.4 (8)	Si8—Al23—Al10B	62.3 (5)
Al29B^viii—Ru4B—Al29A^ix	64.5 (3)	Si17^vii—Al23—Si10A	111.40 (6)
Al29B^ix—Ru4B—Al29A^ix	7.6 (2)	Al21—Al23—Si10A	146.97 (12)
Al31A—Ru4B—Al29A^ix	102.8 (7)	Ru3—Al23—Si10A	96.25 (9)
Al13—Ru4B—Al29A^ix	148.2 (3)	Ru6—Al23—Si10A	103.01 (12)
Al29A^viii—Ru4B—Al29A^ix	61.0 (2)	Si8—Al23—Si10A	54.96 (11)
Al31B—Ru4B—Al27	85.1 (3)	Al10B—Al23—Si10A	7.9 (4)
Al31B^vii—Ru4B—Al27	113.4 (5)	Si17^vii—Al23—Ru5A	56.81 (5)
Al31C^vii—Ru4B—Al27	132.4 (7)	Al21—Al23—Ru5A	108.53 (4)
Al31C—Ru4B—Al27	71.1 (4)	Ru3—Al23—Ru5A	106.29 (5)
Al29B^viii—Ru4B—Al27	89.08 (17)	Ru6—Al23—Ru5A	112.15 (4)
Al29B^ix—Ru4B—Al27	154.9 (4)	Si8—Al23—Ru5A	100.65 (4)
Al31A—Ru4B—Al27	94.5 (3)	Al10B—Al23—Ru5A	51.2 (2)
Al13—Ru4B—Al27	62.25 (17)	Si10A—Al23—Ru5A	54.60 (8)
Al29A^viii—Ru4B—Al27	90.80 (10)	Si17^vii—Al23—Ru5B	54.40 (11)
Al29A^ix—Ru4B—Al27	149.4 (3)	Al21—Al23—Ru5B	107.46 (8)
Al31B—Ru4B—Al27^vii	113.4 (5)	Ru3—Al23—Ru5B	108.24 (11)
Al31B^vii—Ru4B—Al27^vii	85.1 (3)	Ru6—Al23—Ru5B	110.30 (10)
Al31C^vii—Ru4B—Al27^vii	71.1 (4)	Si8—Al23—Ru5B	101.71 (8)
Al31C—Ru4B—Al27^vii	132.4 (7)	Al10B—Al23—Ru5B	53.8 (2)
Al29B^viii—Ru4B—Al27^vii	154.9 (4)	Si10A—Al23—Ru5B	57.00 (12)
Al29B^ix—Ru4B—Al27^vii	89.08 (17)	Ru5A—Al23—Ru5B	2.98 (10)
Al31A—Ru4B—Al27^vii	94.5 (3)	Si17^vii—Al23—Al24	80.338 (18)
Al13—Ru4B—Al27^vii	62.25 (17)	Al21—Al23—Al24	137.05 (2)
Al29A^viii—Ru4B—Al27^vii	149.4 (3)	Ru3—Al23—Al24	157.64 (2)
Al29A^ix—Ru4B—Al27^vii	90.80 (10)	Ru6—Al23—Al24	56.553 (13)
Al27—Ru4B—Al27^vii	113.0 (5)	Si8—Al23—Al24	61.690 (16)
Al10B—Ru5A—Al32B^vi	113.0 (3)	Al10B—Al23—Al24	67.6 (4)
Al10B—Ru5A—Al31C^vi	85.0 (6)	Si10A—Al23—Al24	62.38 (8)
Al32B^vi—Ru5A—Al31C^vi	36.8 (4)	Ru5A—Al23—Al24	56.98 (4)
Al10B—Ru5A—Al32B^x	121.0 (2)	Ru5B—Al23—Al24	55.77 (9)
Al32B^vi—Ru5A—Al32B^x	18.9 (2)	Si17^vii—Al23—Si19^vi	66.662 (17)
Al31C^vi—Ru5A—Al32B^x	55.1 (4)	Al21—Al23—Si19^vi	72.882 (17)
Al10B—Ru5A—Al31B^vi	66.8 (5)	Ru3—Al23—Si19^vi	54.261 (13)
Al32B^vi—Ru5A—Al31B^vi	54.8 (2)	Ru6—Al23—Si19^vi	163.70 (2)
Al31C^vi—Ru5A—Al31B^vi	19.1 (4)	Si8—Al23—Si19^vi	127.53 (2)
Al32B^x—Ru5A—Al31B^vi	72.1 (2)	Al10B—Al23—Si19^vi	67.0 (5)
Al10B—Ru5A—Si19^vi	78.5 (5)	Si10A—Al23—Si19^vi	74.84 (12)
Al32B^vi—Ru5A—Si19^vi	107.37 (12)	Ru5A—Al23—Si19^vi	53.13 (4)
Al31C^vi—Ru5A—Si19^vi	78.9 (3)	Ru5B—Al23—Si19^vi	54.65 (10)
Al32B^x—Ru5A—Si19^vi	124.43 (12)	Al24—Al23—Si19^vi	109.956 (19)
Al31B^vi—Ru5A—Si19^vi	70.77 (16)	Si18^vii—Al24—Ru6	108.644 (19)
Al10B—Ru5A—Si10A	8.2 (5)	Si18^vii—Al24—Ru5B	110.23 (12)
Al32B^vi—Ru5A—Si10A	115.65 (14)	Ru6—Al24—Ru5B	118.14 (8)
Al31C^vi—Ru5A—Si10A	90.9 (4)	Si18^vii—Al24—Ru5A	112.93 (6)
Al32B^x—Ru5A—Si10A	120.89 (13)	Ru6—Al24—Ru5A	117.76 (3)
Al31B^vi—Ru5A—Si10A	73.3 (2)	Ru5B—Al24—Ru5A	3.11 (10)
Si19^vi—Ru5A—Si10A	85.24 (13)	Si18^vii—Al24—Al20^vii	59.685 (17)
Al10B—Ru5A—Si17^vii	122.7 (2)	Ru6—Al24—Al20^vii	59.851 (14)
Al32B^vi—Ru5A—Si17^vii	122.58 (15)	Ru5B—Al24—Al20^vii	104.30 (12)
Al31C^vi—Ru5A—Si17^vii	134.1 (3)	Ru5A—Al24—Al20^vii	106.90 (6)
Al32B^x—Ru5A—Si17^vii	116.12 (16)	Si18^vii—Al24—Al22	92.44 (2)
Al31B^vi—Ru5A—Si17^vii	139.43 (14)	Ru6—Al24—Al22	156.41 (2)
Si19^vi—Ru5A—Si17^vii	73.14 (3)	Ru5B—Al24—Al22	60.94 (9)
Si10A—Ru5A—Si17^vii	121.47 (7)	Ru5A—Al24—Al22	59.89 (3)
Al10B—Ru5A—Al29B^vii	141.5 (6)	Al20^vii—Al24—Al22	143.42 (2)
Al32B^vi—Ru5A—Al29B^vii	82.6 (4)	Si18^vii—Al24—Al29A^vii	59.24 (4)
Al31C^vi—Ru5A—Al29B^vii	119.1 (5)	Ru6—Al24—Al29A^vii	112.61 (10)
Al32B^x—Ru5A—Al29B^vii	65.4 (4)	Ru5B—Al24—Al29A^vii	56.43 (16)
Al31B^vi—Ru5A—Al29B^vii	137.3 (4)	Ru5A—Al24—Al29A^vii	59.53 (11)
Si19^vi—Ru5A—Al29B^vii	132.33 (18)	Al20^vii—Al24—Al29A^vii	59.19 (11)
Si10A—Ru5A—Al29B^vii	133.3 (2)	Al22—Al24—Al29A^vii	86.96 (11)
Si17^vii—Ru5A—Al29B^vii	63.1 (3)	Si18^vii—Al24—Ru7	58.295 (14)
Al10B—Ru5A—Al25^v	137.7 (6)	Ru6—Al24—Ru7	118.408 (17)
Al32B^vi—Ru5A—Al25^v	66.26 (12)	Ru5B—Al24—Ru7	122.67 (8)
Al31C^vi—Ru5A—Al25^v	71.2 (3)	Ru5A—Al24—Ru7	122.40 (3)
Al32B^x—Ru5A—Al25^v	72.90 (12)	Al20^vii—Al24—Ru7	111.042 (19)
Al31B^vi—Ru5A—Al25^v	83.44 (16)	Al22—Al24—Ru7	63.710 (14)
Si19^vi—Ru5A—Al25^v	63.15 (3)	Al29A^vii—Al24—Ru7	107.81 (4)
Si10A—Ru5A—Al25^v	145.72 (16)	Si18^vii—Al24—Al26	90.35 (2)
Si17^vii—Ru5A—Al25^v	63.90 (5)	Ru6—Al24—Al26	61.627 (14)
Al29B^vii—Ru5A—Al25^v	80.65 (16)	Ru5B—Al24—Al26	156.80 (13)
Al10B—Ru5A—Al24	75.5 (6)	Ru5A—Al24—Al26	153.69 (7)
Al32B^vi—Ru5A—Al24	123.97 (13)	Al20^vii—Al24—Al26	95.19 (2)
Al31C^vi—Ru5A—Al24	140.8 (3)	Al22—Al24—Al26	109.18 (2)
Al32B^x—Ru5A—Al24	107.45 (13)	Al29A^vii—Al24—Al26	146.73 (8)
Al31B^vi—Ru5A—Al24	133.11 (16)	Ru7—Al24—Al26	58.949 (13)
Si19^vi—Ru5A—Al24	128.12 (6)	Si18^vii—Al24—Al23	145.37 (2)
Si10A—Ru5A—Al24	67.45 (12)	Ru6—Al24—Al23	58.819 (13)
Si17^vii—Ru5A—Al24	84.51 (5)	Ru5B—Al24—Al23	61.68 (8)
Al29B^vii—Ru5A—Al24	67.0 (2)	Ru5A—Al24—Al23	60.48 (4)
Al25^v—Ru5A—Al24	142.69 (11)	Al20^vii—Al24—Al23	88.534 (19)
Al10B—Ru5A—Al29A^vii	137.2 (6)	Al22—Al24—Al23	108.79 (2)
Al32B^vi—Ru5A—Al29A^vii	89.86 (18)	Al29A^vii—Al24—Al23	93.98 (3)
Al31C^vi—Ru5A—Al29A^vii	126.4 (4)	Ru7—Al24—Al23	155.98 (2)
Al32B^x—Ru5A—Al29A^vii	72.55 (17)	Al26—Al24—Al23	107.13 (2)
Al31B^vi—Ru5A—Al29A^vii	144.5 (2)	Si18^vii—Al24—Si8	146.78 (2)
Si19^vi—Ru5A—Al29A^vii	130.35 (8)	Ru6—Al24—Si8	56.304 (14)
Si10A—Ru5A—Al29A^vii	129.07 (15)	Ru5B—Al24—Si8	102.75 (12)
Si17^vii—Ru5A—Al29A^vii	58.77 (8)	Ru5A—Al24—Si8	99.93 (6)
Al29B^vii—Ru5A—Al29A^vii	7.3 (2)	Al20^vii—Al24—Si8	116.11 (2)
Al25^v—Ru5A—Al29A^vii	84.03 (10)	Al22—Al24—Si8	100.20 (2)
Al24—Ru5A—Al29A^vii	61.83 (10)	Al29A^vii—Al24—Si8	151.16 (3)
Al32B^vi—Ru5B—Al32B^x	19.2 (2)	Ru7—Al24—Si8	100.331 (19)
Al32B^vi—Ru5B—Al29B^vii	85.9 (4)	Al26—Al24—Si8	56.507 (18)
Al32B^x—Ru5B—Al29B^vii	68.5 (4)	Al23—Al24—Si8	57.219 (18)
Al32B^vi—Ru5B—Si17^vii	126.7 (2)	Si9A^ix—Al25—Ru5B^xvi	128.55 (13)
Al32B^x—Ru5B—Si17^vii	121.3 (3)	Si9A^ix—Al25—Si9B^ix	21.90 (6)
Al29B^vii—Ru5B—Si17^vii	66.4 (3)	Ru5B^xvi—Al25—Si9B^ix	106.70 (14)
Al32B^vi—Ru5B—Al31C^vi	36.2 (4)	Si9A^ix—Al25—Ru6^vii	114.15 (3)
Al32B^x—Ru5B—Al31C^vi	54.7 (4)	Ru5B^xvi—Al25—Ru6^vii	115.92 (12)
Al29B^vii—Ru5B—Al31C^vi	121.9 (5)	Si9B^ix—Al25—Ru6^vii	135.61 (6)
Si17^vii—Ru5B—Al31C^vi	134.6 (3)	Si9A^ix—Al25—Ru5A^xvi	131.44 (7)
Al32B^vi—Ru5B—Al10B	108.8 (4)	Ru5B^xvi—Al25—Ru5A^xvi	3.09 (11)
Al32B^x—Ru5B—Al10B	117.8 (3)	Si9B^ix—Al25—Ru5A^xvi	109.56 (8)
Al29B^vii—Ru5B—Al10B	142.6 (6)	Ru6^vii—Al25—Ru5A^xvi	113.37 (6)
Si17^vii—Ru5B—Al10B	120.9 (2)	Si9A^ix—Al25—Al32A^vii	110.33 (3)
Al31C^vi—Ru5B—Al10B	80.8 (6)	Ru5B^xvi—Al25—Al32A^vii	61.68 (10)
Al32B^vi—Ru5B—Al29A^vii	93.6 (2)	Si9B^ix—Al25—Al32A^vii	100.19 (5)
Al32B^x—Ru5B—Al29A^vii	76.0 (2)	Ru6^vii—Al25—Al32A^vii	110.16 (3)
Al29B^vii—Ru5B—Al29A^vii	7.7 (2)	Ru5A^xvi—Al25—Al32A^vii	60.43 (4)
Si17^vii—Ru5B—Al29A^vii	61.77 (15)	Si9A^ix—Al25—Si19^vii	164.51 (3)
Al31C^vi—Ru5B—Al29A^vii	129.6 (4)	Ru5B^xvi—Al25—Si19^vii	58.62 (11)
Al10B—Ru5B—Al29A^vii	138.2 (6)	Si9B^ix—Al25—Si19^vii	159.82 (6)
Al32B^vi—Ru5B—Si19^vi	105.1 (2)	Ru6^vii—Al25—Si19^vii	57.349 (14)
Al32B^x—Ru5B—Si19^vi	123.0 (2)	Ru5A^xvi—Al25—Si19^vii	56.18 (5)
Al29B^vii—Ru5B—Si19^vi	135.8 (3)	Al32A^vii—Al25—Si19^vii	85.14 (2)
Si17^vii—Ru5B—Si19^vi	73.17 (10)	Si9A^ix—Al25—Al27^vii	99.80 (3)
Al31C^vi—Ru5B—Si19^vi	76.0 (3)	Ru5B^xvi—Al25—Al27^vii	112.82 (13)
Al10B—Ru5B—Si19^vi	74.8 (5)	Si9B^ix—Al25—Al27^vii	111.92 (5)
Al29A^vii—Ru5B—Si19^vi	133.56 (19)	Ru6^vii—Al25—Al27^vii	62.571 (15)
Al32B^vi—Ru5B—Al25^v	67.10 (14)	Ru5A^xvi—Al25—Al27^vii	110.28 (5)
Al32B^x—Ru5B—Al25^v	74.45 (15)	Al32A^vii—Al25—Al27^vii	59.01 (2)
Al29B^vii—Ru5B—Al25^v	84.3 (2)	Si19^vii—Al25—Al27^vii	87.59 (2)
Si17^vii—Ru5B—Al25^v	65.67 (11)	Si9A^ix—Al25—Si17^xv	104.45 (3)
Al31C^vi—Ru5B—Al25^v	70.8 (3)	Ru5B^xvi—Al25—Si17^xv	55.05 (10)
Al10B—Ru5B—Al25^v	133.0 (6)	Si9B^ix—Al25—Si17^xv	93.09 (5)
Al29A^vii—Ru5B—Al25^v	87.84 (18)	Ru6^vii—Al25—Si17^xv	100.998 (18)
Si19^vi—Ru5B—Al25^v	62.70 (9)	Ru5A^xvi—Al25—Si17^xv	56.63 (4)
Al32B^vi—Ru5B—Al31B^vi	53.4 (2)	Al32A^vii—Al25—Si17^xv	116.53 (3)
Al32B^x—Ru5B—Al31B^vi	70.9 (2)	Si19^vii—Al25—Si17^xv	67.345 (17)
Al29B^vii—Ru5B—Al31B^vi	139.2 (4)	Al27^vii—Al25—Si17^xv	154.93 (2)
Si17^vii—Ru5B—Al31B^vi	137.7 (2)	Si9A^ix—Al25—Al32B^vii	102.03 (10)
Al31C^vi—Ru5B—Al31B^vi	18.3 (3)	Ru5B^xvi—Al25—Al32B^vii	52.82 (12)
Al10B—Ru5B—Al31B^vi	63.3 (5)	Si9B^ix—Al25—Al32B^vii	87.00 (11)
Al29A^vii—Ru5B—Al31B^vi	146.8 (3)	Ru6^vii—Al25—Al32B^vii	128.48 (10)
Si19^vi—Ru5B—Al31B^vi	67.8 (2)	Ru5A^xvi—Al25—Al32B^vii	52.63 (10)
Al25^v—Ru5B—Al31B^vi	82.13 (19)	Al32A^vii—Al25—Al32B^vii	18.95 (9)
Al32B^vi—Ru5B—Al24	126.01 (19)	Si19^vii—Al25—Al32B^vii	92.89 (10)
Al32B^x—Ru5B—Al24	110.14 (19)	Al27^vii—Al25—Al32B^vii	76.56 (10)
Al29B^vii—Ru5B—Al24	69.6 (3)	Si17^xv—Al25—Al32B^vii	104.12 (10)
Si17^vii—Ru5B—Al24	86.99 (15)	Si9A^ix—Al25—Si16	97.04 (3)
Al31C^vi—Ru5B—Al24	138.4 (3)	Ru5B^xvi—Al25—Si16	101.30 (8)
Al10B—Ru5B—Al24	74.1 (6)	Si9B^ix—Al25—Si16	105.52 (5)
Al29A^vii—Ru5B—Al24	64.23 (16)	Ru6^vii—Al25—Si16	55.609 (13)
Si19^vi—Ru5B—Al24	126.23 (15)	Ru5A^xvi—Al25—Si16	101.37 (3)
Al25^v—Ru5B—Al24	148.3 (3)	Al32A^vii—Al25—Si16	152.62 (3)
Al31B^vi—Ru5B—Al24	129.4 (2)	Si19^vii—Al25—Si16	67.479 (16)
Al32B^vi—Ru5B—Si10A	111.8 (2)	Al27^vii—Al25—Si16	117.52 (2)
Al32B^x—Ru5B—Si10A	118.1 (2)	Si17^xv—Al25—Si16	53.440 (15)
Al29B^vii—Ru5B—Si10A	134.7 (3)	Al32B^vii—Al25—Si16	153.98 (10)
Si17^vii—Ru5B—Si10A	120.13 (14)	Si9A^ix—Al25—Al22^xxi	55.52 (2)
Al31C^vi—Ru5B—Si10A	86.6 (4)	Ru5B^xvi—Al25—Al22^xxi	110.56 (8)
Al10B—Ru5B—Si10A	7.9 (4)	Si9B^ix—Al25—Al22^xxi	56.81 (5)
Al29A^vii—Ru5B—Si10A	130.4 (2)	Ru6^vii—Al25—Al22^xxi	114.61 (2)
Si19^vi—Ru5B—Si10A	81.33 (19)	Ru5A^xvi—Al25—Al22^xxi	110.96 (3)
Al25^v—Ru5B—Si10A	140.8 (3)	Al32A^vii—Al25—Al22^xxi	58.16 (2)
Al31B^vi—Ru5B—Si10A	69.6 (2)	Si19^vii—Al25—Al22^xxi	138.51 (2)
Al24—Ru5B—Si10A	66.34 (15)	Al27^vii—Al25—Al22^xxi	58.274 (17)
Si16^vii—Ru6—Si19	73.752 (14)	Si17^xv—Al25—Al22^xxi	143.73 (2)
Si16^vii—Ru6—Si8	119.473 (16)	Al32B^vii—Al25—Al22^xxi	58.96 (10)
Si19—Ru6—Si8	84.882 (16)	Si16—Al25—Al22^xxi	146.74 (2)
Si16^vii—Ru6—Al24	85.523 (14)	Ru3^xv—Al26—Si16^vii	102.244 (18)
Si19—Ru6—Al24	129.919 (14)	Ru3^xv—Al26—Al21^xv	58.455 (14)
Si8—Ru6—Al24	66.403 (16)	Si16^vii—Al26—Al21^xv	59.966 (17)
