Investigation of solid-state photochemical nitro–nitrito linkage isomerization: crystal structures of trans-bis­(ethyl­enedi­amine)(iso­thio­cyanato)­nitritocobalt(III) salts: thio­cyanate, chloride monohydrate, and perchlorate–thio­cyanate­(0.75/0.25)

Ohba, S.; Tsuchimoto, M.; Kurachi, S.

doi:10.1107/S2056989018013634

Acta Crystallographica Section E
Acta Crystallographica
Section E CRYSTALLOGRAPHIC COMMUNICATIONS

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Figure 11
Comparison of the short contact pair of the nitro group in (I)

and (II)

. Dashed lines in blue show the O(nitro)⋯H short contacts shorter than 2.5 Å. Only parts of the diamine ligands are shown for clarity. Symmetry codes for (I)

: (ii) −x + $[{1\over 2}]$ , y − $[{1\over 2}]$ , −z + $[{1\over 2}]$ ; (v) −x + $[{1\over 2}]$ , −y + $[{1\over 2}]$ , −z; (ix) x, −y, z − $[{1\over 2}]$ . For (II)

: (ii) −x + 1, −y + 1, −z + 1, (v) x − $[{1\over 2}]$ , −y + $[{3\over 2}]$ , z + $[{1\over 2}]$ ; (vii) −x + $[{1\over 2}]$ , y + $[{1\over 2}]$ , −z + $[{3\over 2}]$ .

CRYSTALLOGRAPHIC
COMMUNICATIONS

ISSN: 2056-9890

Volume 74| Part 10| October 2018| Pages 1526-1531

https://doi.org/10.1107/S2056989018013634

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