Investigation of nitro–nitrito photoisomerization: crystal structures of trans-bis­(acetyl­acetonato-O,O′)(pyridine/4-methyl­pyridine/3-hy­droxy­pridine)nitro­cobalt(III)

Ohba, S.; Tsuchimoto, M.; Miyazaki, H.

doi:10.1107/S2056989018014731

Acta Crystallographica Section E
Acta Crystallographica
Section E CRYSTALLOGRAPHIC COMMUNICATIONS

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Figure 10
The steric circumstance of the nitro group in (III)

. Only parts of the complex are shown for clarity. The C—H⋯O hydrogen bonds are shown as blue dashed lines, O4⋯H10C^vii = 2.53 Å. The green dashed lines indicate the other O⋯H contacts, O4⋯H19^vi = 2.71 Å. Symmetry codes: (i) x, −y + $[{3\over 2}]$ , z; (ii) x, −y + $[{3\over 2}]$ , z + 1; (iii) x + $[{1\over 2}]$ , −y + $[{3\over 2}]$ , −z + $[{3\over 2}]$ ; (iv) x + $[{1\over 2}]$ , y, −z + $[{1\over 2}]$ ; (v) x + $[{1\over 2}]$ , −y + $[{3\over 2}]$ , −z + $[{1\over 2}]$ ; (vi) x − $[{1\over 2}]$ , −y + $[{3\over 2}]$ , −z + $[{1\over 2}]$ ; (vii) x − $[{1\over 2}]$ , y, $[{1\over 2}]$ − z.

CRYSTALLOGRAPHIC
COMMUNICATIONS

ISSN: 2056-9890

Volume 74| Part 11| November 2018| Pages 1637-1642

https://doi.org/10.1107/S2056989018014731

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