Si16^vii—Ru6—Al25^vii	65.368 (14)	Ru3^xv—Al26—Si8	95.784 (19)
Si19—Ru6—Al25^vii	63.124 (14)	Si16^vii—Al26—Si8	111.61 (2)
Si8—Ru6—Al25^vii	145.654 (17)	Al21^xv—Al26—Si8	146.06 (2)
Al24—Ru6—Al25^vii	144.281 (16)	Ru3^xv—Al26—Ru7	141.451 (19)
Si16^vii—Ru6—Al20^vii	59.439 (14)	Si16^vii—Al26—Ru7	99.520 (18)
Si19—Ru6—Al20^vii	131.436 (15)	Al21^xv—Al26—Ru7	108.583 (19)
Si8—Ru6—Al20^vii	128.011 (16)	Si8—Al26—Ru7	105.23 (2)
Al24—Ru6—Al20^vii	61.662 (15)	Ru3^xv—Al26—Al11	113.311 (19)
Al25^vii—Ru6—Al20^vii	84.991 (15)	Si16^vii—Al26—Al11	144.17 (2)
Si16^vii—Ru6—Al23	147.194 (14)	Al21^xv—Al26—Al11	145.26 (2)
Si19—Ru6—Al23	135.764 (15)	Si8—Al26—Al11	61.90 (2)
Si8—Ru6—Al23	62.146 (17)	Ru7—Al26—Al11	54.412 (12)
Al24—Ru6—Al23	64.628 (14)	Ru3^xv—Al26—Ru6	105.140 (16)
Al25^vii—Ru6—Al23	134.258 (15)	Si16^vii—Al26—Ru6	55.329 (13)
Al20^vii—Ru6—Al23	92.788 (15)	Al21^xv—Al26—Ru6	106.047 (19)
Si16^vii—Ru6—Al13	133.510 (18)	Si8—Al26—Ru6	56.299 (13)
Si19—Ru6—Al13	59.769 (18)	Ru7—Al26—Ru6	113.409 (17)
Si8—Ru6—Al13	58.452 (17)	Al11—Al26—Ru6	108.61 (2)
Al24—Ru6—Al13	122.930 (17)	Ru3^xv—Al26—Al24	155.88 (2)
Al25^vii—Ru6—Al13	92.680 (17)	Si16^vii—Al26—Al24	79.141 (18)
Al20^vii—Ru6—Al13	163.833 (17)	Al21^xv—Al26—Al24	135.83 (2)
Al23—Ru6—Al13	77.385 (18)	Si8—Al26—Al24	62.192 (16)
Si16^vii—Ru6—Al26	59.727 (14)	Ru7—Al26—Al24	59.871 (13)
Si19—Ru6—Al26	67.301 (13)	Al11—Al26—Al24	66.696 (18)
Si8—Ru6—Al26	59.762 (16)	Ru6—Al26—Al24	55.497 (13)
Al24—Ru6—Al26	62.875 (14)	Ru3^xv—Al26—Al26^vii	56.970 (11)
Al25^vii—Ru6—Al26	113.153 (15)	Si16^vii—Al26—Al26^vii	151.308 (13)
Al20^vii—Ru6—Al26	97.033 (15)	Al21^xv—Al26—Al26^vii	112.414 (15)
Al23—Ru6—Al26	112.461 (14)	Si8—Al26—Al26^vii	57.481 (12)
Al13—Ru6—Al26	98.582 (17)	Ru7—Al26—Al26^vii	108.889 (11)
Si16^vii—Ru6—Al27	125.610 (15)	Al11—Al26—Al26^vii	58.656 (12)
Si19—Ru6—Al27	89.805 (15)	Ru6—Al26—Al26^vii	107.552 (10)
Si8—Ru6—Al27	109.764 (16)	Al24—Al26—Al26^vii	111.536 (14)
Al24—Ru6—Al27	137.383 (16)	Ru4A—Al27—Al30A^vii	166.95 (10)
Al25^vii—Ru6—Al27	61.026 (15)	Ru4A—Al27—Ru4B	5.8 (4)
Al20^vii—Ru6—Al27	106.387 (15)	Al30A^vii—Al27—Ru4B	172.7 (5)
Al23—Ru6—Al27	76.151 (15)	Ru4A—Al27—Al32A	65.45 (6)
Al13—Ru6—Al27	59.067 (16)	Al30A^vii—Al27—Al32A	126.77 (9)
Al26—Ru6—Al27	154.792 (15)	Ru4B—Al27—Al32A	60.3 (4)
Si16^vii—Ru6—Al30A^vii	102.70 (7)	Ru4A—Al27—Al13	57.67 (2)
Si19—Ru6—Al30A^vii	132.20 (5)	Al30A^vii—Al27—Al13	122.47 (7)
Si8—Ru6—Al30A^vii	131.46 (8)	Ru4B—Al27—Al13	56.81 (15)
Al24—Ru6—Al30A^vii	96.30 (4)	Al32A—Al27—Al13	88.32 (3)
Al25^vii—Ru6—Al30A^vii	72.10 (7)	Ru4A—Al27—Al22^xx	113.48 (4)
Al20^vii—Ru6—Al30A^vii	55.35 (3)	Al30A^vii—Al27—Al22^xx	74.19 (9)
Al23—Ru6—Al30A^vii	69.43 (8)	Ru4B—Al27—Al22^xx	110.7 (3)
Al13—Ru6—Al30A^vii	108.73 (4)	Al32A—Al27—Al22^xx	59.81 (2)
Al26—Ru6—Al30A^vii	152.08 (3)	Al13—Al27—Al22^xx	144.86 (3)
Al27—Ru6—Al30A^vii	52.71 (2)	Ru4A—Al27—Ru7^xx	112.40 (5)
Al21^x—Ru7—Al11	141.649 (18)	Al30A^vii—Al27—Ru7^xx	60.33 (2)
Al21^x—Ru7—Si18^vii	91.431 (15)	Ru4B—Al27—Ru7^xx	116.2 (3)
Al11—Ru7—Si18^vii	126.820 (18)	Al32A—Al27—Ru7^xx	113.89 (2)
Al21^x—Ru7—Al30Aⁱ	65.17 (9)	Al13—Al27—Ru7^xx	150.38 (3)
Al11—Ru7—Al30Aⁱ	89.79 (9)	Al22^xx—Al27—Ru7^xx	64.048 (15)
Si18^vii—Ru7—Al30Aⁱ	119.80 (5)	Ru4A—Al27—Al25^vii	115.47 (7)
Al21^x—Ru7—Al27^x	74.643 (15)	Al30A^vii—Al27—Al25^vii	77.24 (6)
Al11—Ru7—Al27^x	116.895 (19)	Ru4B—Al27—Al25^vii	109.8 (5)
Si18^vii—Ru7—Al27^x	63.540 (14)	Al32A—Al27—Al25^vii	59.34 (2)
Al30Aⁱ—Ru7—Al27^x	57.08 (4)	Al13—Al27—Al25^vii	89.33 (2)
Al21^x—Ru7—Al30Bⁱ	75.60 (15)	Al22^xx—Al27—Al25^vii	62.742 (18)
Al11—Ru7—Al30Bⁱ	79.40 (15)	Ru7^xx—Al27—Al25^vii	118.42 (2)
Si18^vii—Ru7—Al30Bⁱ	124.40 (8)	Ru4A—Al27—Al30B^vii	172.03 (8)
Al30Aⁱ—Ru7—Al30Bⁱ	10.77 (8)	Al30A^vii—Al27—Al30B^vii	10.21 (7)
Al27^x—Ru7—Al30Bⁱ	60.87 (9)	Ru4B—Al27—Al30B^vii	174.26 (18)
Al21^x—Ru7—Al26	126.897 (15)	Al32A—Al27—Al30B^vii	116.91 (14)
Al11—Ru7—Al26	63.063 (18)	Al13—Al27—Al30B^vii	128.85 (10)
Si18^vii—Ru7—Al26	90.562 (14)	Al22^xx—Al27—Al30B^vii	64.32 (14)
Al30Aⁱ—Ru7—Al26	148.47 (7)	Ru7^xx—Al27—Al30B^vii	59.63 (7)
Al27^x—Ru7—Al26	148.316 (15)	Al25^vii—Al27—Al30B^vii	70.90 (10)
Al30Bⁱ—Ru7—Al26	140.15 (13)	Ru4A—Al27—Ru6	115.40 (3)
Al21^x—Ru7—Al28^xi	64.563 (16)	Al30A^vii—Al27—Ru6	68.21 (4)
Al11—Ru7—Al28^xi	95.882 (19)	Ru4B—Al27—Ru6	113.4 (2)
Si18^vii—Ru7—Al28^xi	116.253 (15)	Al32A—Al27—Ru6	105.41 (2)
Al30Aⁱ—Ru7—Al28^xi	102.54 (4)	Al13—Al27—Ru6	58.283 (15)
Al27^x—Ru7—Al28^xi	139.202 (16)	Al22^xx—Al27—Ru6	113.12 (2)
Al30Bⁱ—Ru7—Al28^xi	106.22 (9)	Ru7^xx—Al27—Ru6	127.19 (2)
Al26—Ru7—Al28^xi	67.242 (15)	Al25^vii—Al27—Ru6	56.403 (14)
Al21^x—Ru7—Al24	147.730 (15)	Al30B^vii—Al27—Ru6	71.86 (8)
Al11—Ru7—Al24	70.529 (17)	Ru4A—Al27—Si18^viii	56.67 (4)
Si18^vii—Ru7—Al24	56.314 (14)	Al30A^vii—Al27—Si18^viii	115.33 (3)
Al30Aⁱ—Ru7—Al24	127.09 (6)	Ru4B—Al27—Si18^viii	60.5 (3)
Al27^x—Ru7—Al24	88.245 (15)	Al32A—Al27—Si18^viii	88.48 (2)
Al30Bⁱ—Ru7—Al24	119.75 (13)	Al13—Al27—Si18^viii	108.54 (2)
Al26—Ru7—Al24	61.180 (14)	Al22^xx—Al27—Si18^viii	86.554 (19)
Al28^xi—Ru7—Al24	127.289 (15)	Ru7^xx—Al27—Si18^viii	55.752 (13)
Al21^x—Ru7—Al28^vii	66.535 (15)	Al25^vii—Al27—Si18^viii	143.16 (2)
Al11—Ru7—Al28^vii	131.540 (19)	Al30B^vii—Al27—Si18^viii	115.37 (7)
Si18^vii—Ru7—Al28^vii	59.617 (14)	Ru6—Al27—Si18^viii	159.70 (2)
Al30Aⁱ—Ru7—Al28^vii	131.67 (9)	Ru4A—Al27—Al15	54.37 (6)
Al27^x—Ru7—Al28^vii	107.887 (16)	Al30A^vii—Al27—Al15	112.87 (9)
Al30Bⁱ—Ru7—Al28^vii	142.13 (15)	Ru4B—Al27—Al15	59.8 (4)
Al26—Ru7—Al28^vii	69.242 (15)	Al32A—Al27—Al15	119.51 (3)
Al28^xi—Ru7—Al28^vii	56.639 (19)	Al13—Al27—Al15	65.91 (2)
Al24—Ru7—Al28^vii	94.190 (14)	Al22^xx—Al27—Al15	140.86 (3)
Al21^x—Ru7—Al22	127.209 (14)	Ru7^xx—Al27—Al15	85.55 (2)
Al11—Ru7—Al22	60.831 (18)	Al25^vii—Al27—Al15	155.08 (3)
Si18^vii—Ru7—Al22	87.294 (15)	Al30B^vii—Al27—Al15	121.91 (13)
Al30Aⁱ—Ru7—Al22	70.12 (7)	Ru6—Al27—Al15	104.73 (2)
Al27^x—Ru7—Al22	57.854 (15)	Si18^viii—Al27—Al15	55.05 (2)
Al30Bⁱ—Ru7—Al22	62.53 (12)	Ru2^ix—Al28—Al28^xiv	165.46 (3)
Al26—Ru7—Al22	105.892 (14)	Ru2^ix—Al28—Si16	57.410 (14)
Al28^xi—Ru7—Al22	154.796 (16)	Al28^xiv—Al28—Si16	109.86 (3)
Al24—Ru7—Al22	57.266 (13)	Ru2^ix—Al28—Si18	57.930 (14)
Al28^vii—Ru7—Al22	145.875 (15)	Al28^xiv—Al28—Si18	114.58 (3)
Si10A—Si8—Al13	134.29 (9)	Si16—Al28—Si18	75.902 (18)
Si10A—Si8—Ru6	112.83 (3)	Ru2^ix—Al28—Ru7^xxii	123.54 (2)
Al13—Si8—Ru6	62.754 (12)	Al28^xiv—Al28—Ru7^xxii	63.76 (2)
Si10A—Si8—Ru6^vii	112.83 (3)	Si16—Al28—Ru7^xxii	104.017 (19)
Al13—Si8—Ru6^vii	62.754 (12)	Si18—Al28—Ru7^xxii	178.26 (2)
Ru6—Si8—Ru6^vii	124.23 (2)	Ru2^ix—Al28—Al14^xiv	59.956 (18)
Si10A—Si8—Al26^vii	113.89 (8)	Al28^xiv—Al28—Al14^xiv	127.43 (3)
Al13—Si8—Al26^vii	104.28 (2)	Si16—Al28—Al14^xiv	77.13 (2)
Ru6—Si8—Al26^vii	120.73 (2)	Si18—Al28—Al14^xiv	117.52 (2)
Ru6^vii—Si8—Al26^vii	63.940 (13)	Ru7^xxii—Al28—Al14^xiv	64.053 (17)
Si10A—Si8—Al26	113.90 (8)	Ru2^ix—Al28—Al21^xvi	107.85 (2)
Al13—Si8—Al26	104.28 (2)	Al28^xiv—Al28—Al21^xvi	65.21 (2)
Ru6—Si8—Al26	63.940 (13)	Si16—Al28—Al21^xvi	57.251 (16)
Ru6^vii—Si8—Al26	120.73 (2)	Si18—Al28—Al21^xvi	125.93 (2)
Al26^vii—Si8—Al26	65.04 (2)	Ru7^xxii—Al28—Al21^xvi	53.162 (13)
Si10A—Si8—Al23^vii	63.42 (7)	Al14^xiv—Al28—Al21^xvi	79.051 (19)
Al13—Si8—Al23^vii	78.61 (2)	Ru2^ix—Al28—Ru7^vii	111.722 (19)
Ru6—Si8—Al23^vii	117.74 (2)	Al28^xiv—Al28—Ru7^vii	59.60 (2)
Ru6^vii—Si8—Al23^vii	60.654 (13)	Si16—Al28—Ru7^vii	94.790 (19)
Al26^vii—Si8—Al23^vii	114.682 (15)	Si18—Al28—Ru7^vii	54.988 (14)
Al26—Si8—Al23^vii	177.11 (3)	Ru7^xxii—Al28—Ru7^vii	123.361 (19)
Si10A—Si8—Al23	63.42 (7)	Al14^xiv—Al28—Ru7^vii	170.62 (2)
Al13—Si8—Al23	78.61 (2)	Al21^xvi—Al28—Ru7^vii	100.73 (2)
Ru6—Si8—Al23	60.653 (13)	Ru2^ix—Al28—Al21^xvii	125.63 (2)
Ru6^vii—Si8—Al23	117.74 (2)	Al28^xiv—Al28—Al21^xvii	59.73 (2)
Al26^vii—Si8—Al23	177.11 (3)	Si16—Al28—Al21^xvii	145.22 (2)
Al26—Si8—Al23	114.681 (15)	Si18—Al28—Al21^xvii	79.480 (18)
Al23^vii—Si8—Al23	65.44 (2)	Ru7^xxii—Al28—Al21^xvii	99.854 (18)
Si10A—Si8—Al11	64.29 (9)	Al14^xiv—Al28—Al21^xvii	136.84 (3)
Al13—Si8—Al11	161.43 (3)	Al21^xvi—Al28—Al21^xvii	124.94 (2)
Ru6—Si8—Al11	113.799 (13)	Ru7^vii—Al28—Al21^xvii	50.654 (12)
Ru6^vii—Si8—Al11	113.799 (13)	Ru5B^vii—Al29A—Ru4Bⁱⁱ	124.8 (3)
Al26^vii—Si8—Al11	60.621 (19)	Ru5B^vii—Al29A—Si17	58.02 (9)
Al26—Si8—Al11	60.621 (19)	Ru4Bⁱⁱ—Al29A—Si17	164.2 (5)
Al23^vii—Si8—Al11	116.60 (2)	Ru5B^vii—Al29A—Al32A^xvii	63.08 (13)
Al23—Si8—Al11	116.60 (2)	Ru4Bⁱⁱ—Al29A—Al32A^xvii	62.9 (3)
Si10A—Si8—Al10B	4.9 (2)	Si17—Al29A—Al32A^xvii	113.93 (14)
Al13—Si8—Al10B	129.4 (3)	Ru5B^vii—Al29A—Al29A^xviii	155.59 (12)
Ru6—Si8—Al10B	111.37 (10)	Ru4Bⁱⁱ—Al29A—Al29A^xviii	59.50 (11)
Ru6^vii—Si8—Al10B	111.37 (10)	Si17—Al29A—Al29A^xviii	110.99 (3)
Al26^vii—Si8—Al10B	117.8 (2)	Al32A^xvii—Al29A—Al29A^xviii	110.11 (4)
Al26—Si8—Al10B	117.8 (2)	Ru5B^vii—Al29A—Ru1^ix	114.81 (10)
Al23^vii—Si8—Al10B	59.6 (2)	Ru4Bⁱⁱ—Al29A—Ru1^ix	118.55 (12)
Al23—Si8—Al10B	59.6 (2)	Si17—Al29A—Ru1^ix	56.86 (6)
Al11—Si8—Al10B	69.2 (3)	Al32A^xvii—Al29A—Ru1^ix	154.35 (16)
Si10A—Si8—Al24^vii	64.91 (3)	Al29A^xviii—Al29A—Ru1^ix	60.23 (4)
Al13—Si8—Al24^vii	118.294 (14)	Ru5B^vii—Al29A—Si18	110.29 (9)
Ru6—Si8—Al24^vii	177.69 (3)	Ru4Bⁱⁱ—Al29A—Si18	64.4 (5)
Ru6^vii—Si8—Al24^vii	57.293 (10)	Si17—Al29A—Si18	130.88 (19)
Al26^vii—Si8—Al24^vii	61.302 (15)	Al32A^xvii—Al29A—Si18	94.94 (7)
Al26—Si8—Al24^vii	117.14 (2)	Al29A^xviii—Al29A—Si18	93.31 (3)
Al23^vii—Si8—Al24^vii	61.091 (15)	Ru1^ix—Al29A—Si18	108.8 (2)
Al23—Si8—Al24^vii	117.26 (2)	Ru5B^vii—Al29A—Ru4Aⁱⁱ	126.87 (19)
Al11—Si8—Al24^vii	65.928 (15)	Ru4Bⁱⁱ—Al29A—Ru4Aⁱⁱ	5.9 (4)
Al10B—Si8—Al24^vii	66.34 (10)	Si17—Al29A—Ru4Aⁱⁱ	169.12 (12)
Si9B—Si9A—Al22^vii	82.44 (11)	Al32A^xvii—Al29A—Ru4Aⁱⁱ	66.40 (11)
Si9B—Si9A—Al22	82.44 (11)	Al29A^xviii—Al29A—Ru4Aⁱⁱ	60.32 (4)
Al22^vii—Si9A—Al22	76.04 (3)	Ru1^ix—Al29A—Ru4Aⁱⁱ	117.76 (8)
Si9B—Si9A—Al12	78.41 (14)	Si18—Al29A—Ru4Aⁱⁱ	58.74 (7)
Al22^vii—Si9A—Al12	137.27 (3)	Ru5B^vii—Al29A—Al29B^xviii	150.30 (15)
Al22—Si9A—Al12	137.26 (3)	Ru4Bⁱⁱ—Al29A—Al29B^xviii	55.6 (2)
Si9B—Si9A—Al25ⁱⁱ	80.16 (5)	Si17—Al29A—Al29B^xviii	113.27 (16)
Al22^vii—Si9A—Al25ⁱⁱ	67.335 (17)	Al32A^xvii—Al29A—Al29B^xviii	102.94 (18)
Al22—Si9A—Al25ⁱⁱ	141.05 (4)	Al29A^xviii—Al29A—Al29B^xviii	7.53 (19)
Al12—Si9A—Al25ⁱⁱ	71.93 (2)	Ru1^ix—Al29A—Al29B^xviii	65.7 (2)
Si9B—Si9A—Al25ⁱ	80.16 (5)	Si18—Al29A—Al29B^xviii	96.40 (12)
Al22^vii—Si9A—Al25ⁱ	141.05 (4)	Ru4Aⁱⁱ—Al29A—Al29B^xviii	57.23 (17)
Al22—Si9A—Al25ⁱ	67.334 (17)	Ru5B^vii—Al29A—Al20	106.68 (14)
Al12—Si9A—Al25ⁱ	71.93 (2)	Ru4Bⁱⁱ—Al29A—Al20	112.8 (5)
Al25ⁱⁱ—Si9A—Al25ⁱ	141.54 (4)	Si17—Al29A—Al20	78.27 (13)
Si9B—Si9A—Al30Bⁱ	146.67 (10)	Al32A^xvii—Al29A—Al20	148.12 (6)
Al22^vii—Si9A—Al30Bⁱ	103.95 (10)	Al29A^xviii—Al29A—Al20	90.59 (3)
Al22—Si9A—Al30Bⁱ	67.98 (7)	Ru1^ix—Al29A—Al20	57.28 (11)
Al12—Si9A—Al30Bⁱ	113.01 (9)	Si18—Al29A—Al20	58.77 (11)
Al25ⁱⁱ—Si9A—Al30Bⁱ	132.77 (9)	Ru4Aⁱⁱ—Al29A—Al20	107.26 (14)
Al25ⁱ—Si9A—Al30Bⁱ	74.62 (10)	Al29B^xviii—Al29A—Al20	98.07 (17)
Si9B—Si9A—Al30Bⁱⁱ	146.67 (10)	Ru5B^vii—Al29A—Ru5A^vii	0.72 (11)
Al22^vii—Si9A—Al30Bⁱⁱ	67.98 (7)	Ru4Bⁱⁱ—Al29A—Ru5A^vii	124.7 (3)
Al22—Si9A—Al30Bⁱⁱ	103.95 (10)	Si17—Al29A—Ru5A^vii	58.34 (4)
Al12—Si9A—Al30Bⁱⁱ	113.01 (9)	Al32A^xvii—Al29A—Ru5A^vii	63.15 (10)
Al25ⁱⁱ—Si9A—Al30Bⁱⁱ	74.62 (10)	Al29A^xviii—Al29A—Ru5A^vii	156.31 (8)
Al25ⁱ—Si9A—Al30Bⁱⁱ	132.77 (9)	Ru1^ix—Al29A—Ru5A^vii	115.09 (6)
Al30Bⁱ—Si9A—Al30Bⁱⁱ	60.00 (18)	Si18—Al29A—Ru5A^vii	109.57 (5)
Si9A—Si9B—Al12	79.39 (14)	Ru4Aⁱⁱ—Al29A—Ru5A^vii	126.69 (16)
Si9A—Si9B—Al22^vii	75.46 (12)	Al29B^xviii—Al29A—Ru5A^vii	150.99 (13)
Al12—Si9B—Al22^vii	134.37 (7)	Al20—Al29A—Ru5A^vii	106.24 (11)
Si9A—Si9B—Al22	75.46 (12)	Al32A^xvii—Al29B—Ru5B^vii	69.7 (3)
Al12—Si9B—Al22	134.37 (7)	Al32A^xvii—Al29B—Ru4Bⁱⁱ	69.5 (4)
Al22^vii—Si9B—Al22	73.94 (6)	Ru5B^vii—Al29B—Ru4Bⁱⁱ	136.4 (6)
Si9A—Si9B—Al25ⁱⁱ	77.95 (7)	Al32A^xvii—Al29B—Ru4Aⁱⁱ	72.7 (3)
Al12—Si9B—Al25ⁱⁱ	71.75 (5)	Ru5B^vii—Al29B—Ru4Aⁱⁱ	137.2 (5)
Al22^vii—Si9B—Al25ⁱⁱ	66.16 (3)	Ru4Bⁱⁱ—Al29B—Ru4Aⁱⁱ	5.9 (4)
Al22—Si9B—Al25ⁱⁱ	136.32 (9)	Al32A^xvii—Al29B—Al31C^xvii	21.2 (4)
Si9A—Si9B—Al25ⁱ	77.95 (7)	Ru5B^vii—Al29B—Al31C^xvii	88.6 (6)
Al12—Si9B—Al25ⁱ	71.75 (5)	Ru4Bⁱⁱ—Al29B—Al31C^xvii	55.2 (6)
Al22^vii—Si9B—Al25ⁱ	136.32 (9)	Ru4Aⁱⁱ—Al29B—Al31C^xvii	59.8 (4)
Al22—Si9B—Al25ⁱ	66.16 (3)	Al32A^xvii—Al29B—Ru5A^vii	69.4 (3)
Al25ⁱⁱ—Si9B—Al25ⁱ	139.17 (10)	Ru5B^vii—Al29B—Ru5A^vii	0.67 (12)
Si8—Si10A—Ru5A^vii	113.04 (8)	Ru4Bⁱⁱ—Al29B—Ru5A^vii	135.9 (5)
Si8—Si10A—Ru5A	113.04 (8)	Ru4Aⁱⁱ—Al29B—Ru5A^vii	136.6 (5)
Ru5A^vii—Si10A—Ru5A	125.3 (3)	Al31C^xvii—Al29B—Ru5A^vii	88.4 (5)
Si8—Si10A—Al31A^vi	163.35 (15)	Al32A^xvii—Al29B—Al29A^xviii	118.8 (3)
Ru5A^vii—Si10A—Al31A^vi	63.66 (12)	Ru5B^vii—Al29B—Al29A^xviii	160.4 (3)
Ru5A—Si10A—Al31A^vi	63.66 (12)	Ru4Bⁱⁱ—Al29B—Al29A^xviii	59.88 (17)
Si8—Si10A—Ru5B	111.39 (12)	Ru4Aⁱⁱ—Al29B—Al29A^xviii	60.44 (13)
Ru5A^vii—Si10A—Ru5B	127.3 (3)	Al31C^xvii—Al29B—Al29A^xviii	97.8 (4)
Ru5A—Si10A—Ru5B	2.00 (11)	Ru5A^vii—Al29B—Al29A^xviii	161.1 (3)
Al31A^vi—Si10A—Ru5B	65.58 (16)	Al32A^xvii—Al29B—Si17	121.8 (3)
Si8—Si10A—Ru5B^vii	111.39 (12)	Ru5B^vii—Al29B—Si17	57.81 (15)
Ru5A^vii—Si10A—Ru5B^vii	2.00 (11)	Ru4Bⁱⁱ—Al29B—Si17	165.4 (4)
Ru5A—Si10A—Ru5B^vii	127.3 (3)	Ru4Aⁱⁱ—Al29B—Si17	164.7 (5)
Al31A^vi—Si10A—Ru5B^vii	65.58 (16)	Al31C^xvii—Al29B—Si17	132.2 (5)
Ru5B—Si10A—Ru5B^vii	129.3 (3)	Ru5A^vii—Al29B—Si17	58.37 (12)
Si8—Si10A—Al22^vii	109.66 (18)	Al29A^xviii—Al29B—Si17	105.5 (3)
Ru5A^vii—Si10A—Al22^vii	61.84 (4)	Al32A^xvii—Al29B—Al29B^xviii	111.79 (14)
Ru5A—Si10A—Al22^vii	124.32 (7)	Ru5B^vii—Al29B—Al29B^xviii	158.92 (15)
Al31A^vi—Si10A—Al22^vii	83.66 (8)	Ru4Bⁱⁱ—Al29B—Al29B^xviii	56.5 (2)
Ru5B—Si10A—Al22^vii	124.72 (10)	Ru4Aⁱⁱ—Al29B—Al29B^xviii	57.86 (17)
Ru5B^vii—Si10A—Al22^vii	61.04 (8)	Al31C^xvii—Al29B—Al29B^xviii	90.7 (4)
Si8—Si10A—Al22	109.66 (18)	Ru5A^vii—Al29B—Al29B^xviii	159.53 (12)
Ru5A^vii—Si10A—Al22	124.32 (7)	Al29A^xviii—Al29B—Al29B^xviii	7.53 (19)
Ru5A—Si10A—Al22	61.84 (4)	Si17—Al29B—Al29B^xviii	108.96 (16)
Al31A^vi—Si10A—Al22	83.66 (8)	Al32A^xvii—Al29B—Al32B^xvii	18.05 (14)
Ru5B—Si10A—Al22	61.04 (8)	Ru5B^vii—Al29B—Al32B^xvii	55.3 (3)
Ru5B^vii—Si10A—Al22	124.72 (10)	Ru4Bⁱⁱ—Al29B—Al32B^xvii	86.7 (5)
Al22^vii—Si10A—Al22	71.31 (5)	Ru4Aⁱⁱ—Al29B—Al32B^xvii	90.3 (4)
Si8—Si10A—Al23^vii	61.62 (5)	Al31C^xvii—Al29B—Al32B^xvii	33.4 (4)
Ru5A^vii—Si10A—Al23^vii	62.95 (5)	Ru5A^vii—Al29B—Al32B^xvii	55.1 (2)
Ru5A—Si10A—Al23^vii	119.35 (13)	Al29A^xviii—Al29B—Al32B^xvii	128.2 (3)
Al31A^vi—Si10A—Al23^vii	104.74 (17)	Si17—Al29B—Al32B^xvii	103.9 (3)
Ru5B—Si10A—Al23^vii	119.82 (14)	Al29B^xviii—Al29B—Al32B^xvii	120.67 (17)
Ru5B^vii—Si10A—Al23^vii	62.35 (9)	Al32A^xvii—Al29B—Si18	98.6 (3)
Al22^vii—Si10A—Al23^vii	111.61 (3)	Ru5B^vii—Al29B—Si18	108.7 (2)
Al22—Si10A—Al23^vii	171.2 (2)	Ru4Bⁱⁱ—Al29B—Si18	63.5 (5)
Si8—Si10A—Al23	61.62 (5)	Ru4Aⁱⁱ—Al29B—Si18	57.63 (13)
Ru5A^vii—Si10A—Al23	119.35 (13)	Al31C^xvii—Al29B—Si18	102.0 (4)
Ru5A—Si10A—Al23	62.95 (5)	Ru5A^vii—Al29B—Si18	108.11 (18)
Al31A^vi—Si10A—Al23	104.74 (17)	Al29A^xviii—Al29B—Si18	88.2 (2)
Ru5B—Si10A—Al23	62.35 (9)	Si17—Al29B—Si18	119.6 (5)
Ru5B^vii—Si10A—Al23	119.82 (14)	Al29B^xviii—Al29B—Si18	92.09 (12)
Al22^vii—Si10A—Al23	171.2 (2)	Al32B^xvii—Al29B—Si18	112.4 (3)
Al22—Si10A—Al23	111.61 (3)	Al32A^xvii—Al29B—Ru1^ix	162.7 (3)
Al23^vii—Si10A—Al23	64.26 (3)	Ru5B^vii—Al29B—Ru1^ix	110.0 (3)
Si8—Si10A—Al11	62.60 (13)	Ru4Bⁱⁱ—Al29B—Ru1^ix	113.5 (4)
Ru5A^vii—Si10A—Al11	113.16 (11)	Ru4Aⁱⁱ—Al29B—Ru1^ix	112.0 (3)
Ru5A—Si10A—Al11	113.16 (11)	Al31C^xvii—Al29B—Ru1^ix	146.8 (4)
Al31A^vi—Si10A—Al11	134.05 (5)	Ru5A^vii—Al29B—Ru1^ix	110.5 (3)
Ru5B—Si10A—Al11	111.49 (14)	Al29A^xviii—Al29B—Ru1^ix	56.21 (15)
Ru5B^vii—Si10A—Al11	111.49 (14)	Si17—Al29B—Ru1^ix	52.7 (2)
Al22^vii—Si10A—Al11	59.88 (9)	Al29B^xviii—Al29B—Ru1^ix	61.96 (12)
Al22—Si10A—Al11	59.88 (9)	Al32B^xvii—Al29B—Ru1^ix	149.2 (2)
Al23^vii—Si10A—Al11	113.80 (16)	Si18—Al29B—Ru1^ix	97.8 (4)
Al23—Si10A—Al11	113.80 (16)	Al30B—Al30A—Al27^vii	106.2 (4)
Al31A^vi—Al10B—Ru5A^vii	71.4 (5)	Al30B—Al30A—Ru1^ix	80.6 (4)
Al31A^vi—Al10B—Ru5A	71.4 (5)	Al27^vii—Al30A—Ru1^ix	168.32 (11)
Ru5A^vii—Al10B—Ru5A	141.5 (11)	Al30B—Al30A—Al20	87.8 (4)
Al31A^vi—Al10B—Ru5B	73.0 (5)	Al27^vii—Al30A—Al20	112.19 (5)
Ru5A^vii—Al10B—Ru5B	143.2 (11)	Ru1^ix—Al30A—Al20	57.91 (2)
Ru5A—Al10B—Ru5B	1.72 (12)	Al30B—Al30A—Ru7^xxi	91.6 (4)
Al31A^vi—Al10B—Ru5B^vii	73.0 (5)	Al27^vii—Al30A—Ru7^xxi	62.59 (3)
Ru5A^vii—Al10B—Ru5B^vii	1.72 (12)	Ru1^ix—Al30A—Ru7^xxi	127.54 (4)
Ru5A—Al10B—Ru5B^vii	143.2 (11)	Al20—Al30A—Ru7^xxi	174.32 (4)
Ru5B—Al10B—Ru5B^vii	144.9 (11)	Al30B—Al30A—Si17	135.5 (5)
Al31A^vi—Al10B—Al31B^v	16.12 (19)	Al27^vii—Al30A—Si17	118.23 (16)
Ru5A^vii—Al10B—Al31B^v	58.7 (4)	Ru1^ix—Al30A—Si17	55.77 (3)
Ru5A—Al10B—Al31B^v	86.1 (7)	Al20—Al30A—Si17	76.97 (5)
Ru5B—Al10B—Al31B^v	87.6 (6)	Ru7^xxi—Al30A—Si17	107.23 (10)
Ru5B^vii—Al10B—Al31B^v	60.2 (4)	Al30B—Al30A—Al21^vii	143.3 (4)
Al31A^vi—Al10B—Al31B^vi	16.12 (19)	Al27^vii—Al30A—Al21^vii	72.38 (8)
Ru5A^vii—Al10B—Al31B^vi	86.1 (7)	Ru1^ix—Al30A—Al21^vii	107.95 (8)
Ru5A—Al10B—Al31B^vi	58.7 (4)	Al20—Al30A—Al21^vii	127.46 (14)
Ru5B—Al10B—Al31B^vi	60.2 (4)	Ru7^xxi—Al30A—Al21^vii	54.39 (5)
Ru5B^vii—Al10B—Al31B^vi	87.6 (6)	Si17—Al30A—Al21^vii	58.36 (8)
Al31B^v—Al10B—Al31B^vi	27.7 (4)	Al30B—Al30A—Al14^ix	73.0 (4)
Al31A^vi—Al10B—Al23^vii	115.5 (7)	Al27^vii—Al30A—Al14^ix	127.62 (4)
Ru5A^vii—Al10B—Al23^vii	64.74 (13)	Ru1^ix—Al30A—Al14^ix	63.04 (4)
Ru5A—Al10B—Al23^vii	125.3 (4)	Al20—Al30A—Al14^ix	120.03 (7)
Ru5B—Al10B—Al23^vii	125.3 (4)	Ru7^xxi—Al30A—Al14^ix	65.06 (3)
Ru5B^vii—Al10B—Al23^vii	64.05 (14)	Si17—Al30A—Al14^ix	79.00 (4)
Al31B^v—Al10B—Al23^vii	112.9 (6)	Al21^vii—Al30A—Al14^ix	79.39 (4)
Al31B^vi—Al10B—Al23^vii	130.1 (8)	Al30B—Al30A—Ru6^vii	114.5 (4)
Al31A^vi—Al10B—Al23	115.5 (7)	Al27^vii—Al30A—Ru6^vii	59.08 (4)
Ru5A^vii—Al10B—Al23	125.3 (4)	Ru1^ix—Al30A—Ru6^vii	109.64 (4)
Ru5A—Al10B—Al23	64.74 (13)	Al20—Al30A—Ru6^vii	54.97 (3)
Ru5B—Al10B—Al23	64.05 (14)	Ru7^xxi—Al30A—Ru6^vii	120.50 (8)
Ru5B^vii—Al10B—Al23	125.3 (4)	Si17—Al30A—Ru6^vii	90.49 (10)
Al31B^v—Al10B—Al23	130.1 (8)	Al21^vii—Al30A—Ru6^vii	96.54 (12)
Al31B^vi—Al10B—Al23	112.9 (6)	Al14^ix—Al30A—Ru6^vii	169.37 (11)
Al23^vii—Al10B—Al23	64.31 (19)	Al30A—Al30B—Ru1^ix	88.0 (5)
Al31A^vi—Al10B—Al22^vii	88.0 (3)	Al30A—Al30B—Al20	81.1 (4)
Ru5A^vii—Al10B—Al22^vii	61.92 (12)	Ru1^ix—Al30B—Al20	57.90 (7)
Ru5A—Al10B—Al22^vii	126.1 (3)	Al30A—Al30B—Al30B^xviii	144.1 (4)
Ru5B—Al10B—Al22^vii	126.1 (3)	Ru1^ix—Al30B—Al30B^xviii	58.35 (17)
Ru5B^vii—Al10B—Al22^vii	61.19 (13)	Al20—Al30B—Al30B^xviii	89.59 (13)
Al31B^v—Al10B—Al22^vii	73.5 (3)	Al30A—Al30B—Si9A^ix	151.0 (5)
Al31B^vi—Al10B—Al22^vii	89.1 (3)	Ru1^ix—Al30B—Si9A^ix	105.2 (2)
Al23^vii—Al10B—Al22^vii	108.6 (3)	Al20—Al30B—Si9A^ix	84.30 (13)
Al23—Al10B—Al22^vii	156.4 (10)	Al30B^xviii—Al30B—Si9A^ix	60.00 (9)
Al31A^vi—Al10B—Al22	88.0 (3)	Al30A—Al30B—Al14^ix	96.5 (5)
Ru5A^vii—Al10B—Al22	126.1 (3)	Ru1^ix—Al30B—Al14^ix	64.97 (8)
Ru5A—Al10B—Al22	61.92 (12)	Al20—Al30B—Al14^ix	122.86 (13)
Ru5B—Al10B—Al22	61.19 (13)	Al30B^xviii—Al30B—Al14^ix	60.05 (14)
Ru5B^vii—Al10B—Al22	126.1 (3)	Si9A^ix—Al30B—Al14^ix	112.4 (2)
Al31B^v—Al10B—Al22	89.1 (3)	Al30A—Al30B—Ru7^xxi	77.7 (4)
Al31B^vi—Al10B—Al22	73.5 (3)	Ru1^ix—Al30B—Ru7^xxi	126.25 (15)
Al23^vii—Al10B—Al22	156.4 (10)	Al20—Al30B—Ru7^xxi	158.1 (3)
Al23—Al10B—Al22	108.6 (3)	Al30B^xviii—Al30B—Ru7^xxi	110.95 (13)
Al22^vii—Al10B—Al22	68.3 (3)	Si9A^ix—Al30B—Ru7^xxi	112.11 (19)
Ru7—Al11—Ru7^vii	134.87 (3)	Al14^ix—Al30B—Ru7^xxi	65.67 (7)
Ru7—Al11—Al26^vii	119.96 (3)	Al30A—Al30B—Al27^vii	63.6 (4)
Ru7^vii—Al11—Al26^vii	62.525 (13)	Ru1^ix—Al30B—Al27^vii	150.0 (3)
Ru7—Al11—Al26	62.525 (14)	Al20—Al30B—Al27^vii	105.66 (16)
Ru7^vii—Al11—Al26	119.96 (3)	Al30B^xviii—Al30B—Al27^vii	151.45 (14)
Al26^vii—Al11—Al26	62.69 (2)	Si9A^ix—Al30B—Al27^vii	96.97 (13)
Ru7—Al11—Al22^vii	130.54 (3)	Al14^ix—Al30B—Al27^vii	124.23 (15)
Ru7^vii—Al11—Al22^vii	66.435 (13)	Ru7^xxi—Al30B—Al27^vii	59.49 (8)
Al26^vii—Al11—Al22^vii	109.406 (16)	Al30A—Al30B—Al22^xxi	118.9 (5)
Al26—Al11—Al22^vii	157.46 (3)	Ru1^ix—Al30B—Al22^xxi	152.7 (3)
Ru7—Al11—Al22	66.435 (13)	Al20—Al30B—Al22^xxi	126.71 (16)
Ru7^vii—Al11—Al22	130.54 (3)	Al30B^xviii—Al30B—Al22^xxi	94.41 (13)
Al26^vii—Al11—Al22	157.46 (3)	Si9A^ix—Al30B—Al22^xxi	53.74 (12)
Al26—Al11—Al22	109.406 (16)	Al14^ix—Al30B—Al22^xxi	104.43 (15)
Al22^vii—Al11—Al22	69.28 (3)	Ru7^xxi—Al30B—Al22^xxi	61.37 (7)
Ru7—Al11—Al14	67.460 (14)	Al27^vii—Al30B—Al22^xxi	57.09 (7)
Ru7^vii—Al11—Al14	67.460 (14)	Al31B^vii—Al31A—Al31B	104.6 (8)
Al26^vii—Al11—Al14	95.15 (2)	Al31B^vii—Al31A—Al31C	111.1 (6)
Al26—Al11—Al14	95.15 (2)	Al31B—Al31A—Al31C	7.5 (6)
Al22^vii—Al11—Al14	106.85 (2)	Al31B^vii—Al31A—Al31C^vii	7.5 (6)
Al22—Al11—Al14	106.85 (2)	Al31B—Al31A—Al31C^vii	111.1 (6)
Ru7—Al11—Si8	108.159 (15)	Al31C—Al31A—Al31C^vii	117.4 (8)
Ru7^vii—Al11—Si8	108.160 (15)	Al31B^vii—Al31A—Al10B^xv	113.3 (4)
Al26^vii—Al11—Si8	57.477 (18)	Al31B—Al31A—Al10B^xv	113.3 (4)
Al26—Al11—Si8	57.478 (18)	Al31C—Al31A—Al10B^xv	112.4 (4)
Al22^vii—Al11—Si8	100.13 (2)	Al31C^vii—Al31A—Al10B^xv	112.4 (4)
Al22—Al11—Si8	100.13 (2)	Al31B^vii—Al31A—Ru4B	63.1 (4)
Al14—Al11—Si8	147.02 (3)	Al31B—Al31A—Ru4B	63.1 (4)
Ru7—Al11—Si10A	111.479 (16)	Al31C—Al31A—Ru4B	65.0 (4)
Ru7^vii—Al11—Si10A	111.479 (16)	Al31C^vii—Al31A—Ru4B	65.0 (4)
Al26^vii—Al11—Si10A	102.01 (5)	Al10B^xv—Al31A—Ru4B	172.6 (4)
Al26—Al11—Si10A	102.01 (5)	Al31B^vii—Al31A—Al32A^vii	8.9 (4)
Al22^vii—Al11—Si10A	57.51 (4)	Al31B—Al31A—Al32A^vii	112.1 (4)
Al22—Al11—Si10A	57.51 (4)	Al31C—Al31A—Al32A^vii	118.2 (4)
Al14—Al11—Si10A	159.87 (6)	Al31C^vii—Al31A—Al32A^vii	1.6 (4)
Si8—Al11—Si10A	53.11 (5)	Al10B^xv—Al31A—Al32A^vii	112.72 (12)
Ru1^iv—Al12—Si9B	105.42 (6)	Ru4B—Al31A—Al32A^vii	64.82 (9)
Ru1^iv—Al12—Si9A	127.62 (3)	Al31B^vii—Al31A—Al32A	112.1 (4)
Si9B—Al12—Si9A	22.19 (6)	Al31B—Al31A—Al32A	8.9 (4)
Ru1^iv—Al12—Ru2	117.87 (3)	Al31C—Al31A—Al32A	1.6 (4)
Si9B—Al12—Ru2	136.71 (7)	Al31C^vii—Al31A—Al32A	118.2 (4)
Si9A—Al12—Ru2	114.52 (3)	Al10B^xv—Al31A—Al32A	112.72 (12)
Ru1^iv—Al12—Si16ⁱⁱ	105.283 (19)	Ru4B—Al31A—Al32A	64.82 (9)
Si9B—Al12—Si16ⁱⁱ	111.35 (3)	Al32A^vii—Al31A—Al32A	119.08 (6)
Si9A—Al12—Si16ⁱⁱ	101.29 (2)	Al31B^vii—Al31A—Si10A^xv	111.3 (4)
Ru2—Al12—Si16ⁱⁱ	58.581 (15)	Al31B—Al31A—Si10A^xv	111.3 (4)
Ru1^iv—Al12—Si16ⁱ	105.283 (19)	Al31C—Al31A—Si10A^xv	110.9 (4)
Si9B—Al12—Si16ⁱ	111.35 (3)	Al31C^vii—Al31A—Si10A^xv	110.9 (4)
Si9A—Al12—Si16ⁱ	101.29 (2)	Al10B^xv—Al31A—Si10A^xv	3.7 (3)
Ru2—Al12—Si16ⁱ	58.581 (15)	Ru4B—Al31A—Si10A^xv	168.9 (3)
Si16ⁱⁱ—Al12—Si16ⁱ	117.10 (3)	Al32A^vii—Al31A—Si10A^xv	111.36 (4)
Ru1^iv—Al12—Si17^xii	56.847 (15)	Al32A—Al31A—Si10A^xv	111.36 (4)
Si9B—Al12—Si17^xii	96.74 (4)	Al31B^vii—Al31A—Si19^vii	97.6 (4)
Si9A—Al12—Si17^xii	108.10 (2)	Al31B—Al31A—Si19^vii	148.1 (4)
Ru2—Al12—Si17^xii	106.339 (18)	Al31C—Al31A—Si19^vii	140.9 (4)
Si16ⁱⁱ—Al12—Si17^xii	56.184 (13)	Al31C^vii—Al31A—Si19^vii	90.2 (4)
Si16ⁱ—Al12—Si17^xii	150.58 (3)	Al10B^xv—Al31A—Si19^vii	77.3 (3)
Ru1^iv—Al12—Si17^xiii	56.847 (15)	Ru4B—Al31A—Si19^vii	109.3 (2)
Si9B—Al12—Si17^xiii	96.74 (4)	Al32A^vii—Al31A—Si19^vii	88.77 (2)
Si9A—Al12—Si17^xiii	108.10 (2)	Al32A—Al31A—Si19^vii	139.39 (4)
Ru2—Al12—Si17^xiii	106.339 (18)	Si10A^xv—Al31A—Si19^vii	80.56 (6)
Si16ⁱⁱ—Al12—Si17^xiii	150.58 (3)	Al31B^vii—Al31A—Si19	148.1 (4)
Si16ⁱ—Al12—Si17^xiii	56.184 (13)	Al31B—Al31A—Si19	97.6 (4)
Si17^xii—Al12—Si17^xiii	113.59 (3)	Al31C—Al31A—Si19	90.2 (4)
Ru1^iv—Al12—Al14^iv	60.71 (2)	Al31C^vii—Al31A—Si19	140.9 (4)
Si9B—Al12—Al14^iv	166.13 (7)	Al10B^xv—Al31A—Si19	77.3 (3)
Si9A—Al12—Al14^iv	171.68 (4)	Ru4B—Al31A—Si19	109.3 (2)
Ru2—Al12—Al14^iv	57.157 (19)	Al32A^vii—Al31A—Si19	139.39 (4)
Si16ⁱⁱ—Al12—Al14^iv	74.706 (18)	Al32A—Al31A—Si19	88.77 (2)
Si16ⁱ—Al12—Al14^iv	74.706 (18)	Si10A^xv—Al31A—Si19	80.55 (6)
Si17^xii—Al12—Al14^iv	75.984 (18)	Si19^vii—Al31A—Si19	53.85 (3)
Si17^xiii—Al12—Al14^iv	75.984 (18)	Al31B^vii—Al31A—Ru5A^xv	155.4 (4)
Ru4B—Al13—Ru4A	6.2 (4)	Al31B—Al31A—Ru5A^xv	66.3 (4)
Ru4B—Al13—Si8	164.9 (5)	Al31C—Al31A—Ru5A^xv	61.9 (4)
Ru4A—Al13—Si8	158.75 (8)	Al31C^vii—Al31A—Ru5A^xv	161.0 (4)
Ru4B—Al13—Si19^vii	109.2 (4)	Al10B^xv—Al31A—Ru5A^xv	56.37 (5)
Ru4A—Al13—Si19^vii	114.51 (6)	Ru4B—Al31A—Ru5A^xv	123.97 (4)
Si8—Al13—Si19^vii	84.06 (2)	Al32A^vii—Al31A—Ru5A^xv	162.40 (5)
Ru4B—Al13—Si19	109.2 (4)	Al32A—Al31A—Ru5A^xv	61.54 (4)
Ru4A—Al13—Si19	114.51 (6)	Si10A^xv—Al31A—Ru5A^xv	56.78 (4)
Si8—Al13—Si19	84.06 (2)	Si19^vii—Al31A—Ru5A^xv	100.90 (5)
Si19^vii—Al13—Si19	55.57 (2)	Si19—Al31A—Ru5A^xv	55.81 (3)
Ru4B—Al13—Ru6^vii	121.61 (3)	Al31A—Al31B—Al31C	165.1 (12)
Ru4A—Al13—Ru6^vii	121.078 (15)	Al31A—Al31B—Al31B^vii	37.7 (4)
Si8—Al13—Ru6^vii	58.794 (12)	Al31C—Al31B—Al31B^vii	154.5 (10)
Si19^vii—Al13—Ru6^vii	57.940 (13)	Al31A—Al31B—Al32A	166.9 (6)
Si19—Al13—Ru6^vii	105.19 (2)	Al31C—Al31B—Al32A	2.0 (9)
Ru4B—Al13—Ru6	121.61 (3)	Al31B^vii—Al31B—Al32A	152.61 (19)
Ru4A—Al13—Ru6	121.078 (15)	Al31A—Al31B—Al31C^vii	47.2 (5)
Si8—Al13—Ru6	58.794 (12)	Al31C—Al31B—Al31C^vii	144.7 (13)
Si19^vii—Al13—Ru6	105.19 (2)	Al31B^vii—Al31B—Al31C^vii	9.9 (4)
Si19—Al13—Ru6	57.941 (13)	Al32A—Al31B—Al31C^vii	142.7 (5)
Ru6^vii—Al13—Ru6	116.50 (2)	Al31A—Al31B—Ru4B	97.9 (5)
Ru4B—Al13—Al27	60.94 (17)	Al31C—Al31B—Ru4B	85.6 (10)
Ru4A—Al13—Al27	59.05 (2)	Al31B^vii—Al31B—Ru4B	73.2 (3)
Si8—Al13—Al27	113.14 (2)	Al32A—Al31B—Ru4B	84.3 (3)
Si19^vii—Al13—Al27	141.60 (3)	Al31C^vii—Al31B—Ru4B	65.2 (4)
Si19—Al13—Al27	90.892 (17)	Al31A—Al31B—Al32B	156.6 (6)
Ru6^vii—Al13—Al27	160.34 (3)	Al31C—Al31B—Al32B	20.9 (9)
Ru6—Al13—Al27	62.650 (11)	Al31B^vii—Al31B—Al32B	158.02 (18)
Ru4B—Al13—Al27^vii	60.94 (17)	Al32A—Al31B—Al32B	21.53 (15)
Ru4A—Al13—Al27^vii	59.05 (2)	Al31C^vii—Al31B—Al32B	151.1 (5)
Si8—Al13—Al27^vii	113.14 (2)	Ru4B—Al31B—Al32B	104.7 (4)
Si19^vii—Al13—Al27^vii	90.892 (16)	Al31A—Al31B—Ru4A	98.4 (5)
Si19—Al13—Al27^vii	141.60 (3)	Al31C—Al31B—Ru4A	84.4 (10)
Ru6^vii—Al13—Al27^vii	62.650 (11)	Al31B^vii—Al31B—Ru4A	74.96 (19)
Ru6—Al13—Al27^vii	160.34 (3)	Al32A—Al31B—Ru4A	83.2 (3)
Al27—Al13—Al27^vii	110.94 (3)	Al31C^vii—Al31B—Ru4A	67.2 (4)
Ru4B—Al13—Al31A	55.7 (5)	Ru4B—Al31B—Ru4A	2.6 (2)
Ru4A—Al13—Al31A	61.84 (7)	Al32B—Al31B—Ru4A	103.9 (3)
Si8—Al13—Al31A	139.41 (4)	Al31A—Al31B—Ru5A^xv	96.4 (4)
Si19^vii—Al13—Al31A	60.45 (3)	Al31C—Al31B—Ru5A^xv	74.8 (10)
Si19—Al13—Al31A	60.45 (3)	Al31B^vii—Al31B—Ru5A^xv	130.0 (2)
Ru6^vii—Al13—Al31A	109.49 (2)	Al32A—Al31B—Ru5A^xv	76.5 (2)
Ru6—Al13—Al31A	109.49 (2)	Al31C^vii—Al31B—Ru5A^xv	139.5 (5)
Al27—Al13—Al31A	88.14 (2)	Ru4B—Al31B—Ru5A^xv	151.4 (4)
Al27^vii—Al13—Al31A	88.14 (2)	Al32B—Al31B—Ru5A^xv	60.6 (2)
Ru4B—Al13—Al31B	47.2 (5)	Ru4A—Al31B—Ru5A^xv	148.9 (3)
Ru4A—Al13—Al31B	53.11 (14)	Al31A—Al31B—Ru5B^xv	98.5 (5)
Si8—Al13—Al31B	146.96 (12)	Al31C—Al31B—Ru5B^xv	72.6 (10)
Si19^vii—Al13—Al31B	75.54 (16)	Al31B^vii—Al31B—Ru5B^xv	132.1 (2)
Si19—Al13—Al31B	62.99 (11)	Al32A—Al31B—Ru5B^xv	74.3 (2)
Ru6^vii—Al13—Al31B	125.08 (16)	Al31C^vii—Al31B—Ru5B^xv	141.5 (5)
Ru6—Al13—Al31B	101.66 (13)	Ru4B—Al31B—Ru5B^xv	150.0 (4)
Al27—Al13—Al31B	72.19 (16)	Al32B—Al31B—Ru5B^xv	58.5 (2)
Al27^vii—Al13—Al31B	93.16 (12)	Ru4A—Al31B—Ru5B^xv	147.5 (3)
Al31A—Al13—Al31B	15.97 (15)	Ru5A^xv—Al31B—Ru5B^xv	2.15 (10)
Ru4B—Al13—Al31B^vii	47.2 (5)	Al31A—Al31B—Al10B^xv	50.6 (4)
Ru4A—Al13—Al31B^vii	53.11 (14)	Al31C—Al31B—Al10B^xv	126.5 (10)
Si8—Al13—Al31B^vii	146.96 (12)	Al31B^vii—Al31B—Al10B^xv	76.16 (19)
Si19^vii—Al13—Al31B^vii	62.99 (11)	Al32A—Al31B—Al10B^xv	127.8 (3)
Si19—Al13—Al31B^vii	75.53 (16)	Al31C^vii—Al31B—Al10B^xv	85.1 (4)
Ru6^vii—Al13—Al31B^vii	101.66 (13)	Ru4B—Al31B—Al10B^xv	147.8 (4)
Ru6—Al13—Al31B^vii	125.08 (16)	Al32B—Al31B—Al10B^xv	107.4 (3)
Al27—Al13—Al31B^vii	93.16 (12)	Ru4A—Al31B—Al10B^xv	148.8 (4)
Al27^vii—Al13—Al31B^vii	72.19 (16)	Ru5A^xv—Al31B—Al10B^xv	54.54 (15)
Al31A—Al13—Al31B^vii	15.97 (15)	Ru5B^xv—Al31B—Al10B^xv	56.55 (17)
Al31B—Al13—Al31B^vii	25.3 (3)	Al31A—Al31B—Si19	66.3 (4)
Al30Bⁱⁱ—Al14—Al30Bⁱ	59.9 (3)	Al31C—Al31B—Si19	98.8 (9)
Al30Bⁱⁱ—Al14—Ru2ⁱⁱⁱ	141.14 (16)	Al31B^vii—Al31B—Si19	101.39 (16)
Al30Bⁱ—Al14—Ru2ⁱⁱⁱ	141.14 (16)	Al32A—Al31B—Si19	100.7 (2)
Al30Bⁱⁱ—Al14—Al11	75.89 (12)	Al31C^vii—Al31B—Si19	109.1 (4)
Al30Bⁱ—Al14—Al11	75.89 (12)	Ru4B—Al31B—Si19	109.4 (3)
Ru2ⁱⁱⁱ—Al14—Al11	132.37 (3)	Al32B—Al31B—Si19	99.9 (2)
Al30Bⁱⁱ—Al14—Al28^xi	162.41 (16)	Ru4A—Al31B—Si19	107.26 (19)
Al30Bⁱ—Al14—Al28^xi	107.05 (13)	Ru5A^xv—Al31B—Si19	55.09 (12)
Ru2ⁱⁱⁱ—Al14—Al28^xi	56.454 (17)	Ru5B^xv—Al31B—Si19	56.06 (14)
Al11—Al14—Al28^xi	89.86 (2)	Al10B^xv—Al31B—Si19	67.3 (3)
Al30Bⁱⁱ—Al14—Al28^xiv	107.05 (13)	Al31B—Al31C—Al32A	176.2 (17)
Al30Bⁱ—Al14—Al28^xiv	162.41 (16)	Al31B—Al31C—Al32B	148.0 (14)
Ru2ⁱⁱⁱ—Al14—Al28^xiv	56.454 (17)	Al32A—Al31C—Al32B	33.2 (5)
Al11—Al14—Al28^xiv	89.86 (2)	Al31B—Al31C—Al31A	7.4 (6)
Al28^xi—Al14—Al28^xiv	82.78 (3)	Al32A—Al31C—Al31A	175.7 (11)
Al30Bⁱⁱ—Al14—Al30Aⁱⁱ	10.48 (9)	Al32B—Al31C—Al31A	148.5 (9)
Al30Bⁱ—Al14—Al30Aⁱⁱ	69.2 (2)	Al31B—Al31C—Al31B^vii	15.6 (6)
Ru2ⁱⁱⁱ—Al14—Al30Aⁱⁱ	130.97 (8)	Al32A—Al31C—Al31B^vii	160.7 (11)
Al11—Al14—Al30Aⁱⁱ	82.35 (6)	Al32B—Al31C—Al31B^vii	153.5 (8)
Al28^xi—Al14—Al30Aⁱⁱ	171.95 (7)	Al31A—Al31C—Al31B^vii	21.6 (2)
Al28^xiv—Al14—Al30Aⁱⁱ	99.12 (7)	Al31B—Al31C—Al32B^xix	138.0 (12)
Al30Bⁱⁱ—Al14—Al30Aⁱ	69.2 (2)	Al32A—Al31C—Al32B^xix	43.3 (6)
Al30Bⁱ—Al14—Al30Aⁱ	10.48 (9)	Al32B—Al31C—Al32B^xix	10.2 (3)
Ru2ⁱⁱⁱ—Al14—Al30Aⁱ	130.97 (8)	Al31A—Al31C—Al32B^xix	138.3 (7)
Al11—Al14—Al30Aⁱ	82.35 (6)	Al31B^vii—Al31C—Al32B^xix	145.3 (7)
Al28^xi—Al14—Al30Aⁱ	99.12 (7)	Al31B—Al31C—Ru4B	73.8 (10)
Al28^xiv—Al14—Al30Aⁱ	171.95 (7)	Al32A—Al31C—Ru4B	103.9 (9)
Al30Aⁱⁱ—Al14—Al30Aⁱ	77.95 (15)	Al32B—Al31C—Ru4B	134.7 (9)
Al30Bⁱⁱ—Al14—Ru1	55.27 (7)	Al31A—Al31C—Ru4B	75.7 (6)
Al30Bⁱ—Al14—Ru1	55.27 (7)	Al31B^vii—Al31C—Ru4B	61.0 (5)
Ru2ⁱⁱⁱ—Al14—Ru1	105.08 (2)	Al32B^xix—Al31C—Ru4B	144.0 (7)
Al11—Al14—Ru1	122.55 (3)	Al31B—Al31C—Ru5A^xv	86.2 (10)
Al28^xi—Al14—Ru1	129.33 (2)	Al32A—Al31C—Ru5A^xv	97.1 (9)
Al28^xiv—Al14—Ru1	129.33 (2)	Al32B—Al31C—Ru5A^xv	71.3 (5)
Al30Aⁱⁱ—Al14—Ru1	54.97 (2)	Al31A—Al31C—Ru5A^xv	81.9 (5)
Al30Aⁱ—Al14—Ru1	54.97 (2)	Al31B^vii—Al31C—Ru5A^xv	101.4 (6)
Al30Bⁱⁱ—Al14—Ru7^vii	57.95 (8)	Al32B^xix—Al31C—Ru5A^xv	63.2 (3)
Al30Bⁱ—Al14—Ru7^vii	104.88 (16)	Ru4B—Al31C—Ru5A^xv	151.1 (7)
Ru2ⁱⁱⁱ—Al14—Ru7^vii	113.742 (17)	Al31B—Al31C—Ru5B^xv	89.1 (10)
Al11—Al14—Ru7^vii	52.088 (11)	Al32A—Al31C—Ru5B^xv	94.1 (9)
Al28^xi—Al14—Ru7^vii	120.55 (3)	Al32B—Al31C—Ru5B^xv	68.6 (5)
Al28^xiv—Al14—Ru7^vii	57.677 (13)	Al31A—Al31C—Ru5B^xv	84.9 (5)
Al30Aⁱⁱ—Al14—Ru7^vii	55.52 (2)	Al31B^vii—Al31C—Ru5B^xv	104.4 (6)
Al30Aⁱ—Al14—Ru7^vii	115.22 (9)	Al32B^xix—Al31C—Ru5B^xv	60.6 (3)
Ru1—Al14—Ru7^vii	110.100 (17)	Ru4B—Al31C—Ru5B^xv	153.2 (6)
Al30Bⁱⁱ—Al14—Ru7	104.88 (16)	Ru5A^xv—Al31C—Ru5B^xv	2.97 (11)
Al30Bⁱ—Al14—Ru7	57.95 (8)	Al31B—Al31C—Ru4A	76.9 (10)
Ru2ⁱⁱⁱ—Al14—Ru7	113.743 (17)	Al32A—Al31C—Ru4A	100.9 (9)
Al11—Al14—Ru7	52.087 (11)	Al32B—Al31C—Ru4A	132.4 (8)
Al28^xi—Al14—Ru7	57.677 (13)	Al31A—Al31C—Ru4A	78.5 (5)
Al28^xiv—Al14—Ru7	120.55 (3)	Al31B^vii—Al31C—Ru4A	64.4 (4)
Al30Aⁱⁱ—Al14—Ru7	115.22 (9)	Al32B^xix—Al31C—Ru4A	142.0 (7)
Al30Aⁱ—Al14—Ru7	55.52 (2)	Ru4B—Al31C—Ru4A	3.9 (3)
Ru1—Al14—Ru7	110.100 (17)	Ru5A^xv—Al31C—Ru4A	151.3 (6)
Ru7^vii—Al14—Ru7	104.15 (2)	Ru5B^xv—Al31C—Ru4A	153.1 (6)
Ru3—Al15—Ru4A	161.17 (5)	Al31B—Al31C—Al29B^viii	114.2 (11)
Ru3—Al15—Si18^viii	133.53 (3)	Al32A—Al31C—Al29B^viii	62.0 (7)
Ru4A—Al15—Si18^viii	60.00 (3)	Al32B—Al31C—Al29B^viii	79.7 (6)
Ru3—Al15—Si18^ix	133.53 (3)	Al31A—Al31C—Al29B^viii	120.6 (7)
Ru4A—Al15—Si18^ix	60.00 (3)	Al31B^vii—Al31C—Al29B^viii	99.0 (6)
Si18^viii—Al15—Si18^ix	66.95 (3)	Al32B^xix—Al31C—Al29B^viii	86.6 (5)
Ru3—Al15—Ru4B	159.3 (2)	Ru4B—Al31C—Al29B^viii	60.3 (4)
Ru4A—Al15—Ru4B	1.90 (19)	Ru5A^xv—Al31C—Al29B^viii	148.5 (6)
Si18^viii—Al15—Ru4B	61.48 (16)	Ru5B^xv—Al31C—Al29B^viii	146.4 (6)
Si18^ix—Al15—Ru4B	61.48 (16)	Ru4A—Al31C—Al29B^viii	60.1 (3)
Ru3—Al15—Al27^vii	114.21 (2)	Al31B—Al31C—Al31C^vii	25.5 (10)
Ru4A—Al15—Al27^vii	57.01 (2)	Al32A—Al31C—Al31C^vii	150.9 (7)
Si18^viii—Al15—Al27^vii	111.82 (3)	Al32B—Al31C—Al31C^vii	152.9 (5)
Si18^ix—Al15—Al27^vii	61.257 (17)	Al31A—Al31C—Al31C^vii	31.3 (4)
Ru4B—Al15—Al27^vii	56.29 (8)	Al31B^vii—Al31C—Al31C^vii	9.9 (4)
Ru3—Al15—Al27	114.21 (2)	Al32B^xix—Al31C—Al31C^vii	147.3 (3)
Ru4A—Al15—Al27	57.01 (2)	Ru4B—Al31C—Al31C^vii	53.3 (5)
Si18^viii—Al15—Al27	61.258 (17)	Ru5A^xv—Al31C—Al31C^vii	111.0 (4)
Si18^ix—Al15—Al27	111.82 (3)	Ru5B^xv—Al31C—Al31C^vii	114.0 (4)
Ru4B—Al15—Al27	56.29 (8)	Ru4A—Al31C—Al31C^vii	56.9 (4)
Al27^vii—Al15—Al27	101.23 (3)	Al29B^viii—Al31C—Al31C^vii	89.3 (4)
Ru3—Al15—Al21	57.760 (15)	Al32B—Al32A—Al31C	112.8 (8)
Ru4A—Al15—Al21	122.019 (17)	Al32B—Al32A—Al32B^xix	2.4 (5)
Si18^viii—Al15—Al21	82.302 (16)	Al31C—Al32A—Al32B^xix	114.9 (8)
Si18^ix—Al15—Al21	142.66 (3)	Al32B—Al32A—Al31B	113.5 (4)
Ru4B—Al15—Al21	121.78 (3)	Al31C—Al32A—Al31B	1.8 (8)
Al27^vii—Al15—Al21	155.18 (4)	Al32B^xix—Al32A—Al31B	115.5 (2)
Al27—Al15—Al21	66.782 (15)	Al32B—Al32A—Al29B^viii	111.2 (3)
Ru3—Al15—Al21^vii	57.759 (15)	Al31C—Al32A—Al29B^viii	96.8 (7)
Ru4A—Al15—Al21^vii	122.019 (17)	Al32B^xix—Al32A—Al29B^viii	111.7 (2)
Si18^viii—Al15—Al21^vii	142.66 (3)	Al31B—Al32A—Al29B^viii	95.1 (2)
Si18^ix—Al15—Al21^vii	82.302 (16)	Al32B—Al32A—Al31A	114.0 (3)
Ru4B—Al15—Al21^vii	121.78 (3)	Al31C—Al32A—Al31A	2.7 (7)
Al27^vii—Al15—Al21^vii	66.782 (15)	Al32B^xix—Al32A—Al31A	115.96 (16)
Al27—Al15—Al21^vii	155.18 (4)	Al31B—Al32A—Al31A	4.16 (18)
Al21—Al15—Al21^vii	114.74 (3)	Al29B^viii—Al32A—Al31A	98.51 (15)
Ru3—Al15—Al13	107.37 (3)	Al32B—Al32A—Al29A^viii	112.6 (3)
Ru4A—Al15—Al13	53.79 (3)	Al31C—Al32A—Al29A^viii	98.7 (7)
Si18^viii—Al15—Al13	104.09 (3)	Al32B^xix—Al32A—Al29A^viii	112.93 (15)
Si18^ix—Al15—Al13	104.09 (3)	Al31B—Al32A—Al29A^viii	96.98 (19)
Ru4B—Al15—Al13	51.9 (2)	Al29B^viii—Al32A—Al29A^viii	3.24 (15)
Al27^vii—Al15—Al13	54.228 (18)	Al31A—Al32A—Al29A^viii	100.31 (5)
Al27—Al15—Al13	54.228 (18)	Al32B—Al32A—Al32A^xix	1.5 (3)
Al21—Al15—Al13	103.53 (2)	Al31C—Al32A—Al32A^xix	114.2 (7)
Al21^vii—Al15—Al13	103.53 (2)	Al32B^xix—Al32A—Al32A^xix	0.82 (16)
Si17^xv—Si16—Ru6^vii	111.935 (18)	Al31B—Al32A—Al32A^xix	114.81 (19)
Si17^xv—Si16—Ru2^ix	112.514 (19)	Al29B^viii—Al32A—Al32A^xix	111.50 (14)
Ru6^vii—Si16—Ru2^ix	124.595 (17)	Al31A—Al32A—Al32A^xix	115.28 (5)
Si17^xv—Si16—Al20	138.74 (2)	Al29A^viii—Al32A—Al32A^xix	112.81 (5)
Ru6^vii—Si16—Al20	62.558 (15)	Al32B—Al32A—Ru5B^xx	62.4 (3)
Ru2^ix—Si16—Al20	62.335 (15)	Al31C—Al32A—Ru5B^xx	143.9 (7)
Si17^xv—Si16—Al12^ix	62.396 (19)	Al32B^xix—Al32A—Ru5B^xx	61.60 (19)
Ru6^vii—Si16—Al12^ix	119.15 (2)	Al31B—Al32A—Ru5B^xx	142.5 (2)
Ru2^ix—Si16—Al12^ix	59.702 (15)	Al29B^viii—Al32A—Ru5B^xx	58.16 (18)
Al20—Si16—Al12^ix	84.14 (2)	Al31A—Al32A—Ru5B^xx	146.61 (11)
Si17^xv—Si16—Al26^vii	111.74 (2)	Al29A^viii—Al32A—Ru5B^xx	57.75 (13)
Ru6^vii—Si16—Al26^vii	64.944 (14)	Al32A^xix—Al32A—Ru5B^xx	61.87 (11)
Ru2^ix—Si16—Al26^vii	123.088 (19)	Al32B—Al32A—Al27	140.0 (3)
Al20—Si16—Al26^vii	102.37 (2)	Al31C—Al32A—Al27	94.7 (7)
Al12^ix—Si16—Al26^vii	173.49 (2)	Al32B^xix—Al32A—Al27	137.76 (16)
Si17^xv—Si16—Al21^xvi	62.572 (17)	Al31B—Al32A—Al27	95.01 (18)
Ru6^vii—Si16—Al21^xvi	114.263 (19)	Al29B^viii—Al32A—Al27	92.69 (15)
Ru2^ix—Si16—Al21^xvi	114.665 (18)	Al31A—Al32A—Al27	92.49 (4)
Al20—Si16—Al21^xvi	158.69 (2)	Al29A^viii—Al32A—Al27	89.91 (6)
Al12^ix—Si16—Al21^xvi	113.27 (2)	Al32A^xix—Al32A—Al27	138.53 (5)
Al26^vii—Si16—Al21^xvi	60.348 (17)	Ru5B^xx—Al32A—Al27	110.71 (8)
Si17^xv—Si16—Al28	110.33 (2)	Al32B—Al32A—Ru4B	160.5 (5)
Ru6^vii—Si16—Al28	128.66 (2)	Al31C—Al32A—Ru4B	56.6 (8)
Ru2^ix—Si16—Al28	58.969 (15)	Al32B^xix—Al32A—Ru4B	162.6 (4)
Al20—Si16—Al28	101.00 (2)	Al31B—Al32A—Ru4B	55.5 (4)
Al12^ix—Si16—Al28	105.54 (2)	Al29B^viii—Al32A—Ru4B	58.5 (2)
Al26^vii—Si16—Al28	73.278 (18)	Al31A—Al32A—Ru4B	56.4 (3)
Al21^xvi—Si16—Al28	63.524 (17)	Al29A^viii—Al32A—Ru4B	58.12 (17)
Si17^xv—Si16—Al25	62.967 (17)	Al32A^xix—Al32A—Ru4B	161.9 (3)
Ru6^vii—Si16—Al25	59.025 (13)	Ru5B^xx—Al32A—Ru4B	114.9 (2)
Ru2^ix—Si16—Al25	118.817 (19)	Al27—Al32A—Ru4B	59.5 (3)
Al20—Si16—Al25	83.338 (19)	Al32B—Al32A—Ru5A^xv	62.3 (3)
Al12^ix—Si16—Al25	68.317 (19)	Al31C—Al32A—Ru5A^xv	63.0 (7)
Al26^vii—Si16—Al25	112.27 (2)	Al32B^xix—Al32A—Ru5A^xv	63.20 (16)
Al21^xvi—Si16—Al25	113.86 (2)	Al31B—Al32A—Ru5A^xv	64.5 (2)
Al28—Si16—Al25	172.26 (2)	Al29B^viii—Al32A—Ru5A^xv	148.96 (17)
Ru1^ix—Si17—Ru5B^vii	122.40 (13)	Al31A—Al32A—Ru5A^xv	62.40 (7)
Ru1^ix—Si17—Si16^vi	111.692 (19)	Al29A^viii—Al32A—Ru5A^xv	152.17 (8)
Ru5B^vii—Si17—Si16^vi	113.65 (11)	Al32A^xix—Al32A—Ru5A^xv	62.89 (6)
Ru1^ix—Si17—Ru5A^vii	125.02 (6)	Ru5B^xx—Al32A—Ru5A^xv	124.72 (10)
Ru5B^vii—Si17—Ru5A^vii	2.76 (11)	Al27—Al32A—Ru5A^xv	111.33 (4)
Si16^vi—Si17—Ru5A^vii	112.18 (4)	Ru4B—Al32A—Ru5A^xv	116.7 (3)
Ru1^ix—Si17—Al29A	62.27 (8)	Al32B^xix—Al32B—Al32A	175.0 (10)
Ru5B^vii—Si17—Al29A	60.21 (15)	Al32B^xix—Al32B—Al31C	150.2 (10)
Si16^vi—Si17—Al29A	140.22 (10)	Al32A—Al32B—Al31C	34.0 (5)
Ru5A^vii—Si17—Al29A	62.89 (9)	Al32B^xix—Al32B—Al32A^xix	2.7 (5)
Ru1^ix—Si17—Al23^vii	125.87 (2)	Al32A—Al32B—Al32A^xix	177.6 (5)
Ru5B^vii—Si17—Al23^vii	66.12 (10)	Al31C—Al32B—Al32A^xix	148.0 (6)
Si16^vi—Si17—Al23^vii	109.97 (2)	Al32B^xix—Al32B—Al31C^xix	19.6 (7)
Ru5A^vii—Si17—Al23^vii	64.14 (5)	Al32A—Al32B—Al31C^xix	156.1 (5)
Al29A—Si17—Al23^vii	102.62 (5)	Al31C—Al32B—Al31C^xix	169.8 (3)
Ru1^ix—Si17—Al12^xii	59.105 (16)	Al32A^xix—Al32B—Al31C^xix	21.8 (4)
Ru5B^vii—Si17—Al12^xii	118.91 (10)	Al32B^xix—Al32B—Al31B	139.3 (8)
Si16^vi—Si17—Al12^xii	61.419 (18)	Al32A—Al32B—Al31B	45.0 (3)
Ru5A^vii—Si17—Al12^xii	120.58 (5)	Al31C—Al32B—Al31B	11.1 (5)
Al29A—Si17—Al12^xii	86.41 (5)	Al32A^xix—Al32B—Al31B	137.0 (3)
Al23^vii—Si17—Al12^xii	170.93 (2)	Al31C^xix—Al32B—Al31B	158.9 (4)
Ru1^ix—Si17—Al21^vii	115.734 (19)	Al32B^xix—Al32B—Ru5B^xv	80.7 (6)
Ru5B^vii—Si17—Al21^vii	116.11 (12)	Al32A—Al32B—Ru5B^xv	101.0 (3)
Si16^vi—Si17—Al21^vii	61.723 (16)	Al31C—Al32B—Ru5B^xv	75.2 (5)
Ru5A^vii—Si17—Al21^vii	113.40 (6)	Al32A^xix—Al32B—Ru5B^xv	79.8 (2)
Al29A—Si17—Al21^vii	158.05 (10)	Al31C^xix—Al32B—Ru5B^xv	96.6 (4)
Al23^vii—Si17—Al21^vii	59.590 (16)	Al31B—Al32B—Ru5B^xv	68.1 (2)
Al12^xii—Si17—Al21^vii	111.82 (2)	Al32B^xix—Al32B—Ru5B^xx	80.2 (6)
Ru1^ix—Si17—Al30A	60.19 (7)	Al32A—Al32B—Ru5B^xx	98.1 (4)
Ru5B^vii—Si17—Al30A	130.58 (10)	Al31C—Al32B—Ru5B^xx	122.9 (5)
Si16^vi—Si17—Al30A	107.71 (3)	Al32A^xix—Al32B—Ru5B^xx	81.0 (2)
Ru5A^vii—Si17—Al30A	130.32 (5)	Al31C^xix—Al32B—Ru5B^xx	64.7 (4)
Al29A—Si17—Al30A	102.02 (13)	Al31B—Al32B—Ru5B^xx	128.6 (3)
Al23^vii—Si17—Al30A	75.34 (7)	Ru5B^xv—Al32B—Ru5B^xx	160.8 (2)
Al12^xii—Si17—Al30A	103.87 (6)	Al32B^xix—Al32B—Ru5A^xv	83.6 (6)
Al21^vii—Si17—Al30A	62.80 (5)	Al32A—Al32B—Ru5A^xv	98.3 (3)
Ru1^ix—Si17—Al29B	67.3 (2)	Al31C—Al32B—Ru5A^xv	71.9 (5)
Ru5B^vii—Si17—Al29B	55.8 (2)	Al32A^xix—Al32B—Ru5A^xv	82.59 (19)
Si16^vi—Si17—Al29B	134.5 (2)	Al31C^xix—Al32B—Ru5A^xv	99.8 (4)
Ru5A^vii—Si17—Al29B	58.5 (2)	Al31B—Al32B—Ru5A^xv	64.6 (2)
Al29A—Si17—Al29B	7.30 (18)	Ru5B^xv—Al32B—Ru5A^xv	3.53 (12)
Al23^vii—Si17—Al29B	104.21 (11)	Ru5B^xx—Al32B—Ru5A^xv	163.6 (3)
Al12^xii—Si17—Al29B	84.64 (11)	Al32B^xix—Al32B—Ru5A^xx	77.5 (6)
Al21^vii—Si17—Al29B	162.70 (15)	Al32A—Al32B—Ru5A^xx	100.6 (3)
Al30A—Si17—Al29B	109.3 (3)	Al31C—Al32B—Ru5A^xx	126.1 (5)
Ru1^ix—Si17—Al25^vi	117.214 (19)	Al32A^xix—Al32B—Ru5A^xx	78.50 (18)
Ru5B^vii—Si17—Al25^vi	59.29 (9)	Al31C^xix—Al32B—Ru5A^xx	61.7 (3)
Si16^vi—Si17—Al25^vi	63.594 (17)	Al31B—Al32B—Ru5A^xx	131.9 (3)
Ru5A^vii—Si17—Al25^vi	59.47 (3)	Ru5B^xv—Al32B—Ru5A^xx	158.1 (2)
Al29A—Si17—Al25^vi	83.82 (13)	Ru5B^xx—Al32B—Ru5A^xx	3.31 (12)
Al23^vii—Si17—Al25^vi	111.48 (2)	Ru5A^xv—Al32B—Ru5A^xx	161.1 (2)
Al12^xii—Si17—Al25^vi	68.218 (19)	Al32B^xix—Al32B—Al29B^viii	130.1 (7)
Al21^vii—Si17—Al25^vi	113.69 (2)	Al32A—Al32B—Al29B^viii	50.8 (3)
Al30A—Si17—Al25^vi	170.09 (4)	Al31C—Al32B—Al29B^viii	66.8 (5)
Al29B—Si17—Al25^vi	76.6 (3)	Al32A^xix—Al32B—Al29B^viii	129.7 (3)
Al24^vii—Si18—Ru4Aⁱⁱ	116.89 (5)	Al31C^xix—Al32B—Al29B^viii	119.7 (4)
Al24^vii—Si18—Ru2^ix	115.631 (19)	Al31B—Al32B—Al29B^viii	72.6 (2)
Ru4Aⁱⁱ—Si18—Ru2^ix	111.39 (3)	Ru5B^xv—Al32B—Al29B^viii	140.5 (3)
Al24^vii—Si18—Ru7^vii	65.391 (15)	Ru5B^xx—Al32B—Al29B^viii	56.3 (2)
Ru4Aⁱⁱ—Si18—Ru7^vii	117.981 (18)	Ru5A^xv—Al32B—Al29B^viii	136.9 (3)
Ru2^ix—Si18—Ru7^vii	122.264 (17)	Ru5A^xx—Al32B—Al29B^viii	59.51 (19)
Al24^vii—Si18—Al20	62.973 (18)	Al32B^xix—Al32B—Al22^xx	99.0 (7)
Ru4Aⁱⁱ—Si18—Al20	111.35 (3)	Al32A—Al32B—Al22^xx	76.1 (3)
Ru2^ix—Si18—Al20	61.341 (15)	Al31C—Al32B—Al22^xx	108.2 (5)
Ru7^vii—Si18—Al20	119.95 (2)	Al32A^xix—Al32B—Al22^xx	101.6 (2)
Al24^vii—Si18—Al29A	64.36 (3)	Al31C^xix—Al32B—Al22^xx	81.1 (4)
Ru4Aⁱⁱ—Si18—Al29A	60.69 (9)	Al31B—Al32B—Al22^xx	118.9 (2)
Ru2^ix—Si18—Al29A	111.40 (10)	Ru5B^xv—Al32B—Al22^xx	120.6 (2)
Ru7^vii—Si18—Al29A	117.65 (6)	Ru5B^xx—Al32B—Al22^xx	62.83 (14)
Al20—Si18—Al29A	61.85 (11)	Ru5A^xv—Al32B—Al22^xx	122.35 (18)
Al24^vii—Si18—Al15ⁱⁱ	153.95 (2)	Ru5A^xx—Al32B—Al22^xx	61.65 (11)
Ru4Aⁱⁱ—Si18—Al15ⁱⁱ	57.69 (5)	Al29B^viii—Al32B—Al22^xx	82.81 (18)

Symmetry codes: (i) −x+1/2, y−1/2, z+1/2; (ii) −x+1/2, −y+1, z+1/2; (iii) x−1/2, y, −z+3/2; (iv) x+1/2, y, −z+3/2; (v) x+1/2, −y+1/2, −z+1/2; (vi) x+1/2, y, −z+1/2; (vii) x, −y+1/2, z; (viii) −x+1/2, y−1/2, z−1/2; (ix) −x+1/2, −y+1, z−1/2; (x) −x+1/2, −y, z+1/2; (xi) −x, y−1/2, −z+1; (xii) −x+1, −y+1, −z+1; (xiii) −x+1, y−1/2, −z+1; (xiv) −x, −y+1, −z+1; (xv) x−1/2, y, −z+1/2; (xvi) x−1/2, −y+1/2, −z+1/2; (xvii) −x+1/2, y+1/2, z+1/2; (xviii) x, −y+3/2, z; (xix) −x, −y, −z; (xx) −x+1/2, −y, z−1/2; (xxi) −x+1/2, y+1/2, z−1/2; (xxii) −x, y+1/2, −z+1.

Trialuminium ruthenium disilicon (IV) top

Crystal data top

~Ru(Al_0.57Si_0.43)₅	D_x = 4.248 Mg m⁻³
M_r = 238.38	Mo Kα radiation, λ = 0.71073 Å
Tetragonal, I4/mcm	Cell parameters from 5393 reflections
a = 6.20079 (8) Å	θ = 4.2–38.2°
c = 9.6937 (2) Å	µ = 5.32 mm⁻¹
V = 372.72 (1) Å³	T = 297 K
Z = 4	Irregular, metallic light silver
F(000) = 440.99	0.05 × 0.03 × 0.02 mm

Data collection top

XtaLAB Synergy R, HyPix diffractometer	295 independent reflections
Radiation source: micro-focus sealed X-ray tube, Mova (Mo) X-ray Source	279 reflections with I > 2σ(I)
Mirror monochromator	R_int = 0.029
Detector resolution: 10.0000 pixels mm^-1	θ_max = 37.9°, θ_min = 4.2°
ω scans	h = −10→10
Absorption correction: gaussian (CrysAlisPro; Matsumoto et al., 2021)	k = −10→10
T_min = 0.833, T_max = 0.906	l = −16→16
8063 measured reflections

Refinement top

Refinement on F²	Primary atom site location: dual
Least-squares matrix: full	w = 1/[σ²(F_o²) + (0.0084P)² + 0.2167P] where P = (F_o² + 2F_c²)/3
R[F² > 2σ(F²)] = 0.009	(Δ/σ)_max < 0.001
wR(F²) = 0.021	Δρ_max = 0.44 e Å⁻³
S = 1.21	Δρ_min = −0.42 e Å⁻³
295 reflections	Extinction correction: SHELXL-2019/3 (Sheldrick, 2015b), Fc^*=kFc[1+0.001xFc²λ³/sin(2θ)]^-1/4
13 parameters	Extinction coefficient: 0.0037 (3)
2 restraints

Special details top

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å²) top

	x	y	z	U_iso*/U_eq	Occ. (<1)
Ru1	0.000000	0.000000	0.250000	0.00545 (5)
Al2	0.000000	0.000000	0.000000	0.01321 (14)
Si3	0.14854 (4)	0.64854 (4)	0.14385 (4)	0.01122 (8)	0.542 (6)
Al3	0.14854 (4)	0.64854 (4)	0.14385 (4)	0.01122 (8)	0.458 (6)

Atomic displacement parameters (Å²) top

	U¹¹	U²²	U³³	U¹²	U¹³	U²³
Ru1	0.00611 (6)	0.00611 (6)	0.00414 (7)	0.000	0.000	0.000
Al2	0.0174 (2)	0.0174 (2)	0.0048 (3)	0.000	0.000	0.000
Si3	0.01030 (10)	0.01030 (10)	0.01304 (15)	0.00364 (11)	0.00111 (8)	0.00111 (8)
Al3	0.01030 (10)	0.01030 (10)	0.01304 (15)	0.00364 (11)	0.00111 (8)	0.00111 (8)

Geometric parameters (Å, º) top

Ru1—Al2ⁱ	2.4234 (1)	Ru1—Si3^ix	2.5800 (2)
Ru1—Al2	2.4234 (1)	Al2—Si3^x	2.7463 (2)
Ru1—Si3ⁱⁱ	2.5800 (2)	Al2—Si3^vii	2.7463 (2)
Ru1—Si3ⁱⁱⁱ	2.5800 (2)	Al2—Si3^xi	2.7463 (2)
Ru1—Si3^iv	2.5800 (2)	Al2—Si3^ix	2.7463 (2)
Ru1—Si3^v	2.5800 (2)	Al2—Si3^xii	2.7463 (2)
Ru1—Si3^vi	2.5800 (2)	Al2—Si3ⁱⁱ	2.7463 (2)
Ru1—Si3^vii	2.5800 (2)	Al2—Si3^xiii	2.7463 (2)
Ru1—Si3^viii	2.5800 (2)	Al2—Si3^iv	2.7463 (2)

Al2ⁱ—Ru1—Al2	180.0	Si3^vii—Al2—Si3^xii	61.029 (13)
Al2ⁱ—Ru1—Si3ⁱⁱ	113.504 (7)	Si3^xi—Al2—Si3^xii	75.060 (6)
Al2—Ru1—Si3ⁱⁱ	66.496 (7)	Si3^ix—Al2—Si3^xii	104.940 (6)
Al2ⁱ—Ru1—Si3ⁱⁱⁱ	66.496 (7)	Ru1^xiv—Al2—Si3ⁱⁱ	120.514 (7)
Al2—Ru1—Si3ⁱⁱⁱ	113.504 (7)	Ru1—Al2—Si3ⁱⁱ	59.486 (7)
Si3ⁱⁱ—Ru1—Si3ⁱⁱⁱ	139.656 (16)	Si3^x—Al2—Si3ⁱⁱ	61.029 (13)
Al2ⁱ—Ru1—Si3^iv	113.504 (7)	Si3^vii—Al2—Si3ⁱⁱ	118.971 (13)
Al2—Ru1—Si3^iv	66.496 (7)	Si3^xi—Al2—Si3ⁱⁱ	104.940 (6)
Si3ⁱⁱ—Ru1—Si3^iv	80.848 (5)	Si3^ix—Al2—Si3ⁱⁱ	75.060 (6)
Si3ⁱⁱⁱ—Ru1—Si3^iv	138.167 (15)	Si3^xii—Al2—Si3ⁱⁱ	180.000 (17)
Al2ⁱ—Ru1—Si3^v	66.496 (7)	Ru1^xiv—Al2—Si3^xiii	59.486 (7)
Al2—Ru1—Si3^v	113.504 (7)	Ru1—Al2—Si3^xiii	120.514 (7)
Si3ⁱⁱ—Ru1—Si3^v	138.167 (15)	Si3^x—Al2—Si3^xiii	75.060 (6)
Si3ⁱⁱⁱ—Ru1—Si3^v	80.848 (5)	Si3^vii—Al2—Si3^xiii	104.940 (6)
Si3^iv—Ru1—Si3^v	63.637 (14)	Si3^xi—Al2—Si3^xiii	118.971 (13)
Al2ⁱ—Ru1—Si3^vi	66.496 (7)	Si3^ix—Al2—Si3^xiii	61.029 (13)
Al2—Ru1—Si3^vi	113.504 (7)	Si3^xii—Al2—Si3^xiii	75.060 (6)
Si3ⁱⁱ—Ru1—Si3^vi	63.637 (14)	Si3ⁱⁱ—Al2—Si3^xiii	104.940 (6)
Si3ⁱⁱⁱ—Ru1—Si3^vi	132.991 (15)	Ru1^xiv—Al2—Si3^iv	120.514 (7)
Si3^iv—Ru1—Si3^vi	64.724 (16)	Ru1—Al2—Si3^iv	59.486 (7)
Si3^v—Ru1—Si3^vi	80.848 (5)	Si3^x—Al2—Si3^iv	104.940 (6)
Al2ⁱ—Ru1—Si3^vii	113.504 (7)	Si3^vii—Al2—Si3^iv	75.060 (6)
Al2—Ru1—Si3^vii	66.496 (7)	Si3^xi—Al2—Si3^iv	61.029 (13)
Si3ⁱⁱ—Ru1—Si3^vii	132.991 (15)	Si3^ix—Al2—Si3^iv	118.971 (13)
Si3ⁱⁱⁱ—Ru1—Si3^vii	63.637 (14)	Si3^xii—Al2—Si3^iv	104.940 (6)
Si3^iv—Ru1—Si3^vii	80.848 (5)	Si3ⁱⁱ—Al2—Si3^iv	75.060 (6)
Si3^v—Ru1—Si3^vii	64.724 (16)	Si3^xiii—Al2—Si3^iv	180.000 (13)
Si3^vi—Ru1—Si3^vii	139.656 (16)	Ru1^xv—Al3—Ru1^v	116.363 (14)
Al2ⁱ—Ru1—Si3^viii	66.496 (7)	Ru1^xv—Al3—Si3^ix	110.173 (8)
Al2—Ru1—Si3^viii	113.504 (7)	Ru1^v—Al3—Si3^ix	110.173 (8)
Si3ⁱⁱ—Ru1—Si3^viii	64.724 (16)	Ru1^xv—Al3—Si3^xvi	58.182 (7)
Si3ⁱⁱⁱ—Ru1—Si3^viii	80.848 (5)	Ru1^v—Al3—Si3^xvi	58.182 (7)
Si3^iv—Ru1—Si3^viii	139.656 (16)	Si3^ix—Al3—Si3^xvi	130.850 (15)
Si3^v—Ru1—Si3^viii	132.991 (15)	Ru1^xv—Al3—Al2^xv	54.019 (3)
Si3^vi—Ru1—Si3^viii	80.848 (5)	Ru1^v—Al3—Al2^xv	140.272 (15)
Si3^vii—Ru1—Si3^viii	138.167 (15)	Si3^ix—Al3—Al2^xv	108.902 (7)
Al2ⁱ—Ru1—Si3^ix	113.504 (7)	Si3^xvi—Al3—Al2^xv	99.916 (13)
Al2—Ru1—Si3^ix	66.496 (7)	Ru1^xv—Al3—Al2^xvii	140.272 (15)
Si3ⁱⁱ—Ru1—Si3^ix	80.848 (5)	Ru1^v—Al3—Al2^xvii	54.019 (3)
Si3ⁱⁱⁱ—Ru1—Si3^ix	64.724 (16)	Si3^ix—Al3—Al2^xvii	108.902 (7)
Si3^iv—Ru1—Si3^ix	132.991 (15)	Si3^xvi—Al3—Al2^xvii	99.916 (13)
Si3^v—Ru1—Si3^ix	139.656 (16)	Al2^xv—Al3—Al2^xvii	105.930 (12)
Si3^vi—Ru1—Si3^ix	138.167 (15)	Ru1^xv—Al3—Si3^xviii	57.638 (8)
Si3^vii—Ru1—Si3^ix	80.848 (5)	Ru1^v—Al3—Si3^xviii	105.441 (17)
Si3^viii—Ru1—Si3^ix	63.637 (14)	Si3^ix—Al3—Si3^xviii	61.861 (8)
Ru1^xiv—Al2—Ru1	180.0	Si3^xvi—Al3—Si3^xviii	75.218 (17)
Ru1^xiv—Al2—Si3^x	59.486 (7)	Al2^xv—Al3—Si3^xviii	98.895 (8)
Ru1—Al2—Si3^x	120.514 (7)	Al2^xvii—Al3—Si3^xviii	155.175 (11)
Ru1^xiv—Al2—Si3^vii	120.514 (7)	Ru1^xv—Al3—Si3ⁱⁱⁱ	105.441 (17)
Ru1—Al2—Si3^vii	59.486 (7)	Ru1^v—Al3—Si3ⁱⁱⁱ	57.638 (8)
Si3^x—Al2—Si3^vii	180.000 (13)	Si3^ix—Al3—Si3ⁱⁱⁱ	61.861 (8)
Ru1^xiv—Al2—Si3^xi	59.486 (7)	Si3^xvi—Al3—Si3ⁱⁱⁱ	75.218 (17)
Ru1—Al2—Si3^xi	120.514 (7)	Al2^xv—Al3—Si3ⁱⁱⁱ	155.175 (11)
Si3^x—Al2—Si3^xi	75.060 (6)	Al2^xvii—Al3—Si3ⁱⁱⁱ	98.895 (8)
Si3^vii—Al2—Si3^xi	104.940 (6)	Si3^xviii—Al3—Si3ⁱⁱⁱ	56.280 (15)
Ru1^xiv—Al2—Si3^ix	120.514 (7)	Ru1^xv—Al3—Si3^xix	113.504 (7)
Ru1—Al2—Si3^ix	59.486 (7)	Ru1^v—Al3—Si3^xix	113.504 (7)
Si3^x—Al2—Si3^ix	104.940 (6)	Si3^ix—Al3—Si3^xix	90.0
Si3^vii—Al2—Si3^ix	75.060 (6)	Si3^xvi—Al3—Si3^xix	139.151 (15)
Si3^xi—Al2—Si3^ix	180.00 (2)	Al2^xv—Al3—Si3^xix	59.485 (7)
Ru1^xiv—Al2—Si3^xii	59.486 (7)	Al2^xvii—Al3—Si3^xix	59.485 (7)
Ru1—Al2—Si3^xii	120.514 (7)	Si3^xviii—Al3—Si3^xix	138.167 (13)
Si3^x—Al2—Si3^xii	118.971 (13)	Si3ⁱⁱⁱ—Al3—Si3^xix	138.167 (13)

Symmetry codes: (i) −x, y, −z+1/2; (ii) y−1, −x, z; (iii) y−1/2, −x+1/2, −z+1/2; (iv) x, y−1, z; (v) −x+1/2, −y+1/2, −z+1/2; (vi) −y+1/2, x−1/2, −z+1/2; (vii) −y+1, x, z; (viii) x−1/2, y−1/2, −z+1/2; (ix) −x, −y+1, z; (x) y−1, −x, −z; (xi) x, y−1, −z; (xii) −y+1, x, −z; (xiii) −x, −y+1, −z; (xiv) −x, −y, −z; (xv) x, y+1, z; (xvi) −x+1/2, −y+3/2, −z+1/2; (xvii) −x+1/2, y+1/2, −z; (xviii) −y+1/2, x+1/2, −z+1/2; (xix) x, y, −z.

Tetraaluminium diruthenium pentasilicon (V) top

Crystal data top

~Ru₂(Al_0.46Si_0.54)₉	D_x = 4.512 Mg m⁻³
M_r = 450.41	Mo Kα radiation, λ = 0.71073 Å
Orthorhombic, Cmcm	Cell parameters from 11544 reflections
a = 8.63058 (14) Å	θ = 2.3–30.7°
b = 8.79888 (15) Å	µ = 5.88 mm⁻¹
c = 17.4620 (3) Å	T = 301 K
V = 1326.05 (4) Å³	Irregular, metallic light silver
Z = 8	0.05 × 0.04 × 0.04 mm
F(000) = 1664.17

Data collection top

XtaLAB Synergy R, HyPix diffractometer	1029 independent reflections
Radiation source: micro-focus sealed X-ray tube, Mova (Mo) X-ray Source	1001 reflections with I > 2σ(I)
Mirror monochromator	R_int = 0.016
Detector resolution: 10.0000 pixels mm^-1	θ_max = 30.8°, θ_min = 2.3°
ω scans	h = −12→11
Absorption correction: gaussian (CrysAlisPro; Matsumoto et al., 2021)	k = −11→11
T_min = 0.826, T_max = 0.868	l = −22→24
17672 measured reflections

Refinement top

Refinement on F²	Primary atom site location: dual
Least-squares matrix: full	w = 1/[σ²(F_o²) + (0.0114P)² + 0.7123P] where P = (F_o² + 2F_c²)/3
R[F² > 2σ(F²)] = 0.011	(Δ/σ)_max = 0.001
wR(F²) = 0.027	Δρ_max = 0.37 e Å⁻³
S = 1.31	Δρ_min = −0.42 e Å⁻³
1029 reflections	Extinction correction: SHELXL-2019/3 (Sheldrick, 2015b), Fc^*=kFc[1+0.001xFc²λ³/sin(2θ)]^-1/4
61 parameters	Extinction coefficient: 0.00053 (3)
2 restraints

Special details top

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å²) top

	x	y	z	U_iso*/U_eq	Occ. (<1)
Ru1	0.25176 (2)	0.12442 (2)	0.11292 (2)	0.00469 (5)
Si2	0.000000	0.50890 (5)	0.16887 (2)	0.00820 (9)
Si3	0.000000	0.28515 (5)	0.56422 (2)	0.00938 (9)
Si4	0.000000	0.10304 (5)	0.04648 (3)	0.01097 (9)
Si5	0.000000	0.23256 (5)	0.17514 (2)	0.0069 (2)	0.65 (4)
Al5	0.000000	0.23256 (5)	0.17514 (2)	0.0069 (2)	0.35 (4)
Al6	0.26445 (6)	0.13651 (5)	0.250000	0.01175 (12)
Si7	0.35637 (4)	0.38251 (3)	0.17041 (2)	0.00739 (13)	0.63 (2)
Al7	0.35637 (4)	0.38251 (3)	0.17041 (2)	0.00739 (13)	0.37 (2)
Al8	0.18469 (5)	0.37313 (3)	0.04292 (2)	0.01109 (9)

Atomic displacement parameters (Å²) top

	U¹¹	U²²	U³³	U¹²	U¹³	U²³
Ru1	0.00473 (7)	0.00517 (7)	0.00417 (7)	0.00013 (3)	−0.00034 (2)	0.00002 (2)
Si2	0.00592 (18)	0.00705 (19)	0.0116 (2)	0.000	0.000	0.00072 (14)
Si3	0.00535 (18)	0.0126 (2)	0.01020 (19)	0.000	0.000	−0.00283 (15)
Si4	0.00543 (19)	0.0197 (2)	0.00778 (19)	0.000	0.000	−0.00166 (15)
Si5	0.0065 (3)	0.0070 (3)	0.0073 (3)	0.000	0.000	−0.00015 (14)
Al5	0.0065 (3)	0.0070 (3)	0.0073 (3)	0.000	0.000	−0.00015 (14)
Al6	0.0146 (3)	0.0162 (3)	0.0045 (2)	0.00041 (17)	0.000	0.000
Si7	0.0068 (2)	0.00576 (18)	0.00963 (19)	0.00060 (10)	−0.00059 (11)	0.00062 (9)
Al7	0.0068 (2)	0.00576 (18)	0.00963 (19)	0.00060 (10)	−0.00059 (11)	0.00062 (9)
Al8	0.0175 (2)	0.00624 (17)	0.00951 (17)	0.00015 (11)	−0.00498 (14)	0.00012 (10)

Geometric parameters (Å, º) top

Ru1—Al6	2.3986 (1)	Si3—Si7^x	2.6742 (5)
Ru1—Si3ⁱ	2.4385 (2)	Si3—Si7^xi	2.6742 (5)
Ru1—Si4	2.4703 (2)	Si4—Si4^xii	2.4337 (9)
Ru1—Si7ⁱⁱ	2.5317 (3)	Si4—Si5	2.5192 (6)
Ru1—Si2ⁱⁱⁱ	2.5647 (2)	Si4—Al8^xiii	2.8622 (5)
Ru1—Al8	2.5727 (3)	Si4—Al8	2.8622 (5)
Ru1—Al8ⁱⁱ	2.5853 (3)	Si5—Si5^viii	2.6144 (8)
Ru1—Si5	2.6091 (2)	Si5—Al6^ix	2.7626 (5)
Ru1—Si7	2.6420 (3)	Si5—Al6	2.7626 (5)
Ru1—Al8^iv	2.7759 (4)	Al6—Si7^viii	2.6918 (5)
Si2—Si5	2.4339 (6)	Al6—Si7	2.6918 (5)
Si2—Si3^v	2.5736 (6)	Al6—Si7ⁱⁱ	2.8309 (5)
Si2—Al6^vi	2.7204 (5)	Al6—Si7^xiv	2.8309 (5)
Si2—Al6^vii	2.7204 (5)	Si7—Si7^xv	2.4792 (7)
Si2—Si2^viii	2.8334 (8)	Si7—Al8	2.6755 (5)
Si3—Si4^viii	2.5108 (6)	Si7—Si7^viii	2.7796 (6)
Si3—Al8^ix	2.5768 (5)	Al8—Al8^xvi	2.6890 (6)
Si3—Al8^viii	2.5768 (5)	Al8—Al8^iv	2.8658 (7)

Al6—Ru1—Si3ⁱ	107.063 (16)	Si4—Si5—Ru1^xiii	57.561 (8)
Al6—Ru1—Si4	120.811 (16)	Ru1—Si5—Ru1^xiii	112.774 (15)
Si3ⁱ—Ru1—Si4	129.335 (13)	Si2—Si5—Si5^viii	92.579 (13)
Al6—Ru1—Si7ⁱⁱ	70.025 (14)	Si4—Si5—Si5^viii	153.104 (14)
Si3ⁱ—Ru1—Si7ⁱⁱ	137.435 (12)	Ru1—Si5—Si5^viii	114.611 (8)
Si4—Ru1—Si7ⁱⁱ	78.346 (13)	Ru1^xiii—Si5—Si5^viii	114.612 (8)
Al6—Ru1—Si2ⁱⁱⁱ	66.376 (15)	Si2—Si5—Al6^ix	109.080 (15)
Si3ⁱ—Ru1—Si2ⁱⁱⁱ	61.852 (12)	Si4—Si5—Al6^ix	106.475 (13)
Si4—Ru1—Si2ⁱⁱⁱ	152.066 (14)	Ru1—Si5—Al6^ix	140.67 (2)
Si7ⁱⁱ—Ru1—Si2ⁱⁱⁱ	79.843 (11)	Ru1^xiii—Si5—Al6^ix	52.949 (6)
Al6—Ru1—Al8	116.532 (14)	Si5^viii—Si5—Al6^ix	61.760 (9)
Si3ⁱ—Ru1—Al8	75.784 (12)	Si2—Si5—Al6	109.080 (15)
Si4—Ru1—Al8	69.127 (14)	Si4—Si5—Al6	106.475 (13)
Si7ⁱⁱ—Ru1—Al8	145.151 (12)	Ru1—Si5—Al6	52.948 (6)
Si2ⁱⁱⁱ—Ru1—Al8	134.919 (12)	Ru1^xiii—Si5—Al6	140.67 (2)
Al6—Ru1—Al8ⁱⁱ	120.008 (14)	Si5^viii—Si5—Al6	61.760 (9)
Si3ⁱ—Ru1—Al8ⁱⁱ	85.859 (13)	Al6^ix—Si5—Al6	111.41 (2)
Si4—Ru1—Al8ⁱⁱ	84.229 (14)	Ru1—Al6—Ru1^viii	172.70 (3)
Si7ⁱⁱ—Ru1—Al8ⁱⁱ	63.042 (11)	Ru1—Al6—Si7^viii	124.360 (19)
Si2ⁱⁱⁱ—Ru1—Al8ⁱⁱ	70.363 (13)	Ru1^viii—Al6—Si7^viii	62.218 (9)
Al8—Ru1—Al8ⁱⁱ	123.409 (15)	Ru1—Al6—Si7	62.216 (9)
Al6—Ru1—Si5	66.810 (15)	Ru1^viii—Al6—Si7	124.362 (19)
Si3ⁱ—Ru1—Si5	139.280 (14)	Si7^viii—Al6—Si7	62.170 (17)
Si4—Ru1—Si5	59.392 (12)	Ru1—Al6—Si2^xix	122.379 (19)
Si7ⁱⁱ—Ru1—Si5	80.473 (12)	Ru1^viii—Al6—Si2^xix	59.741 (10)
Si2ⁱⁱⁱ—Ru1—Si5	132.966 (13)	Si7^viii—Al6—Si2^xix	80.955 (15)
Al8—Ru1—Si5	72.557 (13)	Si7—Al6—Si2^xix	112.37 (2)
Al8ⁱⁱ—Ru1—Si5	133.275 (12)	Ru1—Al6—Si2ⁱⁱⁱ	59.741 (10)
Al6—Ru1—Si7	64.344 (14)	Ru1^viii—Al6—Si2ⁱⁱⁱ	122.378 (19)
Si3ⁱ—Ru1—Si7	63.371 (12)	Si7^viii—Al6—Si2ⁱⁱⁱ	112.37 (2)
Si4—Ru1—Si7	122.988 (13)	Si7—Al6—Si2ⁱⁱⁱ	80.955 (15)
Si7ⁱⁱ—Ru1—Si7	134.263 (14)	Si2^xix—Al6—Si2ⁱⁱⁱ	62.768 (19)
Si2ⁱⁱⁱ—Ru1—Si7	84.862 (11)	Ru1—Al6—Si5	60.241 (11)
Al8—Ru1—Si7	61.722 (10)	Ru1^viii—Al6—Si5	116.619 (19)
Al8ⁱⁱ—Ru1—Si7	147.382 (11)	Si7^viii—Al6—Si5	103.993 (19)
Si5—Ru1—Si7	79.214 (11)	Si7—Al6—Si5	75.712 (14)
Al6—Ru1—Al8^iv	165.673 (16)	Si2^xix—Al6—Si5	171.91 (2)
Si3ⁱ—Ru1—Al8^iv	58.803 (12)	Si2ⁱⁱⁱ—Al6—Si5	119.817 (12)
Si4—Ru1—Al8^iv	73.383 (12)	Ru1—Al6—Si5^viii	116.620 (19)
Si7ⁱⁱ—Ru1—Al8^iv	117.911 (10)	Ru1^viii—Al6—Si5^viii	60.241 (11)
Si2ⁱⁱⁱ—Ru1—Al8^iv	102.208 (12)	Si7^viii—Al6—Si5^viii	75.712 (14)
Al8—Ru1—Al8^iv	64.665 (12)	Si7—Al6—Si5^viii	103.993 (19)
Al8ⁱⁱ—Ru1—Al8^iv	60.083 (11)	Si2^xix—Al6—Si5^viii	119.817 (12)
Si5—Ru1—Al8^iv	124.747 (12)	Si2ⁱⁱⁱ—Al6—Si5^viii	171.91 (2)
Si7—Ru1—Al8^iv	107.354 (10)	Si5—Al6—Si5^viii	56.480 (18)
Si5—Si2—Ru1^xvii	114.396 (11)	Ru1—Al6—Si7ⁱⁱ	57.194 (10)
Si5—Si2—Ru1^vii	114.396 (11)	Ru1^viii—Al6—Si7ⁱⁱ	115.982 (18)
Ru1^xvii—Si2—Ru1^vii	113.304 (16)	Si7^viii—Al6—Si7ⁱⁱ	175.46 (2)
Si5—Si2—Si3^v	137.34 (2)	Si7—Al6—Si7ⁱⁱ	119.334 (12)
Ru1^xvii—Si2—Si3^v	56.663 (8)	Si2^xix—Al6—Si7ⁱⁱ	101.833 (18)
Ru1^vii—Si2—Si3^v	56.663 (8)	Si2ⁱⁱⁱ—Al6—Si7ⁱⁱ	72.165 (13)
Si5—Si2—Al6^vi	112.887 (16)	Si5—Al6—Si7ⁱⁱ	72.836 (15)
Ru1^xvii—Si2—Al6^vi	53.884 (7)	Si5^viii—Al6—Si7ⁱⁱ	99.76 (2)
Ru1^vii—Si2—Al6^vi	131.23 (2)	Ru1—Al6—Si7^xiv	115.982 (18)
Si3^v—Si2—Al6^vi	94.539 (15)	Ru1^viii—Al6—Si7^xiv	57.194 (10)
Si5—Si2—Al6^vii	112.887 (16)	Si7^viii—Al6—Si7^xiv	119.335 (12)
Ru1^xvii—Si2—Al6^vii	131.23 (2)	Si7—Al6—Si7^xiv	175.46 (2)
Ru1^vii—Si2—Al6^vii	53.884 (7)	Si2^xix—Al6—Si7^xiv	72.165 (13)
Si3^v—Si2—Al6^vii	94.539 (15)	Si2ⁱⁱⁱ—Al6—Si7^xiv	101.833 (18)
Al6^vi—Si2—Al6^vii	96.71 (2)	Si5—Al6—Si7^xiv	99.76 (2)
Si5—Si2—Si2^viii	87.421 (13)	Si5^viii—Al6—Si7^xiv	72.836 (15)
Ru1^xvii—Si2—Si2^viii	112.394 (9)	Si7ⁱⁱ—Al6—Si7^xiv	58.805 (16)
Ru1^vii—Si2—Si2^viii	112.394 (9)	Si7^xv—Si7—Ru1^xvii	111.632 (8)
Si3^v—Si2—Si2^viii	135.240 (14)	Si7^xv—Si7—Ru1	109.982 (7)
Al6^vi—Si2—Si2^viii	58.617 (10)	Ru1^xvii—Si7—Ru1	116.489 (12)
Al6^vii—Si2—Si2^viii	58.617 (10)	Si7^xv—Si7—Si3ⁱ	62.385 (8)
Ru1^x—Si3—Ru1^xi	122.944 (17)	Ru1^xvii—Si7—Si3ⁱ	111.082 (14)
Ru1^x—Si3—Si4^viii	118.472 (9)	Ru1—Si7—Si3ⁱ	54.602 (9)
Ru1^xi—Si3—Si4^viii	118.472 (9)	Si7^xv—Si7—Al8	123.630 (11)
Ru1^x—Si3—Si2^xviii	61.485 (9)	Ru1^xvii—Si7—Al8	59.457 (9)
Ru1^xi—Si3—Si2^xviii	61.485 (9)	Ru1—Si7—Al8	57.864 (9)
Si4^viii—Si3—Si2^xviii	174.90 (2)	Si3ⁱ—Si7—Al8	70.290 (12)
Ru1^x—Si3—Al8^ix	134.314 (19)	Si7^xv—Si7—Al6	107.139 (13)
Ru1^xi—Si3—Al8^ix	67.148 (10)	Ru1^xvii—Si7—Al6	140.547 (17)
Si4^viii—Si3—Al8^ix	68.456 (15)	Ru1—Si7—Al6	53.439 (8)
Si2^xviii—Si3—Al8^ix	107.696 (16)	Si3ⁱ—Si7—Al6	92.927 (14)
Ru1^x—Si3—Al8^viii	67.148 (10)	Al8—Si7—Al6	103.982 (14)
Ru1^xi—Si3—Al8^viii	134.314 (19)	Si7^xv—Si7—Si7^viii	89.999 (1)
Si4^viii—Si3—Al8^viii	68.456 (15)	Ru1^xvii—Si7—Si7^viii	113.363 (7)
Si2^xviii—Si3—Al8^viii	107.696 (17)	Ru1—Si7—Si7^viii	112.333 (7)
Al8^ix—Si3—Al8^viii	76.42 (2)	Si3ⁱ—Si7—Si7^viii	133.900 (10)
Ru1^x—Si3—Si7^x	62.028 (9)	Al8—Si7—Si7^viii	146.312 (11)
Ru1^xi—Si3—Si7^x	110.212 (16)	Al6—Si7—Si7^viii	58.914 (9)
Si4^viii—Si3—Si7^x	100.475 (18)	Si7^xv—Si7—Al6^vi	111.613 (13)
Si2^xviii—Si3—Si7^x	84.035 (16)	Ru1^xvii—Si7—Al6^vi	52.782 (8)
Al8^ix—Si3—Si7^x	162.921 (18)	Ru1—Si7—Al6^vi	137.671 (17)
Al8^viii—Si3—Si7^x	112.484 (11)	Si3ⁱ—Si7—Al6^vi	161.207 (16)
Ru1^x—Si3—Si7^xi	110.212 (16)	Al8—Si7—Al6^vi	103.230 (14)
Ru1^xi—Si3—Si7^xi	62.028 (9)	Al6—Si7—Al6^vi	105.829 (11)
Si4^viii—Si3—Si7^xi	100.475 (18)	Si7^viii—Si7—Al6^vi	60.597 (8)
Si2^xviii—Si3—Si7^xi	84.035 (16)	Ru1—Al8—Si3^viii	103.213 (14)
Al8^ix—Si3—Si7^xi	112.484 (11)	Ru1—Al8—Ru1^xvii	117.073 (14)
Al8^viii—Si3—Si7^xi	162.921 (18)	Si3^viii—Al8—Ru1^xvii	137.009 (16)
Si7^x—Si3—Si7^xi	55.233 (16)	Ru1—Al8—Si7	60.413 (10)
Si4^xii—Si4—Ru1^xiii	111.712 (13)	Si3^viii—Al8—Si7	162.927 (17)
Si4^xii—Si4—Ru1	111.713 (13)	Ru1^xvii—Al8—Si7	57.501 (9)
Ru1^xiii—Si4—Ru1	123.183 (18)	Ru1—Al8—Al8^xvi	166.190 (12)
Si4^xii—Si4—Si3^viii	87.82 (2)	Si3^viii—Al8—Al8^xvi	81.071 (16)
Ru1^xiii—Si4—Si3^viii	108.238 (13)	Ru1^xvii—Al8—Al8^xvi	63.478 (11)
Ru1—Si4—Si3^viii	108.238 (13)	Si7—Al8—Al8^xvi	115.988 (15)
Si4^xii—Si4—Si5	158.73 (3)	Ru1—Al8—Ru1^iv	115.335 (12)
Ru1^xiii—Si4—Si5	63.047 (10)	Si3^viii—Al8—Ru1^iv	54.048 (10)
Ru1—Si4—Si5	63.046 (10)	Ru1^xvii—Al8—Ru1^iv	114.514 (12)
Si3^viii—Si4—Si5	113.45 (2)	Si7—Al8—Ru1^iv	134.909 (17)
Si4^xii—Si4—Al8^xiii	127.17 (2)	Al8^xvi—Al8—Ru1^iv	56.439 (12)
Ru1^xiii—Si4—Al8^xiii	57.123 (9)	Ru1—Al8—Si4	53.750 (9)
Ru1—Si4—Al8^xiii	115.901 (18)	Si3^viii—Al8—Si4	54.678 (14)
Si3^viii—Si4—Al8^xiii	56.864 (14)	Ru1^xvii—Al8—Si4	144.883 (17)
Si5—Si4—Al8^xiii	69.132 (14)	Si7—Al8—Si4	108.417 (15)
Si4^xii—Si4—Al8	127.17 (2)	Al8^xvi—Al8—Si4	134.546 (16)
Ru1^xiii—Si4—Al8	115.902 (18)	Ru1^iv—Al8—Si4	97.920 (13)
Ru1—Si4—Al8	57.123 (9)	Ru1—Al8—Al8^iv	61.104 (11)
Si3^viii—Si4—Al8	56.864 (14)	Si3^viii—Al8—Al8^iv	68.684 (15)
Si5—Si4—Al8	69.132 (14)	Ru1^xvii—Al8—Al8^iv	144.14 (2)
Al8^xiii—Si4—Al8	67.682 (18)	Si7—Al8—Al8^iv	103.923 (19)
Si2—Si5—Si4	114.32 (2)	Al8^xvi—Al8—Al8^iv	109.65 (2)
Si2—Si5—Ru1	110.218 (11)	Ru1^iv—Al8—Al8^iv	54.231 (12)
Si4—Si5—Ru1	57.562 (8)	Si4—Al8—Al8^iv	66.587 (13)
Si2—Si5—Ru1^xiii	110.218 (11)

Symmetry codes: (i) −x+1/2, −y+1/2, z−1/2; (ii) −x+1/2, y−1/2, z; (iii) x+1/2, y−1/2, z; (iv) −x+1/2, −y+1/2, −z; (v) −x, −y+1, z−1/2; (vi) −x+1/2, y+1/2, −z+1/2; (vii) x−1/2, y+1/2, z; (viii) x, y, −z+1/2; (ix) −x, y, −z+1/2; (x) −x+1/2, −y+1/2, z+1/2; (xi) x−1/2, −y+1/2, z+1/2; (xii) −x, −y, −z; (xiii) −x, y, z; (xiv) −x+1/2, y−1/2, −z+1/2; (xv) −x+1, y, z; (xvi) x, −y+1, −z; (xvii) −x+1/2, y+1/2, z; (xviii) −x, −y+1, z+1/2; (xix) x+1/2, y−1/2, −z+1/2.

Acknowledgements

Polycrystalline samples from which single crystals were obtained were prepared with the help of Ms Itaya and Ms Nakamura at The University of Tokyo.

Funding information

Funding for this research was provided by: JSPS KAKENHI (grant No. JP19H05818, JP19H05819 and JP19K15274).

References

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Volume 79| Part 10| October 2023| Pages 946-951

